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1. 发明申请

WO2007070040A1 HALOGEN SUBSTITUTED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的卤素取代的金属化合物
公开(公告)号：WO2007070040A1
公开(公告)日：2007-06-21
申请号：PCT/US2005/045241
申请日：2005-12-14
申请人： EXXONMOBIL CHEMICAL PATENTS, INC. , VOSKOBOYNIKOV, Alexander, Z. , RAYABOV, Alexey, N. , UBORSKY, Dimitry, V. , LYGIN, Alexander, V. , COKER, Catalina, L. , CANICH, Jo Ann, M.
发明人： VOSKOBOYNIKOV, Alexander, Z. , RAYABOV, Alexey, N. , UBORSKY, Dimitry, V. , LYGIN, Alexander, V. , COKER, Catalina, L. , CANICH, Jo Ann, M.
IPC分类号： C07F17/00 , C08F10/00 , C08F4/64
CPC分类号： C07F17/00
摘要： A metallocene compound is represented by the formula (1): AMX n-1 wherein M is a transition metal atom having a coordination number of n selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom; A is a substituted monocyclic or polycyclic arenyl ligand pi-bonded to M, wherein said arenyl ligand includes at least one halogen substituent directly bonded to any sp 2 carbon atom at a bondable ring position of the ligand; and the or each X is a univalent anionic ligand, or two X are joined and bound to the metal atom to form a metallocycle ring, or two X are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand.
摘要翻译：金属茂化合物由式（1）表示：其中M是具有选自周期表第3,4,5或6族的配位数n的过渡金属原子的元素，或镧系金属原子，或锕系金属原子; A是与M键合键合的取代的单环或多环的烷基配体，其中所述的异戊基配体包括至少一个与配体的可键合环位置上直接连接到任何sp 2碳原子上的卤素取代基; 并且该X或每个X是一价阴离子配体，或两个X连接并结合到金属原子上以形成金属环，或者两个X连接形成螯合配体，二烯配体或亚烷基配体。

2. 发明申请

WO2007070046A1 HALOGEN SUBSTITUTED HETEROATOM-CONTAINING METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的卤素取代的含异戊烯的金属化合物
公开(公告)号：WO2007070046A1
公开(公告)日：2007-06-21
申请号：PCT/US2005/045292
申请日：2005-12-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , NIKULIN, Mikhail, V. , LYGIN, Alexander, V. , COKER, Catalina, L. , CANICH, Jo Ann, M. , UBORSKY, Dmitry, V.
发明人： VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , NIKULIN, Mikhail, V. , LYGIN, Alexander, V. , COKER, Catalina, L. , CANICH, Jo Ann, M. , UBORSKY, Dmitry, V.
IPC分类号： C08F10/00 , C08F4/6592 , C07F17/00
CPC分类号： C07F17/00 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F2420/02 , C08F2420/05 , C08F4/6592
摘要： Halogen substituted metallocene compounds are described and comprise one or more monocyclic or polycyclic ligands that are pi-bonded to the metal atom and include at least one halogen substituent directly bonded to an sp 2 carbon atom at a bondable ring position of the ligand, wherein the or at least one ligand has one or more ring heteroatoms in its cyclic structure. When combined with a suitable activator, these compounds show activity in the polymerization of olefins, such as ethylene and propylene.
摘要翻译：描述了卤素取代的茂金属化合物，并且包含一个或多个单键或多环配位体，其与金属原子键合，并且包含至少一个与可结合环上的sp 2碳原子键合的卤素取代基配体的位置，其中所述或至少一个配体在其环状结构中具有一个或多个环杂原子。当与合适的活化剂组合时，这些化合物在烯烃如乙烯和丙烯的聚合中显示出活性。

3. 发明申请

WO2007070045A1 PREPARATION OF SUBSTITUTED BRIDGED INDENYL AND RELATED LIGANDS 审中-公开
标题翻译：取代的桥梁和相关配置的准备
公开(公告)号：WO2007070045A1
公开(公告)日：2007-06-21
申请号：PCT/US2005/045284
申请日：2005-12-14
申请人： EXXONMOBIL CHEMICAL PATENTS, INC. , VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , NIKULIN, Mikhail, V. , LYGIN, Alexander, V. , COKER, Catalina, L. , CANICH, Jo Ann, M.
发明人： VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , NIKULIN, Mikhail, V. , LYGIN, Alexander, V. , COKER, Catalina, L. , CANICH, Jo Ann, M.
IPC分类号： C08F4/6592
CPC分类号： B01J31/182 , C07F7/083 , C08F10/00 , C08F4/65927
摘要： A process for preparing a chelating ligand of the formula (II) from a chelating ligand of the formula (I) via an sp 2 -sp 2 or sp 2 -sp 3 coupling reaction with an organometallic compound of the formula (III). wherein B is a bridging group that is bonded to L 1 and L 2 in formula (I) and to L 3 and L 4 in formula (II); L 1 is a substituted monocyclic or polycyclic ligand that comprises at least one chlorine, bromine, iodine, or sulfonate substituent, directly bonded to an sp2 carbon atom of the ring structure of the ligand; L 2 is a monoanionic ligand; or L 2 may, independently, be defined as L 1 ; L 3 is the same group as L 1 , but said at least one chlorine, bromine, iodine, or sulfonate substituent is replaced with a hydrocarbyl, substituted hydrocarbyl, halocarbyl, or substituted halocarbyl fragment; L 4 is the same group as L 2 , though, when L 2 is defined as L 1 , L 4 may be the same as L 3 or L 1 ; R 1 is a hydrocarbyl, substituted hydrocarbyl, halocarbyl, or substituted halocarbyl; M 1 is an element of group 1, 2, 12, 13 or 14 of the Periodic Table of the Elements; each X 2 , if present, is selected independently from the group consisting of halogen atoms, the hydroxyl group, alkoxy groups, aryloxy groups, mesylate, tosylate and triflate; r is 1, 2 or 3, and t is 0, 1 or 2, where r + t corresponds to the oxidation number of M 1 .
摘要翻译：一种通过式（I）的螯合配体经由sp2-2sp2或sp2-2制备式（II）的螯合配体的方法与式（III）的有机金属化合物进行偶联反应。其中B是结合到式（I）中的L 1和L 2的桥连基团和L 3和L 3 式（II）中的4 <！ - SIPO < L 1是取代的单环或多环配体，其包含直接键合到配体的环结构的sp2碳原子上的至少一个氯，溴，碘或磺酸盐取代基; L 2是单阴离子配体; 或L 2可以独立地定义为L 1; L 3是与L 1相同的基团，但是所述至少一个氯，溴，碘或磺酸酯取代基被烃基，取代的烃基，卤代烃基或取代的卤代烃基片段; L 4是与L 2相同的基团，尽管当L 2定义为L 1时，L ^{4 可以与L 3或L 1相同; R 1是烃基，取代的烃基，卤代烃基或取代的卤代烃基; M 1是元素周期表第1,2,12,13或14族的元素; 每个X 2，如果存在，独立地选自卤素原子，羟基，烷氧基，芳氧基，甲磺酸酯，甲苯磺酸酯和三氟甲磺酸酯; r为1,2或3，t为0,1或2，其中r + t对应于M 1的氧化数。}

4. 发明申请

WO2007070041A1 HALOGEN SUBSTITUTED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的卤素取代的金属化合物
公开(公告)号：WO2007070041A1
公开(公告)日：2007-06-21
申请号：PCT/US2005/045244
申请日：2005-12-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , COKER, Catalina, L. , CANICH, Jo Ann, M. , VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , NIKULIN, Mikhail, V. , LYGIN, Alexander, V.
发明人： COKER, Catalina, L. , CANICH, Jo Ann, M. , VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , NIKULIN, Mikhail, V. , LYGIN, Alexander, V.
IPC分类号： C07F17/00 , C08F10/00 , C08F4/64
CPC分类号： C07F17/00
摘要： A metallocene compound is represented by the formula (1): wherein: M is a Group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom, preferably a Group 4 transition metal atom selected from titanium, zirconium or hafnium; E is a substituted or unsubstituted monocyclic or polycyclic arenyl ligand pi-bonded to M; A is a substituted or unsubstituted polycyclic arenyl ligand that is pi-bonded to M and has a different ring structure than the E ligand; at least one of the A and E ligands includes at least one halogen substituent directly bonded to an sp 2 carbon at a bondable ring position; Y is a bridging group containing at least one Group 13, 14, 15, or 16 element and any single position of the ring structure of A and to any single position of the ring structure of E; and y is zero or 1, indicating the absence (y = 0) or presence (y =1) of Y; and each X is a univalent anionic ligand, or two X are joined and bound to the metal atom to form a metallocycle ring, or two X are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand; provided that when E is an unsubstituted cyclopentadienyl ligand, either y is one or A is not 2-bromofluorenyl or 2,7-dibromofluorenyl.
摘要翻译：金属茂化合物由式（1）表示：其中：M是第3,4,5或6族过渡金属原子，或镧系元素金属原子或锕系金属原子，优选选自钛的第4族过渡金属原子，锆或铪; E是与M键合的取代或未取代的单环或多环的烷基配体; A是取代或未取代的与M配体结合并具有不同于E配体的环结构的多环烷基配体; A和E配体中的至少一个配体包括在可键合的环位置上直接键合到sp 2 O 2上的至少一个卤素取代基; Y是含有至少一个第13,14,15或16族元素和A的环结构的任何单个位置和E的环结构的任何单个位置的桥连基团; y为0或1，表示Y不存在（y = 0）或存在（y = 1）; 并且每个X是一价阴离子配体，或两个X连接并结合到金属原子以形成金属环，或者两个X连接形成螯合配体，二烯配体或亚烷基配体; 条件是当E是未取代的环戊二烯基配体时，y是1或A不是2-溴芴基或2,7-二溴芴基。

5. 发明申请

WO2006065906A2 HALOGEN SUBSTITUTED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的卤素取代的金属化合物
公开(公告)号：WO2006065906A2
公开(公告)日：2006-06-22
申请号：PCT/US2005/045245
申请日：2005-12-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , COKER, Catalina, L. , CANICH, Jo Ann, M. , VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , NIKULIN, Mikhail, V. , LYGIN, Alexander, V. , IZMER, Vyatcheslav, V. , ASACHENKO, Andrey
发明人： COKER, Catalina, L. , CANICH, Jo Ann, M. , VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , NIKULIN, Mikhail, V. , LYGIN, Alexander, V. , IZMER, Vyatcheslav, V. , ASACHENKO, Andrey
IPC分类号： C08F10/00 , C08F4/6592 , C07F17/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： Ametallocene compound is represented by the formula (1): A 2 Y y MX n-2 wherein: M is a transition metal atom having a coordination number of n selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom; each A is independently a substituted polycyclic arenyl ligand pi-bonded to M, each A ligand includes at least one halogen substituent directly bonded to an sp 2 carbon at a bondable ring position and, when each A is a substituted indenyl ligand and y is equal to one and the ligand includes at least one chloro, bromo or iodo substituent at the 4, 5, or 6 position of the indenyl ligand, then A also includes at least one other substituent in the indenyl ligand selected from hydrocarbyl, substituted hydrocarbyl, halogen, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, substituted germylcarbyl, or other heteroatom substituents wherein the heteroatom is bonded directly to a ring carbon of the ring structure ligand and is boron, a Group 15 atom, or a Group 16 atom, preferably boron, nitrogen, oxygen, phosphorus, or sulfur; Y is an optional bridging group containing at least one Group 13, 14, 15, or 16 element and is bonded to any single position of the ring structure of A, y is zero or 1, indicating the absence (y = 0) or presence (y =1) of Y; and the or each X is a univalent anionic ligand, or two X are joined and bound to the metal atom to form a metallocycle ring, or two X are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand; provided that when y is equal to 1, then A is not 5,6-dichloroindenyl or an indenyl group having a fluoro- or chloro substituent at the 7 position and a hydrocarbyl or substituted hydrocarbyl substituent at the 4 position, and provided further that when y is equal to 0, then A is not 5,6-difluoroindenyl.
摘要翻译：亚茂金属化合物由式（1）表示：其中：M是具有一个（C 1 -C 6）选自元素周期表第3,4,5或6族的n的配位数，或镧系元素金属原子或锕系金属原子; 每个A独立地是与M键合的取代的多环烷基配体，每个A配位体包括至少一个在可键合的环位置直接键合到sp 2 O 2上的卤素取代基，并且当每个A是取代的茚基配体并且y等于1，并且配体在茚基配体的4,5或6位包含至少一个氯，溴或碘取代基，则A还包括所选择的茚基配体中的至少一个其它取代基由烃基，取代的烃基，卤素，卤代烃基，取代的卤代烃基，甲硅烷基，取代的甲硅烷基，甲硅烷基，取代的烯基羰基或其它杂原子取代基，其中杂原子直接键合到环结构配体的环碳上，并且是硼，，或16族原子，优选硼，氮，氧，磷或硫; Y是任选的含有至少一个第13,14,15或16族的桥连基团，并且键合到A的环结构的任何单个位置，y为0或1，表示不存在（y = 0）或存在（y = 1）; 并且该X或每个X是一价阴离子配体，或两个X连接并结合到金属原子上以形成金属环，或者两个X连接形成螯合配体，二烯配体或亚烷基配体; 条件是当y等于1时，A不是5,6-二氯茚基或在7位具有氟或氯取代基的茚基和在4位上的烃基或取代的烃基取代基，并进一步提供当 y等于0，那么A不是5,6-二氟茚基。

6. 发明申请

WO2007070038A1 HALOGEN SUBSTITUTED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的卤素取代的金属化合物
公开(公告)号：WO2007070038A1
公开(公告)日：2007-06-21
申请号：PCT/US2005/045137
申请日：2005-12-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , NIKULIN, Mikhail, V. , LYGIN, Alexander, V. , IZMER, Vyatcheslav, V. , ASACHENKO, Andrei, F. , COKER, Catalina, L. , CANICH, Jo, Ann, M.
发明人： VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , NIKULIN, Mikhail, V. , LYGIN, Alexander, V. , IZMER, Vyatcheslav, V. , ASACHENKO, Andrei, F. , COKER, Catalina, L. , CANICH, Jo, Ann, M.
IPC分类号： C07F17/00 , C08F4/6592 , C08F10/02
CPC分类号： C08F10/02 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F110/02 , C08F210/16 , C08F4/6592 , C08F4/65925 , C08F2500/03 , C08F210/14
摘要： A metallocene compound comprises a transition metal and at least one substituted monocyclic or polycyclic arene ligand bonded to the transition metal, wherein said arene ligand comprises at least one halogen substituent directly bonded to an sp 2 carbon atom at a bondable ring position of an aromatic five-membered ring of said arene ligand.
摘要翻译：茂金属化合物包含过渡金属和至少一个与过渡金属键合的取代的单环或多环芳族配体，其中所述芳族配体包含至少一个直接连接到sp 2 O 2原子上的卤素取代基所述芳族配体的芳族五元环的可键合环位置。

7. 发明申请

WO2006065809A2 HETEROATOM BRIDGED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的杂原子桥联金属茂化合物
公开(公告)号：WO2006065809A2
公开(公告)日：2006-06-22
申请号：PCT/US2005/045056
申请日：2005-12-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , VOSKOBOYNIKOV, Alexander, Z. , IZMER, Vyatcheslav, V. , ASACHENKO, Andrei, F. , NIKULIN, Mikhail, V. , RYABOV, Alexey, N. , LEBEDEV, Artyom, Y. , COKER, Catalina, L. , CANICH, Jo Ann, M.
发明人： VOSKOBOYNIKOV, Alexander, Z. , IZMER, Vyatcheslav, V. , ASACHENKO, Andrei, F. , NIKULIN, Mikhail, V. , RYABOV, Alexey, N. , LEBEDEV, Artyom, Y. , COKER, Catalina, L. , CANICH, Jo Ann, M.
IPC分类号： C08F10/00 , C08F4/64 , C07F17/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： This invention relates to a transition metal compound represented by the formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is: 1) a substituted or unsubstituted indenyl ligand that is bonded to Y through the four, five, six or seven position of the indenyl ring, or 2) a substituted or unsubstituted heteroindenyl ligand that is bonded to Y through the four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom, or 3) a substituted or unsubstituted fluorenyl ligand that is bonded to Y through the one, two, three, four, five, six, seven or eight position of the fluorenyl ring, or 4) a substituted or unsubstituted heterofluorenyl ligand that is bonded to Y through the one, two, three, four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom; A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand; Y is a Group 15 or 16 bridging heteroatom substituent that is bonded via the heteroatom to E and A; and X are, independently, univalent anionic ligands, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand. This invention further relates to catalyst systems comprising the above transiotioon metal compounds , activators and optional supports and their use to polymerize or oligomerize olefins.
摘要翻译：本发明涉及由下式表示的过渡金属化合物：其中M为3,4,5或6族过渡金属原子或镧系金属原子或act系金属原子; E为：1）取代或未取代的茚基配体，其通过茚基环的四，五，六或七位与Y键合，或2）取代或未取代的杂茚基配体，其通过四个，五个或六个位置，条件是键合位置不同于环杂原子的位置，或3）取代或未取代的芴基配体，其通过一个，两个，三个，四个，五个，6,7或8位的芴基环，或4）取代或未取代的杂芴基配体，其通过杂茚基环的1,2,3,4,5或6位与Y结合，条件是键合位置与环杂原子的位置不同; A是取代或未取代的环戊二烯基配体，取代或未取代的杂环戊二烯基配体，取代或未取代的茚基配体，取代或未取代的杂茚基配体，取代或未取代的芴基配体，取代或未取代的杂芴基配体或其它单阴离子配体 ; Y是通过杂原子与E和A键合的第15族或第16族桥联杂原子取代基; 和X独立地为一价阴离子配体，或两个X连接并键合到金属原子上形成金属环，或者两个X连接形成螯合配体，二烯配体或亚烷基配体。本发明进一步涉及包含上述转铁基金属化合物，活化剂和任选的载体的催化剂体系及其用于聚合或低聚烯烃的用途。

8. 发明申请

WO2006065844A2 PROCESS FOR PRODUCING SUBSTITUTED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：生产用于烯烃聚合的取代的金属化合物的方法
公开(公告)号：WO2006065844A2
公开(公告)日：2006-06-22
申请号：PCT/US2005/045140
申请日：2005-12-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , COKER, Catalina, L. , CANICH, Jo, Ann, M.
发明人： VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , COKER, Catalina, L. , CANICH, Jo, Ann, M.
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： A process for producing a substituted metallocene compound comprises reacting a first compound with a transfer-agent, wherein the first compound comprises a complex of a transition metal atom selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom and at least one monocyclic or polycyclic ligand that is pi-bonded to M and is substituted with at least one halogen or sulfonate substituent and the transfer-agent comprises a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, or germylcarbyl radical capable of replacing said at least one halogen or sulfonate substituent of said first compound under reaction conditions.
摘要翻译：制备取代的茂金属化合物的方法包括使第一化合物与转移剂反应，其中第一化合物包含选自元素周期表第3,4,5或6族的过渡金属原子的络合物，或镧系元素金属原子或锕系金属原子和至少一个单键或多环配体，其与M键合并被至少一个卤素或磺酸盐取代基取代，并且转移剂包含烃基，取代的烃基，卤代烃基，取代的卤代烃基，甲硅烷基或甲锗烷基，其能够在反应条件下替代所述第一化合物的所述至少一个卤素或磺酸盐取代基。

9. 发明申请

WO2006065843A2 HALOGEN SUBSTITUTED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的卤素取代的金属化合物
公开(公告)号：WO2006065843A2
公开(公告)日：2006-06-22
申请号：PCT/US2005/045138
申请日：2005-12-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , VOSKOBOYNIKOV, Alexander, Z. , NIKULIN, Mikhail, V. , IZMER, Vyatcheslav, V. , ASACHENKO, Andrei, F. , RYABOV, Alexey, N. , COKER, Catalina, L. , CANICH, Jo, Ann, M.
发明人： VOSKOBOYNIKOV, Alexander, Z. , NIKULIN, Mikhail, V. , IZMER, Vyatcheslav, V. , ASACHENKO, Andrei, F. , RYABOV, Alexey, N. , COKER, Catalina, L. , CANICH, Jo, Ann, M.
IPC分类号： C08F10/00 , C07F17/00 , C08F4/6592
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： A metallocene compound comprising a transition metal, a first substituted or unsubstituted indenyl or fluorenyl ligand pi-bonded to the transition metal, a second monoanionic ligand bonded to the transition metal, and a divalent bridging group bonded to the indenyl ligand and said second monoanionic ligand, wherein said bridging group is connected to the four, five, six or seven position of the indenyl ligand or to the one, two, three, four, five, six, seven or eight position of the fluorenyl ligand, and wherein at least one of one of the first and second ligands comprises at least one halogen substituent directly bonded to any sp 2 carbon atom at a bondable ring position of the ligand.
摘要翻译：包含过渡金属，与过渡金属键合的第一取代或未取代的茚基或芴基配体的茂金属化合物，与过渡金属键合的第二单离子配体和键合到茚基配体和所述第二单离子配体的二价桥连基团其中所述桥连基连接到茚基配体的四，五，六或七位，或连接到芴基配体的一个，二个，三个，四个，五个，六个，七个或八个位置，并且其中至少一个第一和第二配体之一包含在配体的可键合环位置处直接键合到任何sp2碳原子上的至少一个卤素取代基。

10. 发明申请

WO2005108435A1 PHOSPHORUS BRIDGED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的磷酸盐桥联金属化合物
公开(公告)号：WO2005108435A1
公开(公告)日：2005-11-17
申请号：PCT/US2005/008093
申请日：2005-03-11
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , VOSKOBOYNIKOV, Alexander, Z. , KAZYULKIN, Denis, N. , IZMER, Vyatcheslav, V. , RYABOV, Alexey, N. , CANICH, Jo, Ann, M.
发明人： VOSKOBOYNIKOV, Alexander, Z. , KAZYULKIN, Denis, N. , IZMER, Vyatcheslav, V. , RYABOV, Alexey, N. , CANICH, Jo, Ann, M.
IPC分类号： C08F4/64
CPC分类号： B01J31/2295 , B01J31/143 , B01J31/146 , B01J2531/0225 , B01J2531/0297 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07F17/00 , C08F4/65912 , C08F10/02 , C08F110/02 , C08F210/02 , C08F210/16 , Y10S526/943 , C08F4/65927 , C08F2500/03 , C08F210/14
摘要： This invention relates to metallocene compounds represented by formula: wherein, M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is a substituted or unsubstituted indenyl ligand that is bonded to Y through the two position of the indenyl ring; A is bonded to Y, and is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substututed or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand, or A may, independently, be defined as E; Y is a phosphorus containing group that is bonded to both E and A, and is bonded via the phosphorus atom to E; and X are, independently, univalent anionic ligands, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand.
摘要翻译：本发明涉及由下式表示的茂金属化合物：其中M是3,4,5或6族过渡金属原子，或镧系元素金属原子或锕系金属原子; E是通过茚基环的两个位置与Y键合的取代或未取代的茚基配体; A与Y结合，为取代或未取代的环戊二烯基配体，取代或未取代的杂环戊二烯基配体，取代或未取代的茚基配体，取代或未取代的杂茚基配体，取代或未取代的芴基配体，取代或未取代的芴基配位体，或其它单阴离子配体，或者A可以独立地定义为E; Y是与E和A键合的含磷基团，通过磷原子与E结合; X独立地为一价阴离子配体，或两者X连接并结合到金属原子以形成金属环，或两者X连接形成螯合配体，二烯配体或亚烷基配体。

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