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    • 2. 发明申请
    • POLYESTER NANOCOMPOSITES FOR HIGH BARRIER APPLICATIONS
    • 用于高阻挡应用的聚酯纳米复合材料
    • WO1999032403A1
    • 1999-07-01
    • PCT/US1997024103
    • 1997-12-30
    • EASTMAN CHEMICAL COMPANY
    • EASTMAN CHEMICAL COMPANYBARBEE, Robert, BoydMATAYABAS, James, Christopher, Jr.TREXLER, Jack, Wesley, Jr.PINER, Rodney, Layne
    • C01B33/44
    • C01B33/44C08K9/04C08K2201/008
    • The present invention relates to a composition comprising a polymer having dispersed therein at least one layered clay material which has been cation exchanged with an organic cation salts represented by Formula (I) wherein M represents either nitrogen or phosphorous; X represents an anion selected from the group consisting of halogen, hydroxide, or acetate anions, preferably chloride and bromide; R1 is selected from the group consisting of straight and branched alkyl groups having at least 8 carbon atoms; R2, R3, and R4 are independently selected from straight or branched alkyl groups having 1 to four carbon atoms; and at least one expanding agent which is compatible with said polymer. Preferred polymers include polyesters. The compositions of the present invention show vastly improved platelet separation as evidenced by higher than previously reported basal spacing.
    • 本发明涉及一种组合物,其包含分散有至少一种层状粘土材料的聚合物,所述层状粘土材料已经与由式(I)表示的有机阳离子盐阳离子交换,其中M表示氮或磷; X“表示选自卤素,氢氧根或乙酸根阴离子,优选氯化物和溴化物的阴离子; R1选自具有至少8个碳原子的直链和支链烷基; R 2,R 3和R 4独立地选自具有1至4个碳原子的直链或支链烷基; 和与所述聚合物相容的至少一种发泡剂。 优选的聚合物包括聚酯。 本发明的组合物显示出大大改善的血小板分离,这通过高于先前报道的基础间距来证明。