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    • 4. 发明申请
    • CATALYTIC DEWAXING PROCESS AND CATALYST COMPOSITION
    • 催化脱蜡工艺和催化剂组合物
    • WO1996041849A1
    • 1996-12-27
    • PCT/EP1996002578
    • 1996-06-12
    • SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.SHELL CANADA LIMITED
    • SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.SHELL CANADA LIMITEDGRANDVALLET, PierreHUVE, Laurent, GeorgesMAESEN, Theodorus, Ludovicus, Michael
    • C10G45/64
    • C10G45/64B01J29/40B01J29/65B01J2229/16B01J2229/32
    • Process for the catalytic dewaxing of hydrocarbon oil feed comprising waxy molecules, which process comprises the steps of: (a) contacting the feed under catalytic dewaxing conditions with a catalyst composition comprising a molecular sieve containing covalently bound alumina moieties in its framework and having pores with a diameter in the range of from 0.35 to 0.80 nm, and (b) recovering a product having a reduced pour point, wherein the molecular sieve has been modified to reduce the mole percentage of alumina. Step (a) can be divided into two steps: a first shape selective isomerisation step (a1) and a second selective cracking step (a2). At least in step (a2) a catalyst comprising a modified molecular sieve as described above is used. Catalyst composition comprising a hydrogenation component supported on a carrier comprising a molecular sieve having pores with a diameter in the range of from 0.35 to 0.80 nm and containing covalently bound alumina moieties in its framework, which molecular sieve has been modified to reduce the mole percentage of alumina. Catalyst composition comprising dealuminated ferrierite crystallites, which composition is free of any hydrogenation component.
    • 包含蜡质分子的烃油进料的催化脱蜡方法,该方法包括以下步骤:(a)在催化脱蜡条件下使进料与催化剂组合物接触,所述催化剂组合物包含在其骨架中含有共价结合的氧化铝部分的分子筛, 直径在0.35至0.80nm的范围内,和(b)回收具有降低的倾点的产物,其中分子筛已被改性以降低氧化铝的摩尔百分比。 步骤(a)可以分为两个步骤:第一形状选择异构化步骤(a1)和第二选择性裂解步骤(a2)。 至少在步骤(a2)中,使用包含如上所述的改性分子筛的催化剂。 催化剂组合物,其包含负载在载体上的氢化组分,所述载体包含直径在0.35至0.80nm范围内的孔的分子筛,并且在其骨架中含有共价结合的氧化铝部分,该分子筛已被修饰以降低其摩尔百分数 氧化铝。 包含脱铝镁碱沸石微晶的催化剂组合物,该组合物不含任何氢化组分。