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1. 发明申请

WO2012142625A3 MULTIFUNCTIONAL NANOPARTICLE DESIGNS AND APPLICATIONS 审中-公开
标题翻译：多功能纳米设计与应用
公开(公告)号：WO2012142625A3
公开(公告)日：2013-01-03
申请号：PCT/US2012033853
申请日：2012-04-16
申请人： UNIV CALIFORNIA , ORTAC INANC , ESENER SADIK C , YANG JIAN , TROGLER WILLIAM
发明人： ORTAC INANC , ESENER SADIK C , YANG JIAN , TROGLER WILLIAM
IPC分类号： B82B3/00 , B01J13/02
CPC分类号： A61K9/5192 , A61K9/5073 , A61K9/5115 , A61K9/5146 , B01J13/22 , B01J20/28021 , B22D25/02 , B22D29/001 , B29C67/202 , B29C67/205 , B82B3/0019 , C04B35/14 , C04B35/624 , Y10S977/773 , Y10S977/896 , Y10S977/906 , Y10T428/2989
摘要： Methods, structures, devices and systems are disclosed for fabricating and implementing nanoparticles with hollow core and sealable holes. In one aspect, a nanoparticle device can includes a shell structure including at least two layers including an internal layer and an external layer, the internal layer structured to enclose a hollow interior region and include one or more holes penetrating the internal layer, the external layer is of a porous material and formed around the internal layer and sealing the one or more holes, and a substance contained within the hollow interior region, the substance incapable of passing through the external layer.
摘要翻译：公开了用于制造和实现具有中空芯和可密封孔的纳米颗粒的方法，结构，装置和系统。一方面，纳米颗粒装置可以包括壳结构，其包括至少两层，包括内层和外层，所述内层被构造为包围中空内部区域，并且包括穿透内层的一个或多个孔，外层是多孔材料，并且形成在内层周围并密封一个或多个孔，以及包含在中空内部区域内的物质，该物质不能通过外部层。

2. 发明申请

WO2012142625A2 MULTIFUNCTIONAL NANOPARTICLE DESIGNS AND APPLICATIONS 审中-公开
标题翻译：多功能纳米设计与应用
公开(公告)号：WO2012142625A2
公开(公告)日：2012-10-18
申请号：PCT/US2012/033853
申请日：2012-04-16
申请人： THE REGENTS OF THE UNIVERSITY OF CALIFORNIA , ORTAC, Inanc , ESENER, Sadik C. , YANG, Jian , TROGLER, William
发明人： ORTAC, Inanc , ESENER, Sadik C. , YANG, Jian , TROGLER, William
IPC分类号： B82B3/00 , B01J13/02
CPC分类号： A61K9/5192 , A61K9/5073 , A61K9/5115 , A61K9/5146 , B01J13/22 , B01J20/28021 , B22D25/02 , B22D29/001 , B29C67/202 , B29C67/205 , B82B3/0019 , C04B35/14 , C04B35/624 , Y10S977/773 , Y10S977/896 , Y10S977/906 , Y10T428/2989
摘要： Methods, structures, devices and systems are disclosed for fabricating and implementing nanoparticles with hollow core and sealable holes. In one aspect, a nanoparticle device can includes a shell structure including at least two layers including an internal layer and an external layer, the internal layer structured to enclose a hollow interior region and include one or more holes penetrating the internal layer, the external layer is of a porous material and formed around the internal layer and sealing the one or more holes, and a substance contained within the hollow interior region, the substance incapable of passing through the external layer.
摘要翻译：公开了用于制造和实现具有中空芯和可密封孔的纳米颗粒的方法，结构，装置和系统。一方面，纳米颗粒装置可以包括壳结构，其包括至少两层，包括内层和外层，所述内层被构造为包围中空内部区域，并且包括穿透内层的一个或多个孔，外层是多孔材料，并且形成在内层周围并密封一个或多个孔，以及包含在中空内部区域内的物质，该物质不能通过外部层。

3. 发明申请

WO2008140635A2 FLUORESCENCE DETECTION OF NITROGEN-CONTAINING EXPLOSIVES AND BLUE ORGANIC LED 审中-公开
标题翻译：含氮爆炸物和蓝色有机发光二极管的荧光检测
公开(公告)号：WO2008140635A2
公开(公告)日：2008-11-20
申请号：PCT/US2008001193
申请日：2008-01-29
申请人： UNIV CALIFORNIA , TROGLER WILLIAM C , SANCHEZ JASON
发明人： TROGLER WILLIAM C , SANCHEZ JASON
IPC分类号： G01N23/222 , H05B33/14
CPC分类号： C09K9/02 , C09K2211/1491
摘要： The invention provides a sensor for detecting nitrogen containing high explosives. The sensor includes a substrate and a blue-photoluminescent metallofluorene copolymer to be carried on said substrate during testing for nitrogen containing high explosives. The copolymer is preferably a blue- photoluminescent metallofluorene copolymer, and preferably is a vinyl bridged silafluorene copolymer. A method for detecting nitrogen containing high explosives involves exposing a copolymer to an analyte, preferably by spraying the copolymer or otherwise coating the substrate after it has been exposed to analyte and then exciting the copolymer to luminesce. The copolymer is observed for fluorescence quenching, which can be through human or electronic observation. The invention also provides for synthesis of a vinyl bridged silafluorene polymer by providing diethynylmetallofluorene and dihydrosilafluorene as precursors and conducting catalytic hydrosilation of the precursors. In a blue emitting organic light emitting diode of the invention, an emitting layer is blue-photoluminescent metallofluorene copolymer.
摘要翻译：本发明提供一种用于检测含有高爆炸物的氮的传感器。传感器包括在测试含氮高爆炸物的测试期间在所述基板上承载的基底和蓝色光致发光金属芴共聚物。共聚物优选为蓝色光致发光金属芴共聚物，优选为乙烯基桥接的硅芴共聚物。用于检测含氮高爆炸物的氮的方法包括将共聚物暴露于分析物，优选通过喷雾共聚物或以其它方式在暴露于分析物之后涂覆基底，然后激发共聚物发光而使共聚物暴露于分析物。观察到共聚物用于荧光猝灭，其可以通过人或电子观察。本发明还提供了通过提供二乙炔基金属芴和二氢钐芴作为前体并进行前体的催化硅氢化来合成乙烯基桥接的硅芴聚合物。在本发明的蓝色发光有机发光二极管中，发光层是蓝光发光金属芴共聚物。

4. 发明申请

WO2009023697A2 HOLLOW SILICA NANOSPHERES AND METHODS OF MAKING SAME 审中-公开
标题翻译：空心二氧化硅纳米球及其制备方法
公开(公告)号：WO2009023697A2
公开(公告)日：2009-02-19
申请号：PCT/US2008/072972
申请日：2008-08-13
申请人： THE REGENTS OF THE UNIVERSITY OF CALIFORNIA , TROGLER, William, C. , ESENER, Sadik, C. , MESSMER, Davorka , LIND, Johan, Ulrik , POHAKU, Kristina , YANG, Jian
发明人： TROGLER, William, C. , ESENER, Sadik, C. , MESSMER, Davorka , LIND, Johan, Ulrik , POHAKU, Kristina , YANG, Jian
IPC分类号： C01B33/12 , B82B3/00 , A61K9/51
CPC分类号： A61K47/6923 , A61K9/0019 , A61K9/14 , A61K9/1611 , A61K9/2009 , A61K9/5115 , A61K9/5192 , A61K39/0011 , A61K47/59 , A61K47/6455 , A61K47/6925 , A61K48/0041 , A61K49/04 , A61K49/183 , A61K2039/53 , A61K2039/6093 , B82Y5/00 , C01B33/12 , C01B33/18 , C12N15/87 , Y10S977/773 , Y10T428/2982
摘要： The disclosure provide hollow nanospheres and methods of making and using the same. The methods and compositions of the disclosure are useful for drug delivery and gene transfer.
摘要翻译：本公开提供了中空纳米球及其制备和使用方法。本公开的方法和组合物可用于药物递送和基因转移。

5. 发明申请

WO2009017631A2 PEROXIDE CHEMICAL SENSOR AND SENSING METHOD 审中-公开
标题翻译：过氧化物化学传感器和传感方法
公开(公告)号：WO2009017631A2
公开(公告)日：2009-02-05
申请号：PCT/US2008008916
申请日：2008-07-23
申请人： UNIV CALIFORNIA , TROGLER WILLIAM C , BOHRER FOREST , KUMMEL ANDREW C
发明人： TROGLER WILLIAM C , BOHRER FOREST , KUMMEL ANDREW C
IPC分类号： G01N27/26 , G01N27/32
CPC分类号： G01N33/0036 , G01N27/4141 , G01N27/4146 , Y10T436/145555 , Y10T436/206664 , Y10T436/25875
摘要： Sensors, sensing systems and sensing methods of the invention provide for detection of peroxides, including for example, vapor-phase H2O2 and organic peroxides such as di-tert-buty\ peroxide. A sensor and sensing method of the invention uses at least two phthalocyanines, one of which exhibits an oxidation reaction with peroxides and the other of which exhibits a reduction reaction with peroxides. A peroxide is readily identified by a sensor of the invention when one of the at least two phthalocyanines exhibits increased resistance to current flow and the other of the at least two phthalocyanines exhibits decreased resistance to current flow.
摘要翻译：本发明的传感器，感测系统和感测方法提供了检测过氧化物，包括例如气相H 2 O 2和有机过氧化物如过氧化二叔丁基。本发明的传感器和感测方法使用至少两种酞菁，其中一种与过氧化物发生氧化反应，另一种与过氧化物发生还原反应。当至少两种酞菁中的一种表现出对电流的增加的阻力并且至少两种酞菁中的另一种表现出对电流的阻力降低时，通过本发明的传感器很容易识别过氧化物。

6. 发明申请

WO2008140635A3 FLUORESCENCE DETECTION OF NITROGEN-CONTAINING EXPLOSIVES AND BLUE ORGANIC LED 审中-公开
公开(公告)号：WO2008140635A3
公开(公告)日：2008-11-20
申请号：PCT/US2008/001193
申请日：2008-01-29
申请人： THE REGENTS OF THE UNIVERSITY OF CALIFORNIA , TROGLER, William, C. , SANCHEZ, Jason
发明人： TROGLER, William, C. , SANCHEZ, Jason
IPC分类号： G01N23/222 , H05B33/14
摘要： The invention provides a sensor for detecting nitrogen containing high explosives. The sensor includes a substrate and a blue-photoluminescent metallofluorene copolymer to be carried on said substrate during testing for nitrogen containing high explosives. The copolymer is preferably a blue- photoluminescent metallofluorene copolymer, and preferably is a vinyl bridged silafluorene copolymer. A method for detecting nitrogen containing high explosives involves exposing a copolymer to an analyte, preferably by spraying the copolymer or otherwise coating the substrate after it has been exposed to analyte and then exciting the copolymer to luminesce. The copolymer is observed for fluorescence quenching, which can be through human or electronic observation. The invention also provides for synthesis of a vinyl bridged silafluorene polymer by providing diethynylmetallofluorene and dihydrosilafluorene as precursors and conducting catalytic hydrosilation of the precursors. In a blue emitting organic light emitting diode of the invention, an emitting layer is blue-photoluminescent metallofluorene copolymer.

7. 发明申请

WO2008005096A3 DETECTION OF NITRO-AND NITRATE-CONTAINING COMPOUNDS 审中-公开
标题翻译：检测含硝酸盐和硝酸盐的化合物
公开(公告)号：WO2008005096A3
公开(公告)日：2008-03-13
申请号：PCT/US2007010583
申请日：2007-05-01
申请人： UNIV CALIFORNIA , TROGLER WILLIAM C , SANCHEZ JASON , TOAL SARAH , WANG ZHENG , DUGAN REGINA E
发明人： TROGLER WILLIAM C , SANCHEZ JASON , TOAL SARAH , WANG ZHENG , DUGAN REGINA E
IPC分类号： G01N21/64 , G01N21/77
CPC分类号： G01N21/6428 , G01N21/77 , G01N2021/7786 , Y10T436/17 , Y10T436/173076 , Y10T436/173845
摘要： A method of the invention is a method of detecting nitramines and nitrate esters believed to be present on a sampling substrate. In the method, a sampling substrate is exposed to a first reagent that is formulated to react with nitramine- and nitrate ester-type explosives to release nitrite. The sampling substrate is then exposed to a second reagent that contains an acid to react with the nitrite and a diaminoaromatic. present in either the first or second reagent, to form a triazole that will luminesce. Another method of the invention combines this process for nitramine- and nitrate ester-based explosives detection with a technique to detect nitroaromatic-based explosives using luminescent polymers, for a three-step process for the detection of explosives in these three classes.
摘要翻译：本发明的方法是检测被认为存在于取样基质上的硝胺和硝酸酯的方法。在该方法中，将取样基质暴露于配制成与硝胺和硝酸酯型爆炸物反应以释放亚硝酸盐的第一试剂。然后将取样基质暴露于含有酸的第二试剂以与亚硝酸盐和二氨基芳族化合物反应。存在于第一或第二试剂中以形成将发光的三唑。本发明的另一种方法将该方法用于基于硝胺和硝酸酯的爆炸物检测，以及使用发光聚合物检测基于硝基芳族的爆炸物的技术，用于检测这三类爆炸物的三步过程。

8. 发明申请

WO2008005096A2 DETECTION OF NITRO-AND NITRATE-CONTAINING COMPOUNDS 审中-公开
标题翻译：含有硝酸和硝酸的化合物的检测
公开(公告)号：WO2008005096A2
公开(公告)日：2008-01-10
申请号：PCT/US2007/010583
申请日：2007-05-01
申请人： THE REGENTS OF THE UNIVERSITY OF CALIFORNIA , TROGLER, William, C. , SANCHEZ, Jason , TOAL, Sarah , WANG, Zheng , DUGAN, Regina, E.
发明人： TROGLER, William, C. , SANCHEZ, Jason , TOAL, Sarah , WANG, Zheng , DUGAN, Regina, E.
CPC分类号： G01N21/6428 , G01N21/77 , G01N2021/7786 , Y10T436/17 , Y10T436/173076 , Y10T436/173845
摘要： A method of the invention is a method of detecting nitramines and nitrate esters believed to be present on a sampling substrate. In the method, a sampling substrate is exposed to a first reagent that is formulated to react with nitramine- and nitrate ester-type explosives to release nitrite. The sampling substrate is then exposed to a second reagent that contains an acid to react with the nitrite and a diaminoaromatic. present in either the first or second reagent, to form a triazole that will luminesce. Another method of the invention combines this process for nitramine- and nitrate ester-based explosives detection with a technique to detect nitroaromatic-based explosives using luminescent polymers, for a three-step process for the detection of explosives in these three classes.
摘要翻译：本发明的方法是检测被认为存在于采样基质上的硝胺和硝酸酯的方法。在该方法中，将采样衬底暴露于配制成与硝胺和硝酸酯型炸药反应以释放亚硝酸盐的第一试剂。然后将采样衬底暴露于含有酸的第二试剂，以与亚硝酸盐和二氨基芳族化合物反应。存在于第一或第二试剂中，以形成将发光的三唑。本发明的另一种方法将用硝酸和硝酸酯类爆炸物检测的方法与使用发光聚合物检测基于硝基芳族化合物的爆炸物的技术结合，用于在这三类中检测爆炸物的三步法。

9. 发明申请

WO2007024227A1 INORGANIC POLYMERS AND USE OF INORGANIC POLYMERS FOR DETECTING NITROAROMATIC COMPOUNDS 审中-公开
标题翻译：无机聚合物和无机聚合物用于检测硝基化合物的用途
公开(公告)号：WO2007024227A1
公开(公告)日：2007-03-01
申请号：PCT/US2005/030381
申请日：2005-08-25
申请人： THE REGENTS OF THE UNIVERSITY OF CALIFORNIA , TROGLER, William, C. , URBAS, Sarah , TOAL, Sarah, J. , SANCHEZ, Jason
发明人： TROGLER, William, C. , URBAS, Sarah , TOAL, Sarah, J. , SANCHEZ, Jason
IPC分类号： G01N21/76 , B32B5/02 , C07F5/00
CPC分类号： C07F7/30 , G01N21/77 , G01N2021/6432 , G01N2021/7786
摘要： A method for detecting an analyze that may be present in ambient air, bound to a surface or as part of complex aqueous media that includes providing a metallole-containing polymer or copolymer, exposing the polymer or copolymer to a suspected analyze or a system suspected of including the analyze, and measuring a quenching of photoluminescence of the metallole-containing polymer or copolymer exposed to the system. Also included is a solid state inorganic-organic polymer sensor for detecting nitroaromatic compounds that includes a substrate and a thin film of a metallole-containing polymer or copolymer deposited on said substrate.
摘要翻译：用于检测可能存在于环境空气中，结合到表面或作为复合水性介质的一部分的分析的方法，所述复合水性介质包括提供含金属的聚合物或共聚物，将所述聚合物或共聚物暴露于怀疑分析物或涉嫌包括分析和测量暴露于该体系的含金属醇的聚合物或共聚物的光致发光的淬灭。还包括用于检测硝基芳族化合物的固态无机 - 有机聚合物传感器，其包括基材和沉积在所述基材上的含金属的聚合物或共聚物的薄膜。

10. 发明申请

WO2010044920A1 DETECTION OF EXPLOSIVES THROUGH LUMINESCENCE 审中-公开
标题翻译：通过发光检测爆炸物
公开(公告)号：WO2010044920A1
公开(公告)日：2010-04-22
申请号：PCT/US2009/045930
申请日：2009-06-02
申请人： REDXDEFENSE, LLC , MILLER, Dale, R. , TOAL, Sarah, J. , WATSON, Russell, P. , TROGLER, William, C.
发明人： MILLER, Dale, R. , TOAL, Sarah, J. , WATSON, Russell, P. , TROGLER, William, C.
IPC分类号： G01N21/00
CPC分类号： G01N21/643 , G01N21/6428 , G01N31/22 , G01N2021/6432 , Y10T436/13 , Y10T436/173076 , Y10T436/173845
摘要： A method of simultaneously detecting peroxide and nitrogen-based explosives includes the steps of applying a conversion reagent to a sample, the conversion reagent oxidizing in the presence of peroxide and inorganic nitrate explosives; applying a test reagent including a luminescent compound to the sample; exciting the luminescent compound with ultraviolet light; and simultaneously determining the presence of one or more explosives based on quenching, brightening or a shift in wavelength of the luminescence over time. Explosives may also be detected based on color changes of the sample. Optionally, phase transfer reagents, catalysts, colorimetric agents and zinc dust may be added to improve detection of explosives. Alternatively, an assay-type method may be utilized wherein a sample is added to the conversion and/or test reagents and the reagent is spotted on a substrate before exposure to ultraviolet light.
摘要翻译：同时检测过氧化物和氮基爆炸物的方法包括以下步骤：将转化试剂施用于样品，转化试剂在过氧化物和无机硝酸盐炸药存在下氧化; 将样品中含有发光性化合物的试剂涂布于样品中; 用紫外线激发发光化合物; 并且同时确定基于随着时间的发光的猝灭，增亮或波长的偏移的一种或多种爆炸物的存在。也可以根据样品的颜色变化来检测爆炸物。任选地，可以加入相转移试剂，催化剂，比色剂和锌粉以改善爆炸物的检测。或者，可以使用测定型方法，其中将样品加入到转化和/或测试试剂中，并且在暴露于紫外光之前将试剂点样在基底上。

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