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    • 1. 发明申请
    • REGENERABLE SULFUR TRAPS FOR ON-BOARD VEHICLE APPLICATIONS
    • 适用于车载应用的可再生硫磺行李箱
    • WO2008127671A2
    • 2008-10-23
    • PCT/US2008/004739
    • 2008-04-11
    • EXXONMOBIL RESEARCH AND ENGINEERING COMPANYEL MALKI, El, MekkiWEISSMAN, WalterPOLINI, Paul, J.
    • EL MALKI, El, MekkiWEISSMAN, WalterPOLINI, Paul, J.
    • F01N3/08F01N3/00B01D53/86B01D47/00
    • B01D53/9495B01D53/9404B01D53/9459B01D53/9477B01D2251/202B01D2255/1021B01D2255/2042B01D2255/2063B01D2255/2065B01D2255/2073B01D2255/20738B01D2255/50B01D2255/9207B01D2257/302F01N3/0807F01N3/0814F01N3/0821F01N3/0842F01N3/085F01N13/009F01N2370/02F01N2610/04
    • Provided are improved regenerable SO x trap formulations for on-board vehicle applications. The regenerable sulfur trap formulations reduce the rate of sulfur poisoning of a downstream nitrogen storage reduction (NSR) catalyst trap in exhaust gas cleaning systems for combustion engines by adsorbing SO x as metal sulfate under lean exhaust conditions and desorbing the accumulated SO x under rich exhaust conditions. The regenerable sulfur oxides trap catalyst compositions include a metal (M) oxide, wherein M is selected from Cu, Fe, Mn, Ag, Co and combinations thereof and a metal (M)-La-Zr oxide, wherein M is selected from Cu, Fe, Mn, Ag, Co and combinations thereof. In addition, provided are improved exhaust gas cleaning systems and methods for treating exhaust gas from a combustion source that include a hydrogen generation system, a regenerable sulfur oxides trap, and a regenerable nitrogen storage reduction (NSR) catalyst trap. The improved exhaust gas cleaning systems and methods allow for the sulfur released from the sulfur trap to pass through the nitrogen oxide trap with no or little poisoning of NO x storage and reduction sites, which significantly improves NSR catalyst trap lifetime and performance to meet future emissions standards. The disclosed exhaust gas cleaning systems are suitable for use in internal combustion engines (e.g., diesel, gasoline, CNG) which operate with lean air/fuel ratios over most of the operating period.
    • 提供了用于车载车辆应用的改进的可再生的SO x x陷阱配方。 可再生硫捕集器配方通过在贫排气条件下吸附SO x SO 2作为金属硫酸盐并解吸,降低了用于内燃机的排气净化系统中的下游氮储存还原(NSR)催化剂阱的硫中毒速率 在富排气条件下累积的SO x x。 可再生硫氧化物捕集催化剂组合物包括氧化金属(M),其中M选自Cu,Fe,Mn,Ag,Co及其组合和金属(M)-La-Zr氧化物,其中M选自Cu ,Fe,Mn,Ag,Co及其组合。 此外,提供了改进的废气净化系统和用于处理来自燃烧源的废气的废气净化系统和方法,所述燃烧源包括氢气产生系统,可再生硫氧化物捕集器和可再生氮储存还原(NSR)催化剂阱。 改进的废气清洁系统和方法允许从硫捕获器释放的硫通过氮氧化物捕集器,没有或少量存在NO x N 2存储和还原位点的中毒,这显着改善了NSR催化剂阱 寿命和性能,以满足未来的排放标准。 所公开的废气清洁系统适用于在大部分操作周期内以稀薄空气/燃料比运行的内燃机(例如柴油,汽油,CNG)。
    • 3. 发明申请
    • IMPROVED SULFUR OXIDE/NITROGEN OXIDE TRAP SYSTEM AND METHOD FOR THE PROTECTION OF NITROGEN OXIDE STORAGE REDUCTION CATALYST FROM SULFUR POISONING
    • 改进的硫氧化物/氮氧化物捕获系统和用于保护来自硫磺消毒的氮氧化物储存还原催化剂的方法
    • WO2007008320A2
    • 2007-01-18
    • PCT/US2006/022578
    • 2006-06-09
    • EXXONMOBIL RESEARCH AND ENGINEERING COMPANYWEISSMAN, WalterEL MALKI, El Mekki
    • WEISSMAN, WalterEL MALKI, El Mekki
    • F01N3/00
    • F01N3/0814F01N3/035F01N3/0842F01N3/085F01N3/106F01N13/009F01N2240/40F01N2510/0684F01N2570/04F01N2610/04
    • The present invention relates to an improved exhaust gas cleaning system and method for a combustion source comprising a hydrogen generation system, a sulfur oxides trap, and a nitrogen storage reduction (NSR) catalyst trap. The improved exhaust gas cleaning system and method of the present invention also provides for a water-gas-shift catalyst between the sulfur oxides trap and the NSR catalyst trap, and a clean-up catalyst downstream of the NSR catalyst trap. The invention provides also a sulfur trap regenerable at moderate temperatures with rich pulses, rather than at high temperatures. The improved exhaust gas cleaning system of the present invention provides for the sulfur released from the sulfur trap to pass through the nitrogen oxide trap with no or little poisoning of NOx storage and reduction sites, which significantly improves NSR catalyst trap lifetime and performance to meet future emissions standards. The disclosed exhaust gas cleaning systems are suitable for use in internal combustion engines (e.g., diesel, gasoline, CNG) which operate with lean air/fuel ratios over most of the operating period.
    • 本发明涉及一种用于燃烧源的改进的废气净化系统和方法,其包括氢气产生系统,硫氧化物捕集器和氮储存还原(NSR)催化剂阱。 本发明的改进的废气净化系统和方法还提供了硫氧化物捕集器和NSR催化剂捕集器之间的水煤气变换催化剂,以及NSR催化剂捕集器下游的净化催化剂。 本发明还提供了在中等温度下可富集脉冲而不是在高温下可再生的硫阱。 本发明改进的废气净化系统提供从硫捕集器释放的硫通过氮氧化物捕集器,没有或少量的NOx储存和还原位点的中毒,这显着提高了NSR催化剂捕集器的使用寿命和性能以满足未来 排放标准。 所公开的废气净化系统适用于在大部分操作周期内以稀薄空气/燃料比运行的内燃机(例如柴油,汽油,CNG)。
    • 5. 发明申请
    • REGENERABLE SULFUR TRAPS FOR ON-BOARD VEHICLE APPLICATIONS
    • 适用于车载应用的可再生硫磺行驶
    • WO2008127671A3
    • 2008-12-11
    • PCT/US2008004739
    • 2008-04-11
    • EXXONMOBIL RES & ENG COEL MALKI EL MEKKIWEISSMAN WALTERPOLINI PAUL J
    • EL MALKI EL MEKKIWEISSMAN WALTERPOLINI PAUL J
    • F01N3/08B01D47/00B01D53/86F01N3/00
    • B01D53/9495B01D53/9404B01D53/9459B01D53/9477B01D2251/202B01D2255/1021B01D2255/2042B01D2255/2063B01D2255/2065B01D2255/2073B01D2255/20738B01D2255/50B01D2255/9207B01D2257/302F01N3/0807F01N3/0814F01N3/0821F01N3/0842F01N3/085F01N13/009F01N2370/02F01N2610/04
    • Provided are improved regenerable SOx trap formulations for on-board vehicle applications. The regenerable sulfur trap formulations reduce the rate of sulfur poisoning of a downstream nitrogen storage reduction (NSR) catalyst trap in exhaust gas cleaning systems for combustion engines by adsorbing SOx as metal sulfate under lean exhaust conditions and desorbing the accumulated SOx under rich exhaust conditions. The regenerable sulfur oxides trap catalyst compositions include a metal (M) oxide, wherein M is selected from Cu, Fe, Mn, Ag, Co and combinations thereof and a metal (M)-La-Zr oxide, wherein M is selected from Cu, Fe, Mn, Ag, Co and combinations thereof. In addition, provided are improved exhaust gas cleaning systems and methods for treating exhaust gas from a combustion source that include a hydrogen generation system, a regenerable sulfur oxides trap, and a regenerable nitrogen storage reduction (NSR) catalyst trap. The improved exhaust gas cleaning systems and methods allow for the sulfur released from the sulfur trap to pass through the nitrogen oxide trap with no or little poisoning of NOx storage and reduction sites, which significantly improves NSR catalyst trap lifetime and performance to meet future emissions standards. The disclosed exhaust gas cleaning systems are suitable for use in internal combustion engines (e.g., diesel, gasoline, CNG) which operate with lean air/fuel ratios over most of the operating period.
    • 提供了用于车载车辆应用的改进的可再生SOx捕集剂配方。 可再生硫捕集器配方通过在贫排气条件下吸附SO x作为金属硫酸盐并在富排气条件下解吸累积的SOx,降低内燃机废气净化系统中下游氮储存还原(NSR)催化剂阱的硫中毒速率。 可再生硫氧化物捕集催化剂组合物包括氧化金属(M),其中M选自Cu,Fe,Mn,Ag,Co及其组合,以及金属(M)-La-Zr氧化物,其中M选自Cu ,Fe,Mn,Ag,Co及其组合。 此外,提供了改进的废气净化系统和用于处理来自燃烧源的废气的废气净化系统和方法,所述燃烧源包括氢气产生系统,可再生硫氧化物捕集器和可再生氮储存还原(NSR)催化剂阱。 改进的废气净化系统和方法允许从硫捕获器释放的硫通过氮氧化物捕集器,没有或少量的NOx储存和还原位点的中毒,这显着地提高了NSR催化剂捕集器的使用寿命和性能以满足未来的排放标准 。 所公开的废气清洁系统适用于在大部分操作周期内以稀薄空气/燃料比运行的内燃机(例如柴油,汽油,CNG)。
    • 9. 发明申请
    • IMPROVED SULFUR OXIDE/NITROGEN OXIDE TRAP SYSTEM AND METHOD FOR THE PROTECTION OF NITROGEN OXIDE STORAGE REDUCTION CATALYST FROM SULFUR POISONING
    • 改进的氧化亚氮/氮氧化物捕集系统以及保护从硫中毒到氮氧化物存储还原催化剂的方法
    • WO2007008320A3
    • 2007-11-15
    • PCT/US2006022578
    • 2006-06-09
    • EXXONMOBIL RES & ENG COWEISSMAN WALTEREL MALKI EL MEKKI
    • WEISSMAN WALTEREL MALKI EL MEKKI
    • F01N3/00
    • F01N3/0814F01N3/035F01N3/0842F01N3/085F01N3/106F01N13/009F01N2240/40F01N2510/0684F01N2570/04F01N2610/04
    • The present invention relates to an improved exhaust gas cleaning system and method for a combustion source comprising a hydrogen generation system, a sulfur oxides trap, and a nitrogen storage reduction (NSR) catalyst trap. The improved exhaust gas cleaning system and method of the present invention also provides for a water-gas-shift catalyst between the sulfur oxides trap and the NSR catalyst trap, and a clean-up catalyst downstream of the NSR catalyst trap. The invention provides also a sulfur trap regenerable at moderate temperatures with rich pulses, rather than at high temperatures. The improved exhaust gas cleaning system of the present invention provides for the sulfur released from the sulfur trap to pass through the nitrogen oxide trap with no or little poisoning of NOx storage and reduction sites, which significantly improves NSR catalyst trap lifetime and performance to meet future emissions standards. The disclosed exhaust gas cleaning systems are suitable for use in internal combustion engines (e.g., diesel, gasoline, CNG) which operate with lean air/fuel ratios over most of the operating period.
    • 用于燃烧源的废气净化系统和方法技术领域本发明涉及一种用于燃烧源的改进的废气净化系统和方法,其包括氢生成系统,硫氧化物捕集器和氮储存还原(NSR)催化剂捕集器。 本发明的改进的废气净化系统和方法还提供硫氧化物捕集器和NSR催化剂捕集器之间的水煤气变换催化剂和NSR催化剂捕集器下游的净化催化剂。 本发明还提供了一种硫捕集器,其在中等温度下以丰富的脉冲而不是在高温下可再生。 本发明的改进的废气净化系统使得从硫收集器释放的硫通过氮氧化物收集器而没有或几乎不中毒NOx收集和还原位点,这显着提高了NSR催化剂捕集器寿命和性能以满足未来 排放标准。 所公开的排气净化系统适用于在大部分运行周期内以稀空气/燃料比操作的内燃机(例如,柴油机,汽油机,CNG)。