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    • 4. 发明申请
    • MONOAZO COLORANTS FOR MASS-COLOURING OF POLYMERS
    • 用于聚合物大量染色的MONOAZO颜料
    • WO2008049744A1
    • 2008-05-02
    • PCT/EP2007/060925
    • 2007-10-15
    • CIBA HOLDING INC.RUCH, ThomasLUTERBACHER, Ursula
    • RUCH, ThomasLUTERBACHER, Ursula
    • C09B29/52C08J3/20C08K5/23
    • C09B29/3669C08K5/0041
    • A process for mass-colouring high molecular weight material, in which process a compound of formula (I) or a tautomer thereof, wherein M 1 is H, 1/2 M 2 , 1/3 M 3 or NR 4 R 5 R 6 R 7 , preferably H, 1/2 M 2 or NR 4 R 5 R 6 R 7 , especially H, M 2 is an alkaline earth or transition metal in oxidation state II or an oxo-metal in oxidation state IV, M 3 is Al (III), a transition metal in oxidation state III or an oxo-metal in oxidation state V, R 1 is H or a non-ionic substituent, R 2 is H or, independently of R 1 , a further non-ionic substituent, R 3 is H, C 1 -C 6 alkyl, phenyl, CO-C 1 -C 6 alkyl or CO-phenyl, preferably H or CO-C 1 -Cealkyl, especially H, and R 4 , R 5 , R 6 and R 7 are each independently of the others H or phenyl, benzyl or C 1 -C 6 alkyl, which are unsubstituted or may be substituted by hydroxy or by halogen and in the case of C 3 -C 6 alkyl is uninterrupted or interrupted by O, is incorporated into the high molecular weight material before or during shaping. The colorations obtained have good light stability and thermal stability, especially in polyolefins.
    • 一种用于大量着色高分子量材料的方法,其中式(I)化合物或其互变异构体(其中M 1)为H,1/2 M 2 >,1/3 M 3或NR 4 R 5 R 6 R 7 R 7 / >,优选H,1/2 M 2或NR 4 R 5 R 6 R 7 特别是H 2 M 2是氧化态II的碱土金属或过渡金属或氧化态IV的氧代金属,M 3是Al( III),氧化态III的过渡金属或氧化态V的氧代金属,R 1是H或非离子取代基,R 2是H或 独立于R 1,另外的非离子取代基R 3是H,C 1 -C 6 烷基,苯基,CO-C 1 -C 6烷基或CO-苯基,优选H或CO-C 1 -C 1烷基,特别是 H和R 4,R 5,R 6和R 7各自独立地为H或 苯基,本 或未被取代或可被羟基或卤素取代的C 1 -C 6烷基或C 3 -C 6烷基,并且在C 3 - C 6烷基不间断或被O中断,在成型之前或期间被并入高分子量材料中。 获得的着色具有良好的光稳定性和热稳定性,特别是在聚烯烃中。
    • 7. 发明申请
    • ORGANIC BLACK PIGMENTS AND THEIR PREPARATION
    • 有机黑色素及其制备
    • WO2010081625A3
    • 2010-11-04
    • PCT/EP2009067953
    • 2009-12-28
    • BASF SEEICHENBERGER THOMASRUCH THOMASBAUER RALFKREBS CHRISTOPHLUTERBACHER URSULAMAURER MARC
    • EICHENBERGER THOMASRUCH THOMASBAUER RALFKREBS CHRISTOPHLUTERBACHER URSULAMAURER MARC
    • C09B57/00C07D405/04C08K5/00C09B67/22
    • C09B57/00C07D405/04C07D493/04C08K5/0041C09B67/0034Y10T428/2982Y10T442/30
    • A process for preparing a black colorant, preferably a black pigment, characterized in that a compound of the Formula (I) is reacted with a compound of the Formula (II) in a molar ratio of 1:2, in the presence of a catalyst which in water at 25 °C has a pK = 4.5. For the definition of R1 to R7, refer to the description; preferably all are H. Likewise claimed are new crystal polymorphs obtainable by this process, and preferably single-phase mixed crystals. Also claimed are synergistic compositions. These compositions exhibit increased light stability in plastics stabilized with basic light stabilizers when they are pigmented with colorants of the invention rather than with known black pigments such as carbon black. The specification also relates, furthermore, to the use of the black colorants of the invention for coloring paints, printing inks and plastics in the mass, and to mulch film, instrument panels, woven fabrics, garden furniture items or elements for the construction industry that are pigmented with said colorants.
    • 一种制备黑色着色剂,优选黑色颜料的方法,其特征在于使式(I)化合物与摩尔比为1:2的式(II)化合物在催化剂存在下反应 其在25℃的水中具有pK = 4.5。 关于R1〜R7的定义,请参考说明书; 优选全部为H.同样要求保护的是通过该方法可获得的新晶体多晶型物,优选单相混合晶体。 还要求的是协同组合物。 当用本发明的着色剂着色时,这些组合物在用碱性光稳定剂稳定的塑料中显示增强的光稳定性,而不是已知的黑色颜料如炭黑。 此外,本说明书还涉及本发明的黑色着色剂用于在油漆中着色油漆,印刷油墨和塑料的用途,以及用于建筑行业的膜,仪表板,机织织物,花园家具或元件的覆盖 用着色剂着色。
    • 8. 发明申请
    • ORGANIC BLACK PIGMENTS AND THEIR PREPARATION
    • 有机黑色颜料及其制备
    • WO2010081625A2
    • 2010-07-22
    • PCT/EP2009/067953
    • 2009-12-28
    • BASF SEEICHENBERGER, ThomasRUCH, ThomasBAUER, RalfKREBS, ChristophLUTERBACHER, UrsulaMAURER, Marc
    • EICHENBERGER, ThomasRUCH, ThomasBAUER, RalfKREBS, ChristophLUTERBACHER, UrsulaMAURER, Marc
    • C09B57/00C07D405/04C08K5/00C09B67/22
    • C09B57/00C07D405/04C07D493/04C08K5/0041C09B67/0034Y10T428/2982Y10T442/30
    • A process for preparing a black colorant, preferably a black pigment, characterized in that a compound of the Formula (I) is reacted with a compound of the Formula (II) in a molar ratio of 1:2, in the presence of a catalyst which in water at 25 °C has a pK ≤ 4.5. For the definition of R 1 to R 7 , refer to the description; preferably all are H. Likewise claimed are new crystal polymorphs obtainable by this process, and preferably single-phase mixed crystals. Also claimed are synergistic compositions. These compositions exhibit increased light stability in plastics stabilized with basic light stabilizers when they are pigmented with colorants of the invention rather than with known black pigments such as carbon black. The specification also relates, furthermore, to the use of the black colorants of the invention for coloring paints, printing inks and plastics in the mass, and to mulch film, instrument panels, woven fabrics, garden furniture items or elements for the construction industry that are pigmented with said colorants.
    • 制备黑色着色剂,优选黑色颜料的方法,其特征在于使式(I)化合物与式(II)化合物以摩尔比1:1反应, 2,在25℃的水中具有pK≤4.5的催化剂存在下进行。 对于R 1 到R 7 的定义,请参考说明; 优选全部为H.同样要求保护的是通过该方法可获得的新的晶体多晶型物,并且优选单相混合晶体。 还要求提供协同组合物。 当这些组合物用本发明的着色剂而不是用已知的黑色颜料如炭黑着色时,用碱性光稳定剂稳定的这些组合物表现出增加的光稳定性。 此外,本说明书还涉及本发明的黑色着色剂在涂料,印刷油墨和塑料中的着色中的用途,以及用于建筑工业的覆盖膜,仪表板,机织织物,花园家具物品或元件的用途, 用所述着色剂着色。
    • 10. 发明申请
    • SALTS OF LAKED MONOAZO COMPOUNDS
    • 盐酸单萜化合物的盐
    • WO2005103164A1
    • 2005-11-03
    • PCT/EP2005/051686
    • 2005-04-18
    • CIBA SPECIALTY CHEMICALS HOLDING INC.FOLLY, GrégoireLUTERBACHER, UrsulaRUCH, Thomas
    • FOLLY, GrégoireLUTERBACHER, UrsulaRUCH, Thomas
    • C09B29/33
    • C09B29/332
    • The present invention relates to monoazo compounds of formula (I) which are present in the form of mono-, di-, tri- or tetra-valent mixed salts of different cations, such as, for example, Ca 2+ , Na + , NH 4 + , NR 4 + , H + , Li + , K + , Mg 2+ ,Ba 2+ , Sr 2+ , AI 3+ , Pb 2+ , Mn 2+ , Zn 2+ , Cr 2+ , Co 2 + , Fe 2 + , Fe 3+ , Zr 4+ and Cu 2 + , R being C 1 -C 6 alkyl, in freely selected ratios, and to the calcium salt of the monoazo compound of formula (I) which has two crystal polymorph forms - a reddish yellow and a greenish yellow - having different properties, for example colour shade or high-temperature stability, to the preparation of such compounds and to their use in the mass-pigmenting of organic materials and in the production of wax transfer ribbons, toners or colour filters.
    • 本发明涉及以不同阳离子的单,二,三或四价混合盐形式存在的式(I)单偶氮化合物,例如Ca 2+,Na NH 4 +,NH 4 +,N 4+,H +,Li +,K +,Mg 2+,Ba 2+,Sr 2+, > <3>,Pb 2+,Mn 2+,Zn 2+,Cr 2+,Co 2+,Fe 2+,Fe 3 +,Zr <4+>和Cu 2+,R是以自由选择的比例为C 1 -C 6烷基,和具有两个晶体多晶型形式的式(I)单偶氮化合物的钙盐 - 红色黄色和黄绿色 - 具有不同的性质,例如色调或高温稳定性,用于制备这些化合物,以及它们在有机材料的大量着色中的用途以及生产蜡转移带,调色剂或 滤色片