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    • 1. 发明申请
    • A PROCESS FOR THE PREPARATION OF DETERGENTS
    • 一种制备洗涤剂的方法
    • WO2004058921A1
    • 2004-07-15
    • PCT/EP2003/051106
    • 2003-12-29
    • SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.DIRKZWAGER, HendrikGEIJSEL, Joannes Ignatius
    • DIRKZWAGER, HendrikGEIJSEL, Joannes Ignatius
    • C10G65/04
    • C10G67/02C07C1/0485C10G2/00C10G65/04C10G69/123
    • The invention concerns a process for the preparation of detergents, comprising separating the hydro carbonaceous product stream from a Fischer-Tropsch, process producing normally liquid and normally solid hydrocarbons into a light fraction comprising mainly C20­hydrocarbons, preferably the light fraction comprising at least 90 %wt, more preferably at least 95 %wt, of C 20- ­hydrocarbons, and one or more heavy fractions comprising the remaining hydrocarbons, hydrogenation of at least part of the light fraction to convert unsaturated hydrocarbons and/or oxygenates into saturated hydrocarbons, distillation of product thus obtained into at least one fraction comprising detergent hydrocarbons, dehydrogenation of at least part of the detergent hydrocarbons to obtain a detergent hydrocarbon stream comprising mono-olefins and conversion of the mono-olefins into detergents. The invention further concerns a process for the preparation of detergents in which process a hydrogenated product, which is obtained according to the above process, is dehydrogenated to obtain a detergent hydrocarbon stream comprising monoolefins, followed by conversion of the mono-olefins into detergents. Further, the invention relates to the combined production of detergents or detergent hydrocarbons and fuels from Fischer-Tropsch hydrocarbonaceous reaction product.
    • 本发明涉及一种用于制备洗涤剂的方法,其包括从费 - 托中分离含碳产物流,生产通常为液体和通常为固体烃的方法为主要包含C20烃的轻馏分,优选轻馏分包含至少90重量% ,更优选至少95重量%的C 20烃,以及一种或多种包含剩余烃的重馏分,至少部分轻馏分氢化以将不饱和烃和/或含氧化合物转化为饱和烃,因此蒸馏产物 获得至少一部分包含洗涤剂烃,至少部分洗涤剂烃的脱氢以获得包含单烯烃的洗涤剂烃流和将单烯烃转化成洗涤剂。 本发明还涉及制备洗涤剂的方法,其中根据上述方法获得的氢化产物被脱氢以获得包含单烯烃的洗涤剂烃流,然后将单烯烃转化为洗涤剂。 此外,本发明涉及从费 - 托含烃反应产物组合生产洗涤剂或洗涤剂烃和燃料。