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    • 7. 发明申请
    • BIS(GLYOXIME)-TRANSITION METAL COLORIMETRIC MOISTURE INDICATORS
    • BIS(GLYOXIME)-TRANSITION金属色素水分指示剂
    • WO2013147934A1
    • 2013-10-03
    • PCT/US2012/065022
    • 2012-11-14
    • 3M INNOVATIVE PROPERTIES COMPANYHAJIME, Evan Koon Lun YuujiKANG, Myungchan
    • HAJIME, Evan Koon Lun YuujiKANG, Myungchan
    • G01N31/22G01N21/78
    • G01N31/222G01N21/78
    • Colorimetric moisture-indicating sensors comprising a solid polymeric support and a bis(glyoxime)-transition metal complex bound to the solid polymeric support are described. The solid polymeric support is a strong acid cation exchange resin. These colorimetric moisture-indicating compositions and sensors can be used to detect moisture. In some embodiments, detecting moisture comprises the sequential steps of (1) providing a colorimetric moisture-indicating sensor comprising a solid polymeric support and a bis(glyoxime)-transition metal complex bound to the support, and (2) exposing the composition to a moist atmosphere. A method of making a colorimetric moisture-indicating sensor comprising the sequential steps of (1) adsorbing transition metal ions onto a solid polymeric support, and (2) complexing a bis(glyoxime) to the adsorbed transition metal ions is also provided.
    • 描述了包含固体聚合物载体和结合到固体聚合物载体上的双(乙二肟) - 过渡金属络合物的比色湿度指示传感器。 固体聚合物载体是强酸阳离子交换树脂。 这些比例湿度指示组合物和传感器可用于检测水分。 在一些实施方案中,检测水分包括以下顺序步骤:(1)提供比色湿度指示传感器,其包含固体聚合物载体和与载体结合的双(乙二肟) - 过渡金属络合物,和(2)将组合物暴露于 潮湿的气氛。 还提供了一种制备比色湿度指示传感器的方法,其包括以下顺序步骤:(1)将过渡金属离子吸附到固体聚合物载体上,和(2)将双(乙二醛)与吸附的过渡金属离子络合。