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    • 4. 发明申请
    • HYDROGEN TREATMENT TO IMPROVE PHOTORESIST ADHESION AND REWORK CONSISTENCY
    • 氢化处理提高光电胶粘剂和重量一致性
    • WO2007038635A1
    • 2007-04-05
    • PCT/US2006/037751
    • 2006-09-26
    • APPLIED MATERIALS, INC.YEH, Wendy, H.
    • YEH, Wendy, H.
    • H01L21/311H01L21/3105G03F7/42
    • H01L21/31138G03F7/427H01L21/0206H01L21/3105H01L21/31058
    • A process for selectively removing photoresist, organic overlayers, and/or polymers/residues from a substrate without altering the surface chemistry and adhesion properties of the underlying substrate layers is provided. Generally, the process includes pretreating the substrate with hydrogen (e.g., by way of a hydrogen-based plasma) prior to deposition of a photoresist layer, and then ashing the substrate with a hydrogen-based plasma to selectively remove the photoresist, organic overlayers, and/or polymers/residues from the substrate during etching, post-etch, rework, etc. The hydrogen-based ashing process of the invention may be used post-etch to remove the residue photoresist, or may be used in a rework stripping process to remove misaligned patterns. The hydrogen-based ashing process following the initial hydrogen surface pretreatment substantially reduces surface chemistry poisoning, while retaining adequate adhesion properties following ashing.
    • 提供了一种从衬底选择性地去除光致抗蚀剂,有机覆盖层和/或聚合物/残余物而不改变下面的衬底层的表面化学性质和粘附性质的方法。 通常,该方法包括在沉积光致抗蚀剂层之前用氢气(例如,通过基于氢的等离子体)预处理衬底,然后用基于氢的等离子体灰化衬底以选择性地去除光致抗蚀剂,有机覆盖层, 和/或在蚀刻,蚀刻后,返工等中的来自衬底的聚合物/残余物。本发明的基于氢的灰化方法可以在蚀刻后用于除去残余光致抗蚀剂,或者可以用于返工剥离过程 去除不对齐的图案。 在初始氢表面预处理之后的氢基灰化过程基本上减少了表面化学中毒,同时在灰化之后保持了足够的粘附性能。