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1. 发明申请

WO1995012219A1 STABILISED ELECTROLYTE SOLUTIONS, METHODS OF PREPARATION THEREOF AND REDOX CELLS AND BATTERIES CONTAINING STABILISED ELECTROLYTE SOLUTIONS 审中-公开
标题翻译：稳定的电解质溶液，其制备方法和还原电池和含有稳定电解质溶液的电池
公开(公告)号：WO1995012219A1
公开(公告)日：1995-05-04
申请号：PCT/AU1994000711
申请日：1994-11-17
申请人： UNISEARCH LIMITED , SAMAD, Mohammed, Abdus , KAZACOS, Michael , KAZACOS, Maria, Skyllas
发明人： UNISEARCH LIMITED
IPC分类号： H01M08/08
CPC分类号： H01M8/188 , H01M8/20 , H01M10/36 , Y02E60/528 , Y02P70/56
摘要： A method for stabilising an electrolyte for use in a redox cell, in particular for stabilising an electrolyte for use in an all-vanadium redox cell, a stabilised electrolyte, in particular an all-vanadium stabilised electrolyte, a redox cell, in particular an all-vanadium redox cell, comprising the stabilised electrolyte, a redox battery, in particular an all-vanadium redox battery, comprising the stabilised electrolyte, a process for recharging a discharged or partially discharged redox battery, in particular an all-vanadium redox battery, comprising the stabilised electrolyte, and a process for the production of electricity from a charged redox battery, and in particular a charged all-vanadium redox battery, comprising the stabilised electrolyte are disclosed. Also disclosed are a redox battery/fuel cell and a process for the production of electricity from a redox battery/fuel cell.
摘要翻译：用于稳定用于氧化还原电池的电解质的方法，特别是用于稳定用于全钒氧化还原电池的电解质，稳定的电解质，特别是全钒稳定的电解质，特别是全钒稳定的电解质包含稳定的电解质的氧化还原电池，特别是包含稳定的电解质的全钒氧化还原电池，用于对放电或部分排放的氧化还原电池，特别是全钒氧化还原电池进行再充电的方法，包括：稳定化的电解质，以及由充电的氧化还原电池产生电的方法，特别是包含稳定的电解质的带电的全钒氧化还原电池。还公开了一种氧化还原电池/燃料电池和用于从氧化还原电池/燃料电池产生电力的方法。

2. 发明申请

WO1989005528A1 VANADIUM CHARGING CELL AND VANADIUM DUAL BATTERY SYSTEM 审中-公开
标题翻译： VANADIUM充电电池和VANADIUM双电池系统
公开(公告)号：WO1989005528A1
公开(公告)日：1989-06-15
申请号：PCT/AU1988000473
申请日：1988-12-09
申请人： UNISEARCH LIMITED , SKYLLAS-KAZACOS, Maria , KAZACOS, Michael , McDERMOTT, Rodney, John, Charles
发明人： UNISEARCH LIMITED
IPC分类号： H01M10/44
CPC分类号： B60L11/1879 , H01M2/16 , H01M4/66 , H01M4/661 , H01M4/663 , H01M4/86 , H01M8/04194 , H01M8/188 , H01M10/36 , H01M2300/0005 , Y02E60/528 , Y02T10/7005 , Y02T10/705 , Y02T90/16
摘要： An all-vanadium redox charge cell is disclosed. The cell has a negative charge compartment having a negative charge electrode for charging a charge anolyte in electrical contact with said negative charge electrode, the charge anolyte comprising an electrolyte containing trivalent and/or tetravalent vanadium ions, a positive charge compartment having a positive charge electrode for charging a charge catholyte in electrical contact with said positive charge electrode, the charge catholyte comprising an electrolyte containing tetravalent vanadium ions, and an ionically conducting charge separator disposed between the positive and negative charge compartments to provide ionic communication between the charge catholyte and the charge anolyte. The positive charge electrode is selected such that it is stable in the charge catholyte in the charge potential range during oxidisation of tetravalent vanadium ions to pentavalent vanadium ions at the positive charge electrode and the negative charge electrode is selected such that it is stable in the charge anolyte in the charge potential range during reduction of tetravalent and trivalent vanadium ions to divalent vanadium ions at the negative charge electrode. Also disclosed is an all-vanadium redox dual battery system which incorporates the above all-vanadium redox charge cell.
摘要翻译：公开了一种全钒氧化还原电荷电池。电池具有负电荷室，其具有用于对与所述负电荷电极电接触的电荷阳极电解液充电的负电荷电极，所述电荷阳极电解液包含含有三价和/或四价钒离子的电解质，具有正电荷电极的正电荷室用于对与所述正电荷电极电接触的电荷阴极电荷进行充电，所述电荷阴极电解液包含含有四价钒离子的电解质，以及设置在正电荷室和负电荷室之间的离子导电电荷分离器，以提供电荷阴极电解液和电荷之间的离子连通阳极液。选择正电荷电极，使得在正电荷电极将四价钒离子氧化成五价钒离子时，在充电电势范围内的电荷阴极电解液中是稳定的，并且选择负电荷电极使得其在电荷中是稳定的在负电荷电极将四价和三价钒离子还原成二价钒离子时，电荷电位范围内的阳极电解液。还公开了一种全钒氧化还原双电池系统，其包含上述全钒氧化还原电荷池。

3. 发明申请

WO2004082056A1 NOVEL VANADIUM HALIDE REDOX FLOW BATTERY 审中-公开
标题翻译：新款VANADIUM HALIDE REDOX流量电池
公开(公告)号：WO2004082056A1
公开(公告)日：2004-09-23
申请号：PCT/AU2004/000310
申请日：2004-03-15
申请人： KAZACOS, Michael , SKYLLAS-KAZACOS, Maria , KAZACOS, Nicholas
发明人： KAZACOS, Michael , SKYLLAS-KAZACOS, Maria , KAZACOS, Nicholas
IPC分类号： H01M8/20
CPC分类号： H01M8/188 , B60L11/1822 , B60L11/1879 , B60L2240/545 , H01M8/20 , Y02E60/528 , Y02T10/7011 , Y02T10/705 , Y02T10/7072 , Y02T90/124 , Y02T90/14
摘要： A prior to charge vanadium halide redox cell, a vanadium halide redox cell which is at a state of charge selected from the group consisting of a zero state of charge and a near zero state of charge and vanadium halide redox cell which are fully charged and partially charged are described. The prior to charge vanadium halide redox cell comprises a positive half cell containing a positive half cell solution comprising a halide electrolyte, vanadium (III) halide and vanadium (IV) halide, a negative half cell containing a negative half cell solution comprising a halide electrolyte, vanadium (III) halide and vanadium (N) halide wherein the amounts of vanadium (III) halide, vanadium (IV) halide and halide ions in the positive and negative half cell solutions are such that in a first charging step comprising charging the prior to charge vanadium halide redox cell, a vanadium halide redox cell having a state of charge selected from the group consisting of a zero state of charge and a near zero state of charge comprising predominantly vanadium (N) halide in the positive half cell solution and predominantly V(III) halide in the negative half cell solution can be prepared. The vanadium halide redox cell which is at a state of charge selected from the group consisting of a zero state of charge and a near zero state of charge comprises a positive half cell containing a positive half cell solution comprising a halide electrolyte and a vanadium halide which is predominantly vanadium (N) halide, a negative half cell containing a negative half cell solution comprising a halide electrolyte and a vanadium halide which is predominantly vanadium (III) halide wherein the amount of vanadium (N) halide in the positive half cell solution and the amount of vanadium (III) halide in the negative half cell solution are such that the vanadium halide redox cell is at a state of charge selected from the group consisting of a zero state of charge and a near zero state of charge. The vanadium halide redox cell which is fully charged comprises a positive half cell containing a positive half cell solution comprising a halide electrolyte, a polyhalide complex, vanadium (IV) halide and vanadium (V) halide, a negative half cell containing a negative half cell solution comprising a halide electrolyte and vanadium (II) halide wherein the molar concentration of vanadium (V) and polyhalide complex:molar concentration of vanadium (II) halide is about stoichiometrically balanced. The vanadium halide redox cell which is partially charged comprises a positive half cell containing a positive half cell solution comprising a halide electrolyte, a polyhalide complex, vanadium (IV) halide and vanadium (V) halide, a negative half cell containing a negative half cell solution comprising a halide electrolyte, vanadium (II) halide and vanadium (III) halide wherein the number of moles of moles of polyhalide complex and vanadium (V): number of moles of vanadium (II) halide is about stoichiometrically balanced.
摘要翻译：在对钒卤化物氧化还原电池进行充电之前，将处于充电状态的充满状态的钒卤化物氧化还原电池和充满电的零电荷状态和卤化钒氧化还原电池充满电并部分地描述了充电。先前装载钒卤化物氧化还原电池包括含有阳离子半电池溶液的正半电池，其包含卤化物电解质，卤化钒（III）和卤化钒（IV），负半电池，其含有包含卤化物电解质，卤化钒（III）和卤化钒（N），其中在正和负半电池溶液中卤化物（III），卤化钒（IV）和卤化物离子的量使得在第一充电步骤中，为了对钒卤化物氧化还原电池进行充电，具有选自正电荷溶液中的主要为钒（N）卤化物的零电荷状态和近零电荷状态的电荷状态的钒卤化物氧化还原电池，并且主要是可以制备阴性半细胞溶液中的V（III）卤化物。处于选自零电荷状态和接近零电荷状态的电荷状态的钒卤化物氧化还原电池包括含有包含卤化物电解质和卤化钒的正半胱氨酸溶液的正半电池，主要是钒（N）卤化物，含有负半细胞溶液的负半细胞，其包含卤化物电解质和主要是卤化钒（III）的卤化钒，其中正半胱氨酸溶液中的钒（N）卤化物的量和负半细胞溶液中的卤化钒（III）的量使得卤化钒氧化还原电池处于选自零电荷状态和接近零电荷状态的电荷状态。完全充电的钒卤化物氧化还原电池包含含有阳离子半电池溶液的正半电池，其包含卤化物电解质，多卤化物络合物，卤化钒（IV）和卤化钒（V），含有负半电池的负半电池包含卤化物电解质和卤化钒（II）的溶液，其中钒（V）和多卤化物络合物的摩尔浓度：卤化钒（II）的摩尔浓度约为化学计量平衡。部分充电的钒卤化物氧化还原电池包括含有阳离子半电池溶液的正半电池，其包含卤化物电解质，多卤化物络合物，卤化钒（IV）和卤化钒（V），含有负半电池的负半电池包含卤化物电解质，卤化钒（II）和卤化钒（III）的溶液，其中多卤化物络合物和钒的摩尔数（V）：卤化钒（II）的摩尔数约为化学计量平衡。

4. 发明申请

WO2003092138A2 METAL HALIDE REDOX FLOW BATTERY 审中-公开
标题翻译：金属卤化物回流流量电池
公开(公告)号：WO2003092138A2
公开(公告)日：2003-11-06
申请号：PCT/GB2003/001757
申请日：2003-04-23
申请人： E-FUEL TECHNOLOGY LIMITED , SKYLLAS-KAZACOS, Maria , KAZACOS, Michael , MOUSA, Asem
发明人： SKYLLAS-KAZACOS, Maria , KAZACOS, Michael , MOUSA, Asem
IPC分类号： H02J
CPC分类号： H01M8/188 , B60L11/1894 , H01M8/20 , H01M12/08 , Y02E60/128 , Y02T90/34
摘要： A 3 M V(IV) bromide solution in 3-4 M HBr or HBr/HCl mixture is added to both sides of the redox flow cell or battery. On fully charging the cell, the vanadium (IV) bromide solution is reduced to produce 3M VBr 2 in the negative half-cell, while the bromide ions in the positive half-cell are oxidised to produce 1.5 M Br 3 - or CIBr 2 . On discharge, the VBr 2 is oxidised to VBr 3 in the negative half cell while the Br 3 or ClBr 2 - ions are reduced to Br ions in the positive half cell. The cell comprises carbon or graphite felt bonded onto plastic or conducting plastic sheets as substrate materials and the two half cells are separated by an anion or cation exchange membrane.
摘要翻译：将3-4M HBr或HBr / HCl混合物中的3MV（IV）溴化物溶液加入到氧化还原流动池或电池的两侧。在电池完全充电后，溴化钒（IV）溶液被还原成在负半电池中产生3M VBr2，而正半电池中的溴离子被氧化以产生1.5M Br3-或CIBr2。放电时，VBr2在负半电池中氧化成VBr3，而Br3或ClBr2-离子在正半电池中还原成Br离子。电池包括粘结在塑料上的碳或石墨毡或作为衬底材料的导电塑料片，并且两个半电池被阴离子或阳离子交换膜隔开。

5. 发明申请

WO2003092138A3 IMPROVED VANADIUM BROMIDE BATTERY (METAL HALIDE REDOX FLOW CELL) 审中-公开
公开(公告)号：WO2003092138A3
公开(公告)日：2003-11-06
申请号：PCT/GB2003/001757
申请日：2003-04-23
申请人： E-FUEL TECHNOLOGY LIMITED , SKYLLAS-KAZACOS, Maria , KAZACOS, Michael , MOUSA, Asem
发明人： SKYLLAS-KAZACOS, Maria , KAZACOS, Michael , MOUSA, Asem
IPC分类号： H01M8/20
摘要： A 3 M V(IV) bromide solution in 3-4 M HBr or HBr/HCl mixture is added to both sides of the redox flow cell or battery. On fully charging the cell, the vanadium (IV) bromide solution is reduced to produce 3M VBr 2 in the negative half-cell, while the bromide ions in the positive half-cell are oxidised to produce 1.5 M Br 3 - or CIBr 2 . On discharge, the VBr 2 is oxidised to VBr 3 in the negative half cell while the Br 3 or ClBr 2 - ions are reduced to Br ions in the positive half cell. The cell comprises carbon or graphite felt bonded onto plastic or conducting plastic sheets as substrate materials and the two half cells are separated by an anion or cation exchange membrane.

6. 发明申请

WO1996035239A1 HIGH ENERGY DENSITY VANADIUM ELECTROLYTE SOLUTIONS, METHODS OF PREPARATION THEREOF AND ALL-VANADIUM REDOX CELLS AND BATTERIES CONTAINING HIGH ENERGY VANADIUM ELECTROLYTE SOLUTIONS 审中-公开
标题翻译：高能密度VANADIUM电解质溶液，其制备方法和全钒氧化物电池和含有高能量电解质溶液的电池
公开(公告)号：WO1996035239A1
公开(公告)日：1996-11-07
申请号：PCT/AU1996000268
申请日：1996-05-03
申请人： UNISEARCH LIMITED , KAZACOS, Michael , KAZACOS, Maria, Skyllas
发明人： UNISEARCH LIMITED
IPC分类号： H01M08/20
CPC分类号： B60L11/1879 , B60L11/1822 , B60L2240/545 , H01M8/188 , H01M8/20 , H01M10/36 , Y02E60/528 , Y02P70/56 , Y02T10/7005 , Y02T10/705 , Y02T10/7072 , Y02T90/124 , Y02T90/14
摘要： Disclosed is a method for preparing a high energy density (HED) electrolyte solution for use in an all-vanadium redox cells, a high energy density electrolyte solution, in particular an all-vanadium high energy density electrolyte solution, a redox cell, in particular an all-vanadium redox cell, comprising the high energy density electrolyte solution, a redox battery, in particular an all-vanadium redox battery, comprising the HED electrolyte solution, a process for recharging a discharged or partially discharged redox battery, in particular an all-vanadium redox battery, comprising the HED electrolyte solution, a process for the production of electricity from a charged redox battery, and in particular a charged all-vanadium redox battery, comprising the HED electrolyte, a redox battery/fuel cell and a process for the production of electricity from a redox battery/fuel cell. A method for stabilising an electrolyte solution for use in a redox cell, in particular for stabilising an electrolyte solution for use in an all-vanadium redox cell, a stabilised electrolyte solution, in particular an all-vanadium stabilised electrolyte solution, a redox cell, in particular an all-vanadium redox cell, comprising the stabilised electrolyte solution, a redox battery, in particular an all-vanadium redox battery, comprising the stabilised electrolyte solution, a process for recharging a discharged or partially discharged redox battery, in particular an all-vanadium redox battery, comprising the stabilised electrolyte solution, and a process for the production of electricity from a charged redox battery, and in particular a charged all-vanadium redox battery, comprising the stabilised electrolyte solution are disclosed. Also disclosed are a redox battery/fuel cell and a process for the production of electricity from a redox battery/fuel cell.
摘要翻译：公开了一种用于全钒氧化还原电池，高能量密度电解质溶液，特别是全钒高能量密度电解质溶液，特别是氧化还原电池的高能量密度（HED）电解质溶液的方法包括高能量密度电解质溶液的氧化还原电池，特别是全钒氧化还原电池的全钒氧化还原电池，包括HED电解质溶液，对放电或部分排出的氧化还原电池进行再充电的方法，特别是全部包括HED电解质溶液，用于从充电的氧化还原电池产生电的方法，特别是包含HED电解质，氧化还原电池/燃料电池的充电全钒氧化还原电池，以及用于从氧化还原电池/燃料电池产生电力。用于稳定用于氧化还原电池的电解质溶液的方法，特别是用于稳定用于全钒氧化还原电池的电解质溶液，稳定的电解质溶液，特别是全钒稳定的电解质溶液，氧化还原电池，特别是全钒氧化还原电池，包括稳定的电解质溶液，氧化还原电池，特别是全钒氧化还原电池，包括稳定的电解质溶液，对放电或部分排出的氧化还原电池进行再充电的方法，特别是全部公开了包含稳定的电解质溶液的钒 - 氧化还原电池，以及由充电的氧化还原电池产生电的方法，特别是包含稳定的电解质溶液的充电的全钒氧化还原电池。还公开了一种氧化还原电池/燃料电池和用于从氧化还原电池/燃料电池产生电力的方法。

7. 发明申请

WO1994006164A1 FLEXIBLE, CONDUCTING PLASTIC ELECTRODE AND PROCESS FOR ITS PREPARATION 审中-公开
标题翻译：柔性，导电塑料电极及其制备方法
公开(公告)号：WO1994006164A1
公开(公告)日：1994-03-17
申请号：PCT/AU1993000456
申请日：1993-09-06
申请人： UNISEARCH LIMITED , ZHONG, Shihuang , KAZACOS, Michael , SKYLLAS KAZACOS, Maria , HADDADI-ASL, Vahid
发明人： UNISEARCH LIMITED
IPC分类号： H01M04/88
CPC分类号： B29C70/882 , B29K2021/00 , B29K2101/12 , B29L2031/3061 , C25B11/04 , D01F11/14 , D01F11/16 , H01M4/668 , H01M4/86 , H01M4/96 , H01M6/48 , H01M8/188 , Y02E60/528
摘要： Conducting plastic electrodes and methods of preparing such electrodes are disclosed. The electrodes comprise a thermo-plastic polymer, an elastomeric polymer, and a conductive filler material.
摘要翻译：公开了导电塑料电极及其制备方法。电极包括热塑性聚合物，弹性聚合物和导电填料。

8. 发明申请

WO1993006626A1 PERMEATION SELECTIVE SEPARATORS AND PROCESSES FOR MAKING SUCH SEPARATORS 审中-公开
标题翻译：渗透选择分离器和制造这种分离器的方法
公开(公告)号：WO1993006626A1
公开(公告)日：1993-04-01
申请号：PCT/AU1992000491
申请日：1992-09-17
申请人： UNISEARCH LIMITED , CHIENG, Sie, Chung , KAZACOS, Michael , KAZACOS, Maria
发明人： UNISEARCH LIMITED
IPC分类号： H01M02/16
CPC分类号： H01M2/16 , H01M4/86 , H01M8/0289 , H01M8/188 , Y02E60/528 , Y02P70/56
摘要： A permeation selective separators and a process for making such a separator are disclosed. The permeation selective separator comprises a microporous separator having at least one ion exchange material crosslinked with the separator. The process for making the permeation selective separator comprises contacting a microporous separator with a solvent comprising, at least partially dissolved therein, at least one ion exchange material and at least one crosslinker, for a period sufficient to permit the ion exchange material and the crosslinker to be taken up by the pores of the microporous separator. The ion exchange material is then crosslinked with the microporous separator to form the permeation selective separator, wherein the permeation selective separator has greater permeation selectivity than the permeation selectivity of the uncrosslinked microporous separator.
摘要翻译：公开了一种渗透选择性分离器及其制造方法。渗透选择性分离器包括具有至少一种与分离器交联的离子交换材料的微孔隔膜。用于制备渗透选择性分离器的方法包括使微孔分离器与包含至少部分地溶解有至少一种离子交换材料和至少一种交联剂的溶剂接触足够长的时间以允许离子交换材料和交联剂被微孔隔膜的孔吸收。离子交换材料然后与微孔分离器交联以形成渗透选择性分离器，其中渗透选择性分离器具有比未交联的微孔分离器的渗透选择性更高的渗透选择性。

9. 发明申请

WO1990003666A1 STATE OF CHARGE OF REDOX CELL 审中-公开
标题翻译：红细胞电荷状态
公开(公告)号：WO1990003666A1
公开(公告)日：1990-04-05
申请号：PCT/AU1989000252
申请日：1989-06-09
申请人： UNISEARCH LIMITED , SKYLLAS-KAZACOS, Maria , MADDERN, Barry, George , KAZACOS, Michael , JOY, Jaqui
发明人： UNISEARCH LIMITED
IPC分类号： H01M08/20
CPC分类号： H01M8/04753 , H01M4/661 , H01M4/663 , H01M8/04186 , H01M8/04194 , H01M8/04365 , H01M8/04708 , H01M8/0488 , H01M8/0491 , H01M8/04953 , H01M8/188 , H01M2300/0005 , Y02E60/528
摘要： A redox flow cell system (100) in which the state of charge can be determined is disclosed. The system (100) includes a redox flow cell (101) having a negative compartment (102), a positive compartment (103) and an ionically conducting separator (104) operatively disposed between the positive and negative compartments and in contact with positive and negative electrolytes in compartments (103) and (102) to provide ionic communication therebetween; a positive electrolyte pump (1); means (107), (105) and (107A) for transporting positive electrolyte between the positive compartment (103) and the positive electrolyte pump (1), operatively associated with the positive compartment (103) and the positive electrolyte pump (1); a negative electrolyte pump (2); means (108), (106) and (108A) for transporting negative electrolyte between the negative compartment (102) and the negative electrolyte pump (2), operatively associated with the negative compartment (102) and the negative electrolyte pump (2); means to measure (110), (111) and (109) a characteristic(s) of the positive and/or negative electrolytes related to state of charge of the cell, operatively associated with the positive and/or negative electrolytes; and means (122) to determine the state of charge of the cell from the characteristic(s), operatively associated with the means to measure (110), (111) and (109). Also disclosed are a method of determining state of charge of a redox flow cell, a method of providing a selected discharge voltage/current from a redox flow cell, a method of providing a selected charge voltage/current from a redox flow cell, a redox flow cell system for providing a selected discharge voltage/current from a redox flow cell, and a redox flow cell system having a redox flow cell which is adaptable to require a selected charge voltage/current.
摘要翻译：公开了可以确定电荷状态的氧化还原流通池系统（100）。系统（100）包括具有负隔室（102），阳性室（103）和离子导电分离器（104）的氧化还原流通池（101），其操作地设置在正隔室和负隔室之间并与正和负接触在隔室（103）和（102）中的电解质以提供离子连通; 正电解液泵（1）; 用于在正隔室（103）和正电解液泵（1）之间输送正电解液的装置（107），（105）和（107A），与正隔室（103）和正电解液泵（1）可操作地相连。负电解液泵（2）; 用于在负隔室（102）和负电解质泵（2）之间输送负电解质的装置（108），（106）和（108A），与负隔室（102）和负电解液泵（2）可操作地相关联。用于测量（110），（111）和（109）与正电解质和/或负电解质操作性相关的电池电荷相关的正电解质和/或负电解质的特征的装置; 以及用于从与所述测量装置（110），（111）和（109）可操作地相关联的特征确定所述小区的充电状态的装置（122）。还公开了一种确定氧化还原流动池的电荷状态的方法，从氧化还原流动池提供所选择的放电电压/电流的方法，从氧化还原流动池提供所选择的充电电压/电流的方法，氧化还原用于从氧化还原流动池提供所选择的放电电压/电流的流动池系统，以及具有适于需要选定的充电电压/电流的氧化还原流动池的氧化还原流通池系统。

10. 发明申请

WO1989005363A1 VANADIUM COMPOUND DISSOLUTION PROCESSES 审中-公开
标题翻译：钒化合物溶解过程
公开(公告)号：WO1989005363A1
公开(公告)日：1989-06-15
申请号：PCT/AU1988000471
申请日：1988-12-09
申请人： UNISEARCH LIMITED , SKYLLAS-KAZACOS, Maria , KAZACOS, Michael , McDERMOTT, Rodney, John, Charles
发明人： UNISEARCH LIMITED
IPC分类号： C25B01/00
CPC分类号： C01G31/00 , C22B3/045 , C22B34/22 , H01M8/188 , Y02E60/528 , Y02P10/234
摘要： Processes for dissolving and reducing a reducible vanadium compound disposed in, but not wholly dissolved in, an aqueous electrolyte by utilizing an electrochemical cell and/or a chemical reductant are disclosed. In one process of the invention a reducible vanadium compound is disposed in, but not wholly dissolved in, an aqueous electrolyte and a chemical reductant is added to the electrolyte to dissolve and reduce the compound in the electrolyte. In another process of the invention a reducible vanadium compound is disposed in, but not wholly dissolved in, an aqueous electrolyte by utilizing an electrochemical cell which aqueous electrolyte is in electrical contact with a positive electrode and a negative electrode and electrical energy is provided from an external circuit to the positive and negative electrodes to dissolve and reduce at least a part of the compound in the electrolyte.
摘要翻译：公开了通过利用电化学电池和/或化学还原剂溶解和还原置于水性电解质中但不完全溶解的还原性钒化合物的方法。在本发明的一个方法中，将可还原的钒化合物置于含水电解质中而不是完全溶解，并将化学还原剂加入到电解质中以溶解和还原电解质中的化合物。在本发明的另一个方法中，通过利用电解质与正极和负极电接触的电化学电池，将可还原的钒化合物设置在水性电解质中而不是完全溶解在水性电解质中，并且从外部电路与正极和负极电解以溶解并减少电解质中至少一部分化合物。

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