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1. 发明申请

WO2005003237A1 A METHOD OF PRODUCING AN INTERPENETRATING POLYMER NETWORK (IPN), THE IPN AND USE THEREOF 审中-公开
标题翻译：一种生产互聚聚合物网络（IPN）的方法，其IPN及其用途
公开(公告)号：WO2005003237A1
公开(公告)日：2005-01-13
申请号：PCT/DK2004/000476
申请日：2004-07-02
申请人： NANON A/S , KARTHÄUSER, Joachim
发明人： KARTHÄUSER, Joachim
IPC分类号： C08L83/04
CPC分类号： C08F283/12 , Y02P20/544
摘要： The invention comprises a method of producing an interpenetrating polymer network (IPN) comprising the steps of I) providing a silicone polymer composition; (ii) providing one or more monomers for a polymer; (iii) providing a solvent for the one or more monomers; iv) exposing said silicone polymer composition to said one or more monomers and said solvent to precipitate monomer within said silicone polymer composition and v) polymerizing said monomer to form an IPN, wherein said solvent has a surface tension at the exposing step of about 15mNZm or less. It is preferred that the solvent, which is preferably CO 2 , in the exposing step is in or near its supercritical state. The method is fast and simple, and the dispersion of the monomers may be controled to thereby controle the amount and distribution of the interpenetrating network in the silicone material. Further more the method results in new materials, where silicone polymers are used as the basic materials.
摘要翻译：本发明包括生产互穿聚合物网络（IPN）的方法，包括以下步骤：I）提供硅氧烷聚合物组合物; （ii）为聚合物提供一种或多种单体; （iii）提供一种或多种单体的溶剂; iv）将所述硅氧烷聚合物组合物暴露于所述一种或多种单体和所述溶剂以使所述硅氧烷聚合物组合物中的单体沉淀，以及v）聚合所述单体以形成IPN，其中所述溶剂在暴露步骤下具有约15mNZm的表面张力或减。优选在曝光步骤中优选CO 2的溶剂处于或接近其超临界状态。该方法快速简单，可以控制单体的分散，从而控制硅胶材料中互穿网络的量和分布。此外，该方法还产生新材料，其中使用硅氧烷聚合物作为基础材料。

2. 发明申请

WO2005021625A1 A METHOD OF TREATING A RUBBER CONTAINING WASTE MATERIAL 审中-公开
标题翻译：一种处理含橡胶废物的方法
公开(公告)号：WO2005021625A1
公开(公告)日：2005-03-10
申请号：PCT/DK2004/000586
申请日：2004-09-02
申请人： NANON A/S , KARTHÄUSER, Joachim , KIERKEGAARD, Henry
发明人： KARTHÄUSER, Joachim , KIERKEGAARD, Henry
IPC分类号： C08J11/00
CPC分类号： C08J11/08 , B01D11/0203 , B29B17/02 , B29B2017/0293 , B29K2021/00 , C08J2321/00 , Y02W30/622 , Y02W30/68 , Y02W30/701
摘要： The invention relates to a method of providing a rubber material from a rubber containing waste material. The method comprises the step of subjecting the waste material to a treatment with an extraction solvent in a reactor at a pressure above atmospheric pressure, wherein the extraction solvent comprises an effective amount of carbon dioxide. The extraction may be performed in one or more dynamic and/or one or more static steps, to provide a sufficient extraction without damaging the material. The rubber containing waste material may further be subjected to an impregnation step, which may be performed simultaneously with the extraction step, after the extraction step or overlapping with the extraction step. The invention also relates to a rubber material comprising low amounts or is essentially free of alkylated aromatic oils and heavy metals in the form of inorganic and organic salts.
摘要翻译：本发明涉及一种由含橡胶的废料提供橡胶材料的方法。该方法包括以下步骤：在高于大气压的压力下，用反应器中的提取溶剂处理废料，其中提取溶剂包括有效量的二氧化碳。提取可以在一个或多个动态和/或一个或多个静态步骤中进行，以提供足够的提取而不损坏材料。含橡胶的废料可以进一步进行浸渍步骤，其可以在提取步骤之后或与提取步骤重叠的同时与萃取步骤同时进行。本发明还涉及包含少量或基本上不含烷基化芳族油和无机盐和有机盐形式的重金属的橡胶材料。

3. 发明申请

WO2005002530A1 A METHOD OF PRODUCING A SILANIZED COMPOSITE FILLER AND A METHOD OF PRODUCING A COMPOSITE MATERIAL 审中-公开
标题翻译：生产硅烷化复合填料的方法和生产复合材料的方法
公开(公告)号：WO2005002530A1
公开(公告)日：2005-01-13
申请号：PCT/DK2004/000475
申请日：2004-07-02
申请人： NANON A/S , KARTHÄUSER, Joachim
发明人： KARTHÄUSER, Joachim
IPC分类号： A61K6/083
CPC分类号： A61K6/083 , A61K6/0088 , C03C17/30 , C03C25/40 , C08L33/00 , C08L75/16
摘要： The inventions includes a method of producing a silanized composite filler, said method comprises the steps of (i) providing a filler core material, and (ii) treating said filler core material, which is preferably an inorganic filler core material e.g. in the form of fibers or beads, with a silane coupling agent in the presence of a treatment medium comprising CO 2 . The best result is obtained when the silane coupling agent is relatively small, e.g. with molecular weight below 500g/mol. The invention also comprises a method of producing a composite material comprising the silanized composite filler, as well s the products obtained. The silanized composite filler is simple to produce and has a good adhesion to the polymer matrix of a composite material.
摘要翻译：本发明包括生产硅烷化复合填料的方法，所述方法包括以下步骤：（i）提供填料芯材料，和（ii）处理所述填料芯材料，其优选为无机填料芯材料，例如无机填料芯材料。以纤维或珠粒的形式，在含有CO 2的处理介质的存在下与硅烷偶联剂一起使用。当硅烷偶联剂相对较小时，获得最好的结果。分子量低于500g / mol。本发明还包括一种生产包含硅烷化复合填料的复合材料的方法，以及获得的产物。硅烷化复合填料易于制备，并且与复合材料的聚合物基质具有良好的粘合性。

4. 发明申请

WO2008052568A1 A METHOD OF PRODUCING AN ARTICLE COMPRISING AN INTERPENETRATING POLYMER NETWORK (IPN) AND AN ARTICLE COMPRISING AN IPN 审中-公开
标题翻译：一种生产包含互聚聚合物网络（IPN）和包含IPN的文章的方法
公开(公告)号：WO2008052568A1
公开(公告)日：2008-05-08
申请号：PCT/DK2007/050162
申请日：2007-11-05
申请人： NANON A/S , ALM, Martin , BENTER, Maike , JENSEN, Anne Marie , KARTHÄUSER, Joachim , SCHAUMBURG, Kjeld
发明人： ALM, Martin , BENTER, Maike , JENSEN, Anne Marie , KARTHÄUSER, Joachim , SCHAUMBURG, Kjeld
IPC分类号： C08J7/16
CPC分类号： C08J7/16 , Y02P20/544 , Y10T428/249953 , Y10T428/249954 , Y10T428/249955 , Y10T428/249958 , Y10T428/249987 , Y10T428/249991 , Y10T428/249992 , Y10T428/249993 , Y10T428/263 , Y10T428/31663 , Y10T428/31855
摘要： The invention relates to a method of producing an article comprising an interpenetrating polymer network (IPN) and an IPN comprising article e.g. obtainable by this method. The method comprises i) providing a polymer substrate e.g. shaped to provide the desired article and applying it in a reaction chamber, ii) providing at least one monomer for an interpenetrating polymer, iv) exposing said polymer substrate in said reaction chamber to said at least one monomer in the presence of an impregnation solvent comprising CO 2 under conditions wherein said CO 2 is in its liquid or supercritical state and v) polymerizing and optionally cross linking said at least one monomer to form an interpenetrating polymer in the presence of a polymerization solvent under conditions wherein at least a part of said at least one monomer is dissolved in said polymerization solvent, The article comprises a body formed of a polymer substrate and an interpenetrating polymer of a second polymer different from the polymer of the polymer substrate and an outer surface layer on at least a part of its surface of said second polymer.
摘要翻译：本发明涉及一种生产包含互穿聚合物网络（IPN）和包含制品的IPN的制品的方法。可以通过这种方法获得。该方法包括：i）提供聚合物底物，例如成形以提供期望的制品并将其施加到反应室中，ii）提供用于互穿聚合物的至少一种单体，iv）在浸渍溶剂存在下将所述反应室中的所述聚合物基材暴露于所述至少一种单体，所述浸渍溶剂包含 CO 2在其中所述CO 2 2处于其液体或超临界状态的条件下，和v）聚合并任选地交联所述至少一种单体以在存在下形成互穿聚合物的聚合溶剂，其中至少一部分所述至少一种单体溶解在所述聚合溶剂中。所述制品包括由聚合物基材形成的主体和不同于聚合物基材的聚合物的第二聚合物的互穿聚合物以及在其所述第二聚合物的至少一部分表面上的外表面层。

5. 发明申请

WO2008052563A1 A METHOD OF PRODUCING AN ARTICLE COMPRISING AN INTERPENETRATING POLYMER NETWORK (IPN) AND AN ARTICLE COMPRISING AN IPN 审中-公开
标题翻译：一种包含内联聚合物网络（IPN）和包含IPN的文章的方法
公开(公告)号：WO2008052563A1
公开(公告)日：2008-05-08
申请号：PCT/DK2007/000479
申请日：2007-11-05
申请人： NANON A/S , ALM, Martin , BENTER, Maike , JENSEN, Anne Marie , KARTHÄUSER, Joachim , SCHAUMBURG, Kjeld
发明人： ALM, Martin , BENTER, Maike , JENSEN, Anne Marie , KARTHÄUSER, Joachim , SCHAUMBURG, Kjeld
IPC分类号： C08F283/00 , B01D11/02 , B01J3/00 , B08B7/00 , B29D11/00 , C08F283/12 , G02B1/04 , G02C7/04
CPC分类号： C08F283/00 , B01D11/0203 , B29D11/00038 , C08F283/12 , C08L51/006 , C08L51/04 , C08L51/085 , G02B1/043 , Y02P20/544 , C08L2666/02
摘要： The invention relates to a method of producing an article comprising an interpenetrating polymer network (IPN) and an article e.g. obtainable by the method. The method comprises i) providing an essentially transparent rubber substrate having a refractive index n 0 and being shaped to provide the desired shape of the article, and applying it in a reaction chamber, ii) providing a least one first monomer having a refractive index n 1 in homopolymerized condition wherein n 1 is lower than n 0 , iii) providing a least one second monomer having a refractive index n 2 in homopolymerized condition, wherein n 2 is higher than n 0 , iv) exposing said rubber substrate in said reaction chamber to said first and said second monomers to impregnate said rubber substrate with said monomers in the presence of an impregnation solvent comprising CO 2 under conditions wherein said CO 2 is in its liquid or supercritical state and v) co-polymerizing said first and said second monomers to form an IPN, wherein said at least one first monomer and said at least one second monomer are selected such that r 1 and r 2 independently of each other are 3 or less, where n = (Q 1 /Q 2 ) exp [-e1(e1 -e2)] and r 2 = (Q 2 /Q 1 ) exp [-e2 (e2-e1)] and Q 1 = denotes the intrinsic reactivity of the first monomer, Q 2 = denotes the intrinsic reactivity of the second monomer, and e1= denotes the polarity of the first monomer, and e2= denotes the polarity of the second monomer. The article comprises a body formed of a rubber substrate and an interpenetrating network of an interpenetrating copolymer and the article is essentially transparent.
摘要翻译：本发明涉及生产包含互穿聚合物网络（IPN）和制品的制品的方法。可通过该方法获得。该方法包括：i）提供基本上透明的具有折射率n O 0的橡胶基底，并且成形为提供所需制品的形状，并将其施加到反应室中，ii）提供至少一个在均聚条件下具有折射率为n <1的第一单体，其中n 1低于n O 3，iii）提供至少一个第二单体，其具有在均聚条件下的折射率n 2 N 2，其中n 2高于n O 3，iv）将所述反应室中的所述橡胶基材暴露于所述第一单体和所述第二单体在包含CO 2 2的浸渍溶剂的存在下，在所述CO 2 2处于其液体或超临界状态的条件下用所述单体浸渍所述橡胶基材状态和v）共聚所述第一和所述第二单体以形成IPN，其中所述至少一种第一单体和所述至少一种第二单体 er被选择为使得R 1和R 2彼此独立地为3或更小，其中n =（Q 1 / Q 2 > 2 ）exp [-e1（e1-e2）]和r2 =（Q2 / Q1） [-e2（e2-e1）]和Q1 =表示第一单体的固有反应性，Q 2 =表示第二单体的固有反应性，e1 =表示第一单体的极性，e2 =表示第二单体的极性。该制品包括由橡胶基材形成的本体和互穿共聚物的互穿网络，并且该制品基本上是透明的。

6. 发明申请

WO2006045320A2 A METHOD OF PRODUCING A SILICONE RUBBER ITEM AND THE PRODUCT OBTAINABLE BY THE METHOD 审中-公开
标题翻译：生产硅橡胶项目的方法和方法可以获得的产品
公开(公告)号：WO2006045320A2
公开(公告)日：2006-05-04
申请号：PCT/DK2005/050006
申请日：2005-10-25
申请人： NANON A/S , KARTHÄUSER, Joachim , BENTER, Maike , ALM, Martin
发明人： KARTHÄUSER, Joachim , BENTER, Maike , ALM, Martin
CPC分类号： B08B7/0021 , B29C71/0009 , B29C2071/0027 , B29L2031/753 , C08G77/34 , C08J7/02 , C08J2383/04
摘要： The invention relates to a method of producing a silicone rubber item. The method comprises the steps of i) shaping the silicone rubber item using injection moulding and ii) subjecting the injection moulded item to a cold tempering, wherein the cold tempering includes feeding the injecting moulded item into a reactor, and subjecting the injection moulded item to an extraction treatment using carbon dioxide containing solvent at a pressure between 10 and 50 bars, wherein the item has an initial temperature below 60 °C in the extraction step, and in at least a part of the extraction time the item has a temperature below 25 °C and a pressure so that the carbon dioxide is in its liquid state. The reactor may preferably be rotated during the cold tempering The method provide a highly efficient and fast method of thempring a silicone item under low temperature and pressure condition.
摘要翻译：本发明涉及一种硅橡胶制品的制造方法。该方法包括以下步骤：i）使用注塑成型硅橡胶制品，和ii）使注塑件进行冷回火，其中冷回火包括将注射成型品进料到反应器中，并将注射成型物品在10至50巴之间的压力下使用含二氧化碳的溶剂进行提取处理，其中在提取步骤中该物品的初始温度低于60℃，并且在提取时间的至少一部分中，该物品的温度低于25℃ °C和压力使得二氧化碳处于其液态。反应器可以在冷回火期间优选地旋转。该方法提供了在低温和高压条件下将有机硅物品挤出的高效快速方法。

7. 发明申请

WO2005118945A1 CARBON DIOXIDE DRY CLEANING 审中-公开
标题翻译：二氧化碳干燥清洁
公开(公告)号：WO2005118945A1
公开(公告)日：2005-12-15
申请号：PCT/EP2005/005660
申请日：2005-05-25
申请人： LINDE AKTIENGESELLSCHAFT , KARTHÄUSER, Joachim , MARCUSSON, Anders
发明人： KARTHÄUSER, Joachim , MARCUSSON, Anders
IPC分类号： D06L1/10
CPC分类号： D06L1/10 , D06L1/02
摘要： The invention is related to a method for cleaning objects in a cleaning fluid comprising a dense phase gas and water, wherein at least part of said water is filtered out of said cleaning fluid.
摘要翻译：本发明涉及一种用于清洁包含致密相气体和水的清洁流体中的物体的方法，其中至少部分所述水被从所述清洁流体中滤出。

8. 发明申请

WO2012138282A1 METHOD OF IMPREGNATING AND PURIFYING POLYLACTIC ACID RESIN 审中-公开
标题翻译：渗透和净化聚酯酸树脂的方法
公开(公告)号：WO2012138282A1
公开(公告)日：2012-10-11
申请号：PCT/SE2012/050335
申请日：2012-03-27
申请人： SIOX MACHINES AB , MARCUSSON, Anders , KARTHÄUSER, Joachim , HAMREFORS, Jan
发明人： MARCUSSON, Anders , KARTHÄUSER, Joachim , HAMREFORS, Jan
IPC分类号： C08G63/90 , B01D11/02 , C08G63/08 , C08J9/18 , C08G101/00
CPC分类号： B01D11/0296 , A61L9/042 , B01D11/0203 , C08G63/90 , C08J9/122 , C08J9/18 , C08J9/224 , C08J9/232 , C08J2201/034 , C08J2203/06 , C08J2300/16 , C08J2367/04
摘要： A method of impregnating and purifying polylactic acid (PLA), wherein PLA resin beads are subjected to a liquid C0 2 treatment, which involves impregnation and extraction comprising at least one impregnation and extraction step, in which the PLA resin beads are brought into contact with 0,01 -1000 kg pure liquid C0 2 /kg PLA in a reactor for a predetermined time period, at a temperature and pressure that prevents the beads from sticking together and foaming, and - a portion of the liquid C0 2 is drained from the PLA beads after completion of the impregnation and extraction step, at a temperature that prevents the beads from sticking together and foaming, and at which the C0 2 is in liquid form, while leaving at least 0,01 kg liquid C0 2 /kg PLA, preferably 0,01-1 kg liquid C0 2 /kg PLA in the reactor containing the PLA resin beads, followed by evacuation of C0 2 gas from the reactor so as to decrease the pressure to ambient pressure, whereby the remaining liquid C0 2 is evaporated, thereby decreasing the temperature so as to prevent foaming at ambient pressure.
摘要翻译：一种浸渍和净化聚乳酸（PLA）的方法，其中对PLA树脂珠进行液体CO 2处理，其包括浸渍和提取，其包括至少一个浸渍和提取步骤，其中PLA树脂珠与0接触， 01-1000kg纯液体CO 2 / kg PLA在反应器中预定的时间段，在防止珠子粘在一起并起泡的温度和压力下，和 - 一部分液体CO 2在完成后从PLA珠排出的浸渍和萃取步骤，在防止珠子粘在一起并发泡的温度下，并且在其中CO 2为液体形式的温度下，同时留下至少0.01kg液体CO 2 / kg PLA，优选为0.01-1 kg PLA溶液中，然后从反应器中排出CO 2气体，以将压力降至环境压力，由此蒸发剩余的液体CO 2，从而减少记录温度以防止在环境压力下发泡。

9. 发明申请

WO2012128715A1 METHOD FOR CONVERSION OF LOW TEMPERATURE HEAT TO ELECTRICITY AND COOLING, AND SYSTEM THEREFORE 审中-公开
标题翻译：低温热电转换方法及其系统
公开(公告)号：WO2012128715A1
公开(公告)日：2012-09-27
申请号：PCT/SE2012/050319
申请日：2012-03-22
申请人： CLIMEON AB , KARTHÄUSER, Joachim , ÖSTRÖM, Thomas
发明人： KARTHÄUSER, Joachim , ÖSTRÖM, Thomas
IPC分类号： F01K25/06 , F01K25/10 , F25B15/02 , F25B30/06
CPC分类号： F01K25/065 , F01K3/00 , F01K25/103 , F25B15/00 , F25B27/007 , F25B30/04 , F25B2309/00 , H02K7/1823
摘要： A method for producing electrical energy is disclosed which uses a heat source, such as solar heat, geothermal heat, industrial waste heat or heat from power production processes, providing heat of 150 °C or below, further comprising an absorber system in which a working gas, primarily carbon dioxide CO 2 , is absorbed into an absorbent, typically an amine, further comprising a reactor which receives heat from said heat source and in which the absorbent-CO 2 mixture is split into CO 2 and absorbent, further comprising an expansion machine, an electricity generator and auxiliary equipment such as pumps, pipes and heat exchangers. The system according to the method allows the cost-efficient production of electrical energy and cooling using low value heat source.
摘要翻译：公开了一种生产电能的方法，其使用诸如太阳能热，地热热，工业废热或来自发电生产过程的热源，提供150℃或更低的热量的热源，还包括吸收器系统，其中工作气体，主要是二氧化碳CO 2被吸收到吸收剂中，通常是胺，还包括从所述热源接收热量并且其中吸收剂 - CO 2混合物分成CO 2和吸收剂的反应器，还包括膨胀机，发电机和辅助设备如泵，管道和热交换器。根据该方法的系统允许使用低价值热源成本有效地生产电能和冷却。

10. 发明申请

WO2009150298A1 A METHOD TO PRODUCE ENGINEERED COMPOSITE ARTICLES COMPRISING EPOXY AND CARBON NANO TUBES 审中-公开
标题翻译：生产包含环氧和碳纳米管的工程复合材料的方法
公开(公告)号：WO2009150298A1
公开(公告)日：2009-12-17
申请号：PCT/FI2009/050492
申请日：2009-06-10
申请人： EAGLE TUULIVOIMA OY , KARTHÄUSER, Joachim
发明人： KARTHÄUSER, Joachim
IPC分类号： B29C70/46 , C08J5/00
CPC分类号： B29C70/58 , B29K2063/00 , B29K2105/167 , B29L2031/08 , B82Y30/00 , C08J5/005 , C08J2363/00 , F01D5/282 , F03D1/0675 , F03G6/045 , F05B2230/00 , F05B2230/60 , F05D2230/00 , F05D2230/60 , Y02E10/465 , Y02E10/721 , Y02P70/523
摘要： The invention relates to a method for producing composite articles containing epoxy and functionalized carbon nano tubes (CNT). The method comprises the following steps: a closable mould (10) is provided the mould having open and close positions, the inner parts of the open mould (10) is equipped with a film (3), which has compatibility with said epoxy and it is impermeable at least to the extent that resin is prevented from migrating through the film to the mould, the open mould (10) is further filled with glue containing epoxy and said functionalized carbon nano tubes, solid materials and elements enabling the mechanical connection to other machine elements, the mould (10) is closed and heated until the finished article is sufficiently stable.
摘要翻译：本发明涉及含有环氧和官能化碳纳米管（CNT）的复合制品的制备方法。该方法包括以下步骤：提供具有开闭位置的模具的可闭合模具（10），开模（10）的内部部件配备有与所述环氧树脂具有相容性的膜（3）至少在防止树脂通过膜迁移到模具的程度上是不可渗透的，开放模具（10）还进一步填充含有环氧树脂的胶和所述官能化碳纳米管，固体材料和元件能够与其他机械连接机器元件，模具（10）被关闭并加热直到成品足够稳定。

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