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1. 发明申请

WO2012113058A1 PROCESS FOR FUNGAL MODIFICATION OF LIGNIN AND PREPARING WOOD ADHESIVES WITH THE MODIFIED LIGNIN AND WOOD COMPOSITES MADE FROM SUCH ADHESIVES 审中-公开
标题翻译：木质素修饰和木质粘合剂的改性方法与改性木质素和木质复合材料的制备方法
公开(公告)号：WO2012113058A1
公开(公告)日：2012-08-30
申请号：PCT/CA2012/000153
申请日：2012-02-17
申请人： FPINNOVATIONS , ZHANG, Yaolin , YANG, Dian-Qing , WANG, Xiang-Ming , FENG, Martin , BRUNETTE, Gilles
发明人： ZHANG, Yaolin , YANG, Dian-Qing , WANG, Xiang-Ming , FENG, Martin , BRUNETTE, Gilles
IPC分类号： C12P7/22 , B32B21/13 , B32B7/12 , C09J161/12 , C09J197/00 , C12N1/15 , C12P1/02
CPC分类号： C09J161/06 , C08G8/20 , C08G8/24 , C08H6/00 , C08L97/005 , C09J161/12 , C09J197/02 , C12N1/14 , C12P1/02 , C12P7/22 , C12R1/645
摘要： Disclosed herein are method to modify the lignin with particular fungal species, and procedure to synthesize phenolic adhesives with the modified lignin as raw materials, and the adhesives compositions and methods for making adhesive compositions, and methods for making lingo-cellulosic composites from renewable materials. Four fungi in examples are Lenzites elegans (Spreng.) Pat. (FTK 329A), Phanerochaete cremea (Bres.) Parmasto (FTK 332A), Pycnoporellus alboluteus (Ellis & Everh.) Kotl. & Pouz. (FTK 76A) and Meruliopsis taxicola (Pers.) Bondartsev (FTK 122B). Lignin used in examples are organosolv lignin, Kraft lignin, and ammonium lignosulfonate. The present invention includes methods to (1 ) modify of lignin with fungi; (2) in-situ polymerize modified lignin-phenol-formaldehyde to generate bio-modified lignin-phenol- formaldehyde adhesive in liquid form, and (3) manufacture composite panels with bio- modified lignin-phenol-formaldehyde resins.
摘要翻译：本文公开了用特定真菌种类修饰木质素的方法以及以改性木质素为原料合成酚醛粘合剂的方法，以及用于制备粘合剂组合物的粘合剂组合物和方法，以及由可再生材料制备纤维素复合材料的方法。实例中的四种真菌是Lenzites elegans（Spreng。）Pat。（FTK 329A），Phanerochaete cremea（Bres。）Parmasto（FTK 332A），Pycnoporellus alboluteus（Ellis＆Everh。）Kotl。＆Pouz。（FTK 76A）和Meruliopsis taxicola（Pers。）Bondartsev（FTK 122B）。在实施例中使用的木质素是有机溶剂木质素，牛皮纸木质素和木质素磺酸铵。本发明包括（1）用真菌修饰木质素的方法; （2）原位聚合改性木质素 - 苯酚 - 甲醛以生成液体形式的生物改性木质素 - 苯酚 - 甲醛粘合剂，（3）用生物改性木质素 - 酚醛树脂制造复合板。

2. 发明申请

WO2011113137A1 HEAT-RESISTANT STRUCTURAL WOOD ADHESIVE COMPOSITIONS INVOLVING pMDI, POLYOL AND AROMATIC POLYOLS 审中-公开
标题翻译：涉及pMDI，多元醇和芳香族多元醇的耐热结构木粘合剂组合物
公开(公告)号：WO2011113137A1
公开(公告)日：2011-09-22
申请号：PCT/CA2011/000265
申请日：2011-03-10
申请人： FPINNOVATIONS , JU, Jinlan , FENG, Martin , WANG, Xiang-Ming
发明人： JU, Jinlan , FENG, Martin , WANG, Xiang-Ming
IPC分类号： C09J175/04 , C09K21/14
CPC分类号： C08G18/6674 , C08G18/12 , C08G18/3215 , C08G18/3878 , C09J175/04 , C08G18/307
摘要： This invention describes an adhesive composition that forms the basis of a heat-resistant, fire resistant, and water resistant polyurethane adhesive suitable for applications in the manufacture of wood products, and the method of making the adhesive. The wood finger- jointed studs produced using an adhesive derived from this invention can meet or exceed the fire rating of a period of 60 minutes according to ASTM E 119 and ASTM D 7374. The heat resistance of the adhesive is a result of incorporating thermally stable aromatic polyol molecules into the polymeric structures of the wood adhesive system, which is composed of the reaction products of a poly(methylene diphenyl diisocyanate), at least one of a polyether polyol and a polyester polyol; and the aromatic polyol that is a hydroxyl phenol in a preferred embodiment. Furthermore, this novel wood adhesive system possesses high water-resistance, making it suitable for the manufacture of highly durable engineered wood products. It is fast moisture-curable at ambient temperatures. It is also formaldehyde-free.
摘要翻译：本发明描述了一种粘合剂组合物，其形成了适用于制造木制品的耐热，耐火和防水的聚氨酯粘合剂的基础，以及制造该粘合剂的方法。根据ASTM E 119和ASTM D 7374，使用本发明衍生的粘合剂生产的木指接头螺柱可达到或超过60分钟的防火等级。粘合剂的耐热性是结合热稳定性芳族多元醇分子进入木材粘合剂体系的聚合物结构，其由聚（亚甲基二苯基二异氰酸酯），聚醚多元醇和聚酯多元醇中的至少一种的反应产物组成; 和作为羟基苯酚的芳香族多元醇。此外，这种新型木材粘合剂系统具有高耐水性，使其适用于制造高度耐用的工程木制品。它在环境温度下可快速湿润固化。它也是无甲醛的。

3. 发明申请

WO2012012888A1 A PHENOL-FORMALDEHYDE POLYMER WITH CARBON NANOTUBES, A METHOD OF PRODUCING SAME, AND PRODUCTS DERIVED THEREFROM 审中-公开
标题翻译：具有碳纳米管的酚醛聚合物，其制备方法和衍生自其的产物
公开(公告)号：WO2012012888A1
公开(公告)日：2012-02-02
申请号：PCT/CA2011/000873
申请日：2011-07-28
申请人： FPINNOVATIONS , NATIONAL RESEARCH COUNCIL OF CANADA , ZHANG, Yaolin , CHENG, Fuyong , WANG, Xiang-Ming , FENG, Martin , BRUNETTE, Gilles , SIMARD, Benoit
发明人： ZHANG, Yaolin , CHENG, Fuyong , WANG, Xiang-Ming , FENG, Martin , BRUNETTE, Gilles , SIMARD, Benoit
IPC分类号： C08L97/00 , C08K7/06
CPC分类号： C08J3/20 , C08H6/00 , C08J2361/18 , C08J2397/02 , C08K7/06 , C08K7/24 , C08L61/04 , C08L97/005 , C08L97/02 , C09J161/06 , C09J197/005 , C08L61/06
摘要： The present invention provides methods to functionalize and solubilize WCNT with a phenolic polymer such as a lignin or a PF resin followed by in-situ integration of this functionalized CNT in the presence of formaldehyde and phenol and/or lignin to generate either CNT-reinforced phenol-formaldehyde polymer or CNT-reinforced lignin-phenol-formaldehyde polymer in either liquid or powder form suitable as an adhesive in the manufacture of a lignocellulosic composite material such as OSB and plywood.
摘要翻译：本发明提供了用酚类聚合物如木质素或PF树脂官能化和溶解WCNT的方法，然后在甲醛和苯酚和/或木质素存在下原位整合该官能化CNT以产生CNT-增强的苯酚甲醛聚合物或CNT-增强的木质素 - 酚 - 甲醛聚合物，其以液体或粉末形式适合作为制造木质纤维素复合材料如OSB和胶合板的粘合剂。

4. 发明申请

WO2011091510A1 FUNGAL MODIFIED CHITOSAN ADHESIVES AND WOOD COMPOSITES MADE FROM THE ADHESIVES 审中-公开
标题翻译：来自粘合剂的真菌改性木糖粘合剂和木质复合材料
公开(公告)号：WO2011091510A1
公开(公告)日：2011-08-04
申请号：PCT/CA2011/000078
申请日：2011-01-21
申请人： FPINNOVATIONS , YANG, Dian-Qing , ZHANG, Yaolin , WANG, Xiang-Ming , WAN, Hui , BRUNETTE, Gilles
发明人： YANG, Dian-Qing , ZHANG, Yaolin , WANG, Xiang-Ming , WAN, Hui , BRUNETTE, Gilles
IPC分类号： C12P19/04 , C09J105/08 , C12P1/02
CPC分类号： C12P19/26 , C08B37/003 , C09J105/08 , C12P19/04
摘要： The present invention describes a fungal modified chitosan adhesive for binding a fibrous material and the method of producing the adhesive. The adhesive is produced by providing a chitosan containing raw material; a fungal growing medium; a fungal culture; mixing the raw material, the growing medium and the fungal culture together to produce a suspension; incubating the suspension to produce a broth comprising a modified chitosan solid, an at least partially-consumed medium liquid and a fungal residue; separating the modified chitosan solid from the liquid and the fungal residue, and dissolving the modified chitosan solid to produce the adhesive resin.
摘要翻译：本发明描述了用于粘合纤维材料的真菌改性壳聚糖粘合剂和生产粘合剂的方法。通过提供含壳聚糖的原料制造粘合剂; 真菌生长培养基; 真菌文化; 将原料，生长培养基和真菌培养物混合在一起以产生悬浮液; 孵育悬浮液以产生包含改性的壳聚糖固体，至少部分消耗的中等液体和真菌残渣的肉汤; 将改性的壳聚糖固体与液体和真菌残渣分离，并将改性的壳聚糖固体溶解以制备粘合剂树脂。

5. 发明申请

WO2012106808A1 PHENOL-FORMALDEHYDE AND LIGNIN-PHENOL-FORMALDEHYDE ADHESIVE POLYMERS WITH CARBON BLACK, AND METHOD OF MAKING SAME 审中-公开
标题翻译：具有碳黑的酚醛树脂和木质素 - 酚醛硬脂酸聚合物及其制备方法
公开(公告)号：WO2012106808A1
公开(公告)日：2012-08-16
申请号：PCT/CA2012/000117
申请日：2012-02-10
申请人： FPINNOVATIONS INC. , KOUISNI, Lamfeddal , PALEOLOGOU, Michael , ZHANG, Yaolin , WANG, Xiang-Ming , FENG, Martin
发明人： KOUISNI, Lamfeddal , PALEOLOGOU, Michael , ZHANG, Yaolin , WANG, Xiang-Ming , FENG, Martin
IPC分类号： C09J161/06 , B32B21/13 , C09J11/04
CPC分类号： C09J161/06 , C08K3/04 , C08L97/02 , C09J161/14 , C08L61/06 , C08L97/005
摘要： Phenol-formaldehyde and lignin-phenol formaldehyde adhesive polymers with improved properties are disclosed, as well as the method of production therein. The method comprises providing at least one phenolic compound at least one formaldehyde compound, an alkali metal hydroxide, water and at least one carbon black; mixing the at least one phenolic compound, the at least one formaldehyde compound, the alkali metal hydroxide, the water and the carbon black to produce a methylolation medium at a pH of about 10 or less; maintaining the medium at a methylolation temperature to produce a methylolated medium reacting with the water predominantly; and increasing the temperature of the methylolated medium to produce the phenol-formaldehyde polymer via a condensation reaction.
摘要翻译：公开了具有改进性能的苯酚 - 甲醛和木质素 - 苯酚甲醛粘合剂聚合物及其生产方法。该方法包括提供至少一种酚类化合物至少一种甲醛化合物，碱金属氢氧化物，水和至少一种炭黑; 混合至少一种酚类化合物，至少一种甲醛化合物，碱金属氢氧化物，水和炭黑，以产生约10或更低的pH值的羟甲基化培养基; 将培养基保持在甲氧基化温度以产生主要与水反应的羟甲基化介质; 并通过缩合反应提高羟甲基化介质的温度以产生苯酚 - 甲醛聚合物。

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