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    • 2. 发明申请
    • ORGANIC BLACK PIGMENTS AND THEIR PREPARATION
    • 有机黑色素及其制备
    • WO2010081625A3
    • 2010-11-04
    • PCT/EP2009067953
    • 2009-12-28
    • BASF SEEICHENBERGER THOMASRUCH THOMASBAUER RALFKREBS CHRISTOPHLUTERBACHER URSULAMAURER MARC
    • EICHENBERGER THOMASRUCH THOMASBAUER RALFKREBS CHRISTOPHLUTERBACHER URSULAMAURER MARC
    • C09B57/00C07D405/04C08K5/00C09B67/22
    • C09B57/00C07D405/04C07D493/04C08K5/0041C09B67/0034Y10T428/2982Y10T442/30
    • A process for preparing a black colorant, preferably a black pigment, characterized in that a compound of the Formula (I) is reacted with a compound of the Formula (II) in a molar ratio of 1:2, in the presence of a catalyst which in water at 25 °C has a pK = 4.5. For the definition of R1 to R7, refer to the description; preferably all are H. Likewise claimed are new crystal polymorphs obtainable by this process, and preferably single-phase mixed crystals. Also claimed are synergistic compositions. These compositions exhibit increased light stability in plastics stabilized with basic light stabilizers when they are pigmented with colorants of the invention rather than with known black pigments such as carbon black. The specification also relates, furthermore, to the use of the black colorants of the invention for coloring paints, printing inks and plastics in the mass, and to mulch film, instrument panels, woven fabrics, garden furniture items or elements for the construction industry that are pigmented with said colorants.
    • 一种制备黑色着色剂,优选黑色颜料的方法,其特征在于使式(I)化合物与摩尔比为1:2的式(II)化合物在催化剂存在下反应 其在25℃的水中具有pK = 4.5。 关于R1〜R7的定义,请参考说明书; 优选全部为H.同样要求保护的是通过该方法可获得的新晶体多晶型物,优选单相混合晶体。 还要求的是协同组合物。 当用本发明的着色剂着色时,这些组合物在用碱性光稳定剂稳定的塑料中显示增强的光稳定性,而不是已知的黑色颜料如炭黑。 此外,本说明书还涉及本发明的黑色着色剂用于在油漆中着色油漆,印刷油墨和塑料的用途,以及用于建筑行业的膜,仪表板,机织织物,花园家具或元件的覆盖 用着色剂着色。
    • 3. 发明申请
    • ORGANIC BLACK PIGMENTS AND THEIR PREPARATION
    • 有机黑色颜料及其制备
    • WO2010081625A2
    • 2010-07-22
    • PCT/EP2009/067953
    • 2009-12-28
    • BASF SEEICHENBERGER, ThomasRUCH, ThomasBAUER, RalfKREBS, ChristophLUTERBACHER, UrsulaMAURER, Marc
    • EICHENBERGER, ThomasRUCH, ThomasBAUER, RalfKREBS, ChristophLUTERBACHER, UrsulaMAURER, Marc
    • C09B57/00C07D405/04C08K5/00C09B67/22
    • C09B57/00C07D405/04C07D493/04C08K5/0041C09B67/0034Y10T428/2982Y10T442/30
    • A process for preparing a black colorant, preferably a black pigment, characterized in that a compound of the Formula (I) is reacted with a compound of the Formula (II) in a molar ratio of 1:2, in the presence of a catalyst which in water at 25 °C has a pK ≤ 4.5. For the definition of R 1 to R 7 , refer to the description; preferably all are H. Likewise claimed are new crystal polymorphs obtainable by this process, and preferably single-phase mixed crystals. Also claimed are synergistic compositions. These compositions exhibit increased light stability in plastics stabilized with basic light stabilizers when they are pigmented with colorants of the invention rather than with known black pigments such as carbon black. The specification also relates, furthermore, to the use of the black colorants of the invention for coloring paints, printing inks and plastics in the mass, and to mulch film, instrument panels, woven fabrics, garden furniture items or elements for the construction industry that are pigmented with said colorants.
    • 制备黑色着色剂,优选黑色颜料的方法,其特征在于使式(I)化合物与式(II)化合物以摩尔比1:1反应, 2,在25℃的水中具有pK≤4.5的催化剂存在下进行。 对于R 1 到R 7 的定义,请参考说明; 优选全部为H.同样要求保护的是通过该方法可获得的新的晶体多晶型物,并且优选单相混合晶体。 还要求提供协同组合物。 当这些组合物用本发明的着色剂而不是用已知的黑色颜料如炭黑着色时,用碱性光稳定剂稳定的这些组合物表现出增加的光稳定性。 此外,本说明书还涉及本发明的黑色着色剂在涂料,印刷油墨和塑料中的着色中的用途,以及用于建筑工业的覆盖膜,仪表板,机织织物,花园家具物品或元件的用途, 用所述着色剂着色。
    • 4. 发明申请
    • BISAZOQUINOLONE PIGMENTS, PROCESSES FOR THEIR PREPARATION AND THEIR USE
    • BISAZOQUINOLONE颜料,其制备方法及其使用
    • WO2004111134A1
    • 2004-12-23
    • PCT/EP2004/051023
    • 2004-06-04
    • CIBA SPECIALTY CHEMICALS HOLDING INC.BENKHOFF, JohannesHÜGIN, MaxEICHENBERGER, Thomas
    • BENKHOFF, JohannesHÜGIN, MaxEICHENBERGER, Thomas
    • C09B33/153
    • C08K5/0041C08K5/3437C09B33/153
    • Bisazoquinolone pigments which, in one of the tautomeric forms thereof, correspond to formula (1) wherein W is the radical of an unsubstituted or substituted C 6 -C 24 aryl or the radical of an unsubstituted or substituted heteroaryl, Ar 1 is unsubstituted or substituted C 6 -C 24 aryl or unsubstituted or substituted heteroaryl, Ar 11 is unsubstituted or substituted C 6 -C 24 aryl or unsubstituted or substituted heteroaryl, R 1 R 1 , R 2 , R 10 , R 11 and R 12 are each independently of the others hydrogen, C 1 -C 6 alkyl, halogen, cyano, CF 3 , nitro, NR 3 R 4 , COOR 4 , NR 4 COR 3 , COOX + , COR 4 , OR 4 , SR 3 , S0 2 R 3 , S0 2 NR 3 R 4 , S0 3 -X + , or C 6 -C 24 aryl unsubstituted or mono- or poly-substituted by R 5 , R 3 is C 1 -C 6 alkyl, or C 6 -C l2 aryl unsubstituted or mono- or polysubstituted by halogen, hydroxy, OR7, cyano, nitro, SR 7 , NR 6 R7, COOR 7 , CONR 6 R 7 , NR 6 COR 7 , NR 6 COOR 7 , COO-X + , COR 4 , OR 4 , S0 2 R 7 , S0 2 NR 6 R 7 , S0 3 -X + or by S0 3 R 7 , R 4 is hydrogen or has the same meanings as R 3 , R 5 is hydrogen, C 1 -C 4 alkyl, halogen, nitro, NR 7 R 8 or OR 7 , R 6 is hydrogen or C 1 -C 3 alkyl, R 7 and R 8 are each independently of the other hydrogen, C 1 -C 3 alkyl, phenyl unsubstituted or mono- or poly-substituted by halogen, nitro, OR 5 or by NR 16 R 17 , or benzyl unsubstituted or mono- or poly-substituted by halogen, nitro, OR 5 or by NR 16 R 17 , and X + is a cation H + , Li + , Na + , K + , Mg + + 1/2 , Ca ++ 1/2 , Sr ++ 1/2 , Ba ++ 1/2 , Cu + , Cu ++ 1/2 , Zn ++ 1/2 , Mn ++ 1/2 , Al +++ 1/3 or [NR 19 R 20 R 21 R 22 ] + wherein R 19 , R 20 , R 21 and R 22 are each independently of the others hydrogen, C 1 -C 6 alkyl, phenyl unsubstituted or mono- or polysubstituted by C 1 -C 6 alkyl, halogen, nitro, OR 5 or by NR 16 R 17 , or benzyl unsubstituted or mono- or poly-substituted by C 1 -C 6 alkyl, halogen, nitro, OR 5 or by NR 16 R 17 , R 16 and R 17 are each independently of the other hydrogen or C 1 -C 6 alkyl, Z 1 is -NH- or -0-, and Z 2 is -NH or -0-, are suitable for colouring high molecular weight material and are distinguished by the resulting colorations having good fastness properties.
    • 以其互变异构形式之一对应于式(1)的双偶氮喹诺酮颜料,其中W为未取代或取代的C 6 -C 24芳基或未取代或取代的杂芳基的基团,Ar 1为未取代或取代的C 6 -C 24芳基或 未取代或取代的杂芳基,Ar 11是未取代或取代的C 6 -C 24芳基或未取代或取代的杂芳基,R 1,R 2,R 10,R 11和R 12各自独立地为氢,C 1 -C 6烷基,卤素,氰基,CF 3,硝基, NR3R4,COOR4,NR4COR3,COOX4,NR4COR3,COOX +,COR4,OR4,SR3,SO2R3,SO2NR3R4,SO3-X +或未取代或被R5单取代或多取代的C6-C24芳基,R3是C1-C6烷基, 未被取代或未被卤素,羟基,OR7,氰基,硝基,SR7,NR6R7,COOR7,CONR6R7,NR6COR7,NR6COOR7,COO-X +,COR4,OR4,SO2R7,SO2NR6R7,SO3-X 或者由SO 3 R 7取代,R 4是氢或具有与R 3相同的含义,R 5是氢,C 1 -C 4烷基,卤素,硝基,NR 7 R 8或OR 7,R 6是 氢或C 1 -C 3烷基,R 7和R 8各自独立地为另一个氢,C 1 -C 3烷基,未取代的或被卤素,硝基,OR 5或NR 16 R 17单取代或多取代的苯基,或未取代或单取代或多取代的苄基 通过卤素,硝基,OR5或NR16R17,X +是阳离子H +,Li +,Na +,K +,Mg + + 2+,Ca + +> 1/2,Sr ++,1/2 ++,Cu ++,Cu ++,1/2 ++, +> 1/2,Al <+++> 1/3或[NR19R20R21R22] +其中R19,R20,R21和R22各自独立地为氢,C1-C6烷基,未被取代或被单取代或多取代的苯基 C1-C6烷基,卤素,硝基,OR5或NR16R17,或未取代或被C1-C6烷基,卤素,硝基,OR5或NR16R17,R16和R17单取代或多取代的苄基各自独立地为氢或C1- C6烷基,Z1是-NH-或-O-,Z2是-NH或-O-,适用于着色高分子量材料,并且通过具有良好牢度性质的所得着色来区分。
    • 8. 发明申请
    • AZO DYES SOLUBLE IN ORGANIC SOLVENTS
    • AZO DYES SOLUBLE有机溶剂
    • WO2004050768A2
    • 2004-06-17
    • PCT/EP2003/050898
    • 2003-11-26
    • CIBA SPECIALTY CHEMICALS HOLDING INC.FEILER, LeonhardRAIMANN, ThomasEICHENBERGER, ThomasHÜGIN, Max
    • FEILER, LeonhardRAIMANN, ThomasEICHENBERGER, ThomasHÜGIN, Max
    • C09B
    • C09B69/045C09B29/3617C09B31/14Y10S8/922
    • The present invention relates to azo dyes of formula (1) which are soluble in organic solvents, wherein R 1 is -CN, -COOR 5 , -CONR 6 R 7 or a heterocyclic ring, R 2 is unsubstituted or substituted alkyl, unsubstituted or substituted aryl, -CF 3 , -COOR 5 , -CONR 6 R 7 or -COR 5 , R 3 is hydrogen, -SO 3 M, alkyl, alkoxy, alkylcarbonyl, -NO 2 or halogen, R 4 is substituted aryl, substituted heteroaryl or an aryl-N=N-aryl radical, wherein one or both of the aryl radicals in aryl-N=N-aryl is/are unsubstituted or substituted, or a radical heteroaryl-N=N-heteroaryl, wherein one or both of the heteroaryl radicals in heteroaryl-N=N-heteroaryl is/are unsubstituted or substituted, R 5 is hydrogen, alkyl or unsubstituted or substituted aryl, R 6 is hydrogen, alkyl or unsubstituted or substituted aryl, R 7 is hydrogen, alkyl or unsubstituted or substituted aryl, M + is a cation, n is a number 1, 2 or 3 and m is a number 1, 2 or 3, to a process for the preparation thereof and to the use thereof in the production of coloured plastics or polymeric colour particles, and as printing inks, printing dyes, coating compositions and wood stains.
    • 本发明涉及可溶于有机溶剂的式(1)的偶氮染料,其中R1为-CN,-COOR5,-CONR6R7或杂环,R2为未取代或取代的烷基,未取代或取代的芳基,-CF3, -COOR5,-CONR6R7或-COR5,R3是氢,-SO3M,烷基,烷氧基,烷基羰基,-NO2或卤素,R4是取代的芳基,取代的杂芳基或芳基-N = N-芳基,其中一个或两个 芳基-N = N-芳基中的芳基是未取代的或取代的,或杂芳基-N = N-杂芳基,其中杂芳基-N = N-杂芳基中的一个或两个杂芳基是未取代的或未被取代的 取代的,R 5为氢,烷基或未取代或取代的芳基,R 6为氢,烷基或未取代或取代的芳基,R 7为氢,烷基或未取代或取代的芳基,M +为阳离子,n为数1,2 或3和m是数字1,2或3,其制备方法及其在制备中的用途 塑料或聚合物着色颗粒,以及印刷油墨,印刷染料,涂料组合物和木材污渍。
    • 10. 发明申请
    • USE OF PYRIMIDO[5,4-G]PTERIDINES AS SHADING COMPONENT IN COLOR FILTER COLORANT COMPOSITIONS
    • 在彩色滤色片组合物中使用PYRIMIDO [5,4-G] P子作为染色组分
    • WO2006037728A1
    • 2006-04-13
    • PCT/EP2005/054725
    • 2005-09-21
    • CIBA SPECIALTY CHEMICALS HOLDING INC.DENO, TakashiEICHENBERGER, ThomasVOIGT, Joachim
    • DENO, TakashiEICHENBERGER, ThomasVOIGT, Joachim
    • C09B67/22G02F1/1335G02B5/22C08K5/00
    • C08K5/0041C09B67/0033G02B5/223
    • The present invention relates to the field of color filters and LCDs. More specifically, the invention relates to a colorant composition for making color filters comprising pyrimido[5,4- g]pteridine derivatives of formula (I) wherein A1, A2, A3, and A4 are each independently of the others -NR1R2, wherein R1 and R2 are each independently of the others hydrogen, CrC8alkyl, -CO-C1 -C8alkyl, -CO-Ce-Cuaryl, -COO-C1 -C8alkyl, -COO-Ce-CMaryl, -CONH-d-Cβalkyl or -CONH-Ce-CMaryl, Or A1, A2, A3, and A4 are each independently of the others -OH, -SH, hydrogen, CrC8alkyl, CrC8alkoxy, or C6-C14aryl or -O- C6-C14aryl each unsubstituted or mono- or poly-substituted by halogen, nitro, cyano, -OR10, -SR10, -NR10R11, -CONR10R11, -COOR10, -SO2R10, -SO2NR10R11, -SO3R10, -NR11COR10 or by -NR11COOR10, wherein R10 and R11 are each independently of the others hydrogen, CrC8alkyl, C5-C12cycloalkyl or C2-C8-alkenyl; and to their use for color filter production and to color filters comprising said pyrimido[5,4- g]pteridine derivatives of formula (I).
    • 本发明涉及滤色器和LCD的领域。 更具体地,本发明涉及一种用于制备包含式(I)的嘧啶并[5,4-g]蝶啶衍生物的滤色剂的着色剂组合物,其中A1,A2,A3和A4各自独立地为-NR1R2,其中R1 -CO-C 1 -C 8烷基,-CO-C 1 -C 8芳基,-COO-C 1 -C 8烷基,-COO-C 1 -C 8芳基,-CONH-d-C 1-6烷基或-CONH- C 1 -C 10芳基或者A 1,A 2,A 3和A 4各自独立地为-OH,-SH,氢,C 1 -C 8烷基,C 1 -C 8烷氧基或C 6 -C 14芳基或者C 6 -C 14芳基, 被卤素,硝基,氰基,-OR10,-SR10,-NR10R11,-CONR10R11,-COOR10,-SO2R10,-SO2NR10R11,-SO3R10,-NR11COR10或-NR11COOR10取代,其中R10和R11各自独立地为氢 C 1 -C 8烷基,C 5 -C 12环烷基或C 2 -C 8 - 烯基; 以及它们用于滤色器生产的用途和包含式(I)的所述嘧啶并[5,4-g]蝶啶衍生物的滤色片。