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    • 1. 发明申请
    • IMPROVEMENTS IN AND RELATING TO ORGANIC SEMICONDUCTING LAYERS
    • 包含聚丙烯和有机粘合剂聚合物的有机半导体层制剂
    • WO2005055248A2
    • 2005-06-16
    • PCT/GB2004/004973
    • 2004-11-25
    • AVECIA LIMITEDBROWN, Beverley, AnneVERES, JanosANEMIAN, Remi, ManoukWILLIAMS, Richard, ThomasOGIER, Simon, DominicLEEMING, Stephen, William
    • BROWN, Beverley, AnneVERES, JanosANEMIAN, Remi, ManoukWILLIAMS, Richard, ThomasOGIER, Simon, DominicLEEMING, Stephen, William
    • H01B1/12
    • C08L39/04C07F7/0809C07F7/0818C08L35/06H01L51/0035H01L51/0036H01L51/0039H01L51/0052H01L51/0055H01L51/0056H01L51/0059H01L51/0071H01L51/0072H01L51/0073H01L51/0074H01L51/0094H01L51/0566H01L51/42H01L51/50Y02E10/549C08L2666/02C08L2666/28
    • An organic semiconducting layer formulation, which comprises: an organic binder which has a permittivity, ε, at 1,000 Hz of 3.3 or less; and a polyacene compound of Formula: A: wherein: each of R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 and R 12 , which may be the same or different, independently represents hydrogen; an optionally substituted C 1 -C 40 carbyl or hydrocarbyl group; an optionally substituted C 1 -C 40 alkoxy group; an optionally substituted C 6 -C 40 aryloxy group; an optionally substituted C 7 -C 40 alkylaryloxy group; an optionally substituted C 2 -C 40 alkoxycarbonyl group; an optionally substituted C 7 -C 40 aryloxycarbonyl group; a cyano group (-CN); a carbamoyl group (-C(=O)NH 2 ); a haloformyl group (-C(=O)-X, wherein X represents a halogen atom); a formyl group (-C(=O)-H); an isocyano group; an isocyanate group; a thiocyanate group or a thioisocyanate group; an optionally substituted amino group; a hydroxy group; a nitro group; a CF 3 group; a halo group (CI, Br, F); or an optionally substituted silyl group; and wherein independently each pair of R 2 and R 3 and/or R 8 and R 9 , may be cross-bridged to form a C 4 -C 40 saturated or unsaturated ring, which saturated or unsaturated ring may be intervened by an oxygen atom, a sulphur atom or a group shown by formula -N(R a )- (wherein R a is a hydrogen atom or an optionally substituted hydrocarbon group), or may optionally be substituted; and wherein one or more of the carbon atoms of the polyacene skeleton may optionally be substituted by a heteroatom selected from N, P, As, O, S, Se and Te; and wherein independently any two or more of the substituents R 1 -R 12 which are located on adjacent ring positions of the polyacene may, together, optionally constitute a further C 4 -C 40 saturated or unsaturated ring optionally interrupted by O, S or -N(R a ) where R a is as defined above) or an aromatic ring system, fused to the polyacene; and wherein n is 0, 1, 2, 3 or 4, also claimed is an electronic device, particularly an organic field effect transistor comprising the organic semiconductor layer formulation.
    • 一种有机半导体层制剂,其包含:在1000Hz下介电常数ε为3.3或更小的有机粘合剂; 和式A的多并苯化合物:其中:可以相同或不同的R 1,R 2,R 3,R 4,R 5,R 6,R 7,R 8,R 9,R 10,R 11和R 12各自独立地表示氢; 任选取代的C 1 -C 40碳原子或烃基; 任选取代的C 1 -C 40烷氧基; 任选取代的C 6 -C 40芳氧基; 任选取代的C 7 -C 40烷基芳氧基; 任选取代的C 2 -C 40烷氧基羰基; 任选取代的C 7 -C 40芳氧基羰基; 氰基(-CN); 氨基甲酰基(-C(= O)NH 2); 卤代甲酰基(-C(= O)-X,其中X表示卤素原子); 甲酰基(-C(= O)-H); 异氰基团 异氰酸酯基; 硫氰酸酯基或硫代异氰酸酯基; 任选取代的氨基; 羟基; 硝基; CF3组; 卤代基(CI,Br,F); 或任选取代的甲硅烷基; 并且其中独立地,每对R 2和R 3和/或R 8和R 9可以交桥以形成C 4 -C 40饱和或不饱和环,该饱和或不饱和环可以被氧原子,硫原子或 基团-N(R a) - (其中R a是氢原子或任选取代的烃基),或可以任选地被取代; 并且其中多并苯骨架的一个或多个碳原子可任选地被选自N,P,As,O,S,Se和Te的杂原子取代; 并且其中独立地位于多并苯的相邻环位上的任何两个或更多个取代基R 1 -R 12可以一起任选地构成任选地被O,S或-N(R a)中断的另外的C 4 -C 40饱和或不饱和环, 其中Ra如上所定义)或与多并烯稠合的芳环体系; 并且其中n为0,1,2,3或4,还要求保护的是电子器件,特别是包含有机半导体层配方的有机场效应晶体管。
    • 3. 发明申请
    • FREE RADICAL POLYMERISATION PROCESS
    • 自由放射聚合过程
    • WO1995017435A1
    • 1995-06-29
    • PCT/GB1994002769
    • 1994-12-20
    • ZENECA LIMITEDHADDLETON, David, MarkMUIR, Andrew, Victor, GrahamLEEMING, Stephen, William
    • ZENECA LIMITED
    • C08F02/38
    • C07F5/022C08F2/38
    • A compound for effecting molecular weight control in polymerisation is a CoII chelate of formula (I), wherein each group R is an organic cyclic group which, independently, is a monovalent group which comprises a cyclic structure or taken together as two adjacent groups provides a divalent group, and wherein further at least one of the groups R includes at least one heteroatom selected from O, N, S, P, halogen and Si, which heteroatom provides a substituent group or part of a substituent group on the cyclic structure, or a heteroatom of a heterocyclic ring of the cyclic structure; and wherein each group Q is independently selected from F, Cl, Br, OH, C1-12 alkoxy and C1-12 alkyl; or being a CoIII analogue of the cobalt II chelate of formula (I) in which the Co atom is additionally covalently bonded to H, a halide or other anion, or a homolytically dissociable organic group. Free-radical polymerisation of at least one ethylenically unsaturated monomer is carried out in the presence of such a compound.
    • 用于在聚合中进行分子量控制的化合物是式(I)的CoII螯合物,其中每个基团R是有机环状基团,其独立地是包含环状结构的一价基团或两个相邻的基团一起提供一个 并且其中所述基团R中的至少一个基团包含至少一个选自O,N,S,P,卤素和Si的杂原子,所述杂原子提供环状结构上的取代基或取代基的一部分,或 环状结构的杂环的杂原子; 并且其中每个基团Q独立地选自F,Cl,Br,OH,C 1-12烷氧基和C 1-12烷基; 或者是式(I)的钴II螯合物的CoIII类似物,其中Co原子另外共价键合到H,卤化物或其它阴离子或均分解离的有机基团。 至少一种烯键式不饱和单体的自由基聚合在这种化合物的存在下进行。
    • 6. 发明申请
    • FREE RADICAL POLYMERISATION PROCESS
    • 自由放射聚合过程
    • WO1996013527A1
    • 1996-05-09
    • PCT/GB1995002376
    • 1995-10-09
    • ZENECA LIMITEDHADDLETON, David, MarkMUIR, Andrew, Victor, GrahamLEEMING, Stephen, WilliamO'DONNELL, John, PatrickRICHARDS, Stuart, Nicholas
    • ZENECA LIMITED
    • C08F02/38
    • C08F2/38C07F5/022
    • Process for the free-radical polymerisation of olefinically unsaturated monomer(s) using a free-radical initiator, the polymerisation being performed in the presence of a compound for effecting molecular weight control, wherein the molecular weight control compound is a CoII chelate of formula (I) wherein each group X, independently in each ring and in different rings, is a substituent selected from alkyl of 1 to 14 carbon atoms and cycloalkyl of 6 to 14 carbon atoms; n, independently in each ring, is 0 to 5 provided that in at least one ring, n is 1 to 5; Z, independently on each boron atom, is selected from F, Cl, Br, OH, alkoxy of 1 to 12 carbon atoms, aryloxy of 6 to 12 carbon atoms, alkyl of 1 to 12 carbon atoms, and aryl of 6 to 12 carbon atoms; or two Z groups taken together provide on one or both boron atoms a group -O-(Q)-O- where Q is a divalent aryl or alicyclic linking group or an alkylene linking group, or two Z groups taken together on one or both boron atoms provide a 1,5-cyclooctanediyl linking group; or being a CoIII analogue of said CoII chelate of formula (I) in which the Co atom is additionally covalently bonded, in a direction at right angles to the macrocyclic chelate ring system, to H, halide or other anion, or a homolytically dissociable organic group; and wherein optionally at least one further ligand is coordinated to the CoII or CoIII atom, being a ligand which does not alter the Co valency state. Also the Co chelates used in the polymerisation process, a process for their production, and the use in various applications of oligomers made using the polymerisation process.
    • 使用自由基引发剂使烯属不饱和单体自由基聚合的方法,该聚合在化合物存在下进行以进行分子量控制,其中分子量控制化合物是式(I)的CoII螯合物 I),其中每个基团X独立地为每个环和不同的环,是选自1至14个碳原子的烷基和6至14个碳原子的环烷基的取代基; n在每个环中独立地为0至5,条件是在至少一个环中,n为1至5; Z独立地为每个硼原子,选自F,Cl,Br,OH,1至12个碳原子的烷氧基,6至12个碳原子的芳氧基,1至12个碳原子的烷基和6至12个碳的芳基 原子; 或两个Z基团在一个或两个硼原子上提供基团-O-(Q)-O-,其中Q是二价芳基或脂环族连接基团或亚烷基连接基团,或两个Z基团在一个或两个上合在一起 硼原子提供1,5-环辛二基连接基团; 或作为式(I)的所述CoII螯合物的CoIII类似物,其中Co原子在与大环螯合环体系成直角的方向上额外共价键合到H,卤化物或其它阴离子或均分离的有机物 组; 并且其中任选地至少一个另外的配体与CoII或CoIII原子配位,作为不改变Co价态的配体。 还有在聚合过程中使用的Co螯合物,它们的生产方法以及在使用聚合方法制备的低聚物的各种应用中的用途。
    • 8. 发明申请
    • ORGANIC SEMICONDUCTING LAYER FORMULATIONS COMPRISING POLYACENES AND ORGANIC BINDER POLYMERS
    • 包含聚丙烯和有机粘合剂聚合物的有机半导体层制剂
    • WO2005055248A3
    • 2005-07-28
    • PCT/GB2004004973
    • 2004-11-25
    • AVECIA LTDBROWN BEVERLEY ANNEVERES JANOSANEMIAN REMI MANOUKWILLIAMS RICHARD THOMASOGIER SIMON DOMINICLEEMING STEPHEN WILLIAM
    • BROWN BEVERLEY ANNEVERES JANOSANEMIAN REMI MANOUKWILLIAMS RICHARD THOMASOGIER SIMON DOMINICLEEMING STEPHEN WILLIAM
    • C07F7/08C08L35/06C08L39/04H01B1/12H01B1/20H01L51/00H01L51/05H01L51/30H01L51/20
    • C08L39/04C07F7/0809C07F7/0818C08L35/06H01L51/0035H01L51/0036H01L51/0039H01L51/0052H01L51/0055H01L51/0056H01L51/0059H01L51/0071H01L51/0072H01L51/0073H01L51/0074H01L51/0094H01L51/0566H01L51/42H01L51/50Y02E10/549C08L2666/02C08L2666/28
    • An organic semiconducting layer formulation, which comprises: an organic binder which has a permittivity, ϵ, at 1,000 Hz of 3.3 or less; and a polyacene compound of Formula: (A) wherein: each of R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11 and R12, which may be the same or different, independently represents hydrogen; an optionally substituted C1-C40 carbyl or hydrocarbyl group; an optionally substituted C1-C40 alkoxy group; an optionally substituted C6-C40 aryloxy group; an optionally substituted C7-C40 alkylaryloxy group; an optionally substituted C2-C40 alkoxycarbonyl group; an optionally substituted C7-C40 aryloxycarbonyl group; a cyano group (-CN); a carbamoyl group (-C(=O)NH2); a haloformyl group (-C(=O)-X, wherein X represents a halogen atom); a formyl group (-C(=O)-H); an isocyano group; an isocyanate group; a thiocyanate group or a thioisocyanate group; an optionally substituted amino group; a hydroxy group; a nitro group; a CF3 group; a halo group (CI, Br, F); or an optionally substituted silyl group; and wherein independently each pair of R2 and R3 and/or R8 and R9, may be cross-bridged to form a C4-C40 saturated or unsaturated ring, which saturated or unsaturated ring may be intervened by an oxygen atom, a sulphur atom or a group shown by formula -N(Ra)- (wherein Ra is a hydrogen atom or an optionally substituted hydrocarbon group), or may optionally be substituted; and wherein one or more of the carbon atoms of the polyacene skeleton may optionally be substituted by a heteroatom selected from N, P, As, O, S, Se and Te; and wherein independently any two or more of the substituents R1-R12 which are located on adjacent ring positions of the polyacene may, together, optionally constitute a further C4-C40 saturated or unsaturated ring optionally interrupted by O, S or -N(Ra) where Ra is as defined above) or an aromatic ring system, fused to the polyacene; and wherein n is 0, 1, 2, 3 or 4, also claimed is an electronic device, particularly an organic field effect transistor comprising the organic semiconductor layer formulation.
    • 一种有机半导体层制剂,其包含:在1000Hz下介电常数ε为3.3或更小的有机粘合剂; 和(A)的多并苯化合物,其中:可以相同或不同的R 1,R 2,R 3,R 4,R 5,R 6,R 7,R 8,R 9,R 10,R 11和R 12各自独立地表示氢; 任选取代的C 1 -C 40碳原子或烃基; 任选取代的C 1 -C 40烷氧基; 任选取代的C 6 -C 40芳氧基; 任选取代的C 7 -C 40烷基芳氧基; 任选取代的C 2 -C 40烷氧基羰基; 任选取代的C 7 -C 40芳氧基羰基; 氰基(-CN); 氨基甲酰基(-C(= O)NH 2); 卤代甲酰基(-C(= O)-X,其中X表示卤素原子); 甲酰基(-C(= O)-H); 异氰基团 异氰酸酯基; 硫氰酸酯基或硫代异氰酸酯基; 任选取代的氨基; 羟基; 硝基; CF3组; 卤代基(CI,Br,F); 或任选取代的甲硅烷基; 并且其中独立地,每对R 2和R 3和/或R 8和R 9可以交桥以形成C 4 -C 40饱和或不饱和环,该饱和或不饱和环可以被氧原子,硫原子或 基团-N(R a) - (其中R a是氢原子或任选取代的烃基),或可以任选地被取代; 并且其中多并苯骨架的一个或多个碳原子可任选地被选自N,P,As,O,S,Se和Te的杂原子取代; 并且其中独立地位于多并苯的相邻环位上的任何两个或更多个取代基R 1 -R 12可以一起任选地构成任选地被O,S或-N(R a)中断的另外的C 4 -C 40饱和或不饱和环, 其中Ra如上所定义)或与多并烯稠合的芳环体系; 并且其中n为0,1,2,3或4,还要求保护的是电子器件,特别是包含有机半导体层配方的有机场效应晶体管。