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    • 2. 发明申请
    • SELF-DISINFECTING SURFACES
    • 自消光表面
    • WO2014118350A1
    • 2014-08-07
    • PCT/EP2014/051970
    • 2014-01-31
    • CRODA INTERNATIONAL PLC
    • HOSSEIN, Mahmoud
    • A01N33/12A01N25/10A01P1/00C07C217/50C08K5/00C08K5/19C09D5/02
    • C09D5/14A01N25/10A01N33/12A01N37/06C07C217/50C07C271/22C08K5/0058C08K5/19C09D5/02C09D175/04Y10T428/31551
    • The invention relates to an aqueous coating composition comprising a compound having reactive groups A, and a quaternary ammonium compound according to Formula (I), (II) or (III), wherein R 1 is an alkyl, alkenyl, alkylaryl or arylalkyl group having from 5 to 50 carbon atoms; R 2 is a C 1 -C 100 hydrocarbyl group, optionally containing heteroatoms; R 3 and R 4 are alkylene groups having from 1 to 4 carbon atoms; R 5 and R 6 are H or C 1 -C 100 hydrocarbyl group, optionally containing heteroatoms; R 7 is a C 1 -C 100 hydrocarbyl group, optionally containing heteroatoms; R 8 is a C 1 -C 100 hydrocarbyl group, optionally containing heteroatoms; R 9 is H or a methyl group; Z is a substituent containing at least one reactive group B which is capable of reacting with the reactive group A; X - is an anion; y is 0 or 1; a is 0 or 1; and the sum of y and a is 1 or 2 and m is an integer from 1 to 30, preferably between 1 and 10, or between 2 and 6, n is an integer from 0-30, preferably between 1 and 10, or 2 and 6, T is a monomer unit; U is a monomer unit; V is a C 1 -C 100 hydrocarbyl group, optionally containing hetero atoms; d is an integer between 1 and 5, preferably 1; e is an integer between 1 and 1000, preferably between 5 and 100; g is an integer between 1 and 100, preferably between 2 and 10; h is an integer between 1 and 5, preferably 2 or 3.
    • 本发明涉及包含具有反应性基团A的化合物和根据式(I),(II)或(III)的季铵化合物的水性涂料组合物,其中R 1是具有烷基,烯基,烷基芳基或芳基烷基, 5至50个碳原子; R2是任选地含有杂原子的C1-C100烃基; R3和R4是具有1至4个碳原子的亚烷基; R5和R6是H或C1-C100烃基,任选含有杂原子; R7是任选含有杂原子的C1-C100烃基; R8是任选含有杂原子的C1-C100烃基; R9为H或甲基; Z是含有能够与反应性基团A反应的至少一个反应性基团B的取代基; X-是阴离子; y为0或1; a是0或1; y和a的和为1或2,m为1〜30的整数,优选为1〜10,或2〜6的整数,n为0〜30的整数,优选为1〜10,或2 和6,T是单体单元; U是单体单元; V是任选含有杂原子的C1-C100烃基; d是1和5之间的整数,优选1; e为1〜1000,优选为5〜100的整数。 g为1〜100,优选为2〜10的整数。 h为1〜5,优选为2或3的整数。
    • 4. 发明申请
    • LAUNDRY DETERGENT COMPOSITIONS COMPRISING HYDROPHOBICALLY MODIFIED POLYAMINES
    • 洗涤剂洗涤剂组合物包含疏水改性聚氨酯
    • WO0134739A3
    • 2002-01-31
    • PCT/US0030644
    • 2000-11-07
    • PROCTER & GAMBLEDUPONT JEFFREY SCOTTGOSSELINK EUGENE PAULPRICE KENNETH NATHANROHRBAUGH ROBERT HENRY
    • DUPONT JEFFREY SCOTTGOSSELINK EUGENE PAULPRICE KENNETH NATHANROHRBAUGH ROBERT HENRY
    • C11D3/30C07C217/50C08G65/26C11D1/14C11D1/22C11D1/29C11D1/62C11D3/37C11D3/39
    • C07C217/50C08G65/2621C11D1/62C11D3/3723
    • The present invention relates to hydrophobically modified polyamines and laundry detergent compositions which comprise said polyamines, said compositions comprising: A) from about 0.01 %, preferably from about 0.1 %, more preferably from about 1 %, most preferably from about 3 % to about 50 %, preferably to about 20 %, more preferably to about 10 %, most preferably to about 7 % by weight, of a hydrophobically modified polyamine having formula (I) wherein R is C6-C20 linear or branched alkylene, and mixtures thereof; R is an alkyleneoxy unit having the formula: -(R O)x-R wherein R is C2-C4 linear or branched alkylene, and mixtures thereof; R is hydrogen, C1-C22 alkyl, C7-C22 alkylenearyl, and mixtures thereof; x is from about 15 to about 30; Q is a hydrophobic quaternizing unit selected from the group consisting of C8-C30 linear or branched alkyl, C6-C30 cycloalkyl, C7-C30 substituted or unsubstituted alkylenearyl, and mixtures thereof; X is an anion present in sufficient amount to provide electronic neutrality; n is from 0 to 3; B) from about 0.01 % by weight, of a surfactant system comprising one or more surfactants selected from: i) from 0 % to 100 % by weight, of one or more anionic surfactants; ii) from 0 % to 100 % by weight, of one or more nonionic surfactants; iii) optionally from 0.1 % to about 80 % by weight, of one or more cationic surfactants; iv) optionally from 0.1 % to about 80 % by weight, of one or more zwitterionic surfactants; v) optionally from 0.1 % to about 80 % by weight, of one or more ampholytic surfactants; or vi) mixtures thereof; C) the balance carriers and adjunct ingredients.
    • 本发明涉及包含所述多胺的疏水改性多胺和衣物洗涤剂组合物,所述组合物包含:A)约0.01%,优选约0.1%,更优选约1%,最优选约3%至约50 %,优选约20%,更优选至约10%,最优选至约7%重量的具有式(I)的疏水改性多胺其中R为C 6 -C 20直链或支链亚烷基,及其混合物; R 1是具有下式的亚烷氧基单元: - (R 2 O)x -R 3其中R 2是C 2 -C 4直链或支链亚烷基,及其混合物; R 3是氢,C 1 -C 22烷基,C 7 -C 22亚烷基硬脂基,及其混合物; x为约15至约30; Q是选自C8-C30直链或支链烷基,C6-C30环烷基,C7-C30取代或未取代的亚烷基硬脂基的疏水季铵化单元及其混合物; X是存在足以提供电子中性的阴离子; n为0〜3; B)约0.01重量%的包含一种或多种表面活性剂的表面活性剂体系,所述表面活性剂体系选自:i)0重量%至100重量%的一种或多种阴离子表面活性剂; ii)0重量%至100重量%的一种或多种非离子表面活性剂; iii)任选地0.1%至约80%重量的一种或多种阳离子表面活性剂; iv)任选地0.1%至约80%重量的一种或多种两性离子表面活性剂; v)任选地0.1%至约80%重量的一种或多种两性表面活性剂; 或vi)其混合物; C)平衡载体和辅助成分。
    • 5. 发明申请
    • LAUNDRY DETERGENT COMPOSITIONS COMPRISING HYDROPHOBICALLY MODIFIED POLYAMINES
    • 洗涤剂洗涤剂组合物包含疏水改性聚氨酯
    • WO01034739A2
    • 2001-05-17
    • PCT/US2000/030644
    • 2000-11-07
    • C11D3/30C07C217/50C08G65/26C11D1/14C11D1/22C11D1/29C11D1/62C11D3/37C11D3/39C11D
    • C07C217/50C08G65/2621C11D1/62C11D3/3723
    • The present invention relates to hydrophobically modified polyamines and laundry detergent compositions which comprise said polyamines, said compositions comprising: A) from about 0.01 %, preferably from about 0.1 %, more preferably from about 1 %, most preferably from about 3 % to about 50 %, preferably to about 20 %, more preferably to about 10 %, most preferably to about 7 % by weight, of a hydrophobically modified polyamine having formula (I) wherein R is C6-C20 linear or branched alkylene, and mixtures thereof; R is an alkyleneoxy unit having the formula: -(R O)x-R wherein R is C2-C4 linear or branched alkylene, and mixtures thereof; R is hydrogen, C1-C22 alkyl, C7-C22 alkylenearyl, and mixtures thereof; x is from about 15 to about 30; Q is a hydrophobic quaternizing unit selected from the group consisting of C8-C30 linear or branched alkyl, C6-C30 cycloalkyl, C7-C30 substituted or unsubstituted alkylenearyl, and mixtures thereof; X is an anion present in sufficient amount to provide electronic neutrality; n is from 0 to 3; B) from about 0.01 % by weight, of a surfactant system comprising one or more surfactants selected from: i) from 0 % to 100 % by weight, of one or more anionic surfactants; ii) from 0 % to 100 % by weight, of one or more nonionic surfactants; iii) optionally from 0.1 % to about 80 % by weight, of one or more cationic surfactants; iv) optionally from 0.1 % to about 80 % by weight, of one or more zwitterionic surfactants; v) optionally from 0.1 % to about 80 % by weight, of one or more ampholytic surfactants; or vi) mixtures thereof; C) the balance carriers and adjunct ingredients.
    • 本发明涉及包含所述多胺的疏水改性多胺和衣物洗涤剂组合物,所述组合物包含:A)约0.01%,优选约0.1%,更优选约1%,最优选约3%至约50 %,优选约20%,更优选至约10%,最优选至约7%重量的具有式(I)的疏水改性多胺其中R为C 6 -C 20直链或支链亚烷基,及其混合物; R 1是具有下式的亚烷氧基单元: - (R 2 O)x -R 3其中R 2是C 2 -C 4直链或支链亚烷基,及其混合物; R 3是氢,C 1 -C 22烷基,C 7 -C 22亚烷基硬脂基,及其混合物; x为约15至约30; Q是选自C8-C30直链或支链烷基,C6-C30环烷基,C7-C30取代或未取代的亚烷基硬脂基的疏水季铵化单元及其混合物; X是存在足以提供电子中性的阴离子; n为0〜3; B)约0.01重量%的包含一种或多种表面活性剂的表面活性剂体系,所述表面活性剂体系选自:i)0重量%至100重量%的一种或多种阴离子表面活性剂; ii)0重量%至100重量%的一种或多种非离子表面活性剂; iii)任选地0.1%至约80%重量的一种或多种阳离子表面活性剂; iv)任选地0.1%至约80%重量的一种或多种两性离子表面活性剂; v)任选地0.1%至约80%重量的一种或多种两性表面活性剂; 或vi)其混合物; C)平衡载体和辅助成分。
    • 6. 发明申请
    • AMINE CAPPED POLYETHERS AND PROCESS FOR PRODUCING SAME
    • 胺嵌段聚合物及其生产方法
    • WO1997012928A1
    • 1997-04-10
    • PCT/US1996015875
    • 1996-10-03
    • THE DOW CHEMICAL COMPANY
    • THE DOW CHEMICAL COMPANYCHANG, Dane
    • C08G65/32
    • C10L1/2225B01D19/0445B01D19/0477C07C213/02C08G65/322C08G65/3255C10L1/2235C10L1/226C10L1/232C10L1/238C10L1/2387C10L1/2443C10M149/12C07C217/50
    • This invention includes catalysts comprising rhenium (atomic number 75), nickel, cobalt, boron and copper and/or ruthenium impregnated on a support material and a process for preparing said catalyst, said process comprising (i) impregnating a mixture of metals comprising rhenium, cobalt, copper and/or ruthenium, boron and nickel on a support material selected from the group consisting of alpha-alumina, silica, silica-alumina, kieselguhrs or diatomaceous earths, and silica-titanias; and (ii) activating said catalyst by heating the catalyst in the presence of hydrogen at an effective temperature preferably in the range of about 150 DEG C to about 500 DEG C for a sufficient period preferably of from about 30 minutes to about 6 hours. A further feature of the present invention is a method for producing amine products by the catalytic amination of polyether derivatives including epoxides, monols, diols, polyethers, polyols, alcoholamines, ketones, imino compounds iminoalcohols, ether alcohols, and mixtures thereof, said process comprising contacting said lower polyether derivatives with ammonia and/or reactant amine at an effective temperature preferably from 150 DEG C to about 500 DEG C and at an effective pressure preferably from 1000-5000 psig (6895-34,474 kPag) and in the presence of hydrogen and the nickel-rhenium-cobalt-boron-copper and /or ruthenium catalyst as described hereinabove.
    • 本发明包括包含浸渍在载体材料上的铼(原子序号75),镍,钴,硼和铜和/或钌的催化剂和所述催化剂的制备方法,所述方法包括(i)浸渍包含铼, 钴,铜和/或钌,硼和镍在选自α-氧化铝,二氧化硅,二氧化硅 - 氧化铝,硅藻土或硅藻土的载体材料上,和二氧化硅 - 钛合金; 和(ii)通过在优选在约150℃至约500℃的有效温度下在氢气存在下加热催化剂活化所述催化剂足够的时间,优选约30分钟至约6小时。 本发明的另一个特征是通过包括环氧化物,单醇,二醇,聚醚,多元醇,醇胺,酮,亚氨基化合物亚氨基醇,醚醇及其混合物的聚醚衍生物的催化胺化制备胺产物的方法,所述方法包括 在优选150℃至约500℃的有效温度和优选1000-5000psig(6895-34,474kPag)的有效压力下和在氢气和/或氢气存在下,将所述下部聚醚衍生物与氨和/或反应物胺接触 如上所述的镍 - 铼 - 钴 - 硼 - 铜和/或钌催化剂。
    • 8. 发明申请
    • GASOLINE COMPOSITION
    • 汽油组合物
    • WO1995016764A1
    • 1995-06-22
    • PCT/EP1993003556
    • 1993-12-13
    • SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
    • SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.JOHNSON, Thomas, Howard
    • C10L01/22
    • C10L1/2225C07C217/50C07C255/15C08G65/33365C10L1/143C10L1/2286C10L1/238C10L1/2387C10L10/04
    • The present invention provides gasoline compositions and gasoline additive concentrates containing compounds of general formula (I), wherein R represents a hydrogen atom or an alkyl, aryl or alkaryl group; R O is a residue of a polyether mono-ol or a hydrocarbyl mono-ol of formula R OH; and R and R each represent a hydrogen atom or together represent a carbon-carbon single bond, wherein when R and R each represent a hydrogen atom, then each of R and R independently represents a group -CH2N(R )2 in which each R independently represents a hydrogen atom or an optionally substituted alkyl group, and when R and R together represent a carbon-carbon single bond, then R and R each represent a cyano group; use of the compounds of formula (I) as gasoline additives for reducing intake valve deposit formation; novel compounds, being compounds of formula (I) above, with the proviso that when R is a hydrogen atom or a C1-C4 alkyl group, R and R together represent a carbon-carbon single bond, and R and R each represent a cyano group, then R O is a residue of a polyether mono-ol of formula R OH; and a process for the preparation of the novel compounds of formula (I).
    • 本发明提供含有通式(I)化合物的汽油组合物和汽油添加剂浓缩物,其中R 1表示氢原子或烷基,芳基或烷芳基; R 2 O是式R 2 OH的聚醚一元醇或烃基单醇的残基; R 3和R 4各自表示氢原子或一起代表碳 - 碳单键,其中当R 3和R 4各自表示氢原子时,R 5和 R 6独立地表示基团-CH 2 N(R 7)2,其中每个R 7独立地表示氢原子或任选取代的烷基,并且当R 3和R 4一起表示 碳 - 碳单键,则R 5和R 6各自表示氰基; 使用式(I)化合物作为汽油添加剂减少进气阀沉积物形成; 新化合物,其为上述式(I)的化合物,条件是当R 1为氢原子或C 1 -C 4烷基时,R 3和R 4一起代表碳 - 碳单键 ,R 5和R 6各自表示氰基,则R 2 O是式R 2 OH的聚醚一元醇的残基; 和制备式(I)的新型化合物的方法。