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    • 2. 发明申请
    • AZIDE COMPOSITIONS AND METHODS OF MAKING AND USING THEREOF
    • AZIDE组合物及其制备和使用方法
    • WO2010014276A8
    • 2011-09-22
    • PCT/US2009041105
    • 2009-04-20
    • 3M INNOVATIVE PROPERTIES COMANZARA ANTHONY PGOODNER ARON YJOHANNESSEN JUDITH A
    • MANZARA ANTHONY PGOODNER ARON YJOHANNESSEN BIRGER
    • C08K5/28C07C247/04C07C247/12
    • C07C247/04C07C271/12C08K5/28C08K2201/014
    • Azide compositions selected from i) UOCR2CR2N3 wherein U is D, or a urethane (-CO-NR2) and R is independently H, D, or an organic group; ii) R'2NCR2CR2N3 or A-R'3N CR2CR2N3 wherein R' is an organic group and A is an anion; or iii) G(N3)m wherein m is an integer from 2 to about 10 and G is a m-valent organic group wherein at least two of the azido groups are connected via aliphatic carbon atoms wherein G may contain organic groups, and uses thereof are described. Specifically, the azide compositions selected from the group consisting of: N3CH2CH2OCH2CHOHCH2N3, CH3OCH2CHOHCH2N3, CH3OCH2CH(OCONHC4H9)CH2N3, N3CH2CH2O[CH2CH(CH2N3)O]6H, CH3CH2C[CH2(OCH2CH(CH2N3))2OCOCH3 ]3 N3CH2CH2OCONH(CH2)6NHCOOCH2CH2N3, (CH3)3CNHCOOCH2CH2N3, n-C4H9NDCOOCH2CH2N3, C6H5NHCOOCH2CH2N3, C4F9OCFCF3NDCOOCH2CH2N3, DOCH2CH2N3, and [(CH3)3NCH2CH2N3]+ I are described.
    • 选自i)UOCR2CR2N3,其中U是D的叠氮化物组合物或氨基甲酸酯(-CO-NR 2),R独立地是H,D或有机基团; ii)R'2NCR2CR2N3或A-R'3N CR2CR2N3,其中R'是有机基团,A是阴离子; 或iii)G(N 3)m,其中m为2至约10的整数,G为m价有机基团,其中至少两个叠氮基通过脂族碳原子连接,其中G可以含有有机基团,并且使用 描述。 具体地,选自N 3 CH 2 CH 2 OCH 2 CHOHCH 2 N 3,CH 3 OCH 2 CHOHCH 2 N 3,CH 3 OCH 2 CH(OCONHC 4 H 9)CH 2 N 3,N 3 CH 2 CH 2 O [CH 2 CH(CH 2 N 3)O] 6H,CH 3 CH 2 C [CH 2(OCH 2 CH(CH 2 N 3))2 COOCH 3] 3 N 3 CH 2 CH 2 OCONH(CH 2)6 NHCOOCH 2 CH 2 N 3, (CH3)3CNHCOOCH2CH2N3,n-C4H9NDCOOCH2CH2N3,C6H5NHCOOCH2CH2N3,C4F9OCFCF3NDCOOCH2CH2N3,DOCH2CH2N3和[(CH3)3NCH2CH2N3] + I。
    • 3. 发明申请
    • AZIDE COMPOSITIONS AND METHODS OF MAKING AND USING THEREOF
    • AZIDE组合物及其制备和使用方法
    • WO2010014276A1
    • 2010-02-04
    • PCT/US2009/041105
    • 2009-04-20
    • 3M INNOVATIVE PROPERTIES COMPANYMANZARA, Anthony, P.GOODNER, Aron, Y.JOHANNESSEN, Judith, A.
    • MANZARA, Anthony, P.GOODNER, Aron, Y.JOHANNESSEN, Judith, A.
    • C08K5/28C07C247/12C07C247/04
    • C07C247/04C07C271/12C08K5/28C08K2201/014
    • Azide compositions selected from i) UOCR 2 CR 2 N 3 wherein U is D, or a urethane (-CO-NR 2 ) and R is independently H, D, or an organic group; ii) R' 2 NCR 2 CR 2 N3 or A-R' 3 N CR 2 CR 2 N 3 wherein R' is an organic group and A is an anion; or iii) G(N 3) m wherein m is an integer from 2 to about 10 and G is a m-valent organic group wherein at least two of the azido groups are connected via aliphatic carbon atoms wherein G may contain organic groups, and uses thereof are described. Specifically, the azide compositions selected from the group consisting of: N 3 CH 2 CH 2 OCH 2 CHOHCH 2 N 3 , CH 3 OCH 2 CHOHCH 2 N 3 , CH 3 OCH 2 CH(OCONHC 4 H 9 )CH 2 N 3 , N 3 CH 2 CH 2 O[CH 2 CH(CH 2 N 3 )O] 6 H, CH 3 CH 2 C[CH 2 (OCH 2 CH(CH 2 N 3 )) 2 OCOCH 3 ]3 N 3 CH 2 CH 2 OCONH(CH 2 ) 6 NHCOOCH 2 CH 2 N 3 , (CH 3 ) 3 CNHCOOCH 2 CH 2 N 3 , n-C 4 H 9 NDCOOCH 2 CH 2 N 3 , C 6 H 5 NHCOOCH 2 CH 2 N 3 , C 4 F 9 OCFCF 3 NDCOOCH 2 CH 2 N 3 , DOCH 2 CH 2 N 3 , and [(CH 3 ) 3 NCH 2 CH 2 N 3 ] + I are described.
    • 选自i)UOCR2CR2N3,其中U是D的叠氮化物组合物或氨基甲酸酯(-CO-NR 2),R独立地是H,D或有机基团; ii)R'2NCR2CR2N3或A-R'3N CR2CR2N3,其中R'是有机基团,A是阴离子; 或iii)G(N 3)m,其中m为2至约10的整数,G为m价有机基团,其中至少两个叠氮基通过脂族碳原子连接,其中G可以含有有机基团,并且使用 描述。 具体地,选自N 3 CH 2 CH 2 OCH 2 CHOHCH 2 N 3,CH 3 OCH 2 CHOHCH 2 N 3,CH 3 OCH 2 CH(OCONHC 4 H 9)CH 2 N 3,N 3 CH 2 CH 2 O [CH 2 CH(CH 2 N 3)O] 6H,CH 3 CH 2 C [CH 2(OCH 2 CH(CH 2 N 3))2 COOCH 3] 3 N 3 CH 2 CH 2 OCONH(CH 2)6 NHCOOCH 2 CH 2 N 3, (CH3)3CNHCOOCH2CH2N3,n-C4H9NDCOOCH2CH2N3,C6H5NHCOOCH2CH2N3,C4F9OCFCF3NDCOOCH2CH2N3,DOCH2CH2N3和[(CH3)3NCH2CH2N3] + I。