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    • 1. 发明申请
    • 2,5-DIAMINO SUBSTITUTED AZO DYES
    • 2,5-DIAMINO取代的AZO染料
    • WO2005095522A2
    • 2005-10-13
    • PCT/EP2005/051323
    • 2005-03-23
    • CIBA SPECIALTY CHEMICALS HOLDING INC.ELIU, Victor PaulSAUDER, ThomasKAUFFMANN, DominiqueFRÖHLING, Beate
    • ELIU, Victor PaulSAUDER, ThomasKAUFFMANN, DominiqueFRÖHLING, Beate
    • C09B44/16
    • C09B44/16
    • Disclosed are azo dyes of formula (1) , wherein R 1 is hydrogen; C 1 -C 14 alkyl; hydroxy- C 1 -C 14 alkyl; C 2 -C 14 alkenyl; a radical of formula (1a) -(CH 2 ) n1 -O-(CH 2 ) n2 -CH 3 ; a radical of formula (1b) C 10 aryl; or C 6 -C 10 aryl-C 1 -C 6 alkyl; R3 is hydrogen; C 1 -C 14 alkyl; C 2 -C 14 alkenyl; C 6 -C 10 aryl; C 6 -C 1 0aryl-C 1 -C 6 alkyl; or CO-R 6 ; R 4 is CO-R 6 ; R 5 is C 1 -C 14 alkyl; C 2 -C 14 alkenyl; C 6 -C 10 aryl; or C 6 -C 10 aryl-C 1 -C 6 alkyl; R 6 is hydrogen; C 1 -C 14 alkyl; C 2 -C 14 alkenyl; or C 6 -C 10 aryl; R 7 , R 8 , R 9 and R 10 , independently from each other are hydrogen; or C 1 -C 5 alkyl; m is 1; or 2; An - is an anion; If m = 1, R 2 is hydrogen; C 1 -C 14 alkyl; C 2 -C 14 alkenyl; a radical of formula (1a); a radical of formula (1b) ; C 6 -C 10 aryl; or C 6 -C 10 aryl-C 1 -C 6 alkyl; If m = 2, R 2 is the direct bond; or C 1 -C 14 alkylene, which is optionally substituted by one or more C 1 -C 4 alkyl, or which is optionally interrupted by C 5 -C 10 arylene, -O- or -NR 9 R 10 -; R 9 and R 10 , independently from each other are hydrogen; or C 1 -C 5 alkyl; and n1, n2, n3 and n4, independently from each other are a number from 0 to 5. The compounds are useful for the dyeing of organic material, preferably human hair.
    • 公开了式(1)的偶氮染料,其中R 1是氢; ç<子> 1 -C <子> 14 烷基; 羟基-C 1 -C 14 - 烷基; ç<子> 2 -C <子> 14 烯基; 式(1a) - (CH 2)n1 -O-(CH 2)n2 -n- CH <子> 3 ; 式(1b)C10芳基的基团; 或C 6 -C 10芳基-C 1 -C 6烷基;或C 6 -C 10芳基-C 1 -C 6烷基。 R3是氢; ç<子> 1 -C <子> 14 烷基; ç<子> 2 -C <子> 14 烯基; ç<子> 6 -C <子> 10 芳基; ç<子> 6 -C <子> 1 0aryl-C <子> 1 -C <子> 6 烷基; 或CO-R 6; R 4是CO-R 6; R 5是C 1 -C 14烷基; R 5是C 1 -C 14烷基。 ç<子> 2 -C <子> 14 烯基; ç<子> 6 -C <子> 10 芳基; 或C 6 -C 10芳基-C 1 -C 6烷基;或C 6 -C 10芳基-C 1 -C 6烷基。 R 6是氢; ç<子> 1 -C <子> 14 烷基; ç<子> 2 -C <子> 14 烯基; 或C≡C-C10芳基; R 7,R 8,R 9和R 10彼此独立地为氢; R 7,R 8,R 9和R 10彼此独立地为氢; 或C 1 -C 5烷基; m是1; 或2; An - 是一个阴离子; 如果m = 1,则R 2是氢; ç<子> 1 -C <子> 14 烷基; ç<子> 2 -C <子> 14 烯基; 式(1a)的基团; 式(1b)的基团; ç<子> 6 -C <子> 10 芳基; 或C 6 -C 10芳基-C 1 -C 6烷基;或C 6 -C 10芳基-C 1 -C 6烷基。 如果m = 2,则R 2是直接键; 或C 1 -C 14亚烷基,其任选被一个或多个C 1 -C 4烷基 ,或者任选地被C 5 -C 10亚芳基,-O-或-NR 9 R 10取代的亚苯基, > - ; R 9和R 10彼此独立地为氢; 或C 1 -C 5烷基; 并且n1,n2,n3和n4彼此独立地为0-5的数。所述化合物可用于染色有机材料,优选人发。
    • 2. 发明申请
    • CATIONIC DIRECT DYES
    • 阳光直射
    • WO2005012437A1
    • 2005-02-10
    • PCT/EP2004/051481
    • 2004-07-14
    • CIBA SPECIALTY CHEMICALS HOLDING INC.ELIU, Victor, PaulFRÖHLING, Beate
    • ELIU, Victor, PaulFRÖHLING, Beate
    • C09B44/16
    • C09B44/16
    • The present invention relates to novel the cationic dyes of formula (1) wherein R 1 is an unsubstituted or substituted C 1 -C 14 alkyl or an aryl radical; X - is an anion; R 3 is an unsubstituted or substituted C 1 -C 14 alkyl, aryl radical, C 1 -C 6 alkoxy, cyanid, nitro or halide; n is 1 or 2; and if n is 1, then R 2 is hydrogen, unsubstituted or substituted C 1 -C 14 alkyl; or if n is 2, then R 2 is an unsubstituted or substituted C 1 -C 14 alkylen. Further, the present invention relates to compositions thereof, especially comprising other dyes, to processes for the preparation thereof and to the use thereof in the dyeing of organic material, such as keratin, wool, leather, silk, paper, cellulose or polyamides, and preferably human hair.
    • 本发明涉及式(1)的阳离子染料,其中R 1是未取代或取代的C 1 -C 14烷基或芳基; X - 是阴离子; R 3是未取代或取代的C 1 -C 14烷基,芳基,C 1 -C 6烷氧基,氰基,硝基或卤素; n为1或2; 如果n为1,则R2为氢,未取代或取代的C 1 -C 14烷基; 或者如果n为2,则R2为未取代或取代的C1-C14亚烷基。 此外,本发明涉及其组合物,特别是其它染料,其制备方法及其在染色有机材料如角蛋白,羊毛,皮革,丝,纸,纤维素或聚酰胺中的用途,以及 优选人发。
    • 3. 发明申请
    • CATIONIC DYES, THEIR PRODUCTION AND USE
    • 阳光染色体,其生产和使用
    • WO2004076564A1
    • 2004-09-10
    • PCT/EP2004/050132
    • 2004-02-16
    • CIBA SPECIALTY CHEMICALS HOLDING INC.ELIU, Victor PaulFRÖHLING, Beate
    • ELIU, Victor PaulFRÖHLING, Beate
    • C09B69/06
    • C09B69/065A61K8/4946A61Q5/065C09B44/103
    • The present invention relates to novel cationic dye of formula (1) wherein R 1 and R 7 are each independently of the other hydrogen, hydroxyl; unsubstituted or substituted C 1 -C 6 alkyl, aryl radical or C 1 I-C 6 alkoxy; or -NR 3 R 4 , wherein R 3 and R 4 are each independently of the other hydrogen, unsubstituted or substituted aryl radical or C 1 -C 6 alkyl, and R 2 is hydrogen, hydroxyl, unsubstituted or substituted C 1 ­C 6 alkyl, aryl radical or C 1 -C 6 alkoxy, - NR3R4 , or an organic radical of formula (2) wherein R 5 is hydrogen, unsubstituted or substituted aryl radical or C 1 -C 6 alkyl, and X is an anion. Further, the present invention relates to compositions thereof, especially comprising other dyes, to processes for the preparation thereof and to the use thereof in the dyeing of organic material, such as keratin, wool, leather, silk, cellulose or polyamides, and preferably human hair.
    • 本发明涉及式(1)的新型阳离子染料,其中R 1和R 7各自独立地为氢,羟基; 未取代或取代的C 1 -C 6烷基,芳基或C 1 -C 6烷氧基; 或-NR 3 R 4,其中R 3和R 4各自独立地为氢,未取代或取代的芳基或C 1 -C 6烷基,且R 2为氢,羟基,未取代或取代的C 1 -C 6烷基,芳基或C 1 -C 6烷氧基,-NR 3 R 4或 式(2)的有机基团,其中R 5是氢,未取代或取代的芳基或C 1 -C 6烷基,X是阴离子。 此外,本发明涉及其组合物,特别是其它染料,其制备方法及其在染色有机材料如角蛋白,羊毛,皮革,丝,纤维素或聚酰胺,优选人 头发。
    • 4. 发明申请
    • XANTHENE DYES
    • 黄嘌呤染料
    • WO2007039502A2
    • 2007-04-12
    • PCT/EP2006/066673
    • 2006-09-25
    • CIBA SPECIALTY CHEMICALS HOLDING INC.ELIU, Victor PaulFRÖHLING, BeateKAUFFMANN, Dominique
    • ELIU, Victor PaulFRÖHLING, BeateKAUFFMANN, Dominique
    • C09B49/126A61K8/49A61K8/498A61Q5/10C09B11/24C09B11/245
    • Disclosed are compounds of formula (1a), wherein R 1 is N + R 8 R 9 ; R 8 and/or R 9 independently from each other are hydrogen; C 1 -C 12 alkyl; or phenyl-C 1 -C 4 -alkyl; or R 8 and/or R 9 are a bivalent C 3 -C 6 alkylene radical which is linked to the carbon atoms C 1 or C 2 respectively and, together with the linking nitrogen atom form a 6 to 16-membered carbocyclic ring; R 2 is NR 10 R 11 ; or OR 10 ; R 10 and R 11 , independently from each other are hydrogen; C 1 -C 12 alkyl; or phenyl-C 1 -C 4 alkyl; or R 10 and/or R 11 are a bivalent C 3 -C 6 alkylene radical which is linked to the carbon atoms C 3 or C 4 respectively and, together with the linking nitrogen or oxygen atom form a 6 to 16- membered carbocyclic ring; or R 10 and R 11 together with the linking nitrogen atom form a 4 to 8 membered carbocyclic ring; R 3 , R 4 , R 5 , R 6 and R 7 independently form each other are hydrogen; C 1 -C 12 alkyl; halogen; NR 12 R 13 ; or a radical of formula (1a 1 ); R 12 and R 13 independently from each other are hydrogen; C 1 -C 12 alkyl; phenyl-C 1 -C 4 alkyl; or a radical of formula (1a 2 ); V is -O-; Or -NR 15 ; R 14 , R 15 R- 16 and R 17 independently from each other are hydrogen; or C 1 -C 5 alkyl; and Hal is a halogen atom; and wherein at least one of R 3 , R 4 , R 5 , R 6 and R 7 is hydrogen. The compounds are useful for dyeing of keratin-containing fibres with or without reducing agents.
    • 公开了式(1a)的化合物,其中R 1是N + 8 R 8 R 8, 9 ; R 8和/或R 9彼此独立地为氢; ç<子> 1 -C <子> 12 烷基; 或苯基-C 1 -C 4 - 烷基;或苯基-C 1 -C 4 - 烷基。 或R 8和/或R 9是二价C 3 -C 6亚烷基,其连接到 碳原子C 1或C 2分别与连接的氮原子一起形成6至16元碳环; R 2 = NR 10 R 11; 或OR 10 ; R 10和R 11彼此独立地为氢; ç<子> 1 -C <子> 12 烷基; 或苯基-C 1 -C 4烷基;或苯基-C 1 -C 4烷基。 或R 10和/或R 11是二价C 3 -C 6亚烷基,其连接到 碳原子C 3或C 4分别与连接的氮或氧原子一起形成6至16元碳环; 或者R 10和R 11与连接的氮原子一起形成4至8元碳环; R 3,R 4,R 5,R 6和R 7各自独立地 彼此形成氢; ç<子> 1 -C <子> 12 烷基; 卤素; NR <子> 12 ř<子> 13 ; 或式(1a1)的基团; R 12和R 13彼此独立地为氢; ç<子> 1 -C <子> 12 烷基; 苯基-C <子> 1 -C <子> 4 烷基; 或式(1a2)的基团; V是-O-; 或-NR 15 15; R 14,R 15,R 16和R 17彼此独立地为氢; R 14,R 15,R 16和R 17彼此独立地为氢; 或C 1 -C 5烷基; Hal是卤素原子; 并且其中R 3,R 4,R 5,R 6和R 6中的至少一个为氢, 7是氢。 该化合物可用于含或不含还原剂的含角蛋白纤维的染色。
    • 6. 发明申请
    • METHOD OF COLOURING POROUS MATERIAL
    • 多孔材料着色方法
    • WO2004019896A1
    • 2004-03-11
    • PCT/EP2003/009416
    • 2003-08-26
    • CIBA SPECIALTY CHEMICALS HOLDING INC.ADAM, Jean-MarieYOUSAF, TaherFRÖHLING, BeateELIU, Victor, Paul
    • ADAM, Jean-MarieYOUSAF, TaherFRÖHLING, BeateELIU, Victor, Paul
    • A61K7/13
    • A61K8/4966A61Q5/065C07C245/24C09B67/0079
    • A method of colouring porous material, especially human hair, is described, which method comprises applying to the material being coloured, in any desired order successively, or simultaneously, a) at least one capped diazonium compound of Formula (1) and/or at least one compound of Formula (2) and/or at least one compound of Formula (3) wherein Q is an unsubstituted or substituted aromatic or heterocyclic residue, R is the radical of an unsubstituted or substituted, water-soluble aliphatic or aromatic amine, and T is an unsubstituted or substituted, water-soluble aliphatic or aromatic residue, wherein at least one of the groups must contain a radical imparting water solubility, and a) at least one water-soluble coupling component under conditions such that, initially, coupling does not take place, and then causing the capped diazonium compound present on the material to react with the coupling component.
    • 描述了一种着色多孔材料,特别是人发的方法,该方法包括以任何所需顺序依次或同时施用着色的材料,a)至少一种式(1)的封端重氮化合物和/或在 至少一种式(2)的化合物和/或至少一种式(3)的化合物,其中Q是未取代或取代的芳族或杂环残基,R是未取代或取代的水溶性脂族或芳族胺的基团, 并且T是未取代或取代的水溶性脂族或芳族残基,其中所述基团中的至少一个必须含有自由基赋予水溶性,和a)至少一种水溶性偶联组分, 不会发生,然后使存在于材料上的覆盖的重氮化合物与偶联组分反应。
    • 9. 发明申请
    • PYRIDO-THIAZINIUM DYES
    • WO2007003506A1
    • 2007-01-11
    • PCT/EP2006/063374
    • 2006-06-21
    • CIBA SPECIALTY CHEMICALS HOLDING INC.ELIU, Victor, PaulFRÖHLING, BeateKAUFFMANN, Dominique
    • ELIU, Victor, PaulFRÖHLING, BeateKAUFFMANN, Dominique
    • C07D513/04C09B23/00A61K8/49A61Q5/10
    • A61Q5/10A61K8/49C07D513/04C09B23/0091
    • Disclosed is a method of dyeing keratin-containing fibers comprising treating the fiber with at least one compound of formula (1), wherein R 1 , R 2 , R 3 , R 4 independently from each other are hydrogen; hydroxy; -S-H; -S-C 1 -C 12 alkyl; halogen; C 1 -C 12 alkyl or C 1 -C 12 alkoxy, which may be substituted by one or more C 1 - C 5 alkyl, C 1 -C 5 -alkoxy, hydroxy, -(CO)-H or -(CO)-C 1 -C5alkyl; -NR 5 R 6 ; -NO 2 ; -(CO)H or (CO)-C 1 -C 5 alkyl; C 6 -C 12 aryl, C 6 -C 12 aryl-C 1 -C 4 alkyl or C 6 -C 12 aryl-C 1 -C 4 alkoxy, wherein the aryl moiety may be substituted by one or more C 1 -C 5 alkyl, C 1 -C 5 alkoxy, -(CO)-H or -(CO)-C 1 -C 5 alkyl; R 5 and R 6 independently from each other are hydrogen; hydroxy; C 1 -C 12 alkyl; hydroxy-C 1 - C 12 alkyl; -(CO)-H; -(CO)-C 1 -C 5 alkyl; phenyl or phenyl-C 1 -C 5 alkyl, wherein the phenyl moiety may be substituted by one or more C1-C 5 alkyl, C 1 -C 5 alkoxy, halogen, -NH2, mono-C 1 -C 5 alkylamino, di-C 1 -C5alkylamino, -NO 2 , carboxy or hydroxy; and An is an anion. Furthermore, the present invention relates to novel heterocyclic compounds, compositions thereof, especially comprising other dyes, and to processes for their preparation and application to hair dying.
    • 公开了一种染色含角蛋白纤维的方法,包括用至少一种式(1)化合物处理纤维,其中R 1,R 2,R 2, 3个,R 4彼此独立地是氢; 羟基; -S-H; -S-C 1 -C 12 烷基; 卤素; C 1 -C 12烷基或C 1 -C 12烷氧基,其可以被一个或多个 C 1 -C 5烷基,C 1 -C 5 - 烷氧基,羟基, - (CO) - H或 - (CO)-C 1 -C 5烷基; -NR 5 - [R 6 ; -NO 2 ; - (CO)H或(CO)-C 1 -C 5烷基; C 6 -C 12芳基,C 6 -C 12芳基-C 1 H 12 C 1 -C 4烷基或C 6 -C 12芳基-C 1 -C 4 - 其中芳基部分可以被一个或多个C 1 -C 5烷基取代,C 1 -C 3亚烷基 烷氧基, - (CO)-H或 - (CO)-C 1 -C 5烷基; R 5和R 6彼此独立地是氢; 羟基; ç 1 -C 12 烷基; 羟基-C 1 -C 12烷基; - (CO)-H; - (CO)-C 1 -C 5 烷基; 苯基或苯基-C 1 -C 5烷基,其中苯基部分可以被一个或多个C 1 -C 5烷基取代,C 1 -C 5烷基 烷氧基,卤素,-NH 2,单-C 1 -C 5烷基氨基,二 - (C 1 -C 6)烷基氨基, C 1 -C 5烷基氨基,-NO 2 2,羧基或羟基; 而An是阴离子。 此外,本发明涉及新颖的杂环化合物,其组合物,特别是其它染料,以及其制备和应用于染发的方法。
    • 10. 发明申请
    • STYRYL SULFIDE DYES
    • WO2006134043A2
    • 2006-12-21
    • PCT/EP2006/062946
    • 2006-06-07
    • CIBA SPECIALTY CHEMICALS HOLDING INC.ELIU, Victor PaulFRÖHLING, BeateKAUFFMANN, Dominique
    • ELIU, Victor PaulFRÖHLING, BeateKAUFFMANN, Dominique
    • C09B23/14A61K8/4926A61Q5/10C09B23/145C09B49/00
    • Disclosed are styryl sulfide dyes of formula (1), wherein R 1 , R' 1 , R 2 , R' 2 , R 3 and R' 3 , independently from each other are hydrogen; C 1 -C 20 alkyl or C 1 - C 20 alkoxy, which may be substituted by one or more C 1 -C 5 alkoxy, halogen, -NH 2 , mono-C 1 -C 5 alkylamino, di-C 1 -C 5 alkylamino, -NO 2 or hydroxy; C 3 -C 6 cycloalkyl; -C(O)H; -C(O)-C 1 -C 5 alkyl; halogen; NO 2 ; OH; phenyl, which may be substituted by one or more C 1 -C 5 alkyl, C 1 -C 5 alkoxy, halogen, -NH 2 , mono-C 1 -C 5 alkylamino, di-C 1 -C 5 alkylamino, -NO 2 or hydroxy; or a radical of formula -NR 4 R 5 , wherein R 4 and R 5 independently from each other are hydrogen; C 1 -C 12 alkyl, which may be substituted by one or more C 1 -C 5 alkyl, C 1 -C 5 -alkoxy, hydroxy or -(CO)-H; -(CO)-C 1 -C 5 alkyl; phenyl or phenyl-C 1 -C 4 alkyl, wherein the phenyl moiety may be substituted by one or more C 1 -C 5 alkyl, C 1 -C 5 alkoxy, halogen, -NH 2 , mono-C 1 -C 5 alkylamino, di-C 1 -C 5 alkylamino, -NO 2 , carboxy or hydroxy; W 1 , W' 1 , W 2 , W' 2 , W 3 , W' 3 , W 4 or W' 4 , independently from each other are -CH- or -N + -; wherein only one of W 1 /W' 1 , W 2 /W' 2 , W 3 /W' 3 , W 4 /W 4 ' is -N + ; and the bivalent radical -Q-Z-Y-S-S-Y'-Z'-Q'- is bonded to W 1 or W 2 and W' 1 or W' 2 respectively; Y 1 and Y 2 independently from each other are C 1 -C 10 alkylene; C 5 -C 10 cycloalkylene; C 5 -C 12 arylene; or C 5 -C 12 arylene-(C 1 -C 10 alkylene); Q and Q' independently from each other are the direct bond; or -C(O)-; -C(O)O-; -OCO-; -N(R 6 )-; formula (AA); -C(O)N(R 6 )-; -(R 6 )NC(O)-; -O-; -S-; -S(O)-; or -S(O) 2 -; and R 6 and R 7 independently from each other are hydrogen; C 1 -C 14 alkyl; C 2 -C 14 alkenyl; C 6 - C 12 aryl; C 6 -C 12 aryl-C 1 -C 10 alkyl; or C 1 -C 10 alkyl(C 5 -C 12 aryl). Further, the present invention relates to novel styryl sulfide compounds, compositions thereof, especially comprising other dyes, and to processes for their preparation.
    • 公开了式(1)的苯乙烯基硫化物染料,其中R 1,R'1,R 2,R'2, R 3,R 3和R 3'彼此独立地是氢; C 1 -C 20烷基或C 1 -C 20烷氧基,其可以被一个或多个 C 1 -C 5 -C 5烷氧基,卤素,-NH 2,单-C 1 -C 3烷基, 5个烷基氨基,二-C 1 -C 5烷基氨基,-NO 2 2或羟基; ç 3 -C 6 环烷基; -C(O)H; -C(O)-C 1 -C 5 烷基; 卤素; NO 2 ; 哦; 苯基,其可以被一个或多个C 1 -C 5烷基取代,C 1 -C 5 -C 5烷基, 烷氧基,卤素,-NH 2,单-C 1 -C 5烷基氨基,二-C 1 - C 5烷基氨基,-NO 2或羟基; 或式-NR 4 R 5的基团,其中R 4和R 5彼此独立地为 氢; C 1 -C 12烷基,其可以被一个或多个C 1 -C 5烷基取代, C 1 -C 5 - 烷氧基,羟基或 - (CO)-H; - (CO)-C 1 -C 5 烷基; 苯基或苯基-C 1 -C 4烷基,其中苯基部分可以被一个或多个C 1 -C 4烷基取代, C 1 -C 5烷基,C 1 -C 5烷氧基,卤素,-NH 2,C 1 -C 12烷基, C 1 -C 5烷基氨基,二-C 1 -C 5烷基氨基,-NO 2 2,羧基或 羟基; W 1,W 2,W 2,W'2,W 3,/ SO 2 >,W'3,W 4或W'4,彼此独立地是-CH-或-N + / SUP> - ; 其中W 1 / W'1,W 2 / W'2,W 2中的仅一个, 3 / W 3,W 4或W 4是-N + O 3。 并且二价基团-QZYSS-Y'-Z'-Q'-键合到W 1或W 2和W'1或 分别为W'2 Y 1和Y 2彼此独立地是C 1 -C 10亚烷基; ç 5 -C 10 亚环烷基; ç 5 -C 12 亚芳基; 或C 5 -C 12亚芳基 - (C 1 -C 10亚烷基); Q和Q'彼此独立是直接键; 或-C(O) - ; -C(O)O-; -OCO-; -N(R 6 ) - ; 式(AA); -C(O)N(R 6 ) - ; - (R 6 )NC(O) - ; -O-; -S-; -所以)-; 或-S(O)2 - ; R 6和R 7和R 7彼此独立地是氢; ç 1 -C 14 烷基; ç 2 -C 14 烯基; C 6 -C 12芳基; ç 6 -C 12 芳基-C 1 -C 10 烷基; 或C 1 -C 10烷基(C 5 -C 12 - 芳基)。 此外,本发明涉及新颖的苯乙烯基硫化物,其组合物,特别是其它染料,以及其制备方法。