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    • 1. 发明申请
    • STABLE AMINO-CONTAINING POLYMER BLENDS
    • 稳定的含氨基聚合物混合物
    • WO1997045490A1
    • 1997-12-04
    • PCT/US1997008809
    • 1997-05-28
    • EASTMAN CHEMICAL COMPANY
    • EASTMAN CHEMICAL COMPANYCOLLINS, Martha, JeanTAYLOR, James, Wayne
    • C08L101/06
    • C09D11/106
    • This invention provides the composition, preparation, and end-use of waterborne cross-linking technology-based compositions prepared from water-based latexes. The invention provides a water-based latex comprising dispersed, waterborne amino-functional polymer particles; dispersed, waterborne acetoacetoxy-functional polymer particles; and water. In a preferred embodiment, a latex of the invention comprises dispersed, waterborne polymeric (polyamino)enamine (PPAE) particles; dispersed, waterborne acetoacetoxy-functional polymer particles; and water. The PPAE is the reaction product of a surfactant-stabilized acetoacetoxy-functional polymer (SAAP) and a poly(alkylenimine). The water-based latexes of the invention provide stable emulsions containing a blend of waterborne polymer particles which undergo cross-linking upon film formation. The latex films or coatings may be cured at ambient temperatures or may be thermally cured. The latex is useful in a variety of coating compositions such as, for example, paints, inks, sealants, and adhesives.
    • 本发明提供了由水性胶乳制备的基于水性交联技术的组合物的组合物,制备和最终用途。 本发明提供一种包含分散的水性氨基官能聚合物颗粒的水性胶乳; 水性乙酰乙酰氧基官能聚合物颗粒; 和水。 在优选的实施方案中,本发明的胶乳包含分散的水性聚合物(聚氨基)烯胺(PPAE)颗粒; 水性乙酰乙酰氧基官能聚合物颗粒; 和水。 PPAE是表面活性剂稳定的乙酰乙酰氧基官能聚合物(SAAP)和聚(亚烷基亚胺)的反应产物。 本发明的水基胶乳提供了稳定的乳液,其含有在成膜时经历交联的水性聚合物颗粒的共混物。 胶乳膜或涂层可以在环境温度下固化或者可以热固化。 胶乳可用于各种涂料组合物,例如油漆,油墨,密封剂和粘合剂。
    • 4. 发明申请
    • SURFACTANT-CONTAINING ACETOACETOXY-FUNCTIONAL AND ENAMINE-FUNCTIONAL POLYMERS
    • 含有表面活性剂的乙酰氧基官能和功能聚合物
    • WO1997045468A1
    • 1997-12-04
    • PCT/US1997008808
    • 1997-05-28
    • EASTMAN CHEMICAL COMPANY
    • EASTMAN CHEMICAL COMPANYCOLLINS, Martha, JeanTAYLOR, James, Wayne
    • C08F220/04
    • C09J133/062C08F8/30C08F220/28C08F2800/20C09D11/106C09D133/062Y10S525/902C08F265/04
    • Surfactant-containing acetoacetoxy-functional polymers (SAAPs) are described. The acetoacetoxy-functional polymer may be a surfactant-containing enamine-functional polymer and more preferably a surfactant-containing, polymeric (polyamino)enamine (PPAE). The PPAE is the reaction product of a surfactant-containing acetoacetoxy-functional polymer (SAAP) and a poly(alkylenimine). The polymers may be prepared as waterborne polymer compositions, such as latexes. The waterborne polymer compositions can be prepared with high solids content while maintaining low viscosity. Waterborne polymer compositions containing the polymers of the inventions are useful in a variety of coating formulations such as, for example, paints, inks, sealants, and adhesives. When used in coating formulations, the polymers of the invention provide adhesion and crosslinking in the final film or coating. The film or coating may be cured at ambient temperatures or may be thermally cured.
    • 描述含表面活性剂的乙酰乙酰氧基官能聚合物(SAAP)。 乙酰乙酰氧基官能聚合物可以是含表面活性剂的烯胺官能聚合物,更优选含表面活性剂的聚合(聚氨基)烯胺(PPAE))。 PPAE是含表面活性剂的乙酰乙酰氧基官能聚合物(SAAP)和聚(亚烷基亚胺)的反应产物。 聚合物可以制备为水性聚合物组合物,例如胶乳。 水性聚合物组合物可以以高固体含量制备,同时保持低粘度。 含有本发明聚合物的水性聚合物组合物可用于各种涂料配方,例如涂料,油墨,密封剂和粘合剂。 当用于涂料制剂时,本发明的聚合物在最终的膜或涂层中提供粘合和交联。 膜或涂层可以在环境温度下固化或者可以热固化。