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    • 3. 发明申请
    • PESTICIDALLY ACTIVE AMINOACETONITRILES
    • 农药活性氨基嘌呤
    • WO2003004474A1
    • 2003-01-16
    • PCT/EP2002/007515
    • 2002-07-05
    • SYNGENTA PARTICIPATIONS AGSTEIGER, ArthurEBERLE, MartinRENOLD, PeterO'SULLIVAN, Anthony, CorneliusZAMBACH, Werner
    • STEIGER, ArthurEBERLE, MartinRENOLD, PeterO'SULLIVAN, Anthony, CorneliusZAMBACH, Werner
    • C07D239/28
    • C07D239/28C07D237/14C07D239/34C07D241/16C07D241/18C07D241/24C07D333/32
    • Compounds of formula (I), wherein A 1 and A 2 are each independently of the other unsubstituted or mono- to penta-substituted aryl or unsubstituted or, depending upon the possibility of substitution at the ring, mono- to tetra-substituted heteroaryl bonded via a ring carbon atom; X and y are each independently of the other a bond, C 1 -C 6 alkylene, C 2 -C 6 alkenylene, C 2 -C 6 alkynylene, phenylene, -O-, -S- or C(=O)-; R 1 is, for example, hydrogen, C 1 -C 6 alkyl or halo-C 1 -C 6 alkyl; R2 is, for example, C 1 -C 6 alkyl, halo-C 1 -C 6 alkyl or C 1 -C 6 alkoxy-C 1 -C 6 alkyl; V is C 1 -C 6 alkylene, C 2 -C 6 alkenylene or C 2 -C 6 Alkynylene; W is O, S, -S(O)-, -S(O)-, -S(O 2 )- or N(R 3 ); and R 3 is hydrogen, C 1 -C 6 alkyl, -C(=O)-C 1 -C 6 alkyl or C 1 -C 6 alkyl or C 1 -C 6 alkyl-O-C 1 -C 6 alkyl; n is 0 or 1; and, when n is 1, R 4 and R 5 are, for example, hydrogen, C 1 -C 6 alkyl or halo-C 1 -C 6 akyl; and, where applicable, diastereoisomers, E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form; a process for the preparation of those compounds and their tautomers and the use thereof; pesticidal compositions in which the active ingredient has been selected from those compounds and their tautomers, and a process for the preparation of such compositions and the use thereof; intermediates, in free form or in salt form, for the preparation of such compounds and, where applicable, their tautomers, in free form or in salt form are described.
    • 式(I)化合物,其中A 1和A 2各自独立地为另一个未取代或单 - 或五 - 取代的芳基或未被取代的或根据在环上取代的可能性,通过一个或多个 - 环碳原子; X和Y各自独立地为键,C1-C6亚烷基,C2-C6亚烯基,C2-C6亚炔基,亚苯基,-O - , - S-或C(= O) - ; R 1是例如氢,C 1 -C 6烷基或卤代-C 1 -C 6烷基; R 2是例如C 1 -C 6烷基,卤代-C 1 -C 6烷基或C 1 -C 6烷氧基-C 1 -C 6烷基; V是C 1 -C 6亚烷基,C 2 -C 6亚烯基或C 2 -C 6亚炔基; W是O,S,-S(O) - , - S(O) - , - S(O 2) - 或N(R 3)。 且R 3为氢,C 1 -C 6烷基,-C(= O)-C 1 -C 6烷基或C 1 -C 6烷基或C 1 -C 6烷基-O-C 1 -C 6烷基; n为0或1; 当n为1时,R 4和R 5为例如氢,C 1 -C 6烷基或卤代C 1 -C 6烷基; 和/或互变异构体,在各种情况下均为游离形式或盐形式;以及(如适用)非对映异构体,E / Z异构体,E / Z异构体混合物和/或互变异构体。 制备这些化合物及其互变异构体的方法及其用途; 活性成分选自那些化合物及其互变异构体的杀虫组合物及其制备方法及其用途; 描述了游离形式或盐形式的中间体,用于制备这些化合物,并且在适用的情况下,其互变异构体以游离形式或盐形式。