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    • 2. 发明申请
    • A METHOD OF ETCHING COPPER ON CARDS
    • 一种在卡片上蚀刻铜的方法
    • WO2003024172A2
    • 2003-03-20
    • PCT/SE2002/001602
    • 2002-09-09
    • OBDUCAT AKTIEBOLAGFRENNESSON, GöranBIERINGS, GustBJARNASON, BjarniSJÖBERG, Jenny
    • FRENNESSON, GöranBIERINGS, GustBJARNASON, BjarniSJÖBERG, Jenny
    • H05K3/07
    • H05K3/07C25F3/02C25F7/00
    • Etching of copper on a card is achieved by applying an electrical voltage between a cathode (102) and the card (42), the card (42) thereby forming an anode. The cathode (102) and the card (42) are immersed in an electrolyte comprising a first component, which may be reduced from a first state in the form of an ion having a metal atom with a first positive oxidation number to a second state in the form of an ion having said metal atom with a second positive oxidation number, which is less than said first positive oxidation number. A first redox potential in the electrolyte for reduction from the first to the second state is larger than a second redox potential in the electrolyte for reduction of divalent copper ions to metallic copper. During the etching metallic copper on the card is oxidised and transferred into positively charged copper ions while the first component is reduced from its first state to its second state. The quality of the etched structures on the card is improved since no metallic copper is precipitated on the cathode.
    • 通过在阴极(102)和卡(42),卡(42)之间施加电压从而形成阳极来实现在卡上蚀刻铜。 将阴极(102)和卡(42)浸入包含第一组分的电解质中,该第一组分可以从具有第一正氧化数的金属原子的离子形式的第一状态降低到 具有所述金属原子的具有小于所述第一正氧化数的第二正氧化数的离子形式。 用于从第一状态降低到第二状态的电解质中的第一氧化还原电位大于电解液中用于将二价铜离子还原成金属铜的第二氧化还原电位。 在蚀刻期间,卡上的金属铜被氧化并转移成带正电荷的铜离子,而第一组分从第一状态减少到第二状态。 由于没有金属铜沉积在阴极上,卡上蚀刻结构的质量得到了改善。