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    • 3. 发明申请
    • A PROCESS FOR REACTIVE DISTILLATION OF A CARBOXYLIC ACID
    • 一种羧酸反应性蒸馏法
    • WO2007099071A1
    • 2007-09-07
    • PCT/EP2007/051782
    • 2007-02-26
    • SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.DIRKZWAGER, HendrikPETRUS, LeonardusPOVEDA-MARTINEZ, Hendrik
    • DIRKZWAGER, HendrikPETRUS, LeonardusPOVEDA-MARTINEZ, Hendrik
    • C07C67/08C07C69/14
    • C07C67/08C07C67/54Y02P20/127C07C69/24C07C69/716
    • A process for reactive distillation wherein a carboxylic acid is reacted in a reaction section of a reactive distillation column with an alcohol under esterifying conditions in the presence of a catalyst to form an ester, wherein a first supply stream comprising the carboxylic acid, a second supply stream comprising the alcohol and a third supply stream comprising an inert entrainer are supplied to the reactive distillation column, wherein the first supply stream is supplied to the column at a first entry level located just above or at the top of the reaction section, the second supply stream is supplied to the column at a second entry level located in or just below the reaction section and below the first entry level, and the third supply stream is supplied to the column at a third entry level located in or below the reaction section and not above the second entry level and wherein a bottom stream comprising the ester formed and unreacted carboxylic acid is obtained and a top stream comprising unreacted alcohol, water and entrainer is obtained.
    • 一种用于反应蒸馏的方法,其中羧酸在反应蒸馏塔的反应段中与醇在催化剂存在下在酯化条件下反应形成酯,其中包含羧酸的第一供应流,第二供应 将包含醇和包含惰性夹带剂的第三供应流的料流供应到反应蒸馏塔,其中第一供应流在位于反应段正上方或顶部的第一入口级供应至塔,第二 供应流在位于反应部分或正下方的第二入口级别并在第一入口级别下方供应到塔中,并且第三供应流在位于反应段内或下方的第三入口级处供应到塔, 不高于第二入口水平,并且其中获得包含形成的酯和未反应的羧酸的底部流,以及顶部流c 获得未反应的醇,水和夹带剂。
    • 4. 发明申请
    • A PROCESS FOR THE PREPARATION OF DETERGENTS
    • 一种制备洗涤剂的方法
    • WO2004058921A1
    • 2004-07-15
    • PCT/EP2003/051106
    • 2003-12-29
    • SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.DIRKZWAGER, HendrikGEIJSEL, Joannes Ignatius
    • DIRKZWAGER, HendrikGEIJSEL, Joannes Ignatius
    • C10G65/04
    • C10G67/02C07C1/0485C10G2/00C10G65/04C10G69/123
    • The invention concerns a process for the preparation of detergents, comprising separating the hydro carbonaceous product stream from a Fischer-Tropsch, process producing normally liquid and normally solid hydrocarbons into a light fraction comprising mainly C20­hydrocarbons, preferably the light fraction comprising at least 90 %wt, more preferably at least 95 %wt, of C 20- ­hydrocarbons, and one or more heavy fractions comprising the remaining hydrocarbons, hydrogenation of at least part of the light fraction to convert unsaturated hydrocarbons and/or oxygenates into saturated hydrocarbons, distillation of product thus obtained into at least one fraction comprising detergent hydrocarbons, dehydrogenation of at least part of the detergent hydrocarbons to obtain a detergent hydrocarbon stream comprising mono-olefins and conversion of the mono-olefins into detergents. The invention further concerns a process for the preparation of detergents in which process a hydrogenated product, which is obtained according to the above process, is dehydrogenated to obtain a detergent hydrocarbon stream comprising monoolefins, followed by conversion of the mono-olefins into detergents. Further, the invention relates to the combined production of detergents or detergent hydrocarbons and fuels from Fischer-Tropsch hydrocarbonaceous reaction product.
    • 本发明涉及一种用于制备洗涤剂的方法,其包括从费 - 托中分离含碳产物流,生产通常为液体和通常为固体烃的方法为主要包含C20烃的轻馏分,优选轻馏分包含至少90重量% ,更优选至少95重量%的C 20烃,以及一种或多种包含剩余烃的重馏分,至少部分轻馏分氢化以将不饱和烃和/或含氧化合物转化为饱和烃,因此蒸馏产物 获得至少一部分包含洗涤剂烃,至少部分洗涤剂烃的脱氢以获得包含单烯烃的洗涤剂烃流和将单烯烃转化成洗涤剂。 本发明还涉及制备洗涤剂的方法,其中根据上述方法获得的氢化产物被脱氢以获得包含单烯烃的洗涤剂烃流,然后将单烯烃转化为洗涤剂。 此外,本发明涉及从费 - 托含烃反应产物组合生产洗涤剂或洗涤剂烃和燃料。