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1. 发明申请

WO2006136617A2 MIXTURE OF SULFIDE DYES 审中-公开
标题翻译：硫酸染料混合物
公开(公告)号：WO2006136617A2
公开(公告)日：2006-12-28
申请号：PCT/EP2006/066325
申请日：2006-09-13
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , FRÖHLING, Beate , CREMER, Christian , ELIU, Victor, Paul , WALLQUIST, Olof
发明人： CREMER, Christian , ELIU, Victor, Paul , WALLQUIST, Olof
CPC分类号： A61Q5/10 , A61K8/46 , A61K8/49 , A61K8/492 , A61K8/4926 , A61K8/4946 , A61K8/496 , A61K8/498 , C09B67/0033 , C09B67/0034
摘要： Disclosed are mixtures of sulfide dyes and dyeing compositions comprising mixtures of sulfide dyes. The dye mixtures are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.
摘要翻译：公开了硫化染料和包含硫化染料混合物的染色组合物的混合物。染料混合物可用于染色有机材料，例如角蛋白纤维，优选人发。

2. 发明申请

WO2005012437A1 CATIONIC DIRECT DYES 审中-公开
标题翻译：阳光直射
公开(公告)号：WO2005012437A1
公开(公告)日：2005-02-10
申请号：PCT/EP2004/051481
申请日：2004-07-14
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ELIU, Victor, Paul , FRÖHLING, Beate
发明人： ELIU, Victor, Paul , FRÖHLING, Beate
IPC分类号： C09B44/16
CPC分类号： C09B44/16
摘要： The present invention relates to novel the cationic dyes of formula (1) wherein R 1 is an unsubstituted or substituted C 1 -C 14 alkyl or an aryl radical; X - is an anion; R 3 is an unsubstituted or substituted C 1 -C 14 alkyl, aryl radical, C 1 -C 6 alkoxy, cyanid, nitro or halide; n is 1 or 2; and if n is 1, then R 2 is hydrogen, unsubstituted or substituted C 1 -C 14 alkyl; or if n is 2, then R 2 is an unsubstituted or substituted C 1 -C 14 alkylen. Further, the present invention relates to compositions thereof, especially comprising other dyes, to processes for the preparation thereof and to the use thereof in the dyeing of organic material, such as keratin, wool, leather, silk, paper, cellulose or polyamides, and preferably human hair.
摘要翻译：本发明涉及式（1）的阳离子染料，其中R 1是未取代或取代的C 1 -C 14烷基或芳基; X - 是阴离子; R 3是未取代或取代的C 1 -C 14烷基，芳基，C 1 -C 6烷氧基，氰基，硝基或卤素; n为1或2; 如果n为1，则R2为氢，未取代或取代的C 1 -C 14烷基; 或者如果n为2，则R2为未取代或取代的C1-C14亚烷基。此外，本发明涉及其组合物，特别是其它染料，其制备方法及其在染色有机材料如角蛋白，羊毛，皮革，丝，纸，纤维素或聚酰胺中的用途，以及优选人发。

3. 发明申请

WO2004019896A1 METHOD OF COLOURING POROUS MATERIAL 审中-公开
标题翻译：多孔材料着色方法
公开(公告)号：WO2004019896A1
公开(公告)日：2004-03-11
申请号：PCT/EP2003/009416
申请日：2003-08-26
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ADAM, Jean-Marie , YOUSAF, Taher , FRÖHLING, Beate , ELIU, Victor, Paul
发明人： ADAM, Jean-Marie , YOUSAF, Taher , FRÖHLING, Beate , ELIU, Victor, Paul
IPC分类号： A61K7/13
CPC分类号： A61K8/4966 , A61Q5/065 , C07C245/24 , C09B67/0079
摘要： A method of colouring porous material, especially human hair, is described, which method comprises applying to the material being coloured, in any desired order successively, or simultaneously, a) at least one capped diazonium compound of Formula (1) and/or at least one compound of Formula (2) and/or at least one compound of Formula (3) wherein Q is an unsubstituted or substituted aromatic or heterocyclic residue, R is the radical of an unsubstituted or substituted, water-soluble aliphatic or aromatic amine, and T is an unsubstituted or substituted, water-soluble aliphatic or aromatic residue, wherein at least one of the groups must contain a radical imparting water solubility, and a) at least one water-soluble coupling component under conditions such that, initially, coupling does not take place, and then causing the capped diazonium compound present on the material to react with the coupling component.
摘要翻译：描述了一种着色多孔材料，特别是人发的方法，该方法包括以任何所需顺序依次或同时施用着色的材料，a）至少一种式（1）的封端重氮化合物和/或在至少一种式（2）的化合物和/或至少一种式（3）的化合物，其中Q是未取代或取代的芳族或杂环残基，R是未取代或取代的水溶性脂族或芳族胺的基团，并且T是未取代或取代的水溶性脂族或芳族残基，其中所述基团中的至少一个必须含有自由基赋予水溶性，和a）至少一种水溶性偶联组分，不会发生，然后使存在于材料上的覆盖的重氮化合物与偶联组分反应。

4. 发明申请

WO2007003506A1 PYRIDO-THIAZINIUM DYES 审中-公开
公开(公告)号：WO2007003506A1
公开(公告)日：2007-01-11
申请号：PCT/EP2006/063374
申请日：2006-06-21
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ELIU, Victor, Paul , FRÖHLING, Beate , KAUFFMANN, Dominique
发明人： ELIU, Victor, Paul , FRÖHLING, Beate , KAUFFMANN, Dominique
IPC分类号： C07D513/04 , C09B23/00 , A61K8/49 , A61Q5/10
CPC分类号： A61Q5/10 , A61K8/49 , C07D513/04 , C09B23/0091
摘要： Disclosed is a method of dyeing keratin-containing fibers comprising treating the fiber with at least one compound of formula (1), wherein R 1 , R 2 , R 3 , R 4 independently from each other are hydrogen; hydroxy; -S-H; -S-C 1 -C 12 alkyl; halogen; C 1 -C 12 alkyl or C 1 -C 12 alkoxy, which may be substituted by one or more C 1 - C 5 alkyl, C 1 -C 5 -alkoxy, hydroxy, -(CO)-H or -(CO)-C 1 -C5alkyl; -NR 5 R 6 ; -NO 2 ; -(CO)H or (CO)-C 1 -C 5 alkyl; C 6 -C 12 aryl, C 6 -C 12 aryl-C 1 -C 4 alkyl or C 6 -C 12 aryl-C 1 -C 4 alkoxy, wherein the aryl moiety may be substituted by one or more C 1 -C 5 alkyl, C 1 -C 5 alkoxy, -(CO)-H or -(CO)-C 1 -C 5 alkyl; R 5 and R 6 independently from each other are hydrogen; hydroxy; C 1 -C 12 alkyl; hydroxy-C 1 - C 12 alkyl; -(CO)-H; -(CO)-C 1 -C 5 alkyl; phenyl or phenyl-C 1 -C 5 alkyl, wherein the phenyl moiety may be substituted by one or more C1-C 5 alkyl, C 1 -C 5 alkoxy, halogen, -NH2, mono-C 1 -C 5 alkylamino, di-C 1 -C5alkylamino, -NO 2 , carboxy or hydroxy; and An is an anion. Furthermore, the present invention relates to novel heterocyclic compounds, compositions thereof, especially comprising other dyes, and to processes for their preparation and application to hair dying.
摘要翻译：公开了一种染色含角蛋白纤维的方法，包括用至少一种式（1）化合物处理纤维，其中R 1，R 2，R 2， 3个，R 4彼此独立地是氢; 羟基; -S-H; -S-C _{1 -C _{12 烷基; 卤素; C 1 -C 12烷基或C 1 -C 12烷氧基，其可以被一个或多个 C 1 -C 5烷基，C 1 -C 5 - 烷氧基，羟基， - （CO） - H或 - （CO）-C 1 -C 5烷基; -NR _{5 - [R _{6 ; -NO _{2 ; - （CO）H或（CO）-C 1 -C 5烷基; C 6 -C 12芳基，C 6 -C 12芳基-C 1 H 12 C 1 -C 4烷基或C 6 -C 12芳基-C 1 -C 4 - 其中芳基部分可以被一个或多个C 1 -C 5烷基取代，C 1 -C 3亚烷基烷氧基， - （CO）-H或 - （CO）-C 1 -C 5烷基; R 5和R 6彼此独立地是氢; 羟基; ç_{1 -C _{12 烷基; 羟基-C 1 -C 12烷基; - （CO）-H; - （CO）-C _{1 -C _{5 烷基; 苯基或苯基-C 1 -C 5烷基，其中苯基部分可以被一个或多个C 1 -C 5烷基取代，C 1 -C 5烷基烷氧基，卤素，-NH 2，单-C 1 -C 5烷基氨基，二 - （C 1 -C 6）烷基氨基， C 1 -C 5烷基氨基，-NO 2 2，羧基或羟基; 而An是阴离子。此外，本发明涉及新颖的杂环化合物，其组合物，特别是其它染料，以及其制备和应用于染发的方法。}}}}}}}}}

5. 发明申请

WO2004072183A1 CATIONIC SUBSTITUTED HYDRAZONE DYES 审中-公开
标题翻译：阳离子取代的水痘染发剂
公开(公告)号：WO2004072183A1
公开(公告)日：2004-08-26
申请号：PCT/EP2004/050101
申请日：2004-02-09
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ELIU, Victor, Paul , FRÖHLING, Beate
发明人： ELIU, Victor, Paul , FRÖHLING, Beate
IPC分类号： C09B26/04
CPC分类号： C09B26/04 , A61K8/4926 , A61Q5/065
摘要： The present invention relates to novel cationic dyes of formula (1), (2) or (3) and wherein R 1 and R 2 are each independently of the other a C 1 -C 8 alkyl radical or an unsubstituted or substituted benzyl radical, R 3 is hydrogen, C 1 -C 8 alkyl, C 1 -C 8 alkoxy, cyanide or halide, and R 4 is a C 1 -C 8 alkyl radical or an unsubstituted or substituted aryl radical, and X is an anion. Further, the present invention relates to compositions thereof, especially comprising other dyes, to processes for the preparation thereof and to the use thereof in the dyeing of organic material, such as keratin fibers, especially hair; or wool, leather, silk, cellulose or polyamides, and preferably human hair.
摘要翻译：本发明涉及式（1），（2）或（3）的新型阳离子染料，其中R1和R2各自独立地为C1-C8烷基或未取代或取代的苄基，R3为氢，C1 C 1-8烷基，C 1 -C 8烷氧基，氰基或卤化物，R 4是C 1 -C 8烷基或未取代或取代的芳基，X是阴离子。此外，本发明涉及其组合物，特别是其它染料，其制备方法及其在染色有机材料如角蛋白纤维，特别是毛发中的用途; 或羊毛，皮革，丝绸，纤维素或聚酰胺，优选人发。

6. 发明申请

WO2006134051A1 CATIONIC OLIGOMERIC AZO DYES 审中-公开
标题翻译：阳离子低聚AZO染色
公开(公告)号：WO2006134051A1
公开(公告)日：2006-12-21
申请号：PCT/EP2006/062976
申请日：2006-06-07
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ELIU, Victor, Paul , FRÖHLING, Beate , KAUFFMANN, Dominique
发明人： ELIU, Victor, Paul , FRÖHLING, Beate , KAUFFMANN, Dominique
IPC分类号： A61K8/49 , A61K8/84 , A61Q5/10 , C07D403/00 , C08G73/02 , C09B44/16 , C09B69/10
CPC分类号： C09B44/16 , A61K8/4946 , A61K8/84 , A61K2800/57 , A61Q5/065 , C07D403/00 , C08G73/00 , C08G73/0273 , C08G73/0616 , C09B44/101 , C09B49/00 , C09B69/106
摘要： Disclosed are oligomeric cationic azo dyes of formula (I), wherein their salts, isomers, hydrates and other solvates, wherein R 1 is hydrogen; C 1 -C 12 alkyl, which may be substituted by one or more C 1 -C 5 alkyl, C 1 -C 5 -alkoxy, hydroxy or -(CO)-H; -(CO)-C 1 -C 5 alkyl; phenyl or phenyl-C 1 -C 4 alkyl, wherein the phenyl moiety may be substituted by one or more C 1 -C 5 alkyl, C 1 -C 5 alkoxy, halogen, -NH 2 , mono-C 1 -C 5 alkylamino, di-C 1 -C 5 alkylamino, -NO 2 , carboxy or hydroxy; R 2 is hydrogen; or C 1 -C 5 alkyl; X is C 1 -C 10 alkylene, which may be substituted by one or more C 1 -C 5 alkyl, hydroxy, C 1 -C 5 -alkoxy, amino, mono-C 1 -C 5 alkylamino, di-C 1 -C 5 alkylamino, -SH, and/or interrupted by one or more -O- or -S-S-; C 5 -C 10 cycloalkylene; C 5 -C 12 arylene; C 5 -C 12 arylene-(C 1 -C 10 alkylene); biphenylene, which may be substituted by one or more C 1 -C 5 alkyl, hydroxy, C 1 -C 5 -alkoxy, amino, mono-C 1 -C 5 alkylamino, di-C 1 -C 5 alkylamino, -SH, and/or interrupted by one or more -O-, C 1 -C 4 -alkylene, -NR 3 -, -S- or -S-S-; R 3 is hydrogen; C 1 -C 12 alkyl; C 2 -C 14 alkenyl; C 6 -C 12 aryl; C 6 -C 12 aryl-C 1 -C 12 alkyl; or C 1 -C 12 alkyl-C 6 -C 12 aryl; Y is an anion; Z is 1,3-thiazolyl; 1,2-thiazolyl; 1,3-benzothiazolyl; 2,3-benzothiazolyl; imidazolyl; 1,3,4-thiadiazolyl; 1,3,5-thiadiazolyl; 1,3,4-triazolyl; pyrazolyl; benzimidazolyl; benzopyrazolyl; pyridinyl; quinolinyl; pyrimidinyl; or isoxazolyl; and n is a number from 2-100. Furthermore, the present invention relates to novel cationic oligomeric azo dyes, compositions thereof, especially comprising other dyes, and to application for hair dying.
摘要翻译：公开了式（I）的低聚阳离子偶氮染料，其中其盐，异构体，水合物和其它溶剂合物，其中R 1是氢; C 1 -C 12烷基，其可以被一个或多个C 1 -C 5烷基取代， C 1 -C 5 - 烷氧基，羟基或 - （CO）-H; - （CO）-C _{1 -C _{5 烷基; 苯基或苯基-C 1 -C 4烷基，其中苯基部分可以被一个或多个C 1 -C 4烷基取代， C 1 -C 5烷基，C 1 -C 5烷氧基，卤素，-NH 2，C 1 -C 12烷基， C 1 -C 5烷基氨基，二-C 1 -C 5烷基氨基，-NO 2 2，羧基或羟基; R 2是氢; 或C 1 -C 5烷基; X是C 1 -C 10 - 亚烷基，其可以被一个或多个C 1 -C 5亚烷基取代，烷基，羟基，C 1 -C 5 - 烷氧基，氨基，C 1 -C 15烷基氨基，C 1 -C 6烷基氨基，-SH，和/或被一个或多个-O-或-SS-间隔的二-C 1 -C 5烷基氨基。 ç_{5 -C _{10 亚环烷基; ç_{5 -C _{12 亚芳基; ç_{5 -C _{12 亚芳基 - （C _{1 -C _{10 亚烷基）; 可以被一个或多个C 1 -C 5烷基取代的亚联苯基，羟基，C 1 -C 5烷基，亚烷基，烷氧基，氨基，单-C 1 -C 5烷基氨基，二-C 1 -C 5亚烷基烷基氨基，-SH和/或被一个或多个-O-，C 1 -C 4 - 亚烷基，-NR 3 - - ， - S-或-SS-; R 3是氢; ç_{1 -C _{12 烷基; ç_{2 -C _{14 烯基; ç_{6 -C _{12 芳基; ç_{6 -C _{12 芳基-C _{1 -C _{12 烷基; 或C 1 -C 12烷基-C 6 -C 12芳基;或C 1 -C 12烷基。 Y是阴离子; Z是1,3-噻唑基; 1,2-噻唑基; 1,3-苯并噻唑基; 2,3-苯并噻唑基; 咪唑; 1,3,4-噻二唑基; 1,3,5-噻二唑基; 1,3,4-三唑基; 吡唑; 苯并咪唑; 苯并吡唑; 吡啶基; 喹啉; 嘧啶; 或异恶唑基; n是2-100的数字。此外，本发明涉及新型阳离子低聚偶氮染料，其组合物，特别是其它染料，以及用于染发的应用。}}}}}}}}}}}}}}}}}}}}

7. 发明申请

WO2005097051A2 SULFIDE DYES 审中-公开
公开(公告)号：WO2005097051A2
公开(公告)日：2005-10-20
申请号：PCT/EP2005/051412
申请日：2005-03-29
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ELIU, Victor, Paul , FRÖHLING, Beate , KAUFFMANN, Dominique
发明人： ELIU, Victor, Paul , FRÖHLING, Beate , KAUFFMANN, Dominique
IPC分类号： A61K7/13
CPC分类号： C09B44/16 , A61K8/49 , A61K8/4926 , A61K8/4946 , A61K2800/94 , A61Q5/10 , C09B44/20 , C09B49/00
摘要： Formula (I) wherein R 1 and R 2 each independently from each other are a residue of an organic dye; Y 1 and Y 2 each independently from each other are unsubstituted or substituted, straightchain or branched, interrupted or uninterrupted -C 1 -C 10 alkylene-; -C 5 -C 10 cycloalkylene-; C 5 -C 10 arylene; or-C 5 -C 10 arylene-(C 1 -C 10 alkylene)-; Z 1 and Z 2 independently from each other are Formula (II) are each independently from each other hydrogen; or unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C 1 -C 14 alkyl; C 2 -C 14 alkenyl; C 6 -C 10 aryl; C 6 -C 10 aryl-C 1 -C 10 alkyl; or C 5 -C 10 alkyl(C 5 -C 10 aryl); r, q and n independently from each other are 0 or 1, if n is 0, Z 3 is hydrogen; and if n is 1, Z 3 is -S-; with the proviso that the method does not comprise treating the fiber with an enzyme of the type of a protein disulfidisomerase (EC 5.3.4.1). Further, the present invention relates to novel disulfid compounds, compositions thereof, especially comprising other dyes, and to processes for their preparation.
摘要翻译：式（I）其中R1和R2各自独立地为有机染料的残基; Y1和Y2各自独立地为未取代或取代的直链或支链，间断或不间断的-C 1 -C 10亚烷基 - ; -C 5 -C C10cycloalkylene-， C5-C10arylene; 或-C5-C10arylene-（C1-C10alkylene） - ; Z 1和Z 2彼此独立地是式（II）各自独立地为氢; 或未取代或取代的直链或支链的单环或多环，间断或不间断的C 1 -C 14烷基; C2-C14alkenyl; C6-C10芳基; C6-C10芳基-C1-C10烷基，或C 5 -C 10烷基（C 5 -C 10芳基）; r，q和n彼此独立地为0或1，如果n为0，则Z 3为氢; 如果n为1，则Z 3为-S-; 条件是该方法不包括用蛋白质二硫代异构酶类型的EC（EC 5.3.4.1）处理纤维。此外，本发明涉及新的二硫化物，其组合物，特别是其它染料，以及其制备方法。

8. 发明申请

WO2004083312A2 CATIONIC DIMERIC DYES 审中-公开
标题翻译：阳光二极管
公开(公告)号：WO2004083312A2
公开(公告)日：2004-09-30
申请号：PCT/EP2004/050268
申请日：2004-03-08
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ELIU, Victor, Paul , FRÖHLING, Beate
发明人： ELIU, Victor, Paul , FRÖHLING, Beate
IPC分类号： C09B44/10
CPC分类号： C09B44/10 , A61K8/4926 , A61K8/4946 , A61Q5/065 , Y10S8/919
摘要： The present invention relates to novel cationic dye of formula (1) and (1 a) wherein A is an organic radical of formula (2) or (3) wherein R 1 and R 2 are each independently of the other unsubstituted or substituted C 1 -C 14 alkyl or an aryl radical, R 3 is hydrogen, unsubstituted or substituted C 1 -C 14 alkyl, unsubstituted or substituted C 1 -C 14 alkoxy, cyan or halogenid, R 4 is hydrogen, unsubstituted or substituted C 1 -C 14 alkyl or an aryl radical, and X is an anion. Further, the present invention relates to compositions thereof, especially comprising other dyes, to processes for the preparation thereof and to the use thereof in the dyeing of organic material, such as keratin, wool, leather, paper, silk, cellulose or polyamides, and preferably human hair.
摘要翻译：本发明涉及式（1）和（1a）的新型阳离子染料，其中A是式（2）或（3）的有机基团，其中R 1和R 2各自独立地是其它未取代或取代的C 1 -C 14烷基或芳基，R 3为氢，未取代或取代的C 1 -C 14烷基，未取代或取代的C 1 -C 14烷氧基，氰基或卤素，R 4为氢，未取代或取代的C 1 -C 14烷基或芳基，X为阴离子。此外，本发明涉及其组合物，特别是其它染料，其制备方法及其在染色有机材料如角蛋白，羊毛，皮革，纸，丝，纤维素或聚酰胺中的用途，以及优选人发。

9. 发明申请

WO2004019897A1 METHOD OF COLOURING POROUS MATERIAL 审中-公开
标题翻译：多孔材料着色方法
公开(公告)号：WO2004019897A1
公开(公告)日：2004-03-11
申请号：PCT/EP2003/009417
申请日：2003-08-26
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , FRÖHLING, Beate , ELIU, Victor, Paul
发明人： FRÖHLING, Beate , ELIU, Victor, Paul
IPC分类号： A61K7/13
CPC分类号： A61K8/4966 , A61Q5/065 , C07C245/24 , C09B67/0079
摘要： A method of colouring porous material, especially human hair, is described, which method comprises applying to the material being coloured, in any desired order successively, or simultaneously, a) at least one capped diazonium compound and b) at least one cationic water-soluble aromatic coupling component, under conditions such that, initially, coupling does not take place, and then causing the capped diazonium compound present on the material to react with the coupling component.
摘要翻译：描述了多孔材料，特别是人发的着色方法，该方法包括以任何所需顺序连续地或同时施用着色的材料，a）至少一种封端的重氮化合物和b）至少一种阳离子水溶性聚合物，在最初不发生偶合的条件下，然后使存在于材料上的封端重氮化合物与偶联组分反应的条件下进行。

10. 发明申请

WO2003072657A1 PROCESS FOR THE PREPARATION OF CATIONIC AZO COMPOUNDS 审中-公开
标题翻译：制备阳离子AZO化合物的方法
公开(公告)号：WO2003072657A1
公开(公告)日：2003-09-04
申请号：PCT/EP2003/001732
申请日：2003-02-20
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ELIU, Victor, Paul , HAUSER, Julia
发明人： ELIU, Victor, Paul , HAUSER, Julia
IPC分类号： C09B44/16
CPC分类号： C09B44/10 , C09B43/40 , C09B44/16
摘要： A process for the preparation of certain cationic azo compounds is described, as well as the use thereof for dyeing keratin-containing fibres, especially human hair, in which specific cationic azo dyes are used.
摘要翻译：描述了制备某些阳离子偶氮化合物的方法，以及其用于染色含有特定阳离子偶氮染料的含角蛋白的纤维，特别是人类头发的用途。

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