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    • 2. 发明申请
    • FLEXIBLE REACTOR ASSEMBLY FOR POLYMERIZATION OF OLEFINS
    • 柔性反应器组件用于烯烃的聚合
    • WO2012116845A1
    • 2012-09-07
    • PCT/EP2012/000961
    • 2012-03-02
    • BOREALIS AGERIKSSON, ErikBERGSTRA, MichielNYFORS, KlausWEICKERT, Günter
    • ERIKSSON, ErikBERGSTRA, MichielNYFORS, KlausWEICKERT, Günter
    • B01J8/24B01J8/38B01J19/24B01J8/18
    • B01J8/388B01J8/1827B01J8/1872B01J19/2465B01J2208/00274B01J2219/0004B01J2219/00254C08F10/00C08F110/06C08F2500/12C08F2/34C08F2/01
    • The invention relates to a reactor assembly for the production of polymers including a fluidized bed reactor (1) comprising a bottom zone (5), a middle zone (6) and an upper zone (7), an inlet (8) for the fluidization gas located in the bottom zone (5), an outlet (9) for the fluidization gas located in the upper zone (7); the outlet (9) for the fluidization gas being coupled with the fluidized bed reactor (1) via inlet (8); the equivalent cross-sectional diameter of the bottom zone (5) being monotonically increasing with respect to the flow direction of the fluidization gas through the fluidized bed reactor; the middle zone (6) having an essentially constant equivalent cross-sectional diameter with respect to the flow direction of the fluidization gas through the fluidized bed reactor; the equivalent cross-sectional diameter of the upper zone (7) being monotonically decreasing with respect to the flow direction of the fluidization gas through the fluidized bed reactor; wherein that the ratio of the height of the fluidized bed reactor to the equivalent cross- sectional diameter of the middle zone of the fluidized bed reactor is from 2 to 10; and wherein there is an unobstructed passageway in the direction of flow of the fluidization gas through the fluidized bed reactor from the bottom zone (5) to the upper zone (7).
    • 本发明涉及一种用于生产聚合物的反应器组件,包括流化床反应器(1),其包括底部区域(5),中间区域(6)和上部区域(7),用于流化的入口(8) 位于底部区域(5)中的气体,位于上部区域(7)中的用于流化气体的出口(9); 用于流化气体的出口(9)通过入口(8)与流化床反应器(1)联接; 底部区域(5)的等效横截面直径相对于通过流化床反应器的流化气体的流动方向单调增加; 所述中间区域(6)具有相对于通过所述流化床反应器的流化气体的流动方向具有基本恒定的等效横截面直径; 上部区域(7)的等效横截面直径相对于通过流化床反应器的流化气体的流动方向单调减小; 其中流化床反应器的高度与流化床反应器的中间区域的等效横截面直径之比为2至10; 并且其中在从底部区域(5)到上部区域(7)的流化床反应器的流化气体的流动方向上存在无障碍通道。
    • 3. 发明申请
    • HIGH THROUGHPUT REACTOR ASSEMBLY FOR POLYMERIZATION OF OLEFINS
    • 用于烯烃聚合的高通量反应器组件
    • WO2012116844A1
    • 2012-09-07
    • PCT/EP2012/000960
    • 2012-03-02
    • BOREALIS AGWEICKERT, GünterERIKSSON, ErikBERGSTRA, MichielNYFORS, Klaus
    • WEICKERT, GünterERIKSSON, ErikBERGSTRA, MichielNYFORS, Klaus
    • B01J8/24B01J8/38B01J19/24B01J8/18
    • B01J8/1872B01J8/1827B01J8/388B01J19/2465B01J2208/00274B01J2219/0004B01J2219/00254B01J2219/1947C08F110/06C08F210/16
    • Reactor assembly for the production of polymers including a fluidized bed reactor (1) comprising a bottom zone (5), a middle zone (6) and an upper zone (7), an inlet (8) for the fluidization gas located in the bottom zone (5), an outlet (9) for the fluidization gas located in the upper zone (7); the outlet (9) for the fluidization gas being coupled with the fluidized bed reactor (1) via inlet (8) via a gas circulation line; means for separation of solids from gas (2) being connected to said gas circulation line; the equivalent cross-sectional diameter of the upper zone (7) being monotonically decreasing with respect to the flow direction of the fluidization gas through the fluidized bed reactor; the middle zone (6) having an essentially constant equivalent cross-sectional diameter with respect to the flow direction of the fluidization gas through the fluidized bed reactor; the equivalent cross-sectional diameter of the bottom zone (5) being monotonically increasing with respect to the flow direction of the fluidization gas through the fluidized bed reactor; characterized in that the ratio of the height of the fluidized bed reactor to the equivalent cross-sectional diameter of the middle zone of the fluidized bed reactor is from 2 to 10; and whereby said upper zone (7) is directly connected to said middle zone (6).
    • 用于生产包括流化床反应器(1)的聚合物的反应器组件包括底部区域(5),中间区域(6)和上部区域(7),用于位于底部的流化气体的入口(8) 区域(5),用于位于上部区域(7)中的流化气体的出口(9); 用于流化气体的出口(9)通过气体循环管线通过入口(8)与流化床反应器(1)相连; 用于从与所述气体循环管线连接的气体(2)分离固体的装置; 上部区域(7)的等效横截面直径相对于通过流化床反应器的流化气体的流动方向单调减小; 所述中间区域(6)具有相对于通过所述流化床反应器的流化气体的流动方向具有基本恒定的等效横截面直径; 底部区域(5)的等效横截面直径相对于通过流化床反应器的流化气体的流动方向单调增加; 其特征在于,流化床反应器的高度与流化床反应器的中间区域的等效横截面直径之比为2至10; 并且由此所述上部区域(7)直接连接到所述中间区域(6)。
    • 9. 发明申请
    • PROCESS FOR PRODUCING POLYETHYLENE WITH IMPROVED HOMOGENEITY
    • 生产具有改善的均匀性的聚乙烯的方法
    • WO2012034869A1
    • 2012-03-22
    • PCT/EP2011/065135
    • 2011-09-01
    • BOREALIS AGLENTZAKIS, HelenLYLYKANGAS, MikkoBERGSTRA, MichielVAHTERI, MarkkuAHO, Jani
    • LENTZAKIS, HelenLYLYKANGAS, MikkoBERGSTRA, MichielVAHTERI, MarkkuAHO, Jani
    • C08F10/02
    • C08F210/16C08F10/00C08F2/001C08F210/08C08F2500/01C08F2500/05C08F2500/08C08F2500/12C08F2500/26C08F2500/02C08F2500/07C08F4/6555C08F4/6492
    • Process for producing polyethylene compositions, like LLDPE, MDPE or HDPE, with a high level of homogeneity which comprises the steps of a) preactivating the total amount of a Ziegler-Natta procatalyst with the total amount of a cocatalyst, which cocatalyst comprises an organoaluminium compound, in order to get a preactivated Ziegler-Natta catalyst system, b) introducing the preactivated Ziegler-Natta catalyst system into a prepolymerisation reactor, wherein the preactivated Ziegler-Natta catalyst system is prepolymerised with at least one C 2 -C 10 -alpha-olefin monomer and optionally one or more C 3 -C 10 -alpha- olefin comonomer, in order to get a prepolymerisation product, c) introducing the prepolymerisation product into a first polymerisation reactor, which comprises a slurry reactor, wherein the prepolymerisation product is further polymerised with ethylene monomers and optionally one or more C 3 -C 10 -alpha-olefin comonomers in order to get a first polymerisation product, d) introducing the first polymerisation product into a second polymerisation reactor, wherein the first polymerisation product is further polymerised with ethylene monomers and optionally one or more C 3 to C 10 -alpha-olefin comonomers in order to get a second polymerisation product, e) optionally performing one or two subsequent polymerisation steps in order to get a third or fourth polymerisation product, f) further processing the obtained polymerisation product into pellets by extrusion; its use for forming articles, especially films with a low gel content.
    • 用于生产具有高水平均匀性的聚乙烯组合物如LLDPE,MDPE或HDPE的方法,其包括以下步骤:a)预先活化齐格勒 - 纳塔前催化剂的总量与助催化剂的总量,该助催化剂包含有机铝化合物 ,以便获得预活化的齐格勒 - 纳塔催化剂体系,b)将预活化的齐格勒 - 纳塔催化剂体系引入预聚合反应器,其中预活化的齐格勒 - 纳塔催化剂体系与至少一种C2-C10-α-烯烃单体 和任选的一种或多种C 3 -C 10-α-烯烃共聚单体,以获得预聚合产物,c)将预聚合产物引入第一聚合反应器,该反应器包括浆料反应器,其中预聚合产物进一步与乙烯单体 和任选的一种或多种C 3 -C 10-α-烯烃共聚单体,以获得第一聚合产物,d)引入t 他将第一聚合产物转化成第二聚合反应器,其中第一聚合产物进一步与乙烯单体和任选的一种或多种C 3 -C 10-α-烯烃共聚单体聚合,以获得第二聚合产物,e)任选地进行一个或两个 随后的聚合步骤以获得第三或第四聚合产物,f)通过挤出将所得聚合产物进一步加工成颗粒; 其用于形成制品,特别是具有低凝胶含量的膜。