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1. 发明申请

WO2008143940A3 PROCESS FOR CONVERTING HYDROCARBON FEEDSTOCKS WITH ELECTROLYTIC RECOVERY OF HALOGEN 审中-公开
标题翻译：用卤素电解恢复来转化碳氢化合物的方法
公开(公告)号：WO2008143940A3
公开(公告)日：2009-12-30
申请号：PCT/US2008006244
申请日：2008-05-14
申请人： GRT INC , GROSSO PHILLIP , MCFARLAND ERIC W , SHERMAN JEFFREY H
发明人： GROSSO PHILLIP , MCFARLAND ERIC W , SHERMAN JEFFREY H
IPC分类号： C07C2/00
CPC分类号： C25B1/24 , C07C1/30 , C07C11/02 , C10B53/04 , C10B57/06 , C10G29/02 , C10G2300/1011 , C10G2300/1025 , C10G2400/30 , C25B1/04 , H01L2924/014 , Y02E60/366 , Y02P20/145
摘要： An improved continuous process for converting methane, natural gas, and other hydrocarbon feedstocks into one or more higher hydrocarbons, methanol, amines, or other products comprises continuously cycling through hydrocarbon halogenation, product formation, product separation, and electrolytic regeneration of halogen, optionally using an improved electrolytic cell equipped with an oxygen depolarized cathode.
摘要翻译：将甲烷，天然气和其他烃原料转化成一种或多种高级烃，甲醇，胺或其它产物的改进的连续方法包括连续循环通过烃卤化，产物形成，产物分离和卤素的电解再生，任选地使用配备有氧去极化阴极的改进的电解槽。

2. 发明申请

WO2007092410A2 SEPARATION OF LIGHT GASES FROM HALOGENS 审中-公开
标题翻译：从HALOGENS中分离出轻气体
公开(公告)号：WO2007092410A2
公开(公告)日：2007-08-16
申请号：PCT/US2007003090
申请日：2007-02-05
申请人： GRT INC , GADEWAR SAGAR B , STOIMENOV PETER K , GROSSO PHILIP , MCFARLAND ERIC W , BREED ASHLEY W , WEISS MICHAEL J , WYRSTA MICHAEL D
发明人： GADEWAR SAGAR B , STOIMENOV PETER K , GROSSO PHILIP , MCFARLAND ERIC W , BREED ASHLEY W , WEISS MICHAEL J , WYRSTA MICHAEL D
CPC分类号： B01D3/10 , B01D1/16 , B01D53/685 , B01D53/75 , B01D2251/60 , B01D2257/2022 , B01D2257/2025 , C01B7/0743 , C01B7/096 , C01B21/0433 , C01B21/045 , C01B2210/0009 , C01B2210/0015
摘要： A process is provided for separating one or more light gases from bromine or chlorine using one or more physical separations and contact with a chemical scrubber to recover additional halogen. In one aspect, the process comprises (a) providing a feed of halogen containing one or more light gases to a distillation column or flash vaporizer; (b) operating the distillation column or flash vaporizer to separate the feed into (i) a first liquid containing a major amount of halogen and no more than a minor amount of light gas(es), and (ii) a first vapor containing a major amount of light gas(es) and no more than a minor amount of halogen; and (c) providing the vapor to a chemical scrubber to recover halogen from the vapor.
摘要翻译：提供了使用一种或多种物理分离从溴或氯中分离一种或多种轻质气体并与化学洗涤器接触以回收额外的卤素的方法。一方面，该方法包括（a）提供含有一种或多种轻质气体的卤素进料到蒸馏塔或闪蒸器; （b）操作蒸馏塔或闪蒸器以将进料分离成（i）含有主要量的卤素和不多于少量的轻质气体的第一液体，和（ii）含有主要量的轻质气体和不多于少量的卤素; 和（c）将蒸汽提供给化学洗涤器以从蒸气中回收卤素。

3. 发明申请

WO2010009376A8 CONTINUOUS PROCESS FOR CONVERTING NATURAL GAS TO LIQUID HYDROCARBONS 审中-公开
标题翻译：将天然气转化为液体烃的连续工艺
公开(公告)号：WO2010009376A8
公开(公告)日：2011-02-10
申请号：PCT/US2009050955
申请日：2009-07-17
申请人： GRT INC , GADEWAR SAGAR , ZHANG AIHUA , JULKA VIVEK , MCFARLAND ERIC W , GROSSO PHILIP , JANMANCHI KRISHNA , SARDAR SAYDUL AMIN , STOIMENOV PETER , KOMON ZACHARY J A , LIN HONGFEI , CUTLER CHARLES IAN , CHENG JIHONG , WHEELER JEAN , SUN SHOULI , AUERBACH DANIEL J , WYRSTA MICHAEL D , CORONELLA CHARLES J , HUFF SHAWN
发明人： GADEWAR SAGAR , ZHANG AIHUA , JULKA VIVEK , MCFARLAND ERIC W , GROSSO PHILIP , JANMANCHI KRISHNA , SARDAR SAYDUL AMIN , STOIMENOV PETER , KOMON ZACHARY J A , LIN HONGFEI , CUTLER CHARLES IAN , CHENG JIHONG , WHEELER JEAN , SUN SHOULI , AUERBACH DANIEL J , WYRSTA MICHAEL D , CORONELLA CHARLES J , HUFF SHAWN
IPC分类号： C07C2/00
CPC分类号： C07C17/10 , B01J29/44 , B01J29/46 , B01J29/48 , B01J29/85 , B01J29/90 , B01J2229/16 , B01J2229/183 , B01J2229/186 , C01B7/01 , C01B7/093 , C01B7/096 , C01B7/13 , C01B7/19 , C07C1/26 , C07C17/37 , C07C2529/40 , C07C2529/46 , C07C2529/70 , C07C2529/83 , C07C2529/85 , Y02P20/127 , Y02P20/584 , Y02P20/588 , C07C15/02 , C07C11/02 , C07C19/075
摘要： A method comprising: providing a first halogen stream; providing a first alkane stream; reacting at least a portion of the first halogen stream with at least a portion of the first alkane stream in a first reaction vessel to form a first halogenated stream; providing a second alkane stream comprising C2 and higher hydrocarbons; providing a second halogen stream; and reacting at least a portion of the second halogen stream with at least a portion of the second alkane stream in a second reaction vessel to form a second halogenated stream.
摘要翻译：一种方法，包括：提供第一卤素流; 提供第一烷烃流; 使第一卤素物流的至少一部分与第一烷烃物流的至少一部分在第一反应容器中反应以形成第一卤化物流; 提供包含C2和高级烃的第二烷烃流; 提供第二卤素流; 以及使第二卤代物流的至少一部分与第二烷烃物流的至少一部分在第二反应容器中反应以形成第二卤代物流。

4. 发明申请

WO2008140647A3 IN SITU FABRICATED ELECTROCHEMICAL DEVICE 审中-公开
标题翻译：在现代制造的电化学设备
公开(公告)号：WO2008140647A3
公开(公告)日：2009-01-08
申请号：PCT/US2008002721
申请日：2008-02-29
申请人： UNIV CALIFORNIA , MCFARLAND ERIC W , METIU HORIA , BURATTO STEVEN K , RANASINGHE DEVINDA
发明人： MCFARLAND ERIC W , METIU HORIA , BURATTO STEVEN K , RANASINGHE DEVINDA
IPC分类号： H01M4/88
CPC分类号： H01M4/8853 , C25D5/02 , H01M4/8807 , H01M4/881 , H01M4/92 , H01M8/1004 , H01M8/1023 , H01M8/1039 , H01M8/1058
摘要： An electrochemical device, such as a fuel cell, and method of forming it, in which electrodes, such as anode and cathode, are disposed on a semipermeable or permeable membrane having ion conduction channels. Electrocatalyst is deposited on locations on the electrodes limited to and corresponding to the ion conduction channels. In a first embodiment, anode and cathode electrodes sandwich the membrane, a counter electrode is connected to one of the electrodes, electrolyte containing an electrochemical precursor to the electrocatalyst is applied to the other electrode whereby, upon applying current to the counter electrode, electrocatalyst is deposited on locations on the first electrode corresponding to the ion conduction channels. The process is repeated with the counter electrode connected on the other electrode of the cell. In a second embodiment, a combination of a first electrode and a first membrane is assembled as is a combination of a second electrode and a second membrane. A counter electrode and electrolyte containing an electrochemical precursor to the electrocatalyst are separately applied to the first combination, then the second combination whereby, upon applying current to the counter electrodes, electrocatalyst is deposited on locations on the first and second electrodes corresponding to the ion conduction channels. The surfaces of the first and second membranes are joined opposite their respective electrodes to a porous coupling layer to form the electrochemical device.
摘要翻译：诸如燃料电池的电化学装置及其形成方法，其中诸如阳极和阴极的电极设置在具有离子传导通道的半透膜或可渗透膜上。电催化剂沉积在限定于并对应于离子传导通道的电极上的位置上。在第一实施例中，阳极和阴极电极夹住膜，对电极连接到一个电极，将包含电催化剂的电化学前体的电解质施加到另一个电极，由此，在向对电极施加电流时，电催化剂为沉积在对应于离子传导通道的第一电极上的位置上。重复该过程，反电极连接在电池的另一个电极上。在第二实施例中，第一电极和第一膜的组合如第二电极和第二膜的组合一样被组装。将含有电催化剂的电化学前体的对电极和电解质分别施加到第一组合，然后第二组合，由此，在向对置电极施加电流时，电极催化剂沉积在对应于离子传导的第一和第二电极上的位置通道。第一和第二膜的表面与其各自的电极相对接合到多孔耦合层以形成电化学装置。

5. 发明申请

WO2013177438A3 CONVERSION OF PROPANE TO PROPYLENE 审中-公开
标题翻译：丙烯转化为丙烯
公开(公告)号：WO2013177438A3
公开(公告)日：2014-01-16
申请号：PCT/US2013042491
申请日：2013-05-23
申请人： GRT INC
发明人： JULKA VIVEK , GADEWAR SAGAR , STOIMENOV PETER K , GROSSO PHILIP , SHERMAN JEFFREY H , ZHANG AIHUA , MCFARLAND ERIC W
IPC分类号： C07C5/44
CPC分类号： C07C1/30 , C01B7/096 , C07C17/10 , C07C17/23 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/44 , C07C11/04 , C07C11/06 , C07C11/08 , C07C11/09 , C07C11/10 , C07C11/107 , C07C19/075
摘要： A process is disclosed that includes brominating a C2, C3, C4, C5 or C6 alkane with elemental bromine to form a bromo-alkane. The bromo-alkane is reacted to form a C2, C3, C4, C5 or C6 alkene and HBr. The HBr is oxidized to form elemental bromine.
摘要翻译：公开了一种方法，其包括使C 2，C 3，C 4，C 5或C 6烷烃与元素溴溴化以形成溴代烷烃。溴代烷烃反应形成C2，C3，C4，C5或C6烯烃和HBr。 HBr被氧化形成元素溴。

6. 发明申请

WO2006019399A3 ZONE REACTOR 审中-公开
标题翻译：区域反应器
公开(公告)号：WO2006019399A3
公开(公告)日：2006-11-16
申请号：PCT/US2005002829
申请日：2005-02-02
申请人： GRT INC
发明人： GROSSO PHILIP , SHERMAN JEFFREY H , MCFARLAND ERIC W
IPC分类号： C07C1/26 , C07C29/124 , C07C41/01
CPC分类号： C07C29/124 , C07C1/30 , Y02P20/125 , C07C11/02 , C07C31/04
摘要： In a method of converting alkanes to their corresponding alcohols, ethers, olefins, and other hydrocarbons, a vessel comprises a hollow, unsegregated interior defined first, second, and third zones. In a first embodiment of the invention oxygen reacts with metal halide in the first zone to provide gaseous halide; halide reacts with the alkane in the second zone to form alkyl halide; and the alkyl halide reacts with metal oxide in the third zone to form a hydrocarbon corresponding to the original alkane. Metal halide from the third zone is transported through the vessel to the first zone and metal oxide from the first zone is recycled to the third zone. A second embodiment of the invention differs from the first embodiment in that metal oxide is transported through the vessel from the first zone to the third zone and metal halide is recycled from the third zone to the first zone. In a third embodiment of the invention the flow of gases through the vessel is reversed to convert the metal oxide back to metal halide and to convert the metal halide back to the metal oxide.
摘要翻译：在将烷烃转化成其相应的醇，醚，烯烃和其它烃的方法中，容器包括中空的未分离的内部限定的第一，第二和第三区域。在本发明的第一实施方案中，氧与第一区中的金属卤化物反应以提供气态卤化物; 卤化物与第二区中的烷烃反应形成烷基卤; 并且烷基卤与第三区中的金属氧化物反应以形成对应于原始烷烃的烃。来自第三区域的金属卤化物通过容器输送到第一区域，并且来自第一区域的金属氧化物被再循环到第三区域。本发明的第二实施例与第一实施例的不同之处在于金属氧化物通过容器从第一区传送到第三区，金属卤化物从第三区再循环到第一区。在本发明的第三个实施方案中，反过来通过容器的气体流将金属氧化物转换回金属卤化物并将金属卤化物转化回金属氧化物。

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