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1. 发明申请

WO2011113454A1 METHOD AND DEVICE FOR CONTROLLED DOSING OF A GAS WITH FLUCTUATING SUPPLY PRESSURE 审中-公开
标题翻译：用于控制具有压力供应压力的气体的方法和装置
公开(公告)号：WO2011113454A1
公开(公告)日：2011-09-22
申请号：PCT/EP2010/006704
申请日：2010-11-03
申请人： AMMINEX A/S , PIETRASZEK, Jan , JOHANNESSEN, Tue
发明人： PIETRASZEK, Jan , JOHANNESSEN, Tue
IPC分类号： B01D53/94 , F01N3/20 , B01D53/90 , F01N11/00
CPC分类号： F16K17/00 , B01D53/90 , B01D53/9495 , B01D2251/2062 , B01D2253/102 , B01D2253/108 , B01D2253/204 , B01D2257/404 , B01D2258/01 , B01D2259/12 , F01N3/208 , F01N2610/02 , F01N2610/06 , F01N2610/10 , F01N2610/14 , F17C11/00 , Y02A50/2325 , Y02T10/24
摘要： A method for controlled dosing of a gas with fluctuating supply pressure (P supply ). Dosing of the gas through a valve (6) is performed while a valve (5) is closed, and the decrease in control-volume pressure (P cv ) is recorded. The control-volume pressure (P cv ) is raised by closing dosing valve (6) and opening the valve (5). The amount of the dosed gas is calculated based on the known volume (V cv ) of the control volume (4) and at least one of the change in control-volume pressure (P cv ) and control-volume temperature (T cv ) in the period where valve (5) is closed. The amount of dosed gas is compared with a target or set-point to adjust or regulate the subsequent dosing period or dosing event.
摘要翻译：用于控制供给压力供给压力（Psupply）的方法。在阀（5）关闭的同时进行通过阀（6）的气体的加注，并记录控制体积压力（Pcv）的降低。通过关闭计量阀（6）并打开阀（5）来提高控制体积压力（Pcv）。计量给药气体的量基于控制体积（4）的已知体积（Vcv）和控制体积压力（Pcv）和对照体积温度（Tcv）的变化中的至少一个来计算，阀（5）关闭。将剂量的气体与目标或设定点进行比较，以调整或调节随后的给药时间或给药事件。

2. 发明申请

WO2011038916A1 CONNECTED HEAT CONDUCTING STRUCTURES IN SOLID AMMONIA STORAGE SYSTEMS 审中-公开
标题翻译：固体阿姆斯壮储存系统中的连接导热结构
公开(公告)号：WO2011038916A1
公开(公告)日：2011-04-07
申请号：PCT/EP2010/005982
申请日：2010-09-30
申请人： AMMINEX A/S , SVAGIN, Jakob , QUAADE, Ulrich, J. , JOHANSEN, Johnny , WAGNER-PEDERSEN, Henrik , JOHANNESSEN, Tue
发明人： SVAGIN, Jakob , QUAADE, Ulrich, J. , JOHANSEN, Johnny , WAGNER-PEDERSEN, Henrik , JOHANNESSEN, Tue
IPC分类号： F01N3/20 , C01F11/24 , C01C1/00 , B01J20/04
CPC分类号： C01C1/006 , B01J20/0222 , B01J20/0288 , B01J20/046 , B01J20/2805 , F01N2610/02 , F01N2610/12
摘要： A compacted block of material constructed of one or more units consisting of matter comprising an ammonia-saturated material capable of reversibly desorbing and ad- or absorbing ammonia surrounded by a gas-permeableenclosure made of a flexible material having a thermal conductivity of at least about five times the thermal conductivity of said ammonia-saturated material at -70°C to 250°C and methods for producing the same are described.
摘要翻译：由一个或多个由包含氨饱和材料构成的材料构成的压实块材料，其能够可逆地解吸和吸附或吸收由气体可渗透的封闭体所包围的氨，所述气体可渗透的封闭体由具有至少约五的热导率的柔性材料制成将所述氨饱和材料的导热率乘以-70℃至250℃，并描述其制备方法。

3. 发明申请

WO2008119492A1 A SYSTEM FOR STORING AMMONIA IN AND RELEASING AMMONIA FROM A STORAGE MATERIAL AND METHOD FOR STORING AND RELEASING AMMONIA 审中-公开
标题翻译：用于储存氨和从存储材料中释放氨的系统和用于存储和释放氨的方法
公开(公告)号：WO2008119492A1
公开(公告)日：2008-10-09
申请号：PCT/EP2008/002386
申请日：2008-03-26
申请人： AMMINEX A/S , JOHANNESSEN, Tue , SCHMIDT, Henning
发明人： JOHANNESSEN, Tue , SCHMIDT, Henning
IPC分类号： B01D53/90 , B01D53/94 , C01C1/02 , F01N3/20
CPC分类号： F17C11/00 , B01D53/8631 , B01D53/90 , B01D53/9431 , B01D53/9495 , B01D2251/2062 , C01C1/006 , F01N3/2066 , F01N3/208 , F01N11/00 , F01N2560/026 , F01N2610/02 , F01N2610/06 , F01N2610/10 , F01N2610/14 , F01N2610/1406 , F01N2610/146 , F01N2900/0411 , F01N2900/08 , F01N2900/12 , F01N2900/1808 , F01N2900/1811 , F17C13/00 , F17C2221/01 , F17C2227/0302 , F17C2270/0581 , H01M8/0606 , H01M8/222 , Y02A50/2325 , Y02E60/321 , Y02T10/24
摘要： A system for storing ammonia in and releasing ammonia from a storage material capable of binding and releasing ammonia reversibly by adsorption or absorption for a process with a gradual ammonia demand that can vary over the time. The system has a container capable of housing the ammonia-containing storage material; a heating source arranged to supply heat for the desorption of ammonia from the solid storage medium; and a controller arranged to control the heating source to release ammonia. The heating source is arranged inside the container and surrounded by ammonia storage material. A controllable dosing valve is arranged to dose released ammonia according to the ammonia demand. The controller comprises a feed-forward control arranged to control the heat supplied by the heating source, based on the ammonia demand.
摘要翻译：一种用于将氨从储存材料中储存和释放氨的系统，该储存材料能够通过吸附或吸收可逆地结合和释放氨，以达到可随时间变化的逐渐氨需求的过程。该系统具有能容纳含氨储存材料的容器; 加热源，其设置用于从固体储存介质中提供氨以解吸氨; 以及控制器，其布置成控制加热源以释放氨。加热源设置在容器的内部并被氨储存材料包围。布置可控计量阀以根据氨需求量剂量释放氨。该控制器包括一个前馈控制装置，其基于氨的需求来控制由加热源供应的热量。

4. 发明申请

WO2011107279A1 APPARATUS FOR GENERATING HYDROGEN FROM AMMONIA STORED IN SOLID MATERIALS AND INTEGRATION THEREOF INTO LOW TEMPERATURE FUEL CELLS 审中-公开
标题翻译：用于从存在于固体材料中的氨生成氢的装置以及将其集成到低温燃料电池
公开(公告)号：WO2011107279A1
公开(公告)日：2011-09-09
申请号：PCT/EP2011/001046
申请日：2011-03-02
申请人： AMMINEX A/S , CHAKRABORTY, Debasish , PETERSEN, Henrik Nybo , JOHANNESSEN, Tue
发明人： CHAKRABORTY, Debasish , PETERSEN, Henrik Nybo , JOHANNESSEN, Tue
IPC分类号： H01M8/06 , B01J19/24
CPC分类号： H01M8/0606 , B01J8/0257 , B01J8/0285 , B01J2208/00123 , B01J2208/00504 , B01J2208/0053 , C01B3/047 , H01M8/04216 , H01M8/0631 , H01M8/0687 , H01M8/083 , H01M8/222 , H01M2008/1095 , Y02E60/364 , Y02P20/129
摘要： An ammonia-based hydrogen generation reactor (110) comprises: an ammonia cracking chamber (1) with an ammonia cracking catalyst, an inner combustion chamber (2) with a combustion or oxidation catalyst being in thermal contact with the ammonia cracking chamber, an ammonia gas preheating chamber (3), and an outer jacket annulus (6) for recovery of heat from the combustion products exiting the combustion chamber (2), wherein the cracking chamber (1), the inner combustion chamber (2), the preheating chamber (3) and the heat recovery jacket annulus (6) are arranged concentrically. Further described is a system for generating hydrogen comprising at least one ammonia storage unit (119, 120, 400) which, when in operation, is combined with at least one hydrogen generation reactor (110), wherein, when in operation, the waste heat of the at least one hydrogen generation reactor (110) is transferred to at least one storage unit (119, 120, 400) being in operation. A power generating device further comprising a fuel cell, and a method for operating the system for generating hydrogen are also described.
摘要翻译：氨基氢生成反应器（110）包括：具有氨裂解催化剂的氨裂解室（1），具有与氨裂解室热接触的燃烧或氧化催化剂的内燃室（2），氨气体预热室（3）和用于从离开燃烧室（2）的燃烧产物回收热量的外护套环（6），其中裂解室（1），内燃室（2），预热室（3）和热回收夹套环（6）同心布置。还描述了一种用于产生氢气的系统，其包括至少一个氨储存单元（119,120,400），其在运行时与至少一个氢生成反应器（110）组合，其中，当运行时，废热的至少一个氢生成反应器（110）被传送到正在操作的至少一个存储单元（119,120,400）。还描述了还包括燃料电池的发电装置和用于操作用于产生氢气的系统的方法。

5. 发明申请

WO2008009455A1 METHOD AND DEVICE FOR STORING AND DELIVERING AMMONIA FROM A SOLID AMMONIA STORAGE MEDIUM 审中-公开
标题翻译：用于从固体存储介质存储和递送氨的方法和装置
公开(公告)号：WO2008009455A1
公开(公告)日：2008-01-24
申请号：PCT/EP2007/006447
申请日：2007-07-19
申请人： AMMINEX A/S , JOHANNESSEN, Tue , SCHMIDT, Henning , NORSKOV, Jens, Kehlet , CHRISTENSEN, Claus, Hviid
发明人： JOHANNESSEN, Tue , SCHMIDT, Henning , NORSKOV, Jens, Kehlet , CHRISTENSEN, Claus, Hviid
IPC分类号： B01D53/90 , B01D53/94 , C01C1/02 , F01N3/20 , H01M8/06 , H01M8/22 , H01M8/04
CPC分类号： B01D53/90 , B01D53/9409 , C01C1/006 , F01N3/206 , F01N2610/06 , H01M8/04216 , H01M8/0606 , H01M8/222 , Y02A50/2325 , Y02T10/24
摘要： Solid metal ammine complexes are applied for safe and high-density storage of ammonia to be released for use as reducing agent in selective catalytic reduction of NO x in exhaust gases or as an energy carrier for fuel cell applications. The compositional formula of the metal ammine complexes is M(NH 3 ) n X z , where M z+ represents one or more metal ions capable of binding ammonia, X represents one or more anions, n is the coordination number (from 2 to 12), and z the valency of the metal ion (and thus the total number of compensating anion charges). Ammonia is released by controlled dosing of water into the storage container whereby ammonia is released because water replaces ammonia on the active sites capable of binding ammonia. Consequently, ammonia can be released without applying a normal thermal desorption of ammonia and the operating temperature of the system is reduced as well as the energy needed for releasing ammonia.
摘要翻译：应用固体金属氨络合物用于安全和高密度地存储待释放的氨，以用作废气中NO NO x x的选择性催化还原或用作燃料电池应用的能量载体的还原剂。金属氨络合物的组成式是M（NH 3）n X Z Z，其中M z + O表示能够结合氨的一种或多种金属离子，X表示一种或多种阴离子，n为配位数（2至12），z为金属离子的化合价（因此为补偿阴离子电荷的总数）。氨通过控制计量的水释放到储存容器中而释放出来，由于氨替代能够结合氨的活性位点上的氨，因此释放氨。因此，可以释放氨，而不会对氨进行正常的热解吸，同时降低系统的工作温度以及释放氨所需的能量。

6. 发明申请

WO2010118853A1 PRODUCTION OF SATURATED AMMONIA STORAGE MATERIALS 审中-公开
标题翻译：生产饱和的氨氮储存材料
公开(公告)号：WO2010118853A1
公开(公告)日：2010-10-21
申请号：PCT/EP2010/002266
申请日：2010-04-13
申请人： AMMINEX A/S , JOHANSEN, Johnny , WAGNER-PEDERSEN, Henrik , SVAGIN, Jakob , JOHANNESSEN, Tue , QUAADE, Ulrich
发明人： JOHANSEN, Johnny , WAGNER-PEDERSEN, Henrik , SVAGIN, Jakob , JOHANNESSEN, Tue , QUAADE, Ulrich
IPC分类号： C01F5/30 , C01F11/24 , C09K5/04 , F25B15/04 , C01C1/00
CPC分类号： C09K5/04 , C01C1/006
摘要： A process for saturating a solid material capable of binding ammonia by ad- or absorption and initially free of ammonia or partially saturated with ammonia comprises treating said solid material under a pressure and associated temperature located on the vapor pressure curve of ammonia with an amount of liquid ammonia sufficient to saturate said solid material and an additional amount of a cooling agent selected from liquid ammonia, liquid or solid CO 2 , hydrocarbons and hydrohalocarbons that have a higher vapour pressure than ammonia, ethyl ether, methyl formate, methyl amine and ethyl amine, such that | Q abs | ≤ | Q evap | + Q ext , wherein Q abs is the amount of heat released from said solid material when it absorbs ammonia from the liquid phase thereof to the point where it is saturated with ammonia, Q evap is the amount of heat absorbed by said cooling agent when it evaporates, and Q ext is the amount of heat exchanged with the surroundings and is positive, if heat is removed from the process by external cooling, and negative, if heat is added to the process from the surroundings.
摘要翻译：使能够通过吸收和吸收结合氨并且最初不含氨或部分被氨饱和的固体材料饱和的方法包括在氨的蒸气压曲线下的压力和相关温度下处理所述固体材料，其量为液体足以使所述固体材料饱和的氨和额外量的选自液态氨，液体或固体CO 2，烃和氢卤素的冷却剂，其具有比氨，乙醚，甲酸甲酯，甲胺和乙胺更高的蒸气压，那个 Qabs | = | Qevap | + Qext，其中Q abs是当从其液相吸收氨到其被氨饱和的点时从所述固体材料释放的热量，Qevap是当所述冷却剂蒸发时吸收的热量，以及 Qext是与周围环境交换的热量，如果通过外部冷却从过程中除去热量，则为正，如果从周围环境中加热，则为负值。

7. 发明申请

WO2010025947A1 SATURATION OF AMMONIA STORAGE MATERIALS IN CONTAINERS 审中-公开
标题翻译：集装箱中的氨氮储存材料的饱和度
公开(公告)号：WO2010025947A1
公开(公告)日：2010-03-11
申请号：PCT/EP2009/006470
申请日：2009-09-07
申请人： AMMINEX A/S , SVAGIN, Jakob , QUAADE, Ulrich , BRADLEY, Ryan , JOHANSEN, Johnny , SCHMIDT, Henning , JOHANNESSEN, Tue
发明人： SVAGIN, Jakob , QUAADE, Ulrich , BRADLEY, Ryan , JOHANSEN, Johnny , SCHMIDT, Henning , JOHANNESSEN, Tue
IPC分类号： B01D53/14 , B01D53/90 , B01D53/94 , C01F11/24 , C09K5/04 , F25B17/08 , F25B35/04 , C01C1/00
CPC分类号： F17C11/00 , C01C1/006 , C01F11/24 , F25B17/08
摘要： A method of saturating reversible ammonia storage materials inside a container for the purpose of achieving high volumetric ammonia storage capacity and containers filled with the materials are disclosed.
摘要翻译：公开了一种使可逆氨储存材料在容器内饱和以达到高体积氨储存能力和装满材料的容器的方法。

8. 发明申请

WO2008077652A2 METHOD AND DEVICE FOR AMMONIA STORAGE AND DELIVERY USING IN-SITU RE-SATURATION OF A DELIVERY UNIT 审中-公开
标题翻译：使用现场重新输送单元进行氨氮储存和运输的方法和装置
公开(公告)号：WO2008077652A2
公开(公告)日：2008-07-03
申请号：PCT/EP2007/011502
申请日：2007-12-21
申请人： AMMINEX A/S , JOHANNESSEN, Tue
发明人： JOHANNESSEN, Tue
IPC分类号： B01D53/90 , B01D53/94 , C01C1/02 , F01N3/20 , H01M8/06 , H01M8/22 , H01M8/04 , B01D53/02
CPC分类号： C01C1/02 , B01D53/02 , B01D53/0407 , B01D53/8625 , B01D53/90 , B01D53/9409 , B01D53/9431 , B01D2251/2062 , B01D2253/10 , B01D2253/20 , B01D2257/406 , B01D2259/4525 , C01C1/006 , F01N3/2066 , F01N2610/02 , F01N2610/06 , F01N2610/10 , F01N2610/11 , F01N2610/14 , F01N2610/1406 , F17C11/00 , H01M8/04208 , H01M8/04216 , H01M8/0606 , H01M8/222 , H01M2008/1293 , Y02A50/2325 , Y02T10/24
摘要： Disclosed is a method for storing and delivering ammonia, wherein a first ammonia adsorbing/absorbing material having a higher vapor pressure at a given temperature than a second ammonia adsorbing/absorbing material is used as an ammonia source for said second ammonia adsorbing/absorbing material when said second adsorbing/absorbing material is depleted of ammonia by consumption, and a device for performing the method.
摘要翻译：本发明公开了一种用于储存和输送氨的方法，其中在给定温度下具有比第二氨吸附/吸收材料高的蒸汽压的第一氨吸附材料用作所述第二氨吸附材料的氨源，所述第二吸附/吸收材料通过消耗而耗尽氨，以及用于执行该方法的装置。

9. 发明申请

WO2006012903A2 A SOLID AMMONIA STORAGE AND DELIVERY MATERIAL 审中-公开
标题翻译：一种固体氨储存和运输材料
公开(公告)号：WO2006012903A2
公开(公告)日：2006-02-09
申请号：PCT/DK2005/000516
申请日：2005-08-03
申请人： AMMINEX A/S , CHRISTENSEN, Claus, Hviid , JOHANNESSEN, Tue , QUAADE, Ulrich , NØRSKOV, Jens, Kehlet , SØRENSEN, Rasmus, Zink
发明人： CHRISTENSEN, Claus, Hviid , JOHANNESSEN, Tue , QUAADE, Ulrich , NØRSKOV, Jens, Kehlet , SØRENSEN, Rasmus, Zink
IPC分类号： C01F5/00 , B01D53/94 , F01N3/20 , C01G45/00 , C01G49/00 , C01G3/14
CPC分类号： B01D53/565 , B01D53/90 , B01D53/9431 , B01J20/046 , B01J20/28011 , B01J20/3035 , C01C1/006 , C01F5/00 , C01G3/14 , C01G9/00 , C01G45/00 , C01G49/00 , C01G51/12 , C01G53/12 , C01P2006/10 , F01N3/2066 , F01N2610/02 , F01N2610/06 , F01N2610/10 , F17C11/00 , Y02T10/24
摘要： A solid ammonia storage and delivery material A solid ammonia storage material comprising: an ammonia absorbing salt, wherein the ammonia absorbing salt is an ionic salt of the general formula: M a (NH 3 ) n X z , wherein M is one or more cations selected from alkaline earth metals, and/or one or more transition metals, such as Mn, Fe, Co, Ni, Cu, and/or Zn, X is one or more anions, a is the number of cations per salt molecule, z is the number of anions per salt molecule, and ri is the coordination number of 2 to 12, wherein M is Mg provides a safe, light-weight and cheap compact storage for ammonia to be used in the automotive industry.
摘要翻译：固体氨储存和输送材料固体氨储存材料，其包含：氨吸收盐，其中所述氨吸收盐为通式M离子盐：（NH 3）n -X z -Z其中M是选自碱土金属的一种或多种阳离子，和/或一种或多种过渡金属，如Mn，Fe，Co，Ni，Cu和/或Zn，X是一个或多个阴离子，a是每个盐分子阳离子的数量，z是每个盐分子阴离子的数量，并且ri是配位其中M是Mg提供了一种安全，轻量且便宜的用于汽车工业的氨的紧凑储存。

10. 发明申请

WO2005091418A2 USE OF AN AMMONIA STORAGE DEVICE IN PRODUCTION OF ENERGY 审中-公开
标题翻译：使用氨基酸储存装置生产能源
公开(公告)号：WO2005091418A2
公开(公告)日：2005-09-29
申请号：PCT/DK2005/000196
申请日：2005-03-22
申请人： AMMINEX A/S , CHRISTENSEN, Claus, Hviid , JOHANNESSEN, Tue , NØRSKOV, Jens, Kehlet , QUAADE, Ulrich
发明人： CHRISTENSEN, Claus, Hviid , JOHANNESSEN, Tue , NØRSKOV, Jens, Kehlet , QUAADE, Ulrich
IPC分类号： H01M8/22
CPC分类号： C01C1/006 , C01F5/00 , C01F5/26 , C01P2002/72 , H01M8/04216 , H01M8/0606 , H01M8/22
摘要： An electric power generating unit comprising (i) an ammonia storage device in the form of a container comprising an ammonia absorbing and releasing salt of the general formula: M a (NH 3 ) n X z , wherein M is one or more cations selected from alkali metals, alkaline earth metals, and transition metals such as Li, K, Mg, Ca, V, Cr, Mn, Fe, Co, Ni, Cu or Zn, X is one or more anions selected from fluoride, chloride, bromide, iodide, nitrate, thiocyanate, sulphate, molybdate, phosphate, and chlorate ions, a is the number of cations per salt molecule, Z is the number of anions per salt molecule, and n is the coordination number of 2 to 12. (ii) means for heating said container and ammonia absorbing and releasing salt for releasing ammonia gas and (iiia) a fuel cell for converting ammonia directly into electric power; or (iiib1) a reactor for dissociating ammonia into hydrogen and nitrogen and (iiib2) a fuel cell for converting hydrogen into electric power is useful for large stationary energy producing facilities, but also for use for is useful for large stationary energy producing facilities, but also for use for small rechargeable and/or replaceable power supply units for micro-fabricated or miniaturized ammonia decomposition reactors for use in mobile units and portable devices may be used for large energy producing facilities, and by use of small rechargeable and/or replaceable ammonia storage decomposition reactors, it is also possible to provide energy for mobile units and portable devices.
摘要翻译：一种发电单元，包括（i）容器形式的氨储存装置，其包含通式为：（NH 3）n X z的氨吸收和释放盐，其中M是一种或多种阳离子，其选自碱金属，碱地球金属和过渡金属如Li，K，Mg，Ca，V，Cr，Mn，Fe，Co，Ni，Cu或Zn，X是一种或多种选自氟化物，氯化物，溴化物，碘化物，硝酸盐，硫酸盐，硫酸盐，钼酸盐，磷酸盐和氯酸根离子，a是每个盐分子的阳离子数，Z是每个盐分子的阴离子数，n是2至12的配位数。（ii）用于加热所述用于释放氨气的容器和氨吸收和释放盐和（iiia）用于将氨直接转化为电力的燃料电池; 或（iiib1）用于将氨离解成氢和氮的反应器和（iib2）用于将氢转化为电力的燃料电池对于大型固定能量生产设备是有用的，但也用于大型固定能量生产设施，但是也可用于用于移动单元和便携式设备的微型或微型氨分解反应堆的小型可再充电和/或可更换电源单元，可用于大型能源生产设备，并可使用小型可再充电和/或可更换氨存储分解反应器，还可以为移动单元和便携式设备提供能量。

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