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1. 发明申请

WO2012083107A2 FLUORINE-CONTAINING POLYMER COMPRISING A SULFINATE-CONTAINING MOLECULE 审中-公开
标题翻译：包含含硫分子的含氟聚合物
公开(公告)号：WO2012083107A2
公开(公告)日：2012-06-21
申请号：PCT/US2011/065339
申请日：2011-12-16
申请人： 3M INNOVATIVE PROPERTIES COMPANY , DAHLKE, Gregg D. , DUCHESNE, Denis , FUKUSHI, Tatsuo , GROOTAERT, Werner M.A. , GUERRA, Miguel A. , KASPAR, Harald, , LAST, Larry A. , SCOTT, Peter J. , QIU, Zai-Ming
发明人： DAHLKE, Gregg D. , DUCHESNE, Denis , FUKUSHI, Tatsuo , GROOTAERT, Werner M.A. , GUERRA, Miguel A. , KASPAR, Harald, , LAST, Larry A. , SCOTT, Peter J. , QIU, Zai-Ming
IPC分类号： C08F14/18 , C08F28/00 , C08L27/12 , C08L41/00 , C08J5/00
CPC分类号： C08F228/02 , C07C17/275 , C07C303/22 , C07C313/04 , C08F214/18 , C08F214/182 , Y10T428/139 , C07C19/07 , C07C19/075 , C07C309/82 , C07C309/80 , C07C309/81
摘要： Described herein is a composition having a fluoropolymer derived from the polymerization of a monomer and a sulfinate-containing molecule, wherein the sulfinate-containing molecule is selected from the group consisting of Formula (I), Formula (II); and combinations thereof, wherein X 1 , X 2 , and X 3 are each independently selected from H, F, C1, a C 1 to C 4 alkyl group, and a C 1 to C 4 fluorinated alkyl group; R is a linking group; Z 1 and Z 2 are independently selected from F, CF 3 , and a perfluoroalkyl group; R 1 and R 2 are end-groups; p is 0 or 1; m is at least 1; and M is a cation. Also disclosed are methods of making and articles thereof.
摘要翻译：本文描述了具有衍生自单体和含亚磺酸酯的分子的聚合的含氟聚合物的组合物，其中所述含亚磺酸酯的分子选自式（I），式（II）; 和其组合，其中X1，X2和X3各自独立地选自H，F，C1，C1-C4烷基和C1至C4氟化烷基; R是连接基团; Z 1和Z 2独立地选自F，CF 3和全氟烷基; R1和R2是端基; p为0或1; m至少为1; 而M是阳离子。还公开了制造方法及其制品。

2. 发明申请

WO2012082551A2 PARTIALLY FLUORINATED SULFINIC ACID MONOMERS AND THEIR SALTS 审中-公开
标题翻译：部分氟化硫酸单体及其盐类
公开(公告)号：WO2012082551A2
公开(公告)日：2012-06-21
申请号：PCT/US2011/064154
申请日：2011-12-09
申请人： 3M INNOVATIVE PROPERTIES COMPANY , QIU, Zai-Ming, , DAHLKE, Gregg D., , FUKUSHI, Tatsuo, , GROOTAERT, Werner M.A., , GUERRA, Miguel A.,
发明人： QIU, Zai-Ming, , DAHLKE, Gregg D., , FUKUSHI, Tatsuo, , GROOTAERT, Werner M.A., , GUERRA, Miguel A.,
IPC分类号： C07C17/25 , C07C317/08
CPC分类号： C07C313/04 , C07C17/275 , C07C303/22 , C08F214/186 , C07C19/07 , C07C19/075 , C07C309/82 , C07C309/80 , C07C309/81
摘要： Described herein is a composition according to formula I or its precursor, formula II: CX 1 X 3 =CX 2 -(R 1 ) p -CZ1 Z2-SO 2 M (I) wherein X 1 , X 2 , and X 3 are independently selected from H, F, Cl, Br, I, CF 3 and CH 3 , and wherein at least one of X 1 , X 2 , or X 3 is a H; R 1 is a linking group; Z1 and Z2 are independently selected from F, Cl, Br, I, CF 3 , and a perfluoroalkyl group; p is 0 or 1; and M is a cation; and CX 4 X 1 X 3 -CX 5 X 2 -(R 1 ) p -CZ1Z2-SO 2 M (II) wherein X 1 , X 2 , and X 3 are independently selected from H, F, Cl, Br, I, CF 3 and CH 3 , wherein at least one of X 1 , X 2 , or X 3 is a H, and X 4 and X 5 are independently selected from H, F, Cl, Br and I; R 1 is a linking group; Z1 and Z2 are independently selected from F, Cl, Br, I, CF 3 , and a perfluoroalkyl group, p is 0 or 1; and M is selected from F, and a cation.
摘要翻译：在此描述的是根据式I或其前体，式II的组合物：CX 1 -X 3 = CX 2 - - （R 1）q -Z 1 Z 2 -SO 2 M（I）其中X 1， X 2和X 3独立地选自H，F，Cl，Br，I，CF 3和CH 3。其中X 1，X 2或X 3中的至少一个是H;并且其中X 1，X 2或X 3中的至少一个是H; R 1是连接基团; Z 1和Z 2独立地选自F，Cl，Br，I，CF 3和全氟烷基; p是0或1; M是阳离子; 和CX 4 -X 1 -X 3 -X -X 5 -X 2 - （R （II）其中X 1，X 2，X 1，X 2，X 1，X 2，其中X 1和X 3独立地选自H，F，Cl，Br，I，CF 3和CH 3 3，其中在 X 1，X 2，或X 3中的至少一个是H，并且X 4和X 4都是H，其中5α独立地选自H，F，Cl，Br和I; R 1是连接基团; Z 1和Z 2独立地选自F，Cl，Br，I，CF 3和全氟烷基，p为0或1; M选自F和阳离子。

3. 发明申请

WO2014055406A2 FLUOROPOLYETHER-BASED ELASTOMERS HAVING LOW GLASS TRANSITION TEMPERATURE 审中-公开
标题翻译：具有低玻璃化转变温度的基于荧光玻璃的弹性体
公开(公告)号：WO2014055406A2
公开(公告)日：2014-04-10
申请号：PCT/US2013/062605
申请日：2013-09-30
申请人： 3M INNOVATIVE PROPERTIES COMPANY , CORVELEYN, Steven G. , DAHLKE, Gregg D. , DAMS, Rudolf J. , GROOTAERT, Werner M.A. , GUERRA, Miguel A. , MANZARA, Anthony P. , OPSTAL, Tom
发明人： CORVELEYN, Steven G. , DAHLKE, Gregg D. , DAMS, Rudolf J. , GROOTAERT, Werner M.A. , GUERRA, Miguel A. , MANZARA, Anthony P. , OPSTAL, Tom
IPC分类号： C08L63/04
CPC分类号： C08F122/38 , C08G18/5015 , C08G18/807 , C08G65/00 , C08G65/007 , C08G65/325 , C08G65/332 , C08G65/333 , C08G65/33365 , C08K3/16 , C08K3/36 , C08K5/0025 , C08K5/28 , C09K3/1009 , C09K2003/1053
摘要： A curable precursor composition for a fluoroelastomers, methods of making fluoroelastomers, shaped articles and methods of making shaped articles.
摘要翻译：用于含氟弹性体的可固化前体组合物，制备含氟弹性体的方法，成形制品以及制造成型制品的方法。

4. 发明申请

WO2010151610A3 CURING COMPOSITIONS FOR FLUOROPOLYMERS 审中-公开
公开(公告)号：WO2010151610A3
公开(公告)日：2010-12-29
申请号：PCT/US2010/039730
申请日：2010-06-24
申请人： 3M INNOVATIVE PROPERTIES COMPANY , GROOTAERT, Werner M.A., , VOGEL, Kim M., , VOGEL, Dennis E.,
发明人： GROOTAERT, Werner M.A., , VOGEL, Kim M., , VOGEL, Dennis E.,
IPC分类号： C08F4/32 , C08F214/18 , C08L27/12 , C08K3/04 , C08K3/36 , B01J31/02
摘要： A catalyst composition comprising a cation and an anion of the formula A n q- Q p m+ , wherein m, n, p, and q are positive integers, wherein m * p = n * q, wherein Q m+ is an organo onium, and A q- is an anion, provided that at least one A q- is selected from the formula (I) wherein each R independently is H, halo, alkyl, aryl, aralkyl, or cycloalkyl, and which also may be halogenated, fluorinated, or perfluorinated, wherein two or more of R and R' groups may together form a ring, wherein each R group independently may contain one or more heteroatom(s), wherein R' can be the same as R, with the proviso that R' cannot be halo, and wherein the catalyst composition is essentially free of hydrocarbon containing alcohol. Also provided are a fluoropolymer composition including this curative, a method of making a fluoropolymer, and fluoropolymer articles containing curable or cured fluoropolymer compositions

5. 发明申请

WO2012067937A2 METHOD OF COAGULATING AN AMORPHOUS FLUOROPOLYMER USING MODIFIED INORGANIC NANOPARTICLES 审中-公开
标题翻译：使用改性无机纳米粒子凝聚非晶态含氟聚合物的方法
公开(公告)号：WO2012067937A2
公开(公告)日：2012-05-24
申请号：PCT/US2011/060178
申请日：2011-11-10
申请人： 3M INNOVATIVE PROPERTIES COMPANY , SHEFELBINE, Terri A. , ADAIR, Eric W. , GROOTAERT, Werner M.A. , JING, Naiyong
发明人： SHEFELBINE, Terri A. , ADAIR, Eric W. , GROOTAERT, Werner M.A. , JING, Naiyong
IPC分类号： C08L27/12 , C08K3/00 , C08K9/00 , C08J5/00 , C08F14/18
CPC分类号： C08L27/18 , B82Y30/00 , C08J3/16 , C08J5/005 , C08J2327/18 , C08K3/36 , C08K9/04 , C08L71/02
摘要： Described herein is a method of coagulating a fluoropolymer latex comprising: providing an amorphous fluoropolymer latex; providing modified inorganic nanoparticles; and contacting the amorphous fluoropolymer latex with a sufficient amount of modified inorganic nanoparticles to coagulate the amorphous fluoropolymer latex.
摘要翻译：本文描述了一种凝结含氟聚合物胶乳的方法，其包括：提供无定形含氟聚合物胶乳; 提供改性无机纳米粒子并使无定形含氟聚合物胶乳与足够量的改性无机纳米粒子接触以凝结无定形含氟聚合物胶乳。

6. 发明申请

WO2010080309A2 CURE SYSTEM FOR FLUOROELASTOMER GUM 审中-公开
标题翻译：氟橡胶凝胶固化体系
公开(公告)号：WO2010080309A2
公开(公告)日：2010-07-15
申请号：PCT/US2009/067255
申请日：2009-12-09
申请人： 3M INNOVATIVE PROPERTIES COMPANY , GROOTAERT, Werner M.A.,
发明人： GROOTAERT, Werner M.A.,
IPC分类号： C08L27/12 , C08K5/04 , C08L71/00
CPC分类号： C08G65/007 , C08G2650/48 , C08K5/04 , C08K5/138 , C08K5/37 , C08L27/12 , C08L71/02 , C08L2205/05 , C08L2666/04
摘要： There is provided a curable fluoropolymer composition comprising an amorphous perfluoropolymer, a nucleophile selected from alkoxides, thiolates, and combinations thereof, and an adjuvant selected from dipolar aprotic solvents, or crown ethers, and combinations thereof, where the amorphous perfluoropolymer comprises at least one cure site selected from a CF 2 I cure site, a CF 2 Br cure site, a CF 2 Cl cure site, and combinations thereof. There is also provided a cured fluoroelastomer comprising crosslink units represented by the formula E-CF 2 -A-Q-(A-CF 2 E) n , where E is a fluoroelastomer backbone, A is selected from O or S, Q is a multivalent organic linking group, and n is an integer of at least one, or the formula E-Q-CF 2 -CF 2 -Q-E, where E is a fluoroelastomer backbone, Q is a divalent organic linking group, and n is an integer. Articles derived from the cured fluoroelastomer and processes for making the composition and the cured fluoroelastomer are also provided.
摘要翻译：提供了一种可固化含氟聚合物组合物，其包含无定形全氟聚合物，选自醇盐，硫醇盐及其组合的亲核试剂，以及选自偶极非质子溶剂或冠醚的佐剂及其组合，其中无定形全氟聚合物包含至少一种固化选自CF2I固化位点，CF2Br固化位点，CF2Cl固化位点及其组合。还提供了含有由式E-CF2-AQ-（A-CF2E）n表示的交联单元的固化的含氟弹性体，其中E是含氟弹性体骨架，A选自O或S，Q是多价有机连接基团，且n为至少一个的整数，或式EQ-CF2-CF2-QE，其中E为含氟弹性体主链，Q为二价有机连接基团，n为整数。还提供了衍生自固化的含氟弹性体的制品和用于制备组合物和固化的含氟弹性体的方法。

7. 发明申请

WO2010014274A1 FLUOROPOLYMER COMPOSITIONS AND METHOD OF MAKING AND USING THEREOF 审中-公开
标题翻译：氟聚合物组合物及其制备和使用方法
公开(公告)号：WO2010014274A1
公开(公告)日：2010-02-04
申请号：PCT/US2009/040756
申请日：2009-04-16
申请人： 3M INNOVATIVE PROPERTIES COMPANY , MANZARA, Anthony, P. , BOGAERT, Yvan, A. , CRANDALL, Michael, D. , EGGERS, Robert, E. , GOODNER, Aron, Y. , GROOTAERT, Werner, M.A.
发明人： MANZARA, Anthony, P. , BOGAERT, Yvan, A. , CRANDALL, Michael, D. , EGGERS, Robert, E. , GOODNER, Aron, Y. , GROOTAERT, Werner, M.A.
IPC分类号： C08L27/22 , C08L27/12 , C08K5/28 , C08L27/18 , C08J5/00
CPC分类号： C08K5/28 , Y10T428/139 , Y10T428/1397 , Y10T428/3154 , Y10T428/31544 , C08L27/12
摘要： Compositions having a fluoropolymer with a nitrile-containing cure site and at least a) a mono azide with at least one functional group in the beta position, or b) a polyazide, as a curing agent as well as methods and articles thereof are described. Articles of this disclosure are found to exhibit excellent chemical resistance and thermal stability.
摘要翻译：具有具有含腈固化部位的含氟聚合物和至少a）在β位具有至少一个官能团的单叠氮化物的组合物，或b）作为固化剂的聚叠氮化合物及其制备方法。发现本公开的制品表现出优异的耐化学性和热稳定性。

8. 发明申请

WO2013070723A1 CURING COMPOSITIONS FOR FLUOROPOLYMERS 审中-公开
标题翻译：氟聚合物固化组合物
公开(公告)号：WO2013070723A1
公开(公告)日：2013-05-16
申请号：PCT/US2012/063896
申请日：2012-11-07
申请人： 3M INNOVATIVE PROPERTIES COMPANY , GROOTAERT, Werner, M.A. , WENDLAND, Michael, S. , GRIESGRABER, George, W.
发明人： GROOTAERT, Werner, M.A. , WENDLAND, Michael, S. , GRIESGRABER, George, W.
IPC分类号： C08K5/18 , C07C215/88
CPC分类号： C08F14/26 , C07C215/88 , C07C2603/94 , C08K3/04 , C08K5/18 , C08L27/00 , C08L27/18 , C08L27/12
摘要： Diaminospirobisindane diols, curable compositions, curative compositions, cured articles, and methods of curing are described.
摘要翻译：描述了二氨基螺双双茚二醇，可固化组合物，固化剂，固化制品和固化方法。

9. 发明申请

WO2012082707A1 MICROEMULSIONS AND FLUOROPOLYMERS MADE USING MICROEMULSIONS 审中-公开
标题翻译：使用微乳液制备微乳液和荧光素
公开(公告)号：WO2012082707A1
公开(公告)日：2012-06-21
申请号：PCT/US2011/064571
申请日：2011-12-13
申请人： 3M INNOVATIVE PROPERTIES COMPANY , FUKUSHI, Tatsuo , DAHLKE, Gregg D. , DUCHESNE, Denis , GROOTAERT, Werner M.A. , GUERRA, Miguel A. , LAST, Larry A. , SCOTT, Peter J. , QIU, Zai-Ming
发明人： FUKUSHI, Tatsuo , DAHLKE, Gregg D. , DUCHESNE, Denis , GROOTAERT, Werner M.A. , GUERRA, Miguel A. , LAST, Larry A. , SCOTT, Peter J. , QIU, Zai-Ming
IPC分类号： C08F14/18
CPC分类号： C08L27/20 , C08F14/18 , C08F214/18 , C08F2/24 , C08F2/22
摘要： There are provided microemulsions derived from compositions containing oligomeric fluorosulfinic compounds and/or ethylenically unsaturated, polymerizable monomeric fluorosulfinic compounds and to their uses in (co)polymerization processes in aqueous emulsion of fluorinated monomers.
摘要翻译：提供的衍生自含有低聚氟代亚砜化合物和/或烯属不饱和的可聚合单体氟亚砜化合物的组合物的微乳液及其在氟化单体的水性乳液中的（共）聚合方法中的用途。

10. 发明申请

WO2012082703A2 PREPARATION OF OLIGOMERS AND CO-OLIGOMERS OF HIGHLY FLUORINATED SULFINIC ACIDS AND SALTS THEREOF 审中-公开
标题翻译：高度氟化的硫酸的低聚物和共聚物的制备及其制备
公开(公告)号：WO2012082703A2
公开(公告)日：2012-06-21
申请号：PCT/US2011/064566
申请日：2011-12-13
申请人： 3M INNOVATIVE PROPERTIES COMPANY , GUERRA, Miguel A. , DAHLKE, Gregg D. , DUCHESNE, Denis , FUKUSHI, Tatsuo , GROOTAERT, Werner M.A. , QIU, Zai-Ming
发明人： GUERRA, Miguel A. , DAHLKE, Gregg D. , DUCHESNE, Denis , FUKUSHI, Tatsuo , GROOTAERT, Werner M.A. , QIU, Zai-Ming
IPC分类号： C07C313/12
CPC分类号： C08G75/00 , C07C303/22 , C07C313/04 , C08F214/18 , C07C309/82
摘要： There is provided a method for preparing oligomers and co-oligomers of highly fluorinated sulfinic acids and salts thereof.
摘要翻译：提供了制备高度氟化亚磺酸及其盐的低聚物和共低聚物的方法。

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