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    • 3. 发明申请
    • POLYETHYLENE IMINE BASED DENDRITIC DISPERSANT
    • 聚乙烯基尼龙分散剂
    • WO2008037612A1
    • 2008-04-03
    • PCT/EP2007/059766
    • 2007-09-17
    • CIBA SPECIALTY CHEMICALS HOLDING INC.KOU, HuiguangYU, HaiyangLIU, YanfeiHU, Weiqiu
    • KOU, HuiguangYU, HaiyangLIU, YanfeiHU, Weiqiu
    • B01F17/00C08G83/00C09B67/00C09D17/00C09D7/02C09C3/10C09C3/08B01J13/00
    • B01F17/005B01J13/0034C09B67/0085C09C3/08C09D7/45
    • The invention relates to a liquid dispersant of the Formula (I) wherein T is selected from a polyethylene imine (PEI) or modified PEI moiety, polyvinylamine (PVA) or modified PVA, or polyallylamine (PAA) or modified PAA. B is a branched monomer selected from a monofunctional carboxylic acid moiety having at least two hydroxyl groups or a monofunctional carboxylic acid moiety having at least two hydroxyl groups wherein one or more of the hydroxyl groups are hydroxyalkyl substituted, R 1 and R 2 independently of one another are hydrophobic groups selected from a saturated or unsaturated fatty acid moiety with 3-24 carbon atoms, a monofunctional carboxylic acid moiety or a polymer moiety containing C 3 -C 24 alkyl (hydroxyl)carboxylic acid moieties with MW ranges from 100 to 10,000g/mol, X is B with -OH terminal group, or R 1 or R 2 , q is a number between 5 - 2000, with the proviso that q is less than the sum of all amine groups of PEI,PVA, PAA. n is a number of 1 - 6.
    • 本发明涉及式(I)的液体分散剂,其中T选自聚乙烯亚胺(PEI)或改性PEI部分,聚乙烯胺(PVA)或改性PVA,或聚烯丙胺(PAA)或改性PAA。 B是选自具有至少两个羟基的单官能羧酸部分或具有至少两个羟基的单官能羧酸部分的支链单体,其中一个或多个羟基被羟基烷基取代,R 1 >和R 2彼此独立地是选自具有3-24个碳原子的饱和或不饱和脂肪酸部分的疏水基团,单官能羧酸部分或含有C 3的聚合物部分, MW为100至10,000g / mol的烷基(羟基)羧酸部分,X为具有-OH端基的B,或R 1' 或R 2,q是5至2000之间的数,条件是q小于PEI,PVA,PAA的所有胺基的总和。 n是1到6的数字。
    • 4. 发明申请
    • PERFLUOROALKYL SUBSTITUTED PHENOL DERIVATIVES AS SURFACE MODIFIERS
    • 全氟烷基取代的苯酚衍生物作为表面改性剂
    • WO2008028845A1
    • 2008-03-13
    • PCT/EP2007/058954
    • 2007-08-29
    • CIBA SPECIALTY CHEMICALS HOLDING INC.GERSTER, MichèleMIHALIC, Manuel
    • GERSTER, MichèleMIHALIC, Manuel
    • C07C43/205C07C43/225C07C69/63C07C69/712C07C271/44C07C271/58C07C323/16
    • C07C69/82C07C43/225C07C43/23C07C43/315C07C69/63C07C69/65C07C69/712C07C235/20C07C271/44C07C271/58C07C323/16C08K5/06C08K5/10C08K5/136C08K5/205C08K5/375
    • The instant invention relates to a composition comprising a) an organic material which is susceptible to oxidative, thermal or light-induced degra- dation, and b) at least one compound of the formula (I) wherein the general symbols are as defined in claim 1; especially wherein at least one of the radicals R 2 , R 3 or R 4 is is -CH 2 -CH(CH 3 )-S(O) p -R 12 , -CH 2 -CH 2 -CH 2 -S(O) p -R 12 , -CH 2 -CH(R 11 )-CH 2 -R 12 or -CH 2 -CH=CH-R 12 , R 11 is hydrogen or halogen, R 12 is a monovalent perfluorinated alkyl or alkenyl, linear or branched organic radical having four to twenty fully fluorinated carbon atoms; or -CH 2 CH 2 (CF 2 ) m CF 3 , m is 3 to 12, and p is 0, 1 or 2. The compounds of the formula I are useful as reducers of surface energy for organic mat- erials, for example synthetic polymer. Polymers with such a reduced surface energy possess an "easy-to-clean", "self-cleaning" "antisoiling", "soil-release" "antigraffiti", "oil resistance", "solvent resistance", "chemical resistance", "self lubricating", "scratch resistance", "low moi- sture absorption", "dirt pickup resistance", "slip properties" and "hydrophobic surface"; and anti-adhesion properties against proteins and against microorganism such as for example bacteria, fungi and algae.
    • 本发明涉及一种组合物,其包含a)对氧化,热或光诱导的降解敏感的有机材料,以及b)至少一种式(I)化合物,其中通式如权利要求中所定义 1; 特别是其中基团R 2,R 3或R 4中的至少一个为-CH 2 - CH(CH 3 3)-S(O)p -R 12,-CH 2 -CH 2 -CH 2 -S(O)p -R 12,-CH 2 -CH(R 11) - CH 2 -R 12或-CH 2 -CH = CH-R R 12是氢或卤素,R 12是单价全氟化的烷基或烯基,直链或支链的有机基团,其具有四至二十个完全 氟化碳原子; 或-CH 2 CH 2(CF 2)m CF 3,m,m 为3至12,p为0,1或2.式I的化合物可用作有机物的表面能的还原剂,例如合成聚合物。 具有这种表面能降低的聚合物具有“易清洁”,“自清洁”“防污”,“释放”,“防刮涂”,“耐油性”,“耐溶剂性”,“耐化学性” “自润滑”,“耐擦伤性”,“低吸湿性”,“抗污性”,“滑爽性”和“疏水性表面”; 和抗蛋白质和抗微生物(例如细菌,真菌和藻类)的抗粘附性。
    • 6. 发明申请
    • USE OF AMINOPHENYLBENZOTRIAZOLE DERIVATIVES FOR PROTECTING HUMAN AND ANIMAL SKIN AND HAIR FROM THE HARMFUL EFFECTS OF UV RADIATION AND COSMETIC COMPOSITIONS THEREOF
    • 用于保护人类和动物皮肤和毛发的氨基茚并苯并噻唑衍生物从紫外线辐射及其化妆品组合物的有害作用中的应用
    • WO2008012304A1
    • 2008-01-31
    • PCT/EP2007/057614
    • 2007-07-24
    • CIBA SPECIALTY CHEMICALS HOLDING INC.WAGNER, Barbara
    • WAGNER, Barbara
    • A61K8/49A61Q5/00A61Q17/04
    • A61K8/496A61Q5/00A61Q17/04A61Q19/08
    • Disclosed are-(2'-Hydroxy-4'-aminophenyl)benzotriazole derivatives of formula (1), wherein R 1 and R 4 independently of each other are hydrogen; C 1 -C 28 alkyl; C 1 -C 28 alkoxy; C 2 -C 28 al- kenyl; C 2 -C 28 alkinyl; C 3 -C 12 cycloalkyl; C 3 -C 12 cycloalkenyl; C 7 -C 28 aralkyl; C 1 -C 20 hetero- alkyl; C 3 -C 12 cycloheteroalkyl; or C 5 -C 16 heteroaralkyl; and wherein C 1 -C 28 alkyl, C 1 -C 28 al- koxy, C 2 -C 28 alkenyl and C 2 -C 28 alkinyl are unsubstituted or may be substituted by at least one C 1 -C 5 alkyl, C 1 -C 5 alkoxy or hydroxy; R 2 and R 3 independently of each other are hydrogen; C 1 -C 28 alkyl; C 2 -C 28 alkenyl; C 2 -C 22 alki- nyl; C 3 -C 12 cycloalkyl; C 3 -C 12 cycloalkenyl; C 7 -C 28 aralkyl; C 1 -C 20 heteroalkyl; C 3 -C 12 cyclo- heteroalkyl; C 5 -C 16 heteroaralkyl; and wherein C 1 -C 28 alkyl, C 1 -C 28 alkoxy, C 2 -C 28 alkenyl and C 2 -C 28 alkinyl are unsubstituted or may be substituted by at least one C 1 -C 5 alkyl, C 1 - C 5 alkoxy or hydroxy; or CO-R 5 ; or R 2 and R 3 together together with the linking nitrogen form a 5- to 7-membered, monocyclic, carbocyclic or heterocyclic ring; R 5 is C 1 -C 28 alkyl; C 2 -C 28 alkenyl; C 2 -C 28 alkinyl; C 3 -C 12 cycloalkyl; C 3 -C 12 cycloalkenyl; C 7 -C 20 aralkyl; C 1 -C 20 heteroalkyl; C 3 -C 12 cycloheteroalkyl; C 1 -C 5 alkoxycarbonyl-C 1 - C 5 alkyl; or C 5 -C 16 heteroaralkyl; for protecting human and animal hair and skin from harmful effects of UV radiation.
    • 公开的式(1)的(2'-羟基-4'-氨基苯基)苯并三唑衍生物,其中R 1和R 4彼此独立地是氢; ç 1 -C 28 烷基; ç 1 -C 28 烷氧基; C 2 -C 28亚烯基; ç 2 -C 28 炔基; ç 3 -C 12 环烷基; ç 3 -C 12 环烯基; C 7 -C 28芳烷基; C 1 -C 20 - 杂 - 烷基; ç 3 -C 12 环; 或C 5 -C 16 - 杂芳烷基; 并且其中C 1 -C 28烷基,C 1 -C 28烷氧基,C 1 -C 12烷基,C 1 -C 12烷基, C 2 -C 12烷基和C 2 -C 28炔基是未取代的或可被至少一个C 1 -C 28 烷基; C 2 -C 28链烯基; C 2 -C 22烷基; ç 3 -C 12 环烷基; ç 3 -C 12 环烯基; C 7 -C 28芳烷基; C 1 -C 20杂烷基; C 3 -C 12环杂烷基; ç 5 -C 16 杂芳烷基; 并且其中C 1 -C 28烷基,C 1 -C 28烷氧基,C 2 -C 12烷基, C 1 -C 28烷基和C 2 -C 28炔基是未取代的或可以被至少一个C 1〜 C 1 -C 5烷基,C 1 -C 5烷氧基或羟基; C 1 -C 5烷基,C 1 -C 5烷基,C 1 -C 5烷基, 或CO-R 5; 或R 2和R 3 3与连接氮一起形成5-至7-元单环,碳环或杂环; R 5是C 1 -C 28烷基; ç 2 -C 28 烯基; ç 2 -C 28 炔基; ç 3 -C 12 环烷基; ç 3 -C 12 环烯基; ç 7 -C 20 芳烷基; C 1 -C 20杂烷基; C 3 -C 12环杂烷基; C 1 -C 5烷氧基羰基-C 1 -C 5烷基; C 1 -C 5烷基; 或C 5 -C 16 - 杂芳烷基; 用于保护人体和动物毛发和皮肤免受紫外线辐射的有害影响。
    • 9. 发明申请
    • REVERSIBLY THERMOCHROMIC COMPOSITIONS
    • 可逆热敏成分
    • WO2007147847A2
    • 2007-12-27
    • PCT/EP2007/056132
    • 2007-06-20
    • CIBA SPECIALTY CHEMICALS HOLDING INC.FISCHER, WalterBASBAS, Abdel-IlahBRUNNER, MartinBENZ, Rolf
    • FISCHER, WalterBASBAS, Abdel-IlahBRUNNER, MartinBENZ, Rolf
    • C09B1/06C09B1/12
    • A reversible thermochromic system comprising a) a compound of the formula (IA) or a tautomer thereof or a compound of the formula (IB) or a tautomer thereof (IA) (IB) wherein R 1 is C 1 -C 18 alkyl, C 2 -C 18 alkenyl, C 3 -C 12 cycloalkyl, C 3 -C 12 cycloalkyl substituted by 1, 2 or 3 C 1 -C 4 alkyl; phenyl, phenyl substituted by 1, 2 or 3 C 1 -C 4 alkyl; or C 7 -C 12 phenylalkyl; R 2 is hydrogen or a group -SO 2 -R; R 3 and R 4 independently of one another are hydrogen, C 1 -C 18 alkyl, C 2 -C 18 alkenyl, C 3 -C 12 cycloalkyl, C 3 -C 12 cycloalkyl substituted by 1, 2 or 3 C 1 -C 4 alkyl; phenyl, phenyl substituted by 1, 2 or 3 C 1 -C 4 alkyl; or C 7 -C 12 phenylalkyl; and R is C 1 -C 18 alkyl, C 2 -C 18 alkenyl, C 3 -C 12 cycloalkyl, C 3 -C 12 cycloalkyl substituted by 1, 2 or 3 C 1 -C 4 alkyl; phenyl, phenyl substituted by 1, 2 or 3 C 1 -C 4 alkyl; or C 7 -C 12 phenylalkyl; and b) a compound containing a group of the formula (III).
    • 一种可逆热变色系统,其包含a)式(IA)化合物或其互变异构体或式(IB)的化合物或其互变异构体(IA)(IB),其中R 1为C C 1 -C 18烷基,C 2 -C 18链烯基,C 3 -C 18烷基,C 1 -C 12烷基, -C 12 - 环烷基,被1,2或3个C 1 -C 3烷基取代的C 3 -C 12环烷基 4 烷基; 苯基,被1,2或3个C 1 -C 4烷基取代的苯基; 或C 7 -C 12苯基烷基; R 2是氢或基团-SO 2 R; R 3和R 4彼此独立地是氢,C 1 -C 18烷基,C -C 4 烷基; 苯基,被1,2或3个C 1 -C 4烷基取代的苯基; 或C 7 -C 12苯基烷基; 和b)含有式(III)的基团的化合物。
    • 10. 发明申请
    • OXIME SULFONATES AND THE USE THEROF AS LATENT ACIDS
    • OXIME硫酸盐及其作为酸性物质的用途
    • WO2007147782A2
    • 2007-12-27
    • PCT/EP2007/055936
    • 2007-06-15
    • CIBA SPECIALTY CHEMICALS HOLDING INC.YAMATO, HitoshiASAKURA, ToshikageNISHIMAE, YuichiIWAI, TakeshiIRIE, MakikoNAKAYAMA, Kazuhiko
    • YAMATO, HitoshiASAKURA, ToshikageNISHIMAE, YuichiIWAI, TakeshiIRIE, MakikoNAKAYAMA, Kazuhiko
    • G03F7/039G03F7/027C07C309/00G03C1/73
    • G03F7/0045C07C309/00C07C2603/18C08F20/36G03F7/0046G03F7/0397
    • Compounds of the formula (I), (Il) or (III), wherein R 1 is for example C 1 -C 18 alkylsulfonyl, C 1 -C 10 haloalkylsulfonyl, camphorylsulfonyl, phenyl-C 1 -C 3 alkylsulfonyl, phenylsulfonyl, naphthylsulfonyl, anthrylsulfonyl, phenanthrylsulfonyl or heteroarylsulfonyl, R' 1 is for example phenylenedisulfonyl, R 2 is for example CN, C 1 -C 10 haloalkyl or C 1 -C 10 haloalkyl which is substituted by (IV); Ar 1 is for example phenyl optinally substituted by a group of formula (IV); Ar' 1 is for example phenylene which optionally is substituted by a group of formula (IV); A 1 , A 2 and A 3 independently of each other are for example hydrogen, halogen, CN, or C 1 -C 18 alkyl; D 2 is for example a direct bond, O, (CO)O, (CO)S, SO 2 , OSO 2 or C 1 -C 18 alkylene; or A 3 and D 2 together form C 3 -C 30 cycloalkenyl; or A 2 and D 2 together with the carbon of the ethylenically unsaturated double bond to which they are attached form C 3 -C 30 cycloalkyl; D 3 and D 4 for example independently of each other are a direct bond, O, S, C 1 -C 18 alkylene or C 3 -C 30 cycloalkylene provided that at least one of the radicals R 2 , Ar 1 or Ar 1 ' comprises a group of the formula (IV); are suitable as photolatent acid donors and for the preparation of corresponding polymers to be employed in chemically amplified photoresists.
    • 式(I),(II)或(III)的化合物,其中R 1是例如C 1 -C 18烷基磺酰基, C 1 -C 10卤代烷基磺酰基,樟脑磺酰基,苯基-C 1 -C 3烷基磺酰基,苯基磺酰基,萘基磺酰基, 蒽基磺酰基,菲基磺酰基或杂芳基磺酰基,R 1'是例如亚苯基二磺酰基,R 2是例如CN,C 1 -C 10 (IV)取代的卤代烷基或C 1 -C 10 - 卤代烷基; Ar 1是例如被式(IV)基团取代的苯基; Ar'1是例如任选被式(IV)的基团取代的亚苯基; 彼此独立的A 1,A 2,A 3和A 3是例如氢,卤素,CN或C 1〜 SUB> -C 18 烷基; D 2是例如直接键合O,(CO)O,(CO)S,SO 2,OSO 2或C < SUB> 1 -C 18 亚烷基; 或A 3和D 2一起形成C 3〜C 30环烯基; 或者它们所连接的烯属不饱和双键的碳一起形成C 3 -C 3亚烷基, 30 环烷基; D 3和D 4,例如彼此独立地是直接键,O,S,C 1 -C 18, / SUB>亚烷基或C 3 -C 30亚环烷基,条件是基团R 2,Ar 1中的至少一个, 或者是式(Ⅳ)所示的基团。 适合作为光潜酸供体,并用于制备用于化学放大光致抗蚀剂的相应聚合物。