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1. 发明申请

WO2011098493A1 METHOD AND COMPOSITION FOR ENHANCED OIL RECOVERY 审中-公开
标题翻译：用于增强油回收的方法和组合
公开(公告)号：WO2011098493A1
公开(公告)日：2011-08-18
申请号：PCT/EP2011/051909
申请日：2011-02-09
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , BARNES, Julian Richard , DIRKZWAGER, Hendrik , ON, Quoc An , SMIT, Johan Paul , SMIT, Jasper Roelf
发明人： BARNES, Julian Richard , DIRKZWAGER, Hendrik , ON, Quoc An , SMIT, Johan Paul , SMIT, Jasper Roelf
IPC分类号： C09K8/584
CPC分类号： C09K8/584
摘要： A method is provided for treating a hydrocarbon containing formation. The method comprises providing a hydrocarbon recovery composition comprising a mixture of branched internal olefin sulfonate molecules, and contacting hydrocarbons in the hydrocarbon containing formation with the hydrocarbon recovery composition. The mixture of branched internal olefin sulfonate molecules has an average number of carbon atoms of between 19 and 23, and an average number of branches of at least 0.6 per molecule. A hydrocarbon composition produced from a hydrocarbon containing formation, and a hydrocarbon recovery composition comprising a mixture of branched internal olefin sulfonate molecules are also provided.
摘要翻译：提供了一种处理含烃地层的方法。该方法包括提供一种烃回收组合物，其包含支链内烯烃磺酸盐分子的混合物，并使含烃地层中的烃与烃回收组合物接触。支链内烯烃磺酸盐分子的混合物的平均碳原子数为19-23，每分子平均支链数为至少0.6。还提供了由含烃地层产生的烃组合物和包含支链内烯烃磺酸盐分子的混合物的烃回收组合物。

2. 发明申请

WO2010120833A1 METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY FROM A VERY HIGH SALINITY, HIGH TEMPERATURE FORMATION 审中-公开
标题翻译：来自非常高的盐度，高温形成的增强烃的回收方法和组合
公开(公告)号：WO2010120833A1
公开(公告)日：2010-10-21
申请号：PCT/US2010/030960
申请日：2010-04-14
申请人： SHELL OIL COMPANY , SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , BARNES, Julian Richard , RANEY, Kirk Herbert , SEMPLE, Thomas Carl , SHPAKOFF, Paul Gregory , SMIT, Johan Paul , SMIT, Jasper Roelf
发明人： BARNES, Julian Richard , RANEY, Kirk Herbert , SEMPLE, Thomas Carl , SHPAKOFF, Paul Gregory , SMIT, Johan Paul , SMIT, Jasper Roelf
IPC分类号： C09K8/584
CPC分类号： C09K8/584
摘要： A method of treating a very high salinity high temperature hydrocarbon containing formation is described. The method includes (a) providing a hydrocarbon recovery composition to at least a portion of a hydrocarbon containing formation having a brine salinity of above about 13 wt% and a temperature of above about 7°C, wherein the composition comprises a C 15-18 internal olefin sulfonate; and (b) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation.
摘要翻译：描述了处理非常高盐度的高温含烃地层的方法。该方法包括（a）向至少一部分具有高于约13重量％的盐水盐度和高于约7℃的温度的含烃地层提供烃回收组合物，其中所述组合物包含C15-18内部烯烃磺酸盐; 和（b）允许组合物与含烃地层中的烃相互作用。

3. 发明申请

WO2007057458A1 CATALYTIC PROCESS FOR THE OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
标题翻译：烯烃单体低级化的催化方法
公开(公告)号：WO2007057458A1
公开(公告)日：2007-05-24
申请号：PCT/EP2006/068659
申请日：2006-11-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
发明人： DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
IPC分类号： C07C2/36 , C07C11/107 , B01J31/24
CPC分类号： B01J31/188 , B01J31/143 , B01J2531/62 , B01J2531/64 , B01J2531/66 , C07C2/36 , C07C2531/24 , C07F9/46
摘要： A process for the simultaneous trimerization and tetramerization of olefinic monomers , wherein the process comprises contacting at least one olefinic monomer with catalyst system comprising : a) a source of chromium, molybdenum or tungsten; b) a ligand having the general formula (I) ; (R 1 ) 2 P-X-P (R 1 ) m (R 2 )n wherein : X is a bridging group of the formula -N(R 3 )-, wherein R 3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R 1 groups are independently selected from an optionally substituted aromatic group bearing a polar substituent on at least one of the ortho-positions; and the R 2 groups are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups and c) a cocatalyst, at a pressure in the range of from below atmospheric to about 40 barg and at a temperature in the range of from about 0 °C to about 120 °C. The present invention further relates to a process for the simultaneous trimerization and tetramerization of ethylene to 1-hexene and 1-octene.
摘要翻译：一种用于烯烃单体的同时三聚和四聚的方法，其中所述方法包括使至少一种烯属单体与催化剂体系接触，所述催化剂体系包括：a）铬，钼或钨的来源; b）具有通式（I）的配体; （R 1）2 PXP（R 1）2（R 2）2（R 2） n其中：X是式-N（R 3 O 3） - 的桥连基团，其中R 3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 1基团独立地选自在至少一个邻位上带有极性取代基的任选取代的芳族基团; R 2和R 2独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，和c）助催化剂，其压力范围为低于大气压至约40巴，温度为在约0℃至约120℃的范围内。本发明还涉及一种将乙烯同时三聚和四聚到1-己烯和1-辛烯的方法。

4. 发明申请

WO2006108803A1 CATALYTIC TRIMERIZATION AND TETRAMERIZATION OF OLEFINIC MONOMERS 审中-公开
标题翻译：烯烃单体的催化三聚和四聚体
公开(公告)号：WO2006108803A1
公开(公告)日：2006-10-19
申请号：PCT/EP2006/061425
申请日：2006-04-07
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
发明人： DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
IPC分类号： B01J31/24 , B01J31/18
CPC分类号： B01J31/188 , B01J31/143 , B01J31/2409 , B01J2231/20 , B01J2531/62 , B01J2531/64 , B01J2531/66 , B01J2540/10 , C07C2/36 , C07C2531/24 , C07C11/02 , C07C11/107
摘要： A catalyst precursor composition comprising: a) a source of chromium, molybdenum or tungsten; b) a first ligand having the general formula (I) ; (R 1 ) (R 2 ) P-X-P(R 3 ) (R 4 ) (I), wherein: X is a bivalent organic bridging group; R 1 and R 3 are independently selected from, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups, with the proviso that when R 1 and R 3 are aromatic groups they do not contain a polar substituent at any of the ortho-positions; R 2 and R 4 are independently selected from optionally substituted aromatic groups, each R 2 and R 4 bearing a polar substituent on at least one of the ortho-positions; and c) a second ligand having the general formula (II) ; (R 1' ) (R 2' )P-X'-P(R 3' ) (R 4' ) (II), wherein: X' is a bridging group of the formula -N(R 5' )-, wherein R 5' is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; and R 1' , R 2' , R 3' and R 4' are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups of which at least one of R 1' , R 2' , R 3' and R 4' is substituted with a polar substituent, or R 1' , R 2' , R 3' and R 4' are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups, wherein any substituents on one or more of R 1' , R 2' , R 3' and R 4' are non-polar. The present invention also relates to a catalyst system comprising the catalyst precursor composition of the present invention and additional component; d) a cocatalyst. The present invention further relates to a process for the trimerization and tetramerization of olefinic monomers, particularly the trimerization and tetramerization of ethylene to 1-hexene and 1-octene, wherein the process comprises contacting at least one olefinic monomer with the catalyst system of the present invention.
摘要翻译：一种催化剂前体组合物，其包含：a）铬，钼或钨的来源; b）具有通式（I）的第一配体; （R 1）（R 2）（R 4）（R 4）（R 4）（R 4）（R 4） X是二价有机桥连基团; R 1和R 3独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，条件是当R 1和 R 3是在任何邻位不包含极性取代基的芳族基团; R 2和R 4独立地选自任选取代的芳族基团，每个R 2和R 4都带有一个在至少一个邻位上的极性取代基; 和c）具有通式（II）的第二配体; （R'1'）（R 2'）P-X'-P（R 3'）（R 4' （II），其中：X'是式-N（R 5'）的桥连基团，其中R 5'选自氢烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; 和R 1'，R 2'，R 3'和R 4'独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，其中R 1，R 2，R 3，R'和R“中的至少一个 > 4'被极性取代基取代，或R 1，R 2，R 3，R 3， SO 4“独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，其中R 1，R 2，R 2， SUP>，R 3'和R 4'是非极性的。本发明还涉及包含本发明的催化剂前体组合物和另外的组分的催化剂体系; d）助催化剂。本发明还涉及烯烃单体的三聚和四聚的方法，特别是乙烯对1-己烯和1-辛烯的三聚和四聚，其中该方法包括使至少一种烯属单体与本发明的催化剂体系接触发明。

5. 发明申请

WO2008077911A1 LIGANDS AND CATALYST SYSTEMS FOR THE OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
标题翻译：用于烯烃单体低级化的配体和催化剂体系
公开(公告)号：WO2008077911A1
公开(公告)日：2008-07-03
申请号：PCT/EP2007/064398
申请日：2007-12-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
发明人： DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
IPC分类号： C07F9/535 , C07F11/00 , B01J31/18
CPC分类号： C07F11/005 , B01J31/0265 , B01J31/189 , B01J2231/20 , B01J2531/60 , B01J2531/62 , C07C2/36 , C07C2531/24 , C07F9/5355
摘要： The present invention relates to a ligand having the general formula (I) : (R 1 ) 2 P-P(R 1 )m(R 2 ) n =N(R3) (I) wherein R3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R 1 groups are independently selected from an optionally substituted aromatic group bearing a polar substituent on at least one of the ortho-positions; and the R 2 groups are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups with the proviso that when the group is aromatic it does not contain a polar substituent at any of the ortho-positions, with the proviso that m is 0 or 1, n is 1 or 2 and the total of m + n is 2. The present invention also relates to catalyst systems and a process for the simultaneous trimerization and tetramerization of olefinic monomers using said ligands.
摘要翻译：本发明涉及具有通式（I）的配体：（R 1）2 PP（R 1）2（R 1）其中R 3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 1基团独立地选自在至少一个邻位上带有极性取代基的任选取代的芳族基团; 并且R 0-2基团独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，条件是当基团是芳族的时，其在任何邻位不含极性取代基，条件是m为0或1，n为1或2，m + n的总和为2.本发明还涉及使用所述配体的烯烃单体的同时三聚和四聚的催化剂体系和方法。

6. 发明申请

WO2007057455A1 CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
标题翻译：烯烃单体的催化低聚
公开(公告)号：WO2007057455A1
公开(公告)日：2007-05-24
申请号：PCT/EP2006/068652
申请日：2006-11-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
发明人： DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
IPC分类号： B01J31/24 , B01J31/18 , B01J31/34 , C07C2/32 , C07C2/36
CPC分类号： C07C2/36 , B01J31/188 , B01J31/34 , B01J2231/20 , B01J2531/62 , C07C2531/14 , C07C2531/24 , C07F9/46
摘要： A catalyst precursor composition comprising: a) a source of chromium, molybdenum or tungsten; b) a first ligand having the general formula (I) ; (R 1 ) (R 2 ) P-X-P(R 3 ) (R 4 ) wherein: X is a bridging group of the formula -N(R 5 )-, wherein R 5 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; at least three of R 1 to R 4 are independently selected from optionally substituted aromatic groups, each bearing a polar substituent on at least one of the ortho-positions; and optionally one of R 1 to R 4 is independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups with the proviso that when the group is aromatic it does not contain a polar substituent at any of the ortho-positions; c) a second ligand having the general formula (II) ; (R 1 ' ) (R 2 ' ) P-X'-P(R 3 ' ) (R 4 ' ) wherein: X' is a bridging group as defined for X of the first ligand, component (b) , of general formula (I) ; at least R 1 ' and R 2 ' of R 1 ' to R 4 ' are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups with the proviso that when the group is aromatic it does not contain a polar substituent at any of the ortho-positions; and optionally none, one or both of R 3 ' and R 4 ' are independently selected from an optionally substituted aromatic group bearing a polar substituent on at least one of the ortho-positions. The present invention also relates to a catalyst system comprising the catalyst precursor composition of the present invention and additional component; d) a cocatalyst. The present invention further relates to a process for the trimerization and tetramerization of olefinic monomers, particularly the trimerization and tetramerization of ethylene to 1-hexene and 1-octene, wherein the process comprises contacting at least one olefinic monomer with the catalyst system of the present invention.
摘要翻译：一种催化剂前体组合物，其包含：a）铬，钼或钨的来源; b）具有通式（I）的第一配体; （R 1）（R 2）PXP（R 3）（R 4）其中：X是式-N（R 5） - 的桥连基团，其中R 5选自氢，烃基，取代的烃基，杂烃基，取代的异烃基，甲硅烷基或其衍生物; R 1至R 4中的至少三个独立地选自任选取代的芳族基团，其各自在至少一个邻位上带有极性取代基; 并且任选的R 1至R 4中的一个独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，条件是当该基团为芳族时，其不含任何邻位的极性取代基; c）具有通式（II）的第二配体; （R'1）（R 2）P-X'-P（R 3）（R 4）其中：X'是如通式（I）的第一配体组分（b）的X所定义的桥连基团; R 1至R 4的至少R 1'和R 2'独立地选自烃基取代的烃基，杂烃基和取代的杂烃基，条件是当该基团是芳族的时，它在任何邻位不含极性取代基; 并且任选地，R“3”和“R”4中的任一个或两个独立地选自在至少一个邻位取代基上带有极性取代基的任选取代的芳族基团，位置。本发明还涉及包含本发明的催化剂前体组合物和另外的组分的催化剂体系; d）助催化剂。本发明还涉及烯烃单体的三聚和四聚的方法，特别是乙烯对1-己烯和1-辛烯的三聚和四聚，其中该方法包括使至少一种烯属单体与本发明的催化剂体系接触发明。

7. 发明申请

WO2008077908A1 LIGANDS AND CATALYST SYSTEMS THEREOF FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
标题翻译：烯烃单体催化低级化合物的配体和催化剂体系
公开(公告)号：WO2008077908A1
公开(公告)日：2008-07-03
申请号：PCT/EP2007/064391
申请日：2007-12-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
发明人： DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
IPC分类号： C07F9/6571 , C07F11/00 , B01J31/18
CPC分类号： C07C2/34 , B01J31/0265 , B01J31/189 , B01J2231/14 , B01J2231/20 , B01J2531/62 , B01J2531/64 , B01J2531/66 , C07F9/5355 , C07F9/6571 , C07F9/657154 , C07F11/005 , C08F110/02
摘要： The present invention relates to a ligand having the general Formula (I); P(R 4 J-P(R 1 ) (R 2 )=N(R 3 ) (I) wherein: the R 1 group is selected from a hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl group; the R 2 group is selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups; the R 3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R 4 group is an optionally substituted alkylenedioxy, alkylenedimercapto or alkylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the alkylenedioxy, alkylenedimercapto or alkylenediamino structure or an optionally substituted arylenedioxy, arylenedimercapto or arylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the arylenedioxy, arylenedimercapto or arylenediamino structure.
摘要翻译：本发明涉及具有通式（I）的配体; （R 4）（R 4）（R 2）= N（R 3）（I）其中：R 1基团选自烃基，取代的烃基，杂烃基和取代的杂烃基; R 2基团选自烃基，取代的烃基，杂烃基和取代的杂烃基; R 3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 4，亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构，其通过亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构的两个氧，硫或氮原子或任选取代的亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构与磷原子结合，通过两个氧，硫或硝基键合到磷原子上亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构的原子。

8. 发明申请

WO2012091880A2 METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY FROM A FORMATION CONTAINING A CRUDE OIL 审中-公开
标题翻译：从含有原油的地层采收的增强烃的方法和组合物
公开(公告)号：WO2012091880A2
公开(公告)日：2012-07-05
申请号：PCT/US2011/064083
申请日：2011-12-09
申请人： SHELL OIL COMPANY , SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , BARNES, Julian Richard , BUECHELE, James Laurel , ELLISON, Robert Hardy , RANEY, Kirk Herbert , SEMPLE, Thomas Carl , SMIT, Johan Paul
发明人： BARNES, Julian Richard , BUECHELE, James Laurel , ELLISON, Robert Hardy , RANEY, Kirk Herbert , SEMPLE, Thomas Carl , SMIT, Johan Paul
IPC分类号： C09K8/58 , C09K8/32 , E21B43/16
CPC分类号： C09K8/584
摘要： A hydrocarbon recovery composition comprising vinylidene based alkoxylate derivatives. A method of treating a crude oil formation and a method of preparing the hydrocarbon recovery composition are also described.
摘要翻译：包含基于亚乙烯基的烷氧基化物衍生物的烃采收组合物。还描述了处理原油地层的方法和制备烃采收组合物的方法。

9. 发明申请

WO2012091881A3 METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY FROM A FORMATION CONTAINING A CRUDE OIL 审中-公开
公开(公告)号：WO2012091881A3
公开(公告)日：2012-07-05
申请号：PCT/US2011/064088
申请日：2011-12-09
申请人： SHELL OIL COMPANY , SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , WILLIAM MARSH RICE UNIVERSITY , BARNES, Julian Richard , ELLISON, Robert Hardy , PUERTO, Maura , RANEY, Kirk Herbert , SMIT, Johan Paul
发明人： BARNES, Julian Richard , ELLISON, Robert Hardy , PUERTO, Maura , RANEY, Kirk Herbert , SMIT, Johan Paul
IPC分类号： C09K8/58 , C09K8/32 , E21B43/16
摘要： A hydrocarbon recovery composition comprising vinylidene olefin sulfonates is described. A method of treating a crude oil formation and a method of preparing the hydrocarbon recovery composition are also described.

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