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    • 1. 发明申请
    • METHOD FOR PRODUCING CARBONYL COMPOUNDS
    • 用于生产羰基
    • WO1998028251A1
    • 1998-07-02
    • PCT/EP1997006856
    • 1997-12-09
    • BASF AKTIENGESELLSCHAFTFETZER, ThomasDEMUTH, DirkRÜTTER, HeinzMENIG, HelmuthRESCH, PeterRUPPEL, WilhelmWACHE, Harro
    • BASF AKTIENGESELLSCHAFT
    • C07C45/38
    • C07C45/39C07C45/38C07C47/04C07C47/127
    • The invention relates to a method for producing carbonyl compounds of formula (I), in which R is a hydrogen atom or an alkyl radical with between 1 and 3 C atoms; R is a hydrogen atom or a radical of formula (II) in which R is a hydrogen atom or, together with R , an oxygen atom; R is the radical OR or, together with R , an oxygen atom; R is a hydrogen atom, an alkyl radical with between 1 and 8 C atoms or a cyclohexyl or cyclopentyl radical; and R is an alkyl radical with between 1 and 4 C atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula -CH2-CHO or -CH2-CH2-O-CH2-CHO. According to said method, the carbonyl compounds are produced by gas-phase oxidation of methanol or alcohols of formula (III), in which R and R have the meaning assigned above and R is a hydrogen atom or an OR radical, and R is a hydrogen atom, an alkyl radical with between 1 and 4 C atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula -CH2-CH2-OH or -CH2-CH2-O-CH2-CH2-OH, with a gas containing oxygen, in the presence of catalysts containing copper and/or silver and a phosphorus compounds which is volatile under reaction conditions, in such a quantity that the quantity of phosphorus (calculated as P) in relation to the part by weight of alcohol used is up to 20 ppm. The method is characterized in that the quantity of phosphorus is added in the catalyst bed.
    • 本发明是一种用于制备式(I),其中R <1>是氢原子或具有1至3个碳原子的烷基的羰基化合物的方法,R <2>是一个氢原子或一个基团的式(II) 其中R <3>是氢原子或者与R <4>一起是氧原子,R <4>是或<6>,或者与R <3>一起是氧原子,R <5>是氢原子,具有1的烷基 到8个碳原子或一个环己基或环戊基,且R <6>为1至4个碳原子,环己基或环戊基团或一个式的基团-CH 2 CHO或-CH2-CH2-O-CH2 - 的烷基 CHO指由甲醇或式(III)的醇的气相氧化,其中R <1>和R <5>具有以上所示的含义并且R <7>代表氢原子或基团或<8>和R <8> 氢原子,具有1至4个碳原子,环己基或环戊基团或下式基团-CH2-CH2-OH或-CH2-CH2-O-CH2-CH2-OH b的烷基 edeutet与含氧气体,是含有催化剂和反应条件磷化合物下的易失性的量,使得磷(计算为P)的量,基于醇的重量使用时,达到20ppm的铜和/或银的存在 ,其特征在于,磷的量在催化剂床内加入。
    • 4. 发明申请
    • METHOD FOR PRODUCING CARBONYL COMPOUNDS
    • 用于生产羰基
    • WO1998028250A1
    • 1998-07-02
    • PCT/EP1997006855
    • 1997-12-09
    • BASF AKTIENGESELLSCHAFTFETZER, ThomasDEMUTH, DirkRÜTTER, HeinzMENIG, HelmuthRESCH, PeterRUPPEL, WilhelmWACHE, Harro
    • BASF AKTIENGESELLSCHAFT
    • C07C45/38
    • C07C45/39C07C45/38C07C47/04C07C47/127
    • The invention relates to a method for producing carbonyl compounds of formula (I), in which R is a hydrogen atom or alkyl radical with between 1 and 3 C atoms; R is a hydrogen atom or a radical of formula (II), in which R is a hydrogen atom or, together with R , an oxygen atom; R is the radical OR or, together with R , an oxygen atom; R is a hydrogen atom, an alkyl radical with between 1 and 8 C atoms or a cyclohexyl or cyclopentyl radical; and R is an alkyl radical with between 1 and 4 C atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula -CH2-CHO or -CH2-CH2-O-CH2-CHO. According to said method, the carbonyl compounds are produced by gas phase oxidation of methanol or alcohols of formula (III), in which R and R have the meaning assigned above and R is a hydrogen atom or an OR radical, and R is a hydrogen atom, an alkyl radical with between 1 and 4 C atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula -CH2-CH2-OH or -CH2-CH2-O-CH2-CH2-OH, with a gas containing oxygen, in the presence of catalysts containing copper and/or silver, and a phosphorus compound which is volatile under reaction conditions in such a quantity that the amount of phosphorus (calculated as P), in relation to the part by weight of alcohol used, is up to 20 ppm. Said method is characterized in that the quantity of phosphorus is added in at least two parts: a) the first part is added with the gaseous starting mixture before the catalyst bed, and b) at least one other part is added in the catalyst bed.
    • 本发明是一种用于制备式(I),其中R <1>是氢原子或具有1至3个碳原子的烷基的羰基化合物的方法,R <2>是一个氢原子或一个基团的式(II) 其中R <3>是氢原子或者与R <4>一起是氧原子,R <4>是或<6>,或者与R <3>一起是氧原子,R <5>是氢原子,具有1的烷基 到8个碳原子或一个环己基或环戊基,且R <6>为1至4个碳原子的环己基或Cyclopenthylrest或下式基团-CH 2 CHO或-CH2-CH2-O-CH2 - 的烷基 CHO指由甲醇或式(III)的醇的气相氧化,其中R <1>和R <5>具有以上所示的含义并且R <7>代表氢原子或基团或<8>和R <8> 氢原子,具有1至4个碳原子,环己基或环戊基团或下式基团-CH2-CH2-OH或-CH2-CH2-O-CH2-CH2-OH的烷基 指含氧气体中的铜和/或含银的催化剂和反应条件磷化合物下的易失性的,其量为使得磷(计算为P)的量,基于醇的重量使用时,达到20ppm的存在 ,其特征在于,磷的量在至少两个部分中加入,其中a)与气态原料混合物的催化剂床的上游和b)另一种组分是至少在催化剂床内添加所述第一部分。