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1. 发明申请

WO2010046051A8 PROCESS FOR THE PRODUCTION OF LIPIDS FROM BIOMASS 审中-公开
标题翻译：从生物量生产脂肪的方法
公开(公告)号：WO2010046051A8
公开(公告)日：2010-07-08
申请号：PCT/EP2009007388
申请日：2009-10-14
申请人： ENI SPA , BIANCHI DANIELE , FRANZOSI GIULIANA , ROMANO ANNA MARIA
发明人： BIANCHI DANIELE , FRANZOSI GIULIANA , ROMANO ANNA MARIA
IPC分类号： C12P7/64 , C11B1/02 , C11B1/06 , C12P19/02 , C12P19/14 , C13K1/02 , D21C3/04
CPC分类号： C12P7/649 , C10L1/026 , C11B1/025 , C11B1/06 , C11C3/003 , C12P7/6463 , C12P19/02 , C12P19/14 , C12P2201/00 , C13K1/02 , D21C3/04 , D21C11/0007 , Y02E50/13
摘要： A process for the production of lipids from biomass including at least one polysaccharide comprising: subjecting said biomass to acid hydrolysis in the presence of an aqueous solution of at least one organic acid selected from alkyl- or aryl-sulfonic acids having from C7 to C20 carbon atoms, preferably from C9 to C15 carbon atoms, or from halogenated carboxylic acids, at a temperature ranging from 80°C to 160°C, preferably from 100°C to 150°C, obtaining a first mixture comprising a first solid phase and a first aqueous phase; - subjecting said first mixture to enzymatic hydrolysis obtaining a second mixture comprising a second solid phase and a second aqueous phase; subjecting said second aqueous phase to fermentation in the presence of at least one oleaginous yeast obtaining an oleaginous cellular biomass comprising lipids. The lipids thus obtained can be advantageously used in the production of biodiesel or green diesel which can be used as such, or in a mixture with other fuels for motor vehicles.
摘要翻译：一种从包括至少一种多糖的生物质生产脂质的方法，包括：在至少一种选自具有C7至C20碳原子的烷基或芳基磺酸的有机酸的水溶液存在下使所述生物质进行酸水解原子，优选C 9至C 15碳原子，或卤代羧酸，在80℃至160℃，优选100℃至150℃的温度下，获得包含第一固相和第一水相; - 使所述第一混合物经酶水解获得包含第二固相和第二水相的第二混合物; 使所述第二水相在至少一种含油酵母存在下发酵，得到包含脂质的含油细胞生物质。由此获得的脂质可有利地用于生产可生产生物柴油或绿色柴油的生物柴油或绿色柴油，或与其他用于汽车的燃料混合使用。

2. 发明申请

WO2012117319A1 INTEGRATED PROCESS FOR THE PRODUCTION OF BIO-OIL FROM SLUDGE COMING FROM A WASTEWATER PURIFICATION PLANT 审中-公开
标题翻译：从废水净化厂的泥沙生产生物油的综合工艺
公开(公告)号：WO2012117319A1
公开(公告)日：2012-09-07
申请号：PCT/IB2012/050850
申请日：2012-02-24
申请人： ENI S.P.A. , BOSETTI, Aldo , BIANCHI, Daniele , FRANZOSI, Giuliana
发明人： BOSETTI, Aldo , BIANCHI, Daniele , FRANZOSI, Giuliana
IPC分类号： C02F11/10 , C10G3/00
CPC分类号： C02F11/10 , C10G3/40 , C10G2300/1003 , C10G2300/1014 , C10G2300/1018 , C10G2300/208 , Y02P30/20 , Y02W10/37 , Y02W10/40
摘要： Integrated process for the production of bio-oil from sludge coming from a wastewater purification plant comprising the following steps: (a) sending wastewater to said purification plant obtaining sludge; (b) subjecting the sludge obtained in said step (a) to liquefaction, obtaining a mixture Including an oily phase consisting of bio-oil, a solid phase and an aqueous phase; (c) sending the aqueous phase obtained in said step (b) to said purification plant. The bio-oil (or "bio-crude") thus obtained can be advantageously used in the production of bio-fuels which can be used as such, or in a mixture with other automotive fuels. Otherwise, said bio-oil (or "bio-crude") can be used as such (bio-fuel), or in a mixture with fossil fuels (combustible oil, coal, etc.), for the generation of electric energy or heat.
摘要翻译：用于从污水净化设备的污泥生产生物油的综合过程包括以下步骤：（a）将废水送至所述净化设备获得污泥; （b）使在所述步骤（a）中获得的污泥液化，获得混合物包括由生物油，固相和水相组成的油相; （c）将所述步骤（b）中获得的水相送至所述净化装置。由此获得的生物油（或“生物粗品”）可有利地用于生产可以直接使用或与其它汽车燃料混合使用的生物燃料。否则，所述生物油（或“生物原油”）可以如此使用（生物燃料）或与化石燃料（可燃油，煤等）的混合物用于产生电能或热量。

3. 发明申请

WO2011030196A1 PROCESS FOR THE PRODUCTION OF BIO-OIL FROM SOLID URBAN WASTE 审中-公开
标题翻译：从固体废物生产生物油的工艺
公开(公告)号：WO2011030196A1
公开(公告)日：2011-03-17
申请号：PCT/IB2010/002176
申请日：2010-09-01
申请人： ENI S.P.A. , BOSETTI, Aldo , BIANCHI, Daniele , FRANZOSI, Giuliana , RICCI, Marco
发明人： BOSETTI, Aldo , BIANCHI, Daniele , FRANZOSI, Giuliana , RICCI, Marco
IPC分类号： C10G1/00 , C10G1/04 , C02F3/28
CPC分类号： C10G1/04 , C10G1/002 , C10G1/02 , C10G2300/1003 , C10G2300/1011 , Y02P30/20 , Y02W10/37
摘要： A process for the production of bio-oil from solid urban waste, comprising the following steps: a) subjecting said solid urban waste to liquefaction, obtaining a mixture including an oily phase consisting of bio-oil, a solid phase and an aqueous phase; b) subjecting the aqueous phase obtained in the liquefaction step a) to fermentation, obtaining a fermented biomass; c) feeding the fermented biomass obtained in the fermentation step b) to the liquefaction step a). The bio-oil (or bio-crude) thus obtained can be advantageously used in the production of biofuels which can be used as such or mixed with other motor vehicle fuels. Alternatively, this bio-oil (or bio-crude) can be used as such (biocombustible) or mixed with fossil combustibles (combustible oil, coal, etc.) for the generation of electric energy or heat.
摘要翻译：一种从固体城市废物生产生物油的方法，包括以下步骤：a）使所述固体城市废物进行液化，得到包括由生物油，固相和水相组成的油相的混合物; b）使在液化步骤a）中获得的水相发酵，获得发酵生物质; c）将发酵步骤b）中获得的发酵生物质送入液化步骤a）。由此获得的生物油（或生物粗品）可有利地用于生产生物燃料，其可以原样使用或与其它机动车辆燃料混合。或者，该生物油（或生物粗品）可以原样使用（生物燃烧）或与化石可燃物（可燃油，煤等）混合以产生电能或热量。

4. 发明申请

WO2010099882A1 PROCESS FOR THE PURIFICATION OF AN AQUEOUS STREAM COMING FROM THE FISCHER-TROPSCH REACTION 审中-公开
标题翻译：从FISCHER-TROPSCH反应中净化水质流的方法
公开(公告)号：WO2010099882A1
公开(公告)日：2010-09-10
申请号：PCT/EP2010/001098
申请日：2010-02-18
申请人： ENI S.P.A. , FRANZOSI, Giuliana , CESTI, Pietro , PAGLINO, Roberto , CARNELLI, Lino , MIGLIO, Roberta
发明人： FRANZOSI, Giuliana , CESTI, Pietro , PAGLINO, Roberto , CARNELLI, Lino , MIGLIO, Roberta
IPC分类号： C02F1/04 , C02F3/28 , C02F9/00 , C02F101/32 , C02F101/34
CPC分类号： C02F1/04 , C02F1/20 , C02F1/441 , C02F1/444 , C02F1/66 , C02F3/1268 , C02F3/28 , C02F3/2846 , C02F2101/32 , C02F2101/34 , C02F2103/36 , C02F2303/10 , Y02W10/15 , Y02W10/30
摘要： Process for the purification of an aqueous stream coming from the Fischer-Tropsch reaction which comprises: - feeding said aqueous stream containing the organic by-products of the reaction to a distillation column, obtaining two output streams: - an aqueous stream (i) exiting from the column head, enriched with alcohols having from 1 to 20 carbon atoms, preferably from 1 to 9 carbon atoms, and other optional volatile compounds; an aqueous stream (ii) exiting from the column bottom, enriched with organic acids having from 1 to 10 carbon atoms, preferably from 2 to 6 carbon atoms; - subjecting said aqueous stream (ii) to an anaerobic biological treatment obtaining a purified aqueous stream (iii); wherein said anaerobic biological treatment is carried out with a hydraulic retention time lower than 15 hours, preferably ranging from 4 hours to 10 hours, more preferably ranging from 5 hours to 8 hours.
摘要翻译：净化来自费 - 托反应的含水物流的方法，其包括：将含有反应的有机副产物的所述含水物流送入蒸馏塔，得到两个输出流： - 水流（i）离开富集具有1至20个碳原子，优选1至9个碳原子的醇和其它任选的挥发性化合物; 从塔底出来的含水物流（ii）富含具有1-10个碳原子，优选2-6个碳原子的有机酸; - 对所述含水物流（ii）进行厌氧生物处理，获得纯化的含水物流（iii）; 其中所述厌氧生物处理水力停留时间低于15小时，优选4小时至10小时，更优选5小时至8小时进行。

5. 发明申请

WO2012052368A1 PROCESS FOR THE PRODUCTION OF LIPIDS FROM BIOMASS 审中-公开
标题翻译：从生物量生产脂肪的方法
公开(公告)号：WO2012052368A1
公开(公告)日：2012-04-26
申请号：PCT/EP2011/068043
申请日：2011-10-14
申请人： Eni S.p.A. , FRANZOSI, Giuliana , PIZZA, Francesca , CUCCHETTI, Daniela , BIANCHI, Daniele , COMPAGNO, Concetta Maria , GALAFASSI, Silvia , UNIVERSITA'DEGLI STUDI DI MILANO
发明人： FRANZOSI, Giuliana , PIZZA, Francesca , CUCCHETTI, Daniela , BIANCHI, Daniele , COMPAGNO, Concetta Maria , GALAFASSI, Silvia
IPC分类号： C12P7/64
CPC分类号： C12P7/64 , C10L1/026 , C10L2290/26 , C10L2290/548 , C12P7/6463 , C12P2203/00 , Y02E50/13
摘要： Process for the production of lipids from biomass comprising polysaccharides. The biomass is subjected to acid hydrolysis to obtain a solid phase and an aqueous phase. The solid phase is subjected to acid or to enzymatic hydrolysis obtaining a further solid phase and a further aqueous phase. The aqueous phases obtained from both hydrolysis steps are subjected to fermentation with an oleaginous yeast. The obtained fermentation broth comprises oleaginous cellular biomass which is subjected to microfiltration for the isolation of lipids. Said lipids can be used in the production of biodiesel or green diesel.
摘要翻译：用于从包含多糖的生物质生产脂质的方法。将生物质进行酸水解，得到固相和水相。将固相进行酸或酶水解，得到另外的固相和另外的水相。从两个水解步骤获得的水相用含油酵母进行发酵。所获得的发酵液包含油细胞生物质，其经过微量过滤以分离脂质。所述脂质可用于生产生物柴油或绿色柴油。

6. 发明申请

WO2011128741A1 PROCESS FOR THE PRODUCTION OF BIO-OIL FROM MUNICIPAL SOLID WASTE 审中-公开
标题翻译：生物油从城市固体废物生产的过程
公开(公告)号：WO2011128741A1
公开(公告)日：2011-10-20
申请号：PCT/IB2011/000693
申请日：2011-03-30
申请人： ENI S.P.A. , BOSETTI, Aldo , FRANZOSI, Giuliana
发明人： BOSETTI, Aldo , FRANZOSI, Giuliana
IPC分类号： C10G1/02 , C02F1/28 , C02F3/34
CPC分类号： C12P7/6409 , C02F1/281 , C02F1/42 , C02F3/28 , C02F3/341 , C02F3/347 , C02F11/18 , C02F2301/066 , C02F2303/10 , C10G1/02 , C10G2300/1011 , C10G2300/1014 , C10L3/08 , C10L5/46 , Y02E50/10 , Y02E50/30 , Y02E50/343 , Y02P30/20 , Y02W10/30 , Y02W10/37
摘要： A process for the production of bio-oil from municipal solid waste, comprising the following steps: a) subjecting said municipal solid waste to liquefaction obtaining a mixture including an oily- phase consisting of bio-oil, a solid phase and a first aqueous phase; b) subjecting the first aqueous phase obtained in the liquefaction step a) to a treatment with at least one adsorbing material obtaining a second aqueous phase; c) subjecting the second aqueous phase obtained in the treatment step b) with at least one adsorbing material to fermentation obtaining a biomass; d) subjecting the biomass obtained in the fermentation step c) to said liquefaction step a). The bio-oil (or bio-crude) thus obtained can be advantageously used in the production of biofuels which can be used as such or mixed with other fuels for motor vehicles. Alternatively, said bio-oil (or bio-crude) can be used as such (biocombustible) or mixed with fossil combustibles (combustible oil, coal, etc.) for the generation of electric energy or heat.
摘要翻译：一种从城市固体废物生产生物油的方法，包括以下步骤：a）对所述城市固体废物进行液化，得到包括由生物油，固相和第一水相组成的油相的混合物 ; b）使在液化步骤a）中获得的第一水相用至少一种获得第二水相的吸附材料进行处理; c）使处理步骤b）中获得的第二水相与至少一种吸附材料进行发酵获得生物质; d）使在发酵步骤c）中获得的生物质经历所述液化步骤a）。由此获得的生物油（或生物粗品）可以有利地用于生产生物燃料，其可以原样使用或与机动车辆的其它燃料混合。或者，所述生物油（或生物粗品）可以原样使用（生物燃烧）或与化石可燃物（可燃油，煤等）混合以产生电能或热量。

7. 发明申请

WO2010069516A3 PROCESS FOR THE PRODUCTION OF BIO-OIL FROM BIOMASS 审中-公开
标题翻译：从生物量生产生物油的工艺
公开(公告)号：WO2010069516A3
公开(公告)日：2011-06-30
申请号：PCT/EP2009008862
申请日：2009-12-10
申请人： ENI SPA , BIANCHI DANIELE , ROMANO ANNA MARIA , FRANZOSI GIULIANA , BOSETTI ALDO
发明人： BIANCHI DANIELE , ROMANO ANNA MARIA , FRANZOSI GIULIANA , BOSETTI ALDO
IPC分类号： C12P7/64
CPC分类号： C12P7/6463
摘要： Process for the production of bio-oil from biomass comprising: - subjecting said biomass to acid hydrolysis in the presence of an aqueous solution of at least one organic acid selected from alkyl- or aryl-sulfonic acids having from C7 to C20 carbon atoms, or from halogenated carboxylic acids, at a temperature ranging from 80 °C to 160 °C, obtaining a first mixture comprising a first solid phase and a first aqueous phase; - subjecting said first mixture to enzymatic hydrolysis, obtaining a second mixture comprising a second solid phase and a second aqueous phase; - subjecting said second aqueous phase to fermentation in the presence of at least one oleaginous yeast, obtaining an aqueous suspension comprising cells of said oleaginous yeast; - subjecting said aqueous suspension to thermal treatment obtaining an oily phase comprising bio-oil and a third aqueous phase. The bio-oil thus obtained can be advantageously used in the production of biofuels.
摘要翻译：用于从生物质生产生物油的方法，包括： - 在至少一种选自具有C7至C20碳原子的烷基 - 或芳基 - 磺酸的有机酸的水溶液存在下使所述生物质进行酸水解，或从卤代羧酸，在80℃至160℃的温度范围内，获得包含第一固相和第一水相的第一混合物; - 对所述第一混合物进行酶水解，得到包含第二固相和第二水相的第二混合物; - 在至少一种含油酵母的存在下对所述第二水相进行发酵，得到包含所述含油酵母细胞的含水悬浮液; - 对所述水性悬浮液进行热处理，获得包含生物油和第三水相的油相。由此获得的生物油可有利地用于生物燃料的生产。

8. 发明申请

WO2010046051A3 PROCESS FOR THE PRODUCTION OF LIPIDS FROM BIOMASS 审中-公开
标题翻译：从生物质生产脂质的方法
公开(公告)号：WO2010046051A3
公开(公告)日：2010-08-26
申请号：PCT/EP2009007388
申请日：2009-10-14
申请人： ENI SPA , BIANCHI DANIELE , FRANZOSI GIULIANA , ROMANO ANNA MARIA
发明人： BIANCHI DANIELE , FRANZOSI GIULIANA , ROMANO ANNA MARIA
IPC分类号： C12P7/64 , C11B1/02 , C11B1/06 , C12P19/02 , C12P19/14 , C13K1/02 , D21C3/04
CPC分类号： C12P7/649 , C10L1/026 , C11B1/025 , C11B1/06 , C11C3/003 , C12P7/6463 , C12P19/02 , C12P19/14 , C12P2201/00 , C13K1/02 , D21C3/04 , D21C11/0007 , Y02E50/13
摘要： A process for the production of lipids from biomass including at least one polysaccharide comprising: subjecting said biomass to acid hydrolysis in the presence of an aqueous solution of at least one organic acid selected from alkyl- or aryl-sulfonic acids having from C7 to C20 carbon atoms, preferably from C9 to C15 carbon atoms, or from halogenated carboxylic acids, at a temperature ranging from 80°C to 160°C, preferably from 100°C to 150°C, obtaining a first mixture comprising a first solid phase and a first aqueous phase; - subjecting said first mixture to enzymatic hydrolysis obtaining a second mixture comprising a second solid phase and a second aqueous phase; subjecting said second aqueous phase to fermentation in the presence of at least one oleaginous yeast obtaining an oleaginous cellular biomass comprising lipids. The lipids thus obtained can be advantageously used in the production of biodiesel or green diesel which can be used as such, or in a mixture with other fuels for motor vehicles.
摘要翻译：由生物质生产脂质的方法，所述生物质包括至少一种多糖，所述方法包括：使所述生物质在选自具有C7至C20碳的烷基 - 或芳基 - 磺酸的至少一种有机酸的水溶液存在下进行酸水解原子，优选C9-C15的碳原子或由卤代羧酸在80℃至160℃，优选100℃至150℃的温度下反应，获得包含第一固相和第一固相的第一混合物第一水相; - 使所述第一混合物进行酶水解，获得包含第二固相和第二水相的第二混合物; 使所述第二水相在至少一种含油酵母存在下进行发酵，获得包含脂质的含油细胞生物质。由此获得的脂质可以有利地用于生产生物柴油或绿色柴油，所述生物柴油或绿色柴油可以原样使用，或与其他汽车燃料混合使用。

9. 发明申请

WO2010069516A2 PROCESS FOR THE PRODUCTION OF BIO-OIL FROM BIOMASS 审中-公开
标题翻译：从生物量生产生物油的方法
公开(公告)号：WO2010069516A2
公开(公告)日：2010-06-24
申请号：PCT/EP2009/008862
申请日：2009-12-10
申请人： ENI S.P.A. , BIANCHI, Daniele , ROMANO, Anna Maria , FRANZOSI, Giuliana , BOSETTI, Aldo
发明人： BIANCHI, Daniele , ROMANO, Anna Maria , FRANZOSI, Giuliana , BOSETTI, Aldo
IPC分类号： C12P7/64
CPC分类号： C12P7/6463
摘要： Process for the production of bio-oil from biomass including at least one polysaccharide comprising: subjecting said biomass to acid hydrolysis in the presence of an aqueous solution of at least one organic acid selected from alkyl- or aryl-sulf onic acids having from C 7 to C 20 carbon atoms, preferably from C 9 to C 15 carbon atoms, or from halogenated carboxylic acids, at a temperature ranging from 80 °C to 160 °C, preferably from 100 °C to 150 °C, obtaining a first mixture comprising a first solid phase and a first aqueous phase; subjecting said first mixture to enzymatic hydrolysis, obtaining a second mixture comprising a second solid phase and a second aqueous phase; subjecting said second aqueous phase to fermentation in the presence of at least one oleaginous yeast, obtaining an aqueous suspension comprising cells of said oleaginous yeast; subjecting said aqueous suspension to thermal treatment obtaining an oily phase comprising bio-oil and a third aqueous phase. The bio-oil thus obtained can be advantageously used in the production of biofuels which can be used as such, or in a mixture with other fuels, for motor vehicles. Or, said bio-oil can be used as such (bio-combustible), or in a mixture with fossil combustibles (combustible oil, lignite, etc.), for the generation of electric energy or heat.
摘要翻译：用于从包括至少一种多糖的生物质生产生物油的方法，包括：在至少一种选自具有C7的烷基或芳基 - 磺酸的有机酸的水溶液存在下使所述生物质进行酸水解， C20碳原子，优选C9至C15碳原子，或卤代羧酸，在80℃至160℃，优选100℃至150℃的温度下，获得包含第一固相和第一水相; 使所述第一混合物进行酶水解，得到包含第二固相和第二水相的第二混合物; 在至少一种含油酵母的存在下对所述第二水相进行发酵，得到包含所述含油酵母的细胞的水性悬浮液; 使所述水性悬浮液经受热处理，得到包含生物油和第三水相的油相。由此获得的生物油可以有利地用于生产可以直接使用的生物燃料，或与其它燃料的混合物用于机动车辆。或者，所述生物油可以原样使用（生物可燃），也可以与化石可燃物（易燃油，褐煤等）混合使用，以产生电能或热量。

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