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    • 2. 发明申请
    • FLUORESCENCE DETECTION OF NITROGEN-CONTAINING EXPLOSIVES AND BLUE ORGANIC LED
    • 含氮炸药和蓝色有机发光二极管的荧光检测
    • WO2009011806A2
    • 2009-01-22
    • PCT/US2008/008553
    • 2008-07-10
    • THE REGENTS OF THE UNIVERSITY OF CALIFORNIATROGLER, William, C.SANCHEZ, Jason
    • TROGLER, William, C.SANCHEZ, Jason
    • G01N23/04C08F12/02H05B33/14
    • C09K11/06C09K2211/1491
    • The invention provides a sensor for detecting nitrogen containing high explosives. The sensor includes a substrate and a blue-photoluminescent metallofluorene copolymer to be carried on said substrate during testing for nitrogen containing high explosives. The copolymer is preferably a blue- photoluminescent metallofluorene copolymer, and preferably is a vinyl bridged silafluorene copolymer. A method for detecting nitrogen containing high explosives involves exposing a copolymer to an analyte, preferably by spraying the copolymer or otherwise coating the substrate after it has been exposed to analyte and then exciting the copolymer to luminesce. The copolymer is observed for fluorescence quenching, which can be through human or electronic observation. The invention also provides for synthesis of a vinyl bridged silafluorene polymer by providing diethynylmetallofluorene and dihydrosilafluorene as precursors and conducting catalytic hydrosilation of the precursors. In a blue emitting organic light emitting diode of the invention, an emitting layer is blue-photoluminescent metallofluorene copolymer.
    • 本发明提供了一种用于检测含氮高爆炸药的传感器。 该传感器包括衬底和在测试含氮高爆炸物时在所述衬底上携带的蓝光致发光金属芴共聚物。 该共聚物优选为蓝光致发光金属芴共聚物,并且优选为乙烯基桥联的硅杂芴共聚物。 用于检测含氮高爆炸药的方法涉及将共聚物暴露于分析物,优选通过喷雾共聚物或以其他方式涂覆衬底,之后将衬底暴露于分析物,然后激发共聚物发光。 观察共聚物的荧光猝灭,其可以通过人或电子观察。 本发明还提供了通过提供二乙炔基金属芴和二氢硅烷芴作为前体并且进行前体的催化氢化硅烷化来合成乙烯基桥联的硅杂芴聚合物。 在本发明的蓝色发光有机发光二极管中,发光层是蓝光发光的金属芴共聚物。