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1. 发明申请

WO2010070612A2 PROCESS FOR THE DESTRUCTION OF TOXIC RESIDUES VIA OXIDATION IN PRESENCE OF WATER AND OXYGEN AND CONTINUOUS MOBILE UNIT TO TREAT HAZARDOUS COMPOUNDS 审中-公开
公开(公告)号：WO2010070612A2
公开(公告)日：2010-06-24
申请号：PCT/IB2009055831
申请日：2009-12-17
申请人： UNIV DEL VALLE , BOLANOS BARRERA GUSTAVO EDUARDO , MARULANDA CARDONA VICTOR FERNANDO
发明人： BOLANOS BARRERA GUSTAVO EDUARDO , MARULANDA CARDONA VICTOR FERNANDO
IPC分类号： A62D3/38
CPC分类号： A62D3/20 , A62D3/38 , A62D2101/22 , A62D2101/26 , A62D2203/04
摘要： Process for the destruction of toxic residues via oxidation in the presence of water and oxygen developed in homogenous phase at temperatures over 374°C and pressure of at least 220 atmospheres and a continuous mobile unit easily transferred to treat effluents or contaminated media. This mobile unit is composed of a reactor, which includes pressurization, reaction, cooling, depressurization and sampling zones for the destruction of toxic residues like polychloride biphenyls (PCBs), pyridines, and other hazardous compounds.

2. 发明申请

WO2009123755A1 CATALYTIC WET OXIDATION SYSTEMS AND METHODS 审中-公开
标题翻译：催化湿氧化系统和方法
公开(公告)号：WO2009123755A1
公开(公告)日：2009-10-08
申请号：PCT/US2009/002105
申请日：2009-04-03
申请人： SIEMENS WATER TECHNOLOGIES CORP. , MAUGANS, Clayton, B. , KUMFER, Bryan, J. , FELCH, Chad, L. , COPA, William, M.
发明人： MAUGANS, Clayton, B. , KUMFER, Bryan, J. , FELCH, Chad, L. , COPA, William, M.
IPC分类号： C02F3/00 , C07C51/00
CPC分类号： C02F1/725 , A62D3/20 , A62D2203/10 , B01J21/18 , B01J23/10 , B01J23/34 , B01J23/42 , B01J35/0013 , C02F1/02 , C02F1/727 , C02F1/74 , C02F11/08 , C02F2209/008 , C02F2301/066 , C02F2301/08 , C02F2303/04
摘要： A system and method for the treating at least one undesirable constituent in an aqueous mixture utilizing a particulate solids catalyst. The aqueous mixture and the particulate solids catalyst form a slurry which is wet oxidized.
摘要翻译：一种用于使用颗粒状固体催化剂处理含水混合物中的至少一种不希望的组分的系统和方法。含水混合物和颗粒状固体催化剂形成被湿氧化的浆料。

3. 发明申请

WO1996024558A1 METHOD AND APPARATUS FOR THERMAL DECOMPOSITION AND SEPARATION OF COMPONENTS WITHIN AN AQUEOUS STREAM 审中-公开
标题翻译：用于热分解和分离在水中的组分的方法和装置
公开(公告)号：WO1996024558A1
公开(公告)日：1996-08-15
申请号：PCT/US1996001971
申请日：1996-02-09
申请人： HPR CORPORATION , YOUNG, Robert
发明人： HPR CORPORATION
IPC分类号： C02F01/02
CPC分类号： A62D3/40 , A62D3/20 , A62D2101/02 , A62D2101/04 , A62D2101/20 , A62D2101/22 , A62D2101/24 , A62D2101/26 , A62D2101/28 , A62D2203/10 , B01J6/00 , B01J19/243 , B01J2219/00058 , B01J2219/00069 , B01J2219/0011 , B01J2219/00135 , B01J2219/00159 , B01J2219/00162 , B01J2219/00182 , C02F1/025 , C02F1/048 , C02F2101/006 , G21F9/08
摘要： An apparatus and method for treating materials that present disposal problems is provided. The treatment takes place within an aqueous stream and in an oxygen-deficient multiple zone system, and results in the thermal decomposition and/or separation of components within the treated material. The apparatus and method of this invention may be used for the treatment of non-hazardous and hazardous waste, including organic and inorganic compounds, radioactive materials, toxic compounds, binary chemicals (such as nerve gas) and heavy metals, prior to disposal.
摘要翻译：提供了一种处理存在处理问题的材料的设备和方法。处理发生在含水流和缺氧多区系统内，并导致处理过的材料中组分的热分解和/或分离。本发明的装置和方法可以在处置之前用于处理非危险和有害废物，包括有机和无机化合物，放射性物质，有毒化合物，二元化学物质（如神经气体）和重金属。

4. 发明申请

WO99064112A1 METHOD AND APPARATUS FOR TREATING SALT STREAMS 审中-公开
标题翻译：用于处理盐水的方法和装置
公开(公告)号：WO99064112A1
公开(公告)日：1999-12-16
申请号：PCT/SE1999/001006
申请日：1999-06-09
IPC分类号： A62D3/00 , A62D3/20 , A62D101/22 , A62D101/28 , A62D101/40 , B01J3/00 , C02F11/08
CPC分类号： A62D3/20 , A62D2101/22 , A62D2101/28 , A62D2101/40 , A62D2203/10 , B01J3/008 , C02F11/086 , Y02P20/544
摘要： A method for avoiding the precipitation of salts from a salt containing water stream prior to the stream reaching a supercritical water reactor is presented. The salt containing water stream is preferably kept at temperatures below supercritical conditions as the stream is transferred to the reactor. After the salt stream reaches the reactor the temperature of the salt stream is preferably raised to the appropriate temperature by mixing the salt stream, within the reactor, with a second stream that has been heated above the supercritical temperature of water. Alternatively, a method for preventing the clogging of the conduits upstream from the reactor may involve the mixing of two subcritical waste streams. One stream may include salts, the other preferably includes oxidizable material. The heat produced by the reaction of the oxidizable materials within the reactor preferably allows the mixture to remain at supercritical conditions for a time sufficient to oxidize substantially all of the oxidizable material.
摘要翻译：提出了一种在流到超临界水反应器之前避免盐从含盐水流中沉淀的方法。含盐水流优选保持在低于超临界条件的温度，因为流被转移到反应器中。在盐流到达反应器之后，盐流的温度优选通过将反应器内的盐流与已经被加热到水的超临界温度以上的第二流混合而升高到合适的温度。或者，用于防止在反应器上游的导管堵塞的方法可能涉及两个亚临界废物流的混合。一个流可以包括盐，另一个优选包括可氧化的材料。由反应器内的可氧化材料的反应产生的热量优选允许混合物在超临界条件下保持足以氧化基本上所有可氧化材料的时间。

5. 发明申请

WO1996034662A1 CATALYTIC-HYDROTHERMAL DISPOSAL PROCESS OF CHEMICAL MILITARY MATERIALS 审中-公开
标题翻译：用于催化水处置武器的化学物质
公开(公告)号：WO1996034662A1
公开(公告)日：1996-11-07
申请号：PCT/EP1995001710
申请日：1995-05-05
申请人： UHDE GMBH , HEDERER, Hartmut , THIAGARAJAN, Natarajan , ANDERSEN, Kjeld
发明人： UHDE GMBH
IPC分类号： A62D03/00
CPC分类号： A62D3/20 , A62D3/35 , A62D2101/02 , A62D2101/22 , A62D2101/24 , A62D2101/26
摘要： The chemical military materials include both the group of chemical agents used in chemical weapons and the group of fuels used in military aircraft. Chemical military materials must be disposed of at the end of their storage life. A continuous process is disclosed for that purpose. The chemical military materials are first suspended and/or dissolved in water and an alkaline catalyst is added to the aqueous mixture. A reaction mixture is thus obtained. The reaction mixture is brought to the reaction pressure by liquid feeding means, for example a high pressure pump. The reaction pressure lies between 100 bars and 1000 bars. The reaction mixture is heated up to a reaction temperature lower than the critical temperature of pure water. The usual reaction temperature is 350 DEG C. The reaction mixture heated up to the reaction temperature then flows over a catalyst bed that contains a catalytic zirconium dioxide. The catalysed reactions produce a hot mixture of converted materials that is substantially free of chemical military materials. The hot mixture of converted materials is cooled down and expanded in a separator, producing a gaseous phase with CO2, CH4 and H2, an oily phase and an aqueous phase with dissolved salts that may all be dumped.
摘要翻译：武器的化学物质包括该组的可作为化学武器的化学战剂，以及在军用飞机使用的组的燃料。武器的化学物质必须在其保质期后丢弃。这是在一个连续的过程中完成的。在此，化学武器材料首先悬浮在水和/或溶解的和水的混合物中加入碱性催化活性添加剂。使得进料混合物生产的。然后，与这样的液体资金进料混合物。带来作为高压泵向反应压力。反应压力为100巴和1000巴之间。将进料混合物被加热到低于纯水的临界温度的反应温度。典型的反应温度为350℃。加热到反应温度进料混合物通过催化剂床有催化作用的二氧化锆，其中所述热产生Konvertgemisch在催化的反应，这是无化学物质臂基本上通过。热Konvertgemisch被冷却并在分离器放松。被填埋在此，气相与CO 2，CH 4和H 2，油相和水相含有溶解的盐出现。

6. 发明申请

WO9526127A2 METHOD OF TREATING PLASTIC WASTE 审中-公开
标题翻译：处理塑料废物的方法
公开(公告)号：WO9526127A2
公开(公告)日：1995-10-05
申请号：PCT/BY9500002
申请日：1995-03-24
申请人： SCIENCE TECHNICAL AND PRODUCT , SMALL STATE ENTERPRISE ECORES , ZHURAVSKY GENNADY IVANOVICH , MULYARCHIK VALERY VLADIMIROVIC , MARCHENKO VLADIMIR ALEXEEVICH , KUKHAREV ANATOLY VASILIEVICH , VINOGRADOV LEONID MIKHAILOVICH , GREBENKOV ANATOLY ZHORESOVICH , DROZDOV VLADIMIR NIKOLAEVICH , KONSTANTINOV VALERY GRIGORIEVI , STETSJURENKO VITALY IVANOVICH , KHOMICH IVAN IVANOVICH , CHEMETIEV VALERY VLADIMIROVICH
发明人： ZHURAVSKY GENNADY IVANOVICH , MULYARCHIK VALERY VLADIMIROVIC , MARCHENKO VLADIMIR ALEXEEVICH , KUKHAREV ANATOLY VASILIEVICH , VINOGRADOV LEONID MIKHAILOVICH , GREBENKOV ANATOLY ZHORESOVICH , DROZDOV VLADIMIR NIKOLAEVICH , KONSTANTINOV VALERY GRIGORIEVI , STETSJURENKO VITALY IVANOVICH , KHOMICH IVAN IVANOVICH , CHEMETIEV VALERY VLADIMIROVICH
IPC分类号： A62D3/20 , A62D101/20 , A62D101/22 , C10G1/10
CPC分类号： A62D3/20 , A62D2101/20 , A62D2101/22 , A62D2203/10 , C10G1/10
摘要： The invention relates to the technology of treating industrial and domestic waste and can be applied in the chemical industry as well as in the power generation sector as a way of using plastic and polymer waste. The claimed method involves: melting down the plastic waste in an atmosphere of superheated steam and thermal destruction of the waste at a temperature of 400-500 DEG C in a multi-layered inert material whose particles diminish in size, layer by layer and in the direction of flow of the melt, from 3.83 to 0.12 mm; and the removal and condensation of the gaseous products.
摘要翻译：本发明涉及处理工业和家庭废物的技术，可用于化学工业以及发电领域，作为使用塑料和聚合物废物的一种方式。要求保护的方法包括：在400-500℃的温度下在过热蒸汽气氛中将塑料废料熔化并在多层惰性材料中，其颗粒尺寸逐渐减小，并在熔体流动方向为3.83〜0.12mm; 以及气态产物的去除和冷凝。

7. 发明申请

WO1993014243A1 DECOMPOSITION OF HALOGENATED AND POLYHALOGENATED ORGANIC MATERIALS BY ELECTRIFIED MICROHETEROGENEOUS CATALYSIS 审中-公开
标题翻译：通过电化学微分解催化分解氢化和多金属有机材料
公开(公告)号：WO1993014243A1
公开(公告)日：1993-07-22
申请号：PCT/US1993000578
申请日：1993-01-21
申请人： THE GOVERNMENT OF THE UNITED STATES OF AMERICA, ...
发明人： THE GOVERNMENT OF THE UNITED STATES OF AMERICA, ... , ROLISON, Debra, R. , STEMPLE, Joseph, Z.
IPC分类号： C25B03/00
CPC分类号： A62D3/10 , A62D3/11 , A62D3/20 , A62D2101/20 , A62D2203/04 , B01J8/42
摘要： In a system and method for enhancing chemical reactions, a reactant (22) is brought in contact with a stable, non-soluble, porous, electronically non-conductive solid (reaction enhancer) (20) in a fluidic medium (18) to form a reaction mixture of low ionic strength. The reaction mixture so formed is then subjected to an electrifying force thereby enhancing the chemical reaction. Reaction products are then collected.

8. 发明申请

WO2005012179A3 SUPERCRITICAL WATER OR SUBCRITICAL WATER AND METHOD OF OXIDIZING ORGANIC SUBSTANCE WITH THE SAME 审中-公开
标题翻译：超临界水或亚临界水和有机物质氧化方法
公开(公告)号：WO2005012179A3
公开(公告)日：2005-04-14
申请号：PCT/JP2004010969
申请日：2004-07-30
申请人： TOMIYASU HIROSHI
发明人： TOMIYASU HIROSHI , PARK KI-CHUL
IPC分类号： A62D3/20 , A62D3/38 , A62D101/22 , A62D101/28 , B01J3/00 , B09B3/00 , C02F20060101 , C07B37/06 , C07D319/24 , C08J11/14 , C08J11/16 , C08L27/06 , A62D3/00
CPC分类号： B01J3/008 , A62D3/20 , A62D3/38 , A62D2101/22 , A62D2203/04 , Y02P20/544
摘要： This invention is to provide supercritical water or subcritical water with which chemical substances, in particular, harmful organic substances difficult to decompose, such as p-dichlorobenzene and PCB, can be oxidized into harmless substances under the mild conditions; and a method of oxidizing an organic substance with either of these waters. The supercritical water or subcritical water uses a substance derived from a nitrate as an oxidizing agent.
摘要翻译：本发明提供一种超临界水或亚临界水，在温和条件下，化学物质，特别是不易分解的有害有机物如对二氯苯和PCB可被氧化成无害物质; 以及用这些水中的任一种氧化有机物质的方法。超临界水或亚临界水使用来自硝酸盐的物质作为氧化剂。

9. 发明申请

WO2005000490A3 PROCESS AND PLANT FOR THE HYDROTHERMAL TREATMENT OF ASBESTOS AND/OR ASBESTOS-CONTAINING MATERIALS IN SUPERCRITICAL WATER 审中-公开
标题翻译：在超临界水中水热处理石棉和/或含石棉的材料的方法和设备
公开(公告)号：WO2005000490A3
公开(公告)日：2005-02-03
申请号：PCT/EP2004006809
申请日：2004-06-17
申请人： CESI CT ELETTROTECNICO SPERIME , SIGON FABIO , SERVIDA ALBERTO , GRASSI SIMONA
发明人： SIGON FABIO , SERVIDA ALBERTO , GRASSI SIMONA
IPC分类号： A62D3/20 , A62D101/41 , B01J3/00 , B01J8/00 , B01J16/00 , B09B3/00 , C02F11/08
CPC分类号： A62D3/20 , A62D2101/41 , A62D2203/10 , B01J3/008 , B01J8/006 , B01J16/00 , B01J2219/00083 , B09B3/0066 , C02F11/086 , Y02P20/544
摘要： The invention relates to a plant and a process for the hydrothermal treatment of asbestos and/or materials containing asbestos in supercritical water (Supercritical Water, SCW), that provides for the withdrawal (3) of water from a tank (2), the transformation (5) of the water in supercritical water, the reaction of the supercritical. water with asbestos or with material containing asbestos in a suitable environment (8) by means of a hydrolysis process, the cooling (14) of the waste water, the filtering (15) of the waste water, the collection of the waste water in a tank (17).
摘要翻译：本发明涉及一种用于水冷处理石棉和/或含有石棉的超临界水（超临界水，SCW）的设备和方法，其提供从罐（2）中取出水（3），所述转化（5）水在超临界水中的超临界反应。（8）中通过水解过程，废水冷却（14），废水过滤（15），废水收集在一个合适的环境（8）中的石棉或含有石棉的材料罐（17）。

10. 发明申请

WO2003057318A1 CATALYTIC DESTRUCTION OF HALOGENATED HYDROCARBONS 审中-公开
标题翻译：催化破坏氢化烃
公开(公告)号：WO2003057318A1
公开(公告)日：2003-07-17
申请号：PCT/BE2003/000005
申请日：2003-01-14
申请人： K.U. LEUVEN RESEARCH AND DEVELOPMENT , WECKHUYSEN, Bert , SCHOONHEYDT, Robert , VAN DER AVERT, Pieter
发明人： WECKHUYSEN, Bert , SCHOONHEYDT, Robert , VAN DER AVERT, Pieter
IPC分类号： A62D3/00
CPC分类号： B01D53/8662 , A62D3/20 , A62D3/37 , A62D2101/22 , B01D2255/206 , B01D2257/206
摘要： The destruction of chlorinated hydrocarbons, such as carbon tetrachloride, over lanthanide-based solid catalysts in the presence of steam has been investigated between 200 and 350°C. Ln 2 O 3 /AL 2 O 3 (e.g. Ln = La, Nd, Ce and Pr) show a very high catalytic hydrolysis activity. The destruction capacity gradually increases with increasing temperature and reaches a maximun value of 42.3.10 6 ppm.h -1 at 350°C for a 10 wt% Ln 2 O 3 /AL 2 O 3 catalyst. This destruction capacity could be maintained for a least 48 hours. The catalyst activity is also function of the type of lanthanide oxide; i.e. , La ≈ Nd > Ce ≈ Pr. The process is based on a delicate equilibrium between destructive adsorption of CCI 4 onto the lanthanide oxide and the dechlorination of the formed lanthanide chloride with steam. Steam being responsible for the in situ regeneration of the catalytic active phase.
摘要翻译：在蒸汽存在下，镧系固体催化剂上的氯化烃如四氯化碳的破坏已经在200和350℃之间进行了研究。（例如，Ln = La，Nd，Ce和Pr）显示出非常高的催化水解活性。破坏能力随温度升高而逐渐增加，对于10重量％的Ln ，在350℃下达到最大值为42.3×10 -6 ppm /小时。 2 O 3 / AL 2 O 3 催化剂。这种破坏能力可以维持至少48小时。催化剂活性也是镧系元素氧化物的功能; 即≈≈Nd> Ce≈Pr。该方法基于在镧系元素氧化物上的CCI 4的破坏性吸附与形成的镧系元素氯化物与蒸汽的脱氯之间的微妙平衡。蒸汽负责催化活性相的原位再生。

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