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1. 发明申请

WO2008143940A2 PROCESS FOR CONVERTING HYDROCARBON FEEDSTOCKS WITH ELECTROLYTIC RECOVERY OF HALOGEN 审中-公开
标题翻译：用卤素电解恢复来转化碳氢化合物的方法
公开(公告)号：WO2008143940A2
公开(公告)日：2008-11-27
申请号：PCT/US2008/006244
申请日：2008-05-14
申请人： GRT, INC. , GROSSO, Phillip , MCFARLAND, Eric, W. , SHERMAN, Jeffrey, H.
发明人： GROSSO, Phillip , MCFARLAND, Eric, W. , SHERMAN, Jeffrey, H.
IPC分类号： C25B3/00 , C25B3/06
CPC分类号： C25B1/24 , C07C1/30 , C07C11/02 , C10B53/04 , C10B57/06 , C10G29/02 , C10G2300/1011 , C10G2300/1025 , C10G2400/30 , C25B1/04 , H01L2924/014 , Y02E60/366 , Y02P20/145
摘要： An improved continuous process for converting methane, natural gas, and other hydrocarbon feedstocks into one or more higher hydrocarbons, methanol, amines, or other products comprises continuously cycling through hydrocarbon halogenation, product formation, product separation, and electrolytic regeneration of halogen, optionally using an improved electrolytic cell equipped with an oxygen depolarized cathode.
摘要翻译：将甲烷，天然气和其他烃原料转化成一种或多种高级烃，甲醇，胺或其它产物的改进的连续方法包括连续循环通过烃卤化，产物形成，产物分离和卤素的电解再生，任选地使用配备有氧去极化阴极的改进的电解槽。

2. 发明申请

WO2008140647A2 IN SITU FABRICATED ELECTROCHEMICAL DEVICE 审中-公开
标题翻译：在现代制造的电化学设备
公开(公告)号：WO2008140647A2
公开(公告)日：2008-11-20
申请号：PCT/US2008/002721
申请日：2008-02-29
申请人： THE REGENTS OF THE UNIVERSITY OF CALIFORNIA , MCFARLAND, Eric, W. , METIU, Horia , BURATTO, Steven, K. , RANASINGHE, Devinda
发明人： MCFARLAND, Eric, W. , METIU, Horia , BURATTO, Steven, K. , RANASINGHE, Devinda
IPC分类号： H01M4/88 , H01M4/86
CPC分类号： H01M4/8853 , C25D5/02 , H01M4/8807 , H01M4/881 , H01M4/92 , H01M8/1004 , H01M8/1023 , H01M8/1039 , H01M8/1058
摘要： An electrochemical device, such as a fuel cell, and method of forming it, in which electrodes, such as anode and cathode, are disposed on a semipermeable or permeable membrane having ion conduction channels. Electrocatalyst is deposited on locations on the electrodes limited to and corresponding to the ion conduction channels. In a first embodiment, anode and cathode electrodes sandwich the membrane, a counter electrode is connected to one of the electrodes, electrolyte containing an electrochemical precursor to the electrocatalyst is applied to the other electrode whereby, upon applying current to the counter electrode, electrocatalyst is deposited on locations on the first electrode corresponding to the ion conduction channels. The process is repeated with the counter electrode connected on the other electrode of the cell. In a second embodiment, a combination of a first electrode and a first membrane is assembled as is a combination of a second electrode and a second membrane. A counter electrode and electrolyte containing an electrochemical precursor to the electrocatalyst are separately applied to the first combination, then the second combination whereby, upon applying current to the counter electrodes, electrocatalyst is deposited on locations on the first and second electrodes corresponding to the ion conduction channels. The surfaces of the first and second membranes are joined opposite their respective electrodes to a porous coupling layer to form the electrochemical device.
摘要翻译：诸如燃料电池的电化学装置及其形成方法，其中诸如阳极和阴极的电极设置在具有离子传导通道的半透膜或可渗透膜上。电催化剂沉积在限定于并对应于离子传导通道的电极上的位置上。在第一实施例中，阳极和阴极电极夹住膜，对电极连接到一个电极，将包含电催化剂的电化学前体的电解质施加到另一个电极，由此，在向对电极施加电流时，电催化剂为沉积在对应于离子传导通道的第一电极上的位置上。重复该过程，反电极连接在电池的另一个电极上。在第二实施例中，第一电极和第一膜的组合如第二电极和第二膜的组合一样被组装。将含有电催化剂的电化学前体的对电极和电解质分别施加到第一组合，然后第二组合，由此，在向对置电极施加电流时，电极催化剂沉积在对应于离子传导的第一和第二电极上的位置通道。第一和第二膜的表面与其各自的电极相对接合到多孔耦合层以形成电化学装置。

3. 发明申请

WO2007092410A2 SEPARATION OF LIGHT GASES FROM HALOGENS 审中-公开
标题翻译：从HALOGENS中分离出轻气体
公开(公告)号：WO2007092410A2
公开(公告)日：2007-08-16
申请号：PCT/US2007003090
申请日：2007-02-05
申请人： GRT INC , GADEWAR SAGAR B , STOIMENOV PETER K , GROSSO PHILIP , MCFARLAND ERIC W , BREED ASHLEY W , WEISS MICHAEL J , WYRSTA MICHAEL D
发明人： GADEWAR SAGAR B , STOIMENOV PETER K , GROSSO PHILIP , MCFARLAND ERIC W , BREED ASHLEY W , WEISS MICHAEL J , WYRSTA MICHAEL D
CPC分类号： B01D3/10 , B01D1/16 , B01D53/685 , B01D53/75 , B01D2251/60 , B01D2257/2022 , B01D2257/2025 , C01B7/0743 , C01B7/096 , C01B21/0433 , C01B21/045 , C01B2210/0009 , C01B2210/0015
摘要： A process is provided for separating one or more light gases from bromine or chlorine using one or more physical separations and contact with a chemical scrubber to recover additional halogen. In one aspect, the process comprises (a) providing a feed of halogen containing one or more light gases to a distillation column or flash vaporizer; (b) operating the distillation column or flash vaporizer to separate the feed into (i) a first liquid containing a major amount of halogen and no more than a minor amount of light gas(es), and (ii) a first vapor containing a major amount of light gas(es) and no more than a minor amount of halogen; and (c) providing the vapor to a chemical scrubber to recover halogen from the vapor.
摘要翻译：提供了使用一种或多种物理分离从溴或氯中分离一种或多种轻质气体并与化学洗涤器接触以回收额外的卤素的方法。一方面，该方法包括（a）提供含有一种或多种轻质气体的卤素进料到蒸馏塔或闪蒸器; （b）操作蒸馏塔或闪蒸器以将进料分离成（i）含有主要量的卤素和不多于少量的轻质气体的第一液体，和（ii）含有主要量的轻质气体和不多于少量的卤素; 和（c）将蒸汽提供给化学洗涤器以从蒸气中回收卤素。

4. 发明申请

WO2015142916A1 MULTI-JUNCTION ARTIFICIAL PHOTOSYNTHETIC CELL WITH ENHANCED PHOTOVOLTAGES 审中-公开
标题翻译：具有增强光照的多功能人造光致细胞
公开(公告)号：WO2015142916A1
公开(公告)日：2015-09-24
申请号：PCT/US2015/021059
申请日：2015-03-17
申请人： HUSSAINI, Syed Mubeen Jawahar , MCFARLAND, Eric W. , MOSKOVITS, Martin , LEE, Joun , YOUNG, Tim
发明人： HUSSAINI, Syed Mubeen Jawahar , MCFARLAND, Eric W. , MOSKOVITS, Martin , LEE, Joun , YOUNG, Tim
IPC分类号： C25B1/00 , H01L51/42
CPC分类号： C25B1/003 , C25B1/04 , C25B3/04 , C25B9/00 , H01G9/20 , H01L31/022425 , H01L31/032 , H01L31/043 , H01L31/0481 , H01L31/07 , H01L31/0725 , H01L31/073 , H01L31/0749 , H01L31/078 , Y02E60/366 , Y02E70/10 , Y02P20/134
摘要： A multi-junction artificial photosynthetic unit includes an active element with a plurality of semiconducting layers, with metal layers deposited between the semiconductor layers appropriately forming Schottky barrier junctions or ohmic junctions with a surface of an adjacent semiconductor layer. The active element is formed within a protective structure formed of porous aluminum oxide. Successive layers of the active element can be formed within the protective structure, and additional layers and junctions can be added until desired photovoltages are achieved. A photoreactor for the production of fuels and chemicals driven by solar-powered redox reactions includes a bag reactor filled with a feedstock solution. A plurality of multi-junction photosynthetic units are placed in the feedstock solution to drive the redox reactions and produce the desired fuels and chemicals.
摘要翻译：多结的人造光合单元包括具有多个半导体层的有源元件，其中沉积在半导体层之间的金属层适当地形成与相邻半导体层的表面的肖特基势垒结或欧姆结。有源元件形成在由多孔氧化铝形成的保护结构内。可以在保护结构内形成有源元件的连续层，并且可以添加额外的层和结，直到达到所需的光电压。用于生产由太阳能氧化还原反应驱动的燃料和化学品的光反应器包括填充有原料溶液的袋式反应器。将多个多结光合单元放置在原料溶液中以驱动氧化还原反应并产生所需的燃料和化学品。

5. 发明申请

WO2010009376A8 CONTINUOUS PROCESS FOR CONVERTING NATURAL GAS TO LIQUID HYDROCARBONS 审中-公开
标题翻译：将天然气转化为液体烃的连续工艺
公开(公告)号：WO2010009376A8
公开(公告)日：2011-02-10
申请号：PCT/US2009050955
申请日：2009-07-17
申请人： GRT INC , GADEWAR SAGAR , ZHANG AIHUA , JULKA VIVEK , MCFARLAND ERIC W , GROSSO PHILIP , JANMANCHI KRISHNA , SARDAR SAYDUL AMIN , STOIMENOV PETER , KOMON ZACHARY J A , LIN HONGFEI , CUTLER CHARLES IAN , CHENG JIHONG , WHEELER JEAN , SUN SHOULI , AUERBACH DANIEL J , WYRSTA MICHAEL D , CORONELLA CHARLES J , HUFF SHAWN
发明人： GADEWAR SAGAR , ZHANG AIHUA , JULKA VIVEK , MCFARLAND ERIC W , GROSSO PHILIP , JANMANCHI KRISHNA , SARDAR SAYDUL AMIN , STOIMENOV PETER , KOMON ZACHARY J A , LIN HONGFEI , CUTLER CHARLES IAN , CHENG JIHONG , WHEELER JEAN , SUN SHOULI , AUERBACH DANIEL J , WYRSTA MICHAEL D , CORONELLA CHARLES J , HUFF SHAWN
IPC分类号： C07C2/00
CPC分类号： C07C17/10 , B01J29/44 , B01J29/46 , B01J29/48 , B01J29/85 , B01J29/90 , B01J2229/16 , B01J2229/183 , B01J2229/186 , C01B7/01 , C01B7/093 , C01B7/096 , C01B7/13 , C01B7/19 , C07C1/26 , C07C17/37 , C07C2529/40 , C07C2529/46 , C07C2529/70 , C07C2529/83 , C07C2529/85 , Y02P20/127 , Y02P20/584 , Y02P20/588 , C07C15/02 , C07C11/02 , C07C19/075
摘要： A method comprising: providing a first halogen stream; providing a first alkane stream; reacting at least a portion of the first halogen stream with at least a portion of the first alkane stream in a first reaction vessel to form a first halogenated stream; providing a second alkane stream comprising C2 and higher hydrocarbons; providing a second halogen stream; and reacting at least a portion of the second halogen stream with at least a portion of the second alkane stream in a second reaction vessel to form a second halogenated stream.
摘要翻译：一种方法，包括：提供第一卤素流; 提供第一烷烃流; 使第一卤素物流的至少一部分与第一烷烃物流的至少一部分在第一反应容器中反应以形成第一卤化物流; 提供包含C2和高级烃的第二烷烃流; 提供第二卤素流; 以及使第二卤代物流的至少一部分与第二烷烃物流的至少一部分在第二反应容器中反应以形成第二卤代物流。

6. 发明申请

WO2010124041A1 PROCESS FOR CONVERTING HYDROCARBON FEEDSTOCKS WITH ELECTROLYTIC AND PHOTOELECTROCATALYTIC RECOVERY OF HALOGENS 审中-公开
标题翻译：用电解和光电复原法转化碳氢化合物的方法
公开(公告)号：WO2010124041A1
公开(公告)日：2010-10-28
申请号：PCT/US2010/031971
申请日：2010-04-22
申请人： GRT, INC. , MCFARLAND, Eric, W.
发明人： MCFARLAND, Eric, W.
IPC分类号： C07C6/12
CPC分类号： C25B1/24 , C07C1/26 , C07C17/10 , C07C209/08 , C25B1/003 , C07C15/02 , C07C19/075 , C07C211/05
摘要： A method for converting a hydrocarbon feedstock into higher hydrocarbons is provided comprising reacting a hydrocarbon feedstock with a molecular halogen to form alkyl halides; reacting at least a portion of the alkyl halide in the presence of a catalyst to form higher hydrocarbons and a hydrogen halide; and converting at least a portion of the hydrogen halide into the molecular halogen via photoelectrocatalysis. Additional methods are also provided.
摘要翻译：提供了将烃原料转化成高级烃的方法，包括使烃原料与分子卤素反应形成烷基卤化物; 在催化剂存在下使烷基卤化物的至少一部分反应形成高级烃和卤化氢; 并通过光电催化将至少一部分卤化氢转化成分子卤素。还提供了附加的方法。

7. 发明申请

WO2010009376A1 CONTINUOUS PROCESS FOR CONVERTING NATURAL GAS TO LIQUID HYDROCARBONS 审中-公开
标题翻译：将天然气转化为液体烃的连续工艺
公开(公告)号：WO2010009376A1
公开(公告)日：2010-01-21
申请号：PCT/US2009/050955
申请日：2009-07-17
申请人： GAS REACTION TECHNOLOGIES, INC. , GADEWARD, Sagar , ZHANG, Aihua , JULKA, Vivek , MCFARLAND, Eric, W. , GROSSO, Philip , JANMANCHI, Krishna , SARDAR, Saydul, Amin , STOIMENOV, Peter , KOMON, Zachary, J.A. , LIN, Hongfei , CUTLER, Charles, Ian , CHENG, Jihong , WHEELER, Jean , SUN, Shouli , AUERBACH, Daniel, J. , WYRSTA, Michael, D. , CORONELLA, Charles, J. , HUFF, Shawn
发明人： GADEWARD, Sagar , ZHANG, Aihua , JULKA, Vivek , MCFARLAND, Eric, W. , GROSSO, Philip , JANMANCHI, Krishna , SARDAR, Saydul, Amin , STOIMENOV, Peter , KOMON, Zachary, J.A. , LIN, Hongfei , CUTLER, Charles, Ian , CHENG, Jihong , WHEELER, Jean , SUN, Shouli , AUERBACH, Daniel, J. , WYRSTA, Michael, D. , CORONELLA, Charles, J. , HUFF, Shawn
IPC分类号： C07C2/00
CPC分类号： C07C17/10 , B01J29/44 , B01J29/46 , B01J29/48 , B01J29/85 , B01J29/90 , B01J2229/16 , B01J2229/183 , B01J2229/186 , C01B7/01 , C01B7/093 , C01B7/096 , C01B7/13 , C01B7/19 , C07C1/26 , C07C17/37 , C07C2529/40 , C07C2529/46 , C07C2529/70 , C07C2529/83 , C07C2529/85 , Y02P20/127 , Y02P20/584 , Y02P20/588 , C07C15/02 , C07C11/02 , C07C19/075
摘要： A method comprising: providing a first halogen stream; providing a first alkane stream; reacting at least a portion of the first halogen stream with at least a portion of the first alkane stream in a first reaction vessel to form a first halogenated stream; providing a second alkane stream comprising C 2 and higher hydrocarbons; providing a second halogen stream; and reacting at least a portion of the second halogen stream with at least a portion of the second alkane stream in a second reaction vessel to form a second halogenated stream.
摘要翻译：一种方法，包括：提供第一卤素流; 提供第一烷烃流; 使第一卤素物流的至少一部分与第一烷烃物流的至少一部分在第一反应容器中反应以形成第一卤化物流; 提供包含C2和高级烃的第二烷烃流; 提供第二卤素流; 以及使第二卤代物流的至少一部分与第二烷烃物流的至少一部分在第二反应容器中反应以形成第二卤代物流。

8. 发明申请

WO2008143940A3 PROCESS FOR CONVERTING HYDROCARBON FEEDSTOCKS WITH ELECTROLYTIC RECOVERY OF HALOGEN 审中-公开
标题翻译：用卤素电解恢复来转化碳氢化合物的方法
公开(公告)号：WO2008143940A3
公开(公告)日：2009-12-30
申请号：PCT/US2008006244
申请日：2008-05-14
申请人： GRT INC , GROSSO PHILLIP , MCFARLAND ERIC W , SHERMAN JEFFREY H
发明人： GROSSO PHILLIP , MCFARLAND ERIC W , SHERMAN JEFFREY H
IPC分类号： C07C2/00
CPC分类号： C25B1/24 , C07C1/30 , C07C11/02 , C10B53/04 , C10B57/06 , C10G29/02 , C10G2300/1011 , C10G2300/1025 , C10G2400/30 , C25B1/04 , H01L2924/014 , Y02E60/366 , Y02P20/145
摘要： An improved continuous process for converting methane, natural gas, and other hydrocarbon feedstocks into one or more higher hydrocarbons, methanol, amines, or other products comprises continuously cycling through hydrocarbon halogenation, product formation, product separation, and electrolytic regeneration of halogen, optionally using an improved electrolytic cell equipped with an oxygen depolarized cathode.
摘要翻译：将甲烷，天然气和其他烃原料转化成一种或多种高级烃，甲醇，胺或其它产物的改进的连续方法包括连续循环通过烃卤化，产物形成，产物分离和卤素的电解再生，任选地使用配备有氧去极化阴极的改进的电解槽。

9. 发明申请

WO2008140647A3 IN SITU FABRICATED ELECTROCHEMICAL DEVICE 审中-公开
标题翻译：在现代制造的电化学设备
公开(公告)号：WO2008140647A3
公开(公告)日：2009-01-08
申请号：PCT/US2008002721
申请日：2008-02-29
申请人： UNIV CALIFORNIA , MCFARLAND ERIC W , METIU HORIA , BURATTO STEVEN K , RANASINGHE DEVINDA
发明人： MCFARLAND ERIC W , METIU HORIA , BURATTO STEVEN K , RANASINGHE DEVINDA
IPC分类号： H01M4/88
CPC分类号： H01M4/8853 , C25D5/02 , H01M4/8807 , H01M4/881 , H01M4/92 , H01M8/1004 , H01M8/1023 , H01M8/1039 , H01M8/1058
摘要： An electrochemical device, such as a fuel cell, and method of forming it, in which electrodes, such as anode and cathode, are disposed on a semipermeable or permeable membrane having ion conduction channels. Electrocatalyst is deposited on locations on the electrodes limited to and corresponding to the ion conduction channels. In a first embodiment, anode and cathode electrodes sandwich the membrane, a counter electrode is connected to one of the electrodes, electrolyte containing an electrochemical precursor to the electrocatalyst is applied to the other electrode whereby, upon applying current to the counter electrode, electrocatalyst is deposited on locations on the first electrode corresponding to the ion conduction channels. The process is repeated with the counter electrode connected on the other electrode of the cell. In a second embodiment, a combination of a first electrode and a first membrane is assembled as is a combination of a second electrode and a second membrane. A counter electrode and electrolyte containing an electrochemical precursor to the electrocatalyst are separately applied to the first combination, then the second combination whereby, upon applying current to the counter electrodes, electrocatalyst is deposited on locations on the first and second electrodes corresponding to the ion conduction channels. The surfaces of the first and second membranes are joined opposite their respective electrodes to a porous coupling layer to form the electrochemical device.
摘要翻译：诸如燃料电池的电化学装置及其形成方法，其中诸如阳极和阴极的电极设置在具有离子传导通道的半透膜或可渗透膜上。电催化剂沉积在限定于并对应于离子传导通道的电极上的位置上。在第一实施例中，阳极和阴极电极夹住膜，对电极连接到一个电极，将包含电催化剂的电化学前体的电解质施加到另一个电极，由此，在向对电极施加电流时，电催化剂为沉积在对应于离子传导通道的第一电极上的位置上。重复该过程，反电极连接在电池的另一个电极上。在第二实施例中，第一电极和第一膜的组合如第二电极和第二膜的组合一样被组装。将含有电催化剂的电化学前体的对电极和电解质分别施加到第一组合，然后第二组合，由此，在向对置电极施加电流时，电极催化剂沉积在对应于离子传导的第一和第二电极上的位置通道。第一和第二膜的表面与其各自的电极相对接合到多孔耦合层以形成电化学装置。

10. 发明申请

WO2007092410A3 SEPARATION OF LIGHT GASES FROM HALOGENS 审中-公开
公开(公告)号：WO2007092410A3
公开(公告)日：2007-08-16
申请号：PCT/US2007/003090
申请日：2007-02-05
申请人： GRT, INC. , GADEWAR, Sagar, B. , STOIMENOV, Peter, K. , GROSSO, Philip , MCFARLAND, Eric, W. , BREED, Ashley, W. , WEISS, Michael, J. , WYRSTA, Michael, D.
发明人： GADEWAR, Sagar, B. , STOIMENOV, Peter, K. , GROSSO, Philip , MCFARLAND, Eric, W. , BREED, Ashley, W. , WEISS, Michael, J. , WYRSTA, Michael, D.
IPC分类号： C01B7/00
摘要： A process is provided for separating one or more light gases from bromine or chlorine using one or more physical separations and contact with a chemical scrubber to recover additional halogen. In one aspect, the process comprises (a) providing a feed of halogen containing one or more light gases to a distillation column or flash vaporizer; (b) operating the distillation column or flash vaporizer to separate the feed into (i) a first liquid containing a major amount of halogen and no more than a minor amount of light gas(es), and (ii) a first vapor containing a major amount of light gas(es) and no more than a minor amount of halogen; and (c) providing the vapor to a chemical scrubber to recover halogen from the vapor.

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