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1. 发明申请

WO2010084112A1 PROCESS FOR THE HYDRO-DEMETALLIZATION OF HYDROCARBON FEEDSTOCKS 审中-公开
标题翻译：烃类进料水解的方法
公开(公告)号：WO2010084112A1
公开(公告)日：2010-07-29
申请号：PCT/EP2010/050560
申请日：2010-01-19
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE DEUGD, Ronald Martijn , HERBST, Brendan Michael , HUVE, Laurent Georges , LIN, Wencai
发明人： DE DEUGD, Ronald Martijn , HERBST, Brendan Michael , HUVE, Laurent Georges , LIN, Wencai
IPC分类号： B01J35/02 , C10G45/04 , C10G45/06 , C10G45/08
CPC分类号： B01J35/026 , B01J23/28 , B01J23/85 , B01J27/19 , B01J37/28 , C10G45/04 , C10G45/06 , C10G45/08 , C10G49/002
摘要： A process for the catalytic hydro-demetallization of a hydrocarbon feedstock over a fixed bed of hydro- demetallization catalyst particles, the process comprising contacting the heavy hydrocarbon oil and hydrogen at elevated temperature and elevated pressure with the catalyst particles in the fixed bed, the catalyst particles being extruded catalyst particles of one or more catalytically active metals on a porous carrier, the extruded particles comprising three protrusions each extending from and attached to a central position, wherein the central position is aligned along the longitudinal axis of the particle, the cross-section of the particle occupying the space encompassed by the outer edges of six circles around a central circle, each of the six circles touching two neighbouring circles whilst three alternating circles are equidistant to the central circle and may be attached to the central circle, minus the space occupied by the three remaining outer circles and including the six interstitial regions.
摘要翻译：一种用于在固定床上加氢脱金属催化剂颗粒的烃原料催化加氢脱金属的方法，该方法包括使重烃和氢在高温和高压下与固定床中的催化剂颗粒接触，催化剂颗粒是多孔载体上的一种或多种催化活性金属的挤出催化剂颗粒，所述挤出颗粒包括三个突起，每个突起从中心位置延伸并连接到中心位置，其中中心位置沿着颗粒的纵向轴线排列，占据由围绕中心圆的六个圆的外边缘包围的空间的颗粒的截面，六个圆中的每一个接触两个相邻的圆，而三个交替的圆与中心圆等距，并且可以附着到中心圆，减去其余三个外围占有空间，包括六个间隙区域。

2. 发明申请

WO2005118749A1 A PROCESS FOR DESULPHURISING AND DEWAXING A HYDROCARBON FEEDSTOCK BOILING IN THE GASOIL BOILING RANGE 审中-公开
标题翻译：一种在气体沸腾范围内进行脱硫和脱蜡的方法
公开(公告)号：WO2005118749A1
公开(公告)日：2005-12-15
申请号：PCT/EP2005/052542
申请日：2005-06-02
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , HUVE, Laurent Georges
发明人： HUVE, Laurent Georges
IPC分类号： C10G45/62
CPC分类号： C10G45/62 , C10G45/68 , C10G49/002 , C10G65/043 , C10G65/08
摘要： A process for desulphurising and dewaxing a hydrocarbon feedstock boiling in the gasoil boiling range to obtain a desulphurised and dewaxed gasoil fraction for use in an ultra low sulphur diesel fuel, comprising the following steps: (a) hydrodesulphurising the hydrocarbon feedstock boiling in the gasoil boiling range by contacting the feedstock in a hydrodesulphurisation reaction zone at elevated temperature and pressure, in the presence of hydrogen, with a hydrodesulphurisation catalyst and withdrawing a liquid hydrodesulphurisation effluent from the reaction zone; (b) catalytically dewaxing the liquid hydrodesulphurisation effluent to obtain a desulphurised and dewaxed gasoil fraction by contacting the liquid hydrodesulphurisation effluent, at elevated temperature and pressure in the presence of hydrogen, with a stacked bed of catalysts having a first upstream bed of noble metal containing hydrofinishing catalyst and a second downstream bed of noble metal containing dewaxing catalyst, wherein hydrogen and the liquid effluent are countercurrently supplied to the stacked bed of catalysts.
摘要翻译：一种用于在油烟沸点范围内沸腾的烃原料脱硫和脱蜡以获得用于超低硫柴油燃料的脱硫和脱蜡汽油部分的方法，包括以下步骤：（a）将在沸石沸腾沸腾的烃原料加氢脱硫通过在加氢脱硫反应区中在升高的温度和压力下，在氢的存在下与加氢脱硫催化剂接触原料并从反应区抽出液体加氢脱硫流出物; （b）将液体加氢脱硫流出物进行催化脱蜡以获得脱硫和脱蜡的汽油部分，通过在氢存在下，在高温和高压下使液体加氢脱硫流出物与具有第一上游贵金属上游床的层叠床接触，加氢精制催化剂和含贵金属的脱蜡催化剂的第二下游床，其中氢气和液体流出物逆流供应到催化剂层叠床。

3. 发明申请

WO2006032698A1 FAUJASITE ZEOLITE, ITS PREPARATION AND USE IN HYDROCRACKING 审中-公开
标题翻译： FAUJASITE ZEOLITE，其制备和使用在水力发电
公开(公告)号：WO2006032698A1
公开(公告)日：2006-03-30
申请号：PCT/EP2005/054774
申请日：2005-09-23
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , CREYGHTON, Edward Julius , HUVE, Laurent Georges , KLAZINGA, Aan Hendrik
发明人： CREYGHTON, Edward Julius , HUVE, Laurent Georges , KLAZINGA, Aan Hendrik
IPC分类号： B01J29/08
CPC分类号： C10G47/20 , B01J29/08 , B01J29/084 , B01J29/166 , B01J35/002 , B01J35/026 , B01J35/1023 , B01J37/0009 , B01J2229/16 , B01J2229/18 , B01J2229/20 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C10G47/02 , C10G47/16
摘要： The invention provides a zeolite of the faujasite structure which has a unit cell size in the range of from 24.40 to 24.50 A; a bulk silica to alumina ratio (SAR) in th range of from 5 to 10; and an alkali metal content of less than 0.15 wt%. Such zeolites have been found to have a very useful naphtha selectivity in hydrocracking, particularly a selectivity to heavy naphtha. A preparation process for the zeolite, hydrocracking catalyst composition comprising the zeolite and its use in hydrocracking are also provided.
摘要翻译：本发明提供了八面沸石结构的沸石，其具有在24.40至24.50A范围内的晶胞尺寸; 体积二氧化硅与氧化铝的比例（SAR）在5至10的范围内; 碱金属含量小于0.15重量％。已经发现这种沸石在加氢裂化中具有非常有用的石脑油选择性，特别是重质石脑油的选择性。还提供了沸石的制备方法，包含沸石的加氢裂化催化剂组合物及其在加氢裂化中的用途。

4. 发明申请

WO2012055759A1 HYDROCARBON CONVERSION CATALYST COMPOSITION 审中-公开
标题翻译：碳氢转化催化剂组合物
公开(公告)号：WO2012055759A1
公开(公告)日：2012-05-03
申请号：PCT/EP2011/068345
申请日：2011-10-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DOMOKOS, László , HUVE, Laurent Georges , JONGKIND, Hermanus , KLAZINGA, Aan Hendrik , RIGUTTO, Marcello Stefano
发明人： DOMOKOS, László , HUVE, Laurent Georges , JONGKIND, Hermanus , KLAZINGA, Aan Hendrik , RIGUTTO, Marcello Stefano
IPC分类号： B01J29/70
CPC分类号： B01J29/7446 , B01J23/42 , B01J23/44 , B01J23/755 , B01J29/70 , B01J29/703 , B01J29/7049 , B01J29/708 , B01J29/80 , B01J37/0201 , B01J2229/16 , B01J2229/37 , B01J2229/42 , C10G35/065 , C10G45/64 , C10G49/08 , C10G50/00 , C10G65/12
摘要： A hydrocarbon conversion catalyst composition which comprises ZSM-48 and/or EU-2 zeolite particles and refractory oxide binder essentially free of alumina in which the average aluminium concentration of the ZSM-48 and/or EU-2 zeolite particles is at least 1.3 times the aluminium concentration at the surface of the particles, processes for preparing such catalyst compositions and processes for converting hydrocarbon feedstock with the help of such compositions.
摘要翻译：烃转化催化剂组合物，其包含ZSM-48和/或EU-2沸石颗粒和基本上不含氧化铝的耐火氧化物粘合剂，其中ZSM-48和/或EU-2沸石颗粒的平均铝浓度为至少1.3倍颗粒表面的铝浓度，制备这种催化剂组合物的方法和借助于这些组合物转化烃原料的方法。

5. 发明申请

WO2012055755A1 HYDROCARBON CONVERSION CATALYST COMPOSITION 审中-公开
标题翻译：碳氢转化催化剂组合物
公开(公告)号：WO2012055755A1
公开(公告)日：2012-05-03
申请号：PCT/EP2011/068329
申请日：2011-10-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DOMOKOS, László , HUVE, Laurent Georges , JONGKIND, Hermanus , KLAZINGA, Aan Hendrik , RIGUTTO, Marcello Stefano
发明人： DOMOKOS, László , HUVE, Laurent Georges , JONGKIND, Hermanus , KLAZINGA, Aan Hendrik , RIGUTTO, Marcello Stefano
IPC分类号： B01J29/70
CPC分类号： B01J29/7446 , B01J23/42 , B01J23/44 , B01J23/755 , B01J29/70 , B01J29/703 , B01J29/7049 , B01J29/708 , B01J29/80 , B01J37/0201 , B01J2229/16 , B01J2229/37 , B01J2229/42 , C10G35/065 , C10G45/64 , C10G49/08 , C10G50/00 , C10G65/12
摘要： A hydrocarbon conversion catalyst composition which comprises dealuminated ZSM-48 and/or EU-2 zeolite and a refractory oxide binder essentially free of alumina, processes for preparing such composition and processes for converting hydrocarbon feedstock with the help of such compositions.
摘要翻译：一种烃转化催化剂组合物，其包含脱铝的ZSM-48和/或EU-2沸石和基本上不含氧化铝的耐火氧化物粘合剂，用于制备此类组合物的方法和借助于这种组合物转化烃原料的方法。

6. 发明申请

WO2005085394A1 PROCESS TO CONTINUOUSLY PREPARE TWO OR MORE BASE OIL GRADES AND MIDDLE DISTILLATES 审中-公开
标题翻译：连续制备两种或多种基础油和中间馏分的方法
公开(公告)号：WO2005085394A1
公开(公告)日：2005-09-15
申请号：PCT/EP2005/050860
申请日：2005-03-01
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , ADAMS, Nicholas James , HEGGE, Harmannus Julius , HUVE, Laurent Georges , POLDER, Kevin John Anthony , STEENGE, Wiecher Derk Evert
发明人： ADAMS, Nicholas James , HEGGE, Harmannus Julius , HUVE, Laurent Georges , POLDER, Kevin John Anthony , STEENGE, Wiecher Derk Evert
IPC分类号： C10G65/12
CPC分类号： C10G65/12 , C10G45/64
摘要： Process to prepare simultaneously two or more base oil grades and middle distillates from a mineral crude derived feed, in particular a de-asphalted oil or a vacuum distillate feed or their mixtures, by performing the following steps: (a) hydrocracking the mineral crude derived feed, thereby obtaining an effluent; (b) distillation of the effluent as obtained in step (a) into one or more middle distillates and a full range residue boiling substantially above 340 ° C, (c) catalytically dewaxing the full range residue by contacting the residue with a dewaxing catalyst comprising a zeolite of the MTW type and a Group VIII metal, thereby obtaining a dewaxed oil; (d) isolating by means of distillation two or more base oil grades from the dewaxed oil obtained in step (c); and (e) isolating a dewaxed gas oil from the dewaxed-oil obtained in step (c); wherein the dewaxed oil as obtained in step (c) comprises between 10 and 40 wt% of a dewaxed heavy gas oil boiling for more than 70 wt% between 370 and 400 ° C.
摘要翻译：通过进行以下步骤同时制备来自矿物原油衍生的原料，特别是脱沥青油或真空馏分进料或其混合物的两种或更多种基础油级和中间馏分的方法：（a）加氢裂化衍生的矿物粗品进料，从而获得流出物; （b）将步骤（a）中获得的流出物蒸馏成一个或多个中间馏出物和基本上在340℃以上沸腾的全范围残余物，（c）通过使残余物与脱蜡相接触来催化脱蜡全部残余物包含MTW型沸石和VIII族金属的催化剂，从而得到脱蜡油; （d）通过蒸馏从步骤（c）中获得的脱蜡油中分离出两种或更多种基础油级; 和（e）从步骤（c）中获得的脱蜡油中分离脱蜡瓦斯油; 其中在步骤（c）中获得的脱蜡油包含10-40重量％的在370和400℃之间沸腾超过70重量％的脱蜡重质瓦斯油。

7. 发明申请

WO2005084799A1 CATALYST CARRIER AND CATALYST COMPOSITION, PROCESSES FOR THEIR PREPARATION AND THEIR USE 审中-公开
标题翻译：催化载体和催化剂组合物，其制备方法及其使用
公开(公告)号：WO2005084799A1
公开(公告)日：2005-09-15
申请号：PCT/EP2005/050866
申请日：2005-03-01
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , CREYGHTON, Edward, Julius , HUVE, Laurent, Georges , OUWEHAND, Cornelis , VAN VEEN, Johannes, Anthonius, Robert
发明人： CREYGHTON, Edward, Julius , HUVE, Laurent, Georges , OUWEHAND, Cornelis , VAN VEEN, Johannes, Anthonius, Robert
IPC分类号： B01J29/08
CPC分类号： B01J29/084 , B01J23/888 , B01J35/10 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J37/0018 , B01J37/0203 , C10G47/20
摘要： The invention provides a shaped catalyst carrier which is an inorganic refractory oxide having a monomodal mercury pore volume distribution wherein at least 50% of the total pore volume is present in pores having a pore diameter in the range of from 4 to 50 nm, a catalyst incorporating said carrier and having a high metals content. The catalyst finds use in hydrocracking refinery feedstocks.
摘要翻译：本发明提供一种成型催化剂载体，其是具有单峰汞孔体积分布的无机耐火氧化物，其中总孔体积的至少50％存在于孔径在4至50nm范围内的孔中，催化剂并入所述载体并具有高金属含量。催化剂用于加氢裂化炼油原料。

8. 发明申请

WO2004007647A1 PROCESS TO PREPARE A HEAVY AND A LIGHT LUBRICATING BASE OIL 审中-公开
标题翻译：制备重油和轻质润滑基油的方法
公开(公告)号：WO2004007647A1
公开(公告)日：2004-01-22
申请号：PCT/EP2003/006761
申请日：2003-06-25
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , ADAMS, Nicholas, James , DIERICKX, Jan, Lodewijk, Maria , GERMAINE, Gilbert, Robert, Bernard , HUVE, Laurent, Georges , WEDLOCK, David, John
发明人： ADAMS, Nicholas, James , DIERICKX, Jan, Lodewijk, Maria , GERMAINE, Gilbert, Robert, Bernard , HUVE, Laurent, Georges , WEDLOCK, David, John
IPC分类号： C10G45/64
CPC分类号： C10M111/04 , C10G45/64 , C10G65/16 , C10G2300/1022 , C10G2300/301 , C10G2300/302 , C10G2300/304 , C10G2400/10 , C10M101/02 , C10M107/02 , C10M2203/0206 , C10M2203/065 , C10M2203/1006 , C10M2205/0206 , C10M2205/173 , C10M2207/2805 , C10N2220/02 , C10N2220/022 , C10N2230/02 , C10N2230/04 , C10N2230/40 , C10N2240/10
摘要： Process to prepare a heavy and a light lubricating base oil from a partly isomerised Fischer-Tropsch derived feedstock (1), said feedstock having an initial boiling point of below 400 °C and a final boiling point of above 600 °C by (a) separating, by means of distillation, said fraction into a light base oil precursor fraction and a heavy base oil precursor fraction, (b) reducing the pour point of each separate base oil precursor fraction by means of dewaxing, (c) and isolating the desired base oil products from said dewaxed oil fractions as obtained in step (b).
摘要翻译：从部分异构化的费 - 托衍生的原料（1）制备重和轻的润滑基础油的方法，所述原料的初始沸点低于400℃，最终沸点高于600℃，（a）通过蒸馏将所述馏分分离成轻质基础油前体馏分和重质基础油前体馏分，（b）通过脱蜡来降低每种分离的基础油前体馏分的倾点，（c）和分离所需的从步骤（b）中得到的脱蜡油馏分得到的基础油产物。

9. 发明申请

WO2003033630A1 UPGRADING OF PRE-PROCESSED USED OILS 审中-公开
标题翻译：预处理使用的油的升级
公开(公告)号：WO2003033630A1
公开(公告)日：2003-04-24
申请号：PCT/EP2002/011609
申请日：2002-10-16
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , GRANDVALLET, Pierre , HAGAN, Anthony, Patrick , HUVE, Laurent, Georges
发明人： GRANDVALLET, Pierre , HAGAN, Anthony, Patrick , HUVE, Laurent, Georges
IPC分类号： C10M175/00
CPC分类号： C10M175/0041
摘要： Process to further upgrade a pre-processed used lubricating oil by: (a) contacting the partially upgraded used oil in the presence of hydrogen with a hydrodemetallization catalyst, (b) contacting the effluent of step (a) in the presence of hydrogen with a hydrotreating catalyst, (c) contacting the effluent of step (b) in the presence of hydrogen with a dewaxing (d) contacting the effluent of step (c) in the presence of hydrogen with a hydrotreating catalyst.
摘要翻译：通过以下步骤进一步升级预处理用过的润滑油的方法：（a）在氢气存在下将部分升级的二手油与加氢脱金属催化剂接触，（b）在氢存在下将步骤（a）的流出物与加氢处理催化剂，（c）在氢气存在下使步骤（b）的流出物与在步骤（c）的流出物在氢气存在下与加氢处理催化剂接触的脱蜡（d）接触。

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