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1. 发明申请

WO2011017797A1 FRACTIONATION OF A WASTE LIQUOR STREAM FROM NANOCRYSTALLINE CELLULOSE PRODUCTION 审中-公开
标题翻译：来自纳米晶体纤维素生产的废液流的分离
公开(公告)号：WO2011017797A1
公开(公告)日：2011-02-17
申请号：PCT/CA2010/001198
申请日：2010-07-28
申请人： FPINNOVATIONS , JEMAA, Naceur , PALEOLOGOU, Michael , ZHANG, Xiao
发明人： JEMAA, Naceur , PALEOLOGOU, Michael , ZHANG, Xiao
IPC分类号： C01B17/90 , B01D61/00 , C08B1/00 , D21C11/00
CPC分类号： D21C9/00 , B01D61/027 , C01B17/902 , C08B15/08 , D21C11/0007
摘要： During nanocrystalline cellulose (NCC) production, a considerable amount of sulphuric acid is used. After the separation of the NCC, the remaining solution contains sugars and residual sulphuric acid. The sugars are in the monomeric and oligomeric forms. To reduce the cost of NCC production and to produce other added-value products, the spent acid stream can be fractionated into sugar oligomers, sugar monomers, and acid. The acid can be recycled to the NCC manufacturing process after concentration. The sugar monomers and sugar oligomers can be used for the manufacturing of other valuable chemicals. Membrane nanofiltration can be used to achieve this objective. A polymeric membrane with a molecular weight cut-off in the range of 200 Dalton was employed. Using this approach, the majority of the acid was recovered in the permeate while the sugars were concentrated in a smaller stream. The sugar level in the separated acid/permeate stream was only about 3% of the original concentration. A second membrane filtration stage can be used to separate the monomeric from the oligomeric sugars. The two sugar streams can be employed in different applications to produce value-added products.
摘要翻译：在纳米晶纤维素（NCC）生产过程中，使用了大量的硫酸。在分离NCC后，剩余的溶液含有糖和残留的硫酸。糖是单体和低聚物形式。为了降低NCC生产成本和生产其他附加值产品，废酸流可以分馏成糖低聚物，糖单体和酸。浓缩后，酸可以回收到NCC制造过程。糖单体和糖低聚物可用于制造其他有价值的化学品。膜纳米过滤可以用来达到这个目的。使用分子量截止值在200道尔顿范围内的聚合物膜。使用这种方法，大部分酸在渗透物中回收，而糖被浓缩在较小的流中。分离的酸/渗透物流中的糖含量仅为原始浓度的约3％。可以使用第二膜过滤阶段将单体与低聚糖分离。这两种糖流可用于不同的应用，以产生增值产品。

2. 发明申请

WO9816462A9 TREATMENT OF CHLORINE DIOXIDE GENERATOR EFFLUENT AND FEED STREAMS WITH FIXED-RESIN BED 审中-公开
标题翻译：二氧化氯发生器液体和固定树脂进料流的处理
公开(公告)号：WO9816462A9
公开(公告)日：1999-04-01
申请号：PCT/CA9700750
申请日：1997-10-09
申请人： PULP PAPER RES INST , ECO TEC , PALEOLOGOU MICHAEL , THOMPSON ROKHSAREH , BROWN CRAIG J , SHEEDY MICHAEL
发明人： PALEOLOGOU MICHAEL , THOMPSON ROKHSAREH , BROWN CRAIG J , SHEEDY MICHAEL
IPC分类号： B09B3/00 , B01J39/04 , C01B11/02 , C01B17/90 , C01D5/16 , C02F1/44 , D21C9/14
CPC分类号： C01B17/904 , C01B11/023 , C01D5/16 , Y10S423/14
摘要： A process employing a fixed-resin bed Acid Retardation Unit (ARU) to separate spent acid from chlorine dioxide generators into a de-acidified sodium sulfate component and a purified sulfuric acid component. The de-acidified sodium sulfate produced is returned to the chemical recovery cycle of the kraft mill in place of acidic chlorine dioxide generator effluent thereby avoiding the destruction of alkalinity in pulp mill liquors. In addition, sulfuric acid is purified providing an opportunity for reuse in various mill applications, and/or concentrated and recycled to the generator. Alternatively, to avoid high evaporation costs, the purified acid can be used to regenerate a cation-exchange unit (CEU) used in the conversion of sodium chlorate to a sodium chlorate/chloric acid mixture which is fed to the generator in place of sodium chlorate and sulfuric acid. Using this approach, the sulfuric acid requirement of chlorine dioxide generators and, in turn, the amount of acidic generator effluent can be reduced. The process is applicable to both atmospheric and subatmospheric chlorine dioxide generators. In the latter case, the concentration of the purified sulfuric acid from the ARU or any other acid separation system can be increased by using a portion of it to dissolve the sodium sesquisulfate by-product from such generators.
摘要翻译：一种使用固定树脂床酸延迟单元（ARU）将废酸从二氧化氯发生器分离成脱酸的硫酸钠组分和纯化的硫酸组分的方法。所产生的脱酸硫酸钠返回到牛皮纸磨机的化学回收循环，代替酸性二氧化氯发生器流出物，从而避免纸浆厂液中碱度的破坏。此外，纯化硫酸提供了在各种研磨应用中再利用的机会，和/或浓缩并再循环到发生器中。或者，为了避免高的蒸发成本，可以使用纯化的酸来再生用于将氯酸钠转化成氯酸钠/氯酸混合物的阳离子交换单元（CEU），该氯酸钠/氯酸混合物被供给到发生器代替氯酸钠和硫酸。使用这种方法，可以减少二氧化氯发生器的硫酸需求，进而降低酸性发生器流出物的量。该方法适用于大气和低气压的二氧化氯发生器。在后一种情况下，来自ARU或任何其它酸分离系统的纯化硫酸的浓度可以通过使用其一部分来从这种发生器中溶解倍半硫酸钠副产物而增加。

3. 发明申请

WO1998016462A1 TREATMENT OF CHLORINE DIOXIDE GENERATOR EFFLUENT AND FEED STREAMS WITH FIXED-RESIN BED 审中-公开
标题翻译：二氧化氯发生器液体和固定树脂进料流的处理
公开(公告)号：WO1998016462A1
公开(公告)日：1998-04-23
申请号：PCT/CA1997000750
申请日：1997-10-09
申请人： PULP AND PAPER RESEARCH INSTITUTE OF CANADA , ECO-TEC LIMITED , PALEOLOGOU, Michael , THOMPSON, Rokhsareh , BROWN, Craig, J. , SHEEDY, Michael
发明人： PULP AND PAPER RESEARCH INSTITUTE OF CANADA , ECO-TEC LIMITED
IPC分类号： C01B11/02
CPC分类号： C01B17/904 , C01B11/023 , C01D5/16 , Y10S423/14
摘要： A process employing a fixed-resin bed Acid Retardation Unit (ARU) to separate spent acid from chlorine dioxide generators into a de-acidified sodium sulfate component and a purified sulfuric acid component. The de-acidified sodium sulfate produced is returned to the chemical recovery cycle of the kraft mill in place of acidic chlorine dioxide generator effluent thereby avoiding the destruction of alkalinity in pulp mill liquors. In addition, sulfuric acid is purified providing an opportunity for reuse in various mill applications, and/or concentrated and recycled to the generator. Alternatively, to avoid high evaporation costs, the purified acid can be used to regenerate a cation-exchange unit (CEU) used in the conversion of sodium chlorate to a sodium chlorate/chloric acid mixture which is fed to the generator in place of sodium chlorate and sulfuric acid. Using this approach, the sulfuric acid requirement of chlorine dioxide generators and, in turn, the amount of acidic generator effluent can be reduced. The process is applicable to both atmospheric and subatmospheric chlorine dioxide generators. In the latter case, the concentration of the purified sulfuric acid from the ARU or any other acid separation system can be increased by using a portion of it to dissolve the sodium sesquisulfate by-product from such generators.
摘要翻译：一种使用固定树脂床酸延迟单元（ARU）将废酸从二氧化氯发生器分离成脱酸的硫酸钠组分和纯化的硫酸组分的方法。所产生的脱酸硫酸钠返回到牛皮纸磨机的化学回收循环，代替酸性二氧化氯发生器流出物，从而避免纸浆厂液中碱度的破坏。此外，纯化硫酸提供了在各种研磨应用中再利用的机会，和/或浓缩并再循环到发生器中。或者，为了避免高的蒸发成本，可以使用纯化的酸来再生用于将氯酸钠转化成氯酸钠/氯酸混合物的阳离子交换单元（CEU），该氯酸钠/氯酸混合物被供给发生器代替氯酸钠和硫酸。使用这种方法，可以减少二氧化氯发生器的硫酸需求，进而降低酸性发生器流出物的量。该方法适用于大气和低气压的二氧化氯发生器。在后一种情况下，来自ARU或任何其它酸分离系统的纯化硫酸的浓度可以通过使用其一部分来从这种发生器中溶解倍半硫酸钠副产物而增加。

4. 发明申请

WO1990012637A2 ELECTRODIALYTIC WATER SPLITTING PROCESS FOR THE TREATMENT OF AQUEOUS ELECTROLYTES 审中-公开
标题翻译：电解水分离工艺处理水性电解液
公开(公告)号：WO1990012637A2
公开(公告)日：1990-11-01
申请号：PCT/CA1990000116
申请日：1990-04-09
申请人： PULP AND PAPER RESEARCH INSTITUTE OF CANADA , PALEOLOGOU, Michael , BERRY, Richard, M.
发明人： PULP AND PAPER RESEARCH INSTITUTE OF CANADA
IPC分类号： B01D61/44
CPC分类号： C01B15/043 , B01D61/445 , D21C11/005
摘要： A process for dealkalization or acidification of aqueous salt solutions or for the splitting of the salt of such solutions employs a water splitting system of bipolar membranes (3) in conjunction with ion selective membranes (2); a two-compartment cell employs cation permselective membranes (2) to define acid and base compartments with the bipolar membranes (3), and a three compartment cell employs anion permselective and cation permselective membranes to define with the bipolar membrane salt, acid and base compartments; the process has particular applicability to the dealkalization of a monosodium peroxide solution containing sodium hydroxide produced in a hydrogen peroxide generator.
摘要翻译：用于盐水溶液的脱碱化或酸化或这种溶液的盐分离的方法采用双极膜（3）与离子选择膜（2）结合的水分解系统; 双室细胞采用阳离子选择性选择膜（2）来界定具有双极性膜（3）的酸性和碱性隔室，并且三室电池采用阴离子选择性和阳离子选择性选择膜，以双极性膜盐，酸和碱性隔室 ; 该方法特别适用于在过氧化氢发生器中产生的含有氢氧化钠的过氧化钠溶液的脱碱化。

5. 发明申请

WO2012106808A1 PHENOL-FORMALDEHYDE AND LIGNIN-PHENOL-FORMALDEHYDE ADHESIVE POLYMERS WITH CARBON BLACK, AND METHOD OF MAKING SAME 审中-公开
标题翻译：具有碳黑的酚醛树脂和木质素 - 酚醛硬脂酸聚合物及其制备方法
公开(公告)号：WO2012106808A1
公开(公告)日：2012-08-16
申请号：PCT/CA2012/000117
申请日：2012-02-10
申请人： FPINNOVATIONS INC. , KOUISNI, Lamfeddal , PALEOLOGOU, Michael , ZHANG, Yaolin , WANG, Xiang-Ming , FENG, Martin
发明人： KOUISNI, Lamfeddal , PALEOLOGOU, Michael , ZHANG, Yaolin , WANG, Xiang-Ming , FENG, Martin
IPC分类号： C09J161/06 , B32B21/13 , C09J11/04
CPC分类号： C09J161/06 , C08K3/04 , C08L97/02 , C09J161/14 , C08L61/06 , C08L97/005
摘要： Phenol-formaldehyde and lignin-phenol formaldehyde adhesive polymers with improved properties are disclosed, as well as the method of production therein. The method comprises providing at least one phenolic compound at least one formaldehyde compound, an alkali metal hydroxide, water and at least one carbon black; mixing the at least one phenolic compound, the at least one formaldehyde compound, the alkali metal hydroxide, the water and the carbon black to produce a methylolation medium at a pH of about 10 or less; maintaining the medium at a methylolation temperature to produce a methylolated medium reacting with the water predominantly; and increasing the temperature of the methylolated medium to produce the phenol-formaldehyde polymer via a condensation reaction.
摘要翻译：公开了具有改进性能的苯酚 - 甲醛和木质素 - 苯酚甲醛粘合剂聚合物及其生产方法。该方法包括提供至少一种酚类化合物至少一种甲醛化合物，碱金属氢氧化物，水和至少一种炭黑; 混合至少一种酚类化合物，至少一种甲醛化合物，碱金属氢氧化物，水和炭黑，以产生约10或更低的pH值的羟甲基化培养基; 将培养基保持在甲氧基化温度以产生主要与水反应的羟甲基化介质; 并通过缩合反应提高羟甲基化介质的温度以产生苯酚 - 甲醛聚合物。

6. 发明申请

WO2010034111A1 PROCESS FOR PRODUCING CHLORINE DIOXIDE USING WASTE GLYCEROL FROM A BIODIESEL PLANT 审中-公开
标题翻译：生物柴油厂使用废弃甘油的二氧化氯生产工艺
公开(公告)号：WO2010034111A1
公开(公告)日：2010-04-01
申请号：PCT/CA2009/001331
申请日：2009-09-22
申请人： FPINNOVATIONS , JEMAA, Naceur , PALEOLOGOU, Michael
发明人： JEMAA, Naceur , PALEOLOGOU, Michael
IPC分类号： C01B11/02 , C10G3/00
CPC分类号： C01B11/023 , C10G2300/1014 , C10L1/026 , Y02E50/13 , Y02P30/20
摘要： A process for chlorine dioxide production uses waste glycerol from biodiesel plants as a reducing agent. This untreated waste stream may contain other reducing agents such as sodium chloride and methanol which were found to enhance the chlorine dioxide production. Other chemicals present in this waste stream did not affect the operation of the chlorine dioxide generator. Substituting the waste glycerol for methanol or other reducing agents helps kraft pulp mills in reducing the cost of producing chlorine dioxide while providing a use for the untreated waste glycerol stream.
摘要翻译：生产二氧化氯的方法使用来自生物柴油植物的废甘油作为还原剂。这种未经处理的废物流可能含有其他还原剂，如氯化钠和甲醇，这些还原剂可以增强二氧化氯的产生。存在于该废物流中的其它化学物质不影响二氧化氯发生器的运行。将废甘油代替甲醇或其它还原剂可以帮助牛皮纸浆厂减少生产二氧化氯的成本，同时为未处理的废甘油流提供用途。

7. 发明申请

WO1996025225A1 SEPARATION OF SULPHIDES AND CHLORIDES FROM PULPING LIQUORS BY ELECTRODIALYSIS 审中-公开
标题翻译：通过电化学分离来自搅拌液的硫化物和氯化物
公开(公告)号：WO1996025225A1
公开(公告)日：1996-08-22
申请号：PCT/CA1996000085
申请日：1996-02-09
申请人： PULP AND PAPER RESEARCH INSTITUTE OF CANADA , THOMPSON, Rokhsareh , PALEOLOGOU, Michael , BERRY, Richard, McKinnon
发明人： PULP AND PAPER RESEARCH INSTITUTE OF CANADA
IPC分类号： B01D61/42
CPC分类号： C02F1/4693 , B01D61/44 , C02F2201/46115 , D21C11/0078
摘要： A process using an electrodialysis system employing cation-selective membranes and anion-selective membranes, particularly monovalent anion-selective membranes, is used to separate kraft pulping liquors into two streams; one that is rich in sulphides (to be used in the initial stage of pulping), and another that is poor in sulphides (to be used in the final stage of pulping). By separating pulping liquors in this way, the sulphur balance in the kraft process can be maintained while obtaining the benefits of modified pulping. The same electrodialytic system can be used to separate green and polysulphide liquors into sulphide-rich and sulphide-poor components.
摘要翻译：使用使用阳离子选择性膜和阴离子选择性膜，特别是一价阴离子选择性膜的电渗析系统的方法用于将硫酸盐制浆液分离成两股物流; 一种富含硫化物（用于制浆初期），另一种硫化物较差（用于制浆的最后阶段）。通过以这种方式分离制浆液，可以保持牛皮纸工艺中的硫平衡，同时获得改性制浆的优点。可以使用相同的电渗析系统将绿色和多硫化物液分离成富含硫化物和不含硫化物的组分。

8. 发明申请

WO2011150508A1 METHOD FOR SEPARATING LIGNIN FROM BLACK LIQUOR 审中-公开
标题翻译：从黑液中分离木瓜的方法
公开(公告)号：WO2011150508A1
公开(公告)日：2011-12-08
申请号：PCT/CA2011/000654
申请日：2011-05-31
申请人： FPINNOVATIONS , KOUISNI, Lamfeddal , PALEOLOGOU, Michael
发明人： KOUISNI, Lamfeddal , PALEOLOGOU, Michael
IPC分类号： C08H7/00
CPC分类号： D21C11/0057 , C07G1/00 , C08H8/00 , D21C11/0007
摘要： A process for the removal of lignin from black liquor comprising, a)oxidizing the black liquor containing lignin to remove total reduced sulphur (TRS), b)acidifying the oxidized black liquor to precipitate lignin and c)filtering precipitated lignin from the acidified black liquor. The filtering is followed by an optional washing of the filtered lignin with water and/or acid.
摘要翻译：一种从黑液中除去木质素的方法，包括：a）氧化含木质素的黑液以除去总还原硫（TRS），b）酸化氧化黑液以沉淀木质素，和c）从酸化的黑液中过滤沉淀的木质素。过滤之后是用水和/或酸任选地洗涤过滤的木质素。

9. 发明申请

WO2009079746A1 USE OF CHEMICAL PULP MILL STEAM STRIPPER OFF GASES CONDENSATE AS REDUCING AGENT IN CHLORINE DIOXIDE PRODUCTION 审中-公开
标题翻译：使用化学粉末蒸汽分离器将气体冷凝成二氧化氯生产中的还原剂
公开(公告)号：WO2009079746A1
公开(公告)日：2009-07-02
申请号：PCT/CA2008/002010
申请日：2008-11-12
申请人： FPINNOVATIONS , JEMAA, Naceur , PALEOLOGOU, Michael , SACCIADIS, George , BERRY, Richard M.
发明人： JEMAA, Naceur , PALEOLOGOU, Michael , SACCIADIS, George , BERRY, Richard M.
IPC分类号： C01B11/02 , D21C11/06
CPC分类号： C01B11/023 , D21C9/14 , D21C11/06
摘要： Steam stripper off gas from chemical pulp mills, for example kraft or sulphite pulp mills is rich in methanol and totally reduced sulphur (TRS) compounds. This gaseous stream is usually burned to avoid further handling of this TRS-rich, odorous stream. We found that once this gaseous stream is condensed, it can be used as a reducing agent in the chlorine dioxide generator, in place of purchased methanol. Surprisingly, we found that, in addition to the methanol component, the TRS components act as reducing agents during the production of chlorine dioxide or, at the very least, do not consume chlorine dioxide. The use of this stream in the ClO 2 generator will allow pulp mills to reduce or eliminate the consumption of purchased methanol while providing a new approach to deal with TRS compounds in the chlorine dioxide generator rather than employing a dedicated TRS incinerator or any other combustion device.
摘要翻译：来自化学纸浆厂的蒸汽汽提器，例如硫酸盐或亚硫酸盐纸浆厂富含甲醇和完全还原的硫（TRS）化合物。这种气流通常被燃烧以避免进一步处理这种富含TRS的气味流。我们发现，一旦气态物流被冷凝，就可以用二氧化氯发生器中的还原剂代替购买的甲醇。令人惊讶的是，我们发现除了甲醇成分之外，TRS成分在二氧化氯生产过程中起减压剂的作用，或至少不消耗二氧化氯。在ClO2发生器中使用这种料流将允许纸浆厂减少或消除购买的甲醇的消耗，同时提供了处理二氧化氯发生器中的TRS化合物的新方法，而不是使用专用的TRS焚化炉或任何其它燃烧装置。

10. 发明申请

WO2009012597A1 PROCESS FOR TREATING PULP MILL CONDENSATES USING A HOLLOW FIBER CONTACTOR 审中-公开
标题翻译：使用中空纤维接触器处理浆料冷凝液的方法
公开(公告)号：WO2009012597A1
公开(公告)日：2009-01-29
申请号：PCT/CA2008/001373
申请日：2008-07-24
申请人： FPINNOVATIONS , JEMAA, Naceur , PALEOLOGOU, Michael , O'CONNOR, Brian
发明人： JEMAA, Naceur , PALEOLOGOU, Michael , O'CONNOR, Brian
IPC分类号： C02F1/44 , B01D63/04 , C02F1/00 , C02F1/26 , D21C11/00 , B01D53/22
CPC分类号： B01D63/02 , B01D61/246 , B01D2311/13 , C02F1/20 , C02F2103/28 , C02F2301/063 , D21C11/00
摘要： A method and apparatus for the treatment of pulp mill condensates is described. A hollow fiber contactor, incorporating a hydrophobic membrane, was used to remove several undesirable compounds from pulp mill condensates. For example, TRS compounds and SO 2 were efficiently stripped from kraft and sulphite mill evaporator condensates, respectively. Methanol was also removed from kraft mill condensates but at a lower efficiency than TRS. Furthermore, other undesirable compounds found in condensates of pulp mills that contribute to the BOD and COD loading to effluent treatment systems were also removed. These contactors are cost effective since air, vacuum or a suitable solvent or scrubbing solution can be used as the stripping medium to drive off through the membrane several undesirable compounds from the feed solution. The undesirable compounds removed can thus be burned in the recovery boiler, lime kiln or a dedicated boiler.
摘要翻译：描述了用于处理纸浆厂冷凝物的方法和设备。使用掺入疏水膜的中空纤维接触器从纸浆厂冷凝物中除去若干不需要的化合物。例如，TRS化合物和SO 2分别从硫酸盐和亚硫酸盐蒸发器冷凝物中有效地脱除。甲醇也从牛皮纸浆冷凝物中除去，但效率低于TRS。此外，在纸浆厂的冷凝物中发现的有助于污水处理系统的BOD和COD负载的其他不希望的化合物也被去除。这些接触器具有成本效益，因为空气，真空或合适的溶剂或洗涤溶液可用作汽提介质以从进料溶液中排出几个不需要的化合物。因此，除去的不需要的化合物可以在回收锅炉，石灰窑或专用锅炉中燃烧。

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