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    • 8. 发明申请
    • METHOD FOR PRODUCING MALEIC ANHYDRIDE
    • 制备马来酸酐的方法
    • WO2004014833A2
    • 2004-02-19
    • PCT/EP0307982
    • 2003-07-22
    • BASF AGWEIGUNY JENSRUPPEL WILHELMDUDA MARK
    • WEIGUNY JENSRUPPEL WILHELMDUDA MARK
    • C07B61/00C07D307/60C07C51/00
    • C07D307/60
    • The invention relates to a method for producing maleic anhydride by the heterogeneous catalytic gas phase oxidation of hydrocarbons comprising at least four carbon atoms with gases containing oxygen, in the presence of a volatile phosphorus compound, on a catalyst containing vanadium, phosphor and oxygen in a multitube flow reactor unit with at least one reaction zone that is cooled by a heat-transfer medium, at a temperature ranging between 350 and 500 °C. In the first reaction zone, in relation to the educt supply, the supply temperature and/or the supply quantity is set in such a way that the average temperature of the heat transfer medium in the first reaction zone TSB(1st zone), said temperature being produced by the average value formation of the supply temperature and the drainage temperature of the heat-transfer medium, fulfils the formulas (I) and (II): (I) TSB(1st zone)
    • 一种用于通过具有在挥发性含磷化合物的催化剂在具有钒,磷和氧在管束反应器单元的至少一个的温度在所述范围由载热介质的反应区中冷却的存在下与含氧气体的至少四个碳原子的烃的非均相催化气相氧化制备马来酸酐的方法 从350至500℃,其中,在其中进料的温度和/或载热介质的供给量相对于被调节到反应物供应,在第一反应区,使得在第一反应区TSB载热介质的平均温度(第一区 ),其通过平均入口温度和载热介质的流动温度,式(I)和(II)得到的:TSB(第一区)<= TD(1个区) - TSafety(1个区)(I)... ; TSB,λ最大(1个区) - TA <= TSB(第一区)<= TSB,λ最大+ TB(II)被满足,其中TD(1(1区)(1个区)(1个区)。。。。 用于第一反应区的通过温度; TSafety(第一区)代表第一反应区的安全温度,为1°C; (1个区)TSB,λ最大是在第一反应区中的载热介质,其中,在TSB(第一区)的范围内的平均温度<= TD最大产率在马来酸酐实现。(1个区); TA(第一区)为20°C; 和TB(第一区)是10℃
    • 9. 发明申请
    • METHOD FOR PRODUCING CARBONYL COMPOUNDS
    • 用于生产羰基
    • WO1998028250A1
    • 1998-07-02
    • PCT/EP1997006855
    • 1997-12-09
    • BASF AKTIENGESELLSCHAFTFETZER, ThomasDEMUTH, DirkRÜTTER, HeinzMENIG, HelmuthRESCH, PeterRUPPEL, WilhelmWACHE, Harro
    • BASF AKTIENGESELLSCHAFT
    • C07C45/38
    • C07C45/39C07C45/38C07C47/04C07C47/127
    • The invention relates to a method for producing carbonyl compounds of formula (I), in which R is a hydrogen atom or alkyl radical with between 1 and 3 C atoms; R is a hydrogen atom or a radical of formula (II), in which R is a hydrogen atom or, together with R , an oxygen atom; R is the radical OR or, together with R , an oxygen atom; R is a hydrogen atom, an alkyl radical with between 1 and 8 C atoms or a cyclohexyl or cyclopentyl radical; and R is an alkyl radical with between 1 and 4 C atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula -CH2-CHO or -CH2-CH2-O-CH2-CHO. According to said method, the carbonyl compounds are produced by gas phase oxidation of methanol or alcohols of formula (III), in which R and R have the meaning assigned above and R is a hydrogen atom or an OR radical, and R is a hydrogen atom, an alkyl radical with between 1 and 4 C atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula -CH2-CH2-OH or -CH2-CH2-O-CH2-CH2-OH, with a gas containing oxygen, in the presence of catalysts containing copper and/or silver, and a phosphorus compound which is volatile under reaction conditions in such a quantity that the amount of phosphorus (calculated as P), in relation to the part by weight of alcohol used, is up to 20 ppm. Said method is characterized in that the quantity of phosphorus is added in at least two parts: a) the first part is added with the gaseous starting mixture before the catalyst bed, and b) at least one other part is added in the catalyst bed.
    • 本发明是一种用于制备式(I),其中R <1>是氢原子或具有1至3个碳原子的烷基的羰基化合物的方法,R <2>是一个氢原子或一个基团的式(II) 其中R <3>是氢原子或者与R <4>一起是氧原子,R <4>是或<6>,或者与R <3>一起是氧原子,R <5>是氢原子,具有1的烷基 到8个碳原子或一个环己基或环戊基,且R <6>为1至4个碳原子的环己基或Cyclopenthylrest或下式基团-CH 2 CHO或-CH2-CH2-O-CH2 - 的烷基 CHO指由甲醇或式(III)的醇的气相氧化,其中R <1>和R <5>具有以上所示的含义并且R <7>代表氢原子或基团或<8>和R <8> 氢原子,具有1至4个碳原子,环己基或环戊基团或下式基团-CH2-CH2-OH或-CH2-CH2-O-CH2-CH2-OH的烷基 指含氧气体中的铜和/或含银的催化剂和反应条件磷化合物下的易失性的,其量为使得磷(计算为P)的量,基于醇的重量使用时,达到20ppm的存在 ,其特征在于,磷的量在至少两个部分中加入,其中a)与气态原料混合物的催化剂床的上游和b)另一种组分是至少在催化剂床内添加所述第一部分。
    • 10. 发明申请
    • TUBE BUNDLE REACTOR FOR NON-CATALYZED OR HOMOGENOUSLY CATALYZED REACTIONS
    • 管式反应器非催化或均匀催化反应
    • WO2010083978A3
    • 2011-01-06
    • PCT/EP2010000280
    • 2010-01-19
    • BASF SETELES JOAQUIM HENRIQUERESCH PETERRUPPEL WILHELMWEGERLE ULRIKEGERLINGER WOLFGANGROESSLER-FEIGEL BEATRICEMEIER ANTONMUELLER CHRISTIAN
    • TELES JOAQUIM HENRIQUERESCH PETERRUPPEL WILHELMWEGERLE ULRIKEGERLINGER WOLFGANGROESSLER-FEIGEL BEATRICEMEIER ANTONMUELLER CHRISTIAN
    • B01J19/24B01J19/00
    • B01J19/2425B01J4/001B01J19/006B01J2219/00085B01J2219/00166F28D7/16F28F9/0265F28F9/0275F28F9/0278Y02P20/582
    • The invention relates to a tube bundle reactor having a flat feed dome. Alternatively, the discharge dome can also be designed flat. The flat design reduces the reaction heat developing in the hood in reaction types that take place not only in the tube bundle (non-catalyzed reactions and reactions with homogenously distributed catalyst). Undesired reactions that already take place in the dome due to accumulated heat are thus heavily suppressed, whereby greater selectivity in temperature-sensitive reactions is achieved. Additionally, the temperature distribution within the domes can be precisely controlled. The tube bundle reactor comprises a tube bundle that has a feed end connected to a feed dome of the tube bundle reactor, wherein the feed dome is designed in a flat shape having a cross-sectional surface at the feed end and an inner volume, and the ratio of the inner volume to the cross-sectional surface is less than 0.35 m. The invention is furthermore implemented by a method for operating a tube bundle reactor, comprising: introducing a reactant mixture into a tube bundle and converting at least a portion of the reactant mixture into a product inside the tube bundle. The introduction step comprises: feeding the reactant mixture into an inner space of a feed dome of the tube bundle reactor and forwarding the reactant mixture into a feed end of the tube bundle in the form of a fluid flow. The fluid flow has a cross-sectional surface upon entering the feed end and the inner space of the feed dome through which the fluid flows has an inner volume; wherein the ratio of the inner volume to the cross-sectional surface is less than 0.35 m.
    • 本发明涉及一种具有平面供应罩管束反应器。 可替换地,放电罩可以制成平的。 扁平设计降低导致反应类型,发生不仅在Rohbündel(未催化的反应和反应以均匀地分布催化剂)罩反应热。 其特征在于,由此更高的选择性与对温度敏感的反应实现的是那些已经在罩发生不希望的反应,由于积热,强烈抑制。 此外,该罩内的温度分布可以被精确地控制。 包括具有进料端,其连接到所述管束反应器的供给罩管束管束反应器中,与在进料端的内部容积的横截面面积和扁平形状的供给罩构造,并且内部容积的横截面面积的比例为小于0, 35米。 引入在管束中的反应物混合物,并且至少在管束内的反应混合物的一部分反应,以一个产品:此外,本发明是通过一种用于操作管束反应器的方法,包括的手段来实现。 放电,其包括:供给所述反应物混合物进入管束反应器的供给罩的内和反应物混合物通入在流体流的形式管束的一个进给端。 流体流动的横截面面积,因为它进入的进料端和通过其流体流流,具有内部容积的供给机罩的内部; 其中内部体积与横截面面积的比例为小于0.35微米。