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    • 3. 发明申请
    • N-TYPE SEMICONDUCTING DIAMOND, AND METHOD OF MAKING THE SAME
    • N型半导体金刚石及其制造方法
    • WO1992001314A1
    • 1992-01-23
    • PCT/US1990003818
    • 1990-07-06
    • ADVANCED TECHNOLOGY MATERIALS, INC.
    • ADVANCED TECHNOLOGY MATERIALS, INC.BEETZ, Charles, P., Jr.GORDON, Douglas, C.BROWN, Duncan, W.
    • H01L31/06
    • H01L29/1602C23C16/271C23C16/278H01L21/0237H01L21/02527H01L21/02576H01L21/0262
    • N-type semiconducting diamond (77, 142, 144) is disclosed which is intrinsically, i.e., at the time of diamond formation, doped with n-type dopant atoms. Such diamond is advantageously formed by chemical vapor deposition from a source gas mixture comprising a carbon source compound for the diamond, and a volatile precursor compound for the n-type impurity species, so that the n-type impurity atoms are doped in the diamond film in situ during its formation. By such in situ formation technique, shallow n-type impurity atoms, e.g., lithium, arsenic, phosphorus, scandium, antimony, bismuth, and the like, may be incorporated into the crystal lattice in a uniform manner, and without the occurrence of gross lattice asperities and other lattice damage artifacts which result from ion implantation techniques. A corresponding chemical vapor deposition method of forming the n-type semiconducting diamond is disclosed. The n-type semiconducting diamond of the invention may be usefully employed in the formation of diamond-based transistor devices comprising pn diamond junctions, and in other microelectronic device applications.
    • 公开了N型半导体金刚石(77,142,144),其固有地,即在金刚石形成时,掺杂有n型掺杂剂原子。 这种金刚石有利地通过来自包含用于金刚石的碳源化合物的源气体混合物和用于n型杂质物质的挥发性前体化合物的源气体混合物的化学气相沉积形成,使得n型杂质原子掺杂在金刚石膜 在其形成期间的原位。 通过这种原位形成技术,可以以均匀的方式将浅的n型杂质原子,例如锂,砷,磷,钪,锑,铋等掺入晶格中,而不会发生粗 晶格粗糙度和离子注入技术产生的其他晶格损伤伪像。 公开了形成n型半导体金刚石的相应的化学气相沉积方法。 本发明的n型半导体金刚石可有效地用于形成包括pn金刚石结的金刚石基晶体管器件和其它微电子器件应用中。