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11. 发明申请

WO2008037635A1 PHOTOLATENT BASES FOR SYSTEMS BASED ON BLOCKED ISOCYANATES 审中-公开
标题翻译：基于堵塞的异氰酸酯的系统的光致抗体基础
公开(公告)号：WO2008037635A1
公开(公告)日：2008-04-03
申请号：PCT/EP2007/059865
申请日：2007-09-19
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , STUDER, Katia , DIETLIKER, Kurt , JUNG, Tunja
发明人： STUDER, Katia , DIETLIKER, Kurt , JUNG, Tunja
IPC分类号： C08G18/67
CPC分类号： C08G18/8093 , C08G18/2063 , C08G18/42 , C08G18/792 , C09D5/002 , C09D5/033 , C09D5/4465 , C09D7/63 , C09D11/03 , C09D175/04 , C09J175/04
摘要： The present invention pertains to a composition comprising (a) a photolatent base; (b) a blocked isocyanate or blocked isothiocyanate and (c) a hydrogen donor compound; and its applications.
摘要翻译：本发明涉及一种组合物，其包含（a）光致变色基材; （b）封端的异氰酸酯或封闭的异硫氰酸酯和（c）氢供体化合物; 及其应用。

12. 发明申请

WO2006008251A2 PROCESS FOR THE PHOTOACTIVATION AND USE OF A CATALYST BY AN INVERTED TWO-STAGE PROCEDURE 审中-公开
标题翻译：通过反向两阶段程序进行光催化和使用催化剂的方法
公开(公告)号：WO2006008251A2
公开(公告)日：2006-01-26
申请号：PCT/EP2005/053299
申请日：2005-07-11
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , BENKHOFF, Johannes , JUNG, Tunja , VALET, Andreas , DIETLIKER, Kurt , SITZMANN, Eugene Valentine
发明人： BENKHOFF, Johannes , JUNG, Tunja , VALET, Andreas , DIETLIKER, Kurt , SITZMANN, Eugene Valentine
IPC分类号： B01J31/06
CPC分类号： B01J31/0239 , B01J31/0205 , B01J31/0217 , B01J31/0234 , B01J31/0268 , B01J31/06 , C08G18/10 , C08G18/2018 , C08G18/2063 , C08G18/4812 , C08G18/62 , C08G18/792 , C08G59/4064 , C08G59/686 , C08G2101/0008 , C08G2101/0083 , C09D11/101 , C09D163/00 , C09D175/04 , C09J163/00 , C09J175/04 , G03F7/0045 , C08G18/48
摘要： The invention pertains to a process for the application of a specific photolatent catalyst (a) wherein a composition of matter, comprising said catalyst, is subjected to irradiation before being further processed.
摘要翻译：本发明涉及施加特定的潜光催化剂（a）的方法，其中包含所述催化剂的物质组合物在进一步处理之前经受辐射。

13. 发明申请

WO2003074466A2 NEW REACTIVE DILUENTS AND NEW ALKYD RESIN COATING COMPOSITIONS 审中-公开
标题翻译：新的反应性稀释剂和新的碱性树脂涂料组合物
公开(公告)号：WO2003074466A2
公开(公告)日：2003-09-12
申请号：PCT/EP2003/001899
申请日：2003-02-25
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , PRETÔT, Roger , MÜHLEBACH, Andreas , PETER, Wolfgang , DIETLIKER, Kurt , JUNG, Tunja , AUSCHRA, Clemens , KIRNER, Hans, Jörg , VAN DER SCHAAF, Paul, Adriaan
发明人： PRETÔT, Roger , MÜHLEBACH, Andreas , PETER, Wolfgang , DIETLIKER, Kurt , JUNG, Tunja , AUSCHRA, Clemens , KIRNER, Hans, Jörg , VAN DER SCHAAF, Paul, Adriaan
IPC分类号： C07C69/54
CPC分类号： C09D11/101 , C07C13/28 , C07C13/44 , C07C33/12 , C07C43/162 , C07C69/007 , C07C69/54 , C07C69/60 , C07C69/80 , C07C2601/08 , C07C2602/22 , C09D167/08
摘要： The invention relates to new reactive diluents of the formulae (Ia, Ib, Ic, Id, Ie) and to an alkyd coating composition comprising them. In a preferred embodiment R 1 and R 2 are hydrogen; R 3 is (meth)acryloyloxy-methyl or phenyl para substituted by vinyl, R 4 is phenyl or phenyl para substituted by vinyl or (meth)acryloyloxy; or a substituted phenyl residue of the formula -C 6 H 4 CH 2 -W, wherein W is (meth)acryloyloxy, or an aliphatic residue of the formula -CH 2 -Y-A, wherein Y is a bond, O-C 1 -C 12 alkylene, wherein the alkylene linker is linear or branched and may be interrupted once or more than once by oxygen, A is hydroxy, C 1 -C 6 alkoxy, acetoxy, (meth)acryloyloxy, or a phthalate- or maleate-residue; R 5 is hydrogen; n is 1; X is -(CH 2 )-. The invention further relates to a solvent-based or water-based alkyd coating composition comprising 0.3 to 10 wt. % of a mono-, bis- or trisacylphosphinoxide photoinitiator, especially Irgacure 819.
摘要翻译：本发明涉及式（Ia，Ib，Ic，Id，Ie）的新型反应性稀释剂和包含它们的醇酸树脂涂料组合物。在优选的实施方案中，R 1和R 2是氢; R3是（甲基）丙烯酰氧基 - 甲基或被乙烯基取代的对苯基，R4是苯基或对乙苯基或（甲基）丙烯酰氧基取代的苯基; 或式-C6H4CH2-W的取代苯基残基，其中W是（甲基）丙烯酰氧基，或式-CH2-YA的脂族残基，其中Y是一个键，O-C1-C12亚烷基，其中亚烷基接头是直链或支链，并且可以被氧中断一次或多于一次，A是羟基，C 1 -C 6烷氧基，乙酰氧基，（甲基）丙烯酰氧基或邻苯二甲酸酯或马来酸酯残基; R5是氢; n为1; X是 - （CH 2） - 。本发明还涉及一种溶剂型或水性醇酸涂料组合物，其包含0.3至10wt。％的单，双或三酰基次膦酰基光引发剂，特别是Irgacure 819。

14. 发明申请

WO2004108799A1 NOVEL SURFACE-ACTIVE POLYSILOXANE PHOTOINITIATORS 审中-公开
标题翻译：新型表面活性聚硅氧烷光敏剂
公开(公告)号：WO2004108799A1
公开(公告)日：2004-12-16
申请号：PCT/EP2004/050952
申请日：2004-05-28
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ROGERS, Jonathan , BAUDIN, Gisèle , JUNG, Tunja , ÖHRLEIN, Reinhold , BAISCH, Gabriele
发明人： ROGERS, Jonathan , BAUDIN, Gisèle , JUNG, Tunja , ÖHRLEIN, Reinhold , BAISCH, Gabriele
IPC分类号： C08G77/38
CPC分类号： G03F7/029 , C08F2/50 , C08G77/38 , G03F7/0007 , G03F7/001 , G03F7/0037 , G03F7/0757
摘要： Polymeric photoinitiators of the formula I or II wherein n and m independently of one another are 3-5; o is 10-16; p is 4-8; R is phenyl-CO-CO-O-; Y and Y' independently of one another are C 1 -C 10 alkylene or -[(CH 2 ) a -O-(CH 2 ) b ] c - wherein a is 2-10, b is 0-10, c is 1-3; with the proviso that they are, however, at least 1 if the methylene group in question is between two oxygen atoms.
摘要翻译：其中n和m彼此独立的式I或II的聚合物光引发剂为3-5; o是10-16; p为4-8; R是苯基-CO-CO-O-; Y和Y'彼此独立地是C 1 -C 10亚烷基或 - [（CH 2）a -O-（CH 2）b] c - ，其中a是2-10，b是0-10，c是1-3; 但是，如果所讨论的亚甲基在两个氧原子之间，则它们至少为1。

15. 发明申请

WO2003089479A2 CURING OF COATINGS INDUCED BY PLASMA 审中-公开
标题翻译：等离子体涂层的固化
公开(公告)号：WO2003089479A2
公开(公告)日：2003-10-30
申请号：PCT/EP2003/004036
申请日：2003-04-17
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , MISEV, Ljubomir , VALET, Andreas , SIMMENDINGER, Peter , JUNG, Tunja
发明人： MISEV, Ljubomir , VALET, Andreas , SIMMENDINGER, Peter , JUNG, Tunja
IPC分类号： C08F2/52
CPC分类号： B05D3/147
摘要： The Application relates to a method of curing various polymerisable compositions, comprising a suitable photoinitiator, the curing being effected by means of a plasma in a plasma discharge chamber.
摘要翻译：本申请涉及一种固化各种可聚合组合物的方法，其包含合适的光引发剂，该固化通过等离子体放电室中的等离子体进行。

16. 发明申请

WO2003089479A3 CURING OF COATINGS INDUCED BY PLASMA 审中-公开
公开(公告)号：WO2003089479A3
公开(公告)日：2003-10-30
申请号：PCT/EP2003/004036
申请日：2003-04-17
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , MISEV, Ljubomir , VALET, Andreas , SIMMENDINGER, Peter , JUNG, Tunja
发明人： MISEV, Ljubomir , VALET, Andreas , SIMMENDINGER, Peter , JUNG, Tunja
IPC分类号： C08F2/52
摘要： The Application relates to a method of curing various polymerisable compositions, comprising a suitable photoinitiator, the curing being effected by means of a plasma in a plasma discharge chamber.

17. 发明申请

WO2005040289A1 REINFORCED COATINGS WITH IMPROVED SCRATCH RESISTANCE 审中-公开
标题翻译：具有改进的耐蚀性的增强涂层
公开(公告)号：WO2005040289A1
公开(公告)日：2005-05-06
申请号：PCT/EP2004/052448
申请日：2004-10-06
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ALBRECHT, Martin , JUNG, Tunja , MÜHLEBACH, Andreas
发明人： ALBRECHT, Martin , JUNG, Tunja , MÜHLEBACH, Andreas
IPC分类号： C09D7/12
CPC分类号： C08K3/01 , C08K3/36 , C09D7/60 , C09D7/61 , C09D7/67 , C09D7/68
摘要： The instant invention discloses a coating composition comprising a) an organic film-forming binder, and b) an inorganic additive of small particle size dispersed in an aqueous or alcoholic solvent prepared by a process which comprises the hydrolysis of a metal alcoholate or a compound of the formula (I) in which R 1 is C 1 -C 8 alkyl, C 5 -C 8 cycloalkyl, phenyl or C 1 -C 4 alkyl substituted phenyl; R 2 is C 1 -C 8 salkyl, and n is 0, 1, 2 or 3; with a base. These coatings for protecting surfaces are reinforced and show improved scratch resistance.
摘要翻译：本发明公开了一种涂料组合物，其包含a）有机成膜粘合剂，和b）分散在水溶液或醇溶剂中的小粒径无机添加剂，该无机添加剂通过以下方法制备，该方法包括水解金属醇化物或 R 1是C 1 -C 8烷基，C 5 -C 8环烷基，苯基或C 1 -C 4烷基取代的苯基的式（I） R2是C1-C8烷基，n是0,1,2或3; 有一个基地。这些用于保护表面的涂层被加强并显示出改善的耐划伤性。

18. 发明申请

WO2004106444A1 PROCESS FOR PREPARING PIGMENT CONCENTRATES FOR USE IN RADIATION-CURABLE COATINGS 审中-公开
标题翻译：用于制备可辐射涂料中使用的颜料浓度的方法
公开(公告)号：WO2004106444A1
公开(公告)日：2004-12-09
申请号：PCT/EP2004/050894
申请日：2004-05-24
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , JUNG, Tunja , HEALY, Thomas , FUCHS, André , BOLLE, Thomas
发明人： JUNG, Tunja , HEALY, Thomas , FUCHS, André , BOLLE, Thomas
IPC分类号： C09D11/10
CPC分类号： C09D11/101 , B41M7/0045 , B41M7/0081 , C08F290/061 , C09B67/006
摘要： A process for preparing pigment concentrates is provided which comprises dispersing a dry pigment in a radiation polymerizable (curable) ethylenically-unsaturated compound. The concentrates to which optionally photoinitiators are added can be used for preparing radiation, preferably ultraviolet radiation, curable printing inks, paints or other coating compositions which in turn are applied in printing processes or in the painting or coating of substrates. The performance enhancement of the cured pigmented inks/paints/ coatings include e.g. good tinctorial strength and gloss, as well as surface hardness, good adhesion to substrate and chemical and corrosion resistance.
摘要翻译：提供了一种制备颜料浓缩物的方法，其包括将干颜料分散在可辐射聚合的（可固化的）烯属不饱和化合物中。添加任选的光引发剂的浓缩物可以用于制备辐射，优选紫外线辐射，可固化的印刷油墨，油漆或其它涂料组合物，这些涂料组合物又被应用于印刷方法或涂料或涂料中。固化的着色油墨/油漆/涂料的性能提高包括例如。良好的着色强度和光泽度，以及表面硬度，对基材的良好粘合性以及耐化学腐蚀性。

19. 发明申请

WO2003066693A1 FLUORINATED PHOTOINITIATORS IN HIGHLY FLUORINATED MONOMERS 审中-公开
标题翻译：高荧光单体中的荧光光敏元件
公开(公告)号：WO2003066693A1
公开(公告)日：2003-08-14
申请号：PCT/EP2003/000818
申请日：2003-01-28
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , BAUDIN, Gisèle , JUNG, Tunja
发明人： BAUDIN, Gisèle , JUNG, Tunja
IPC分类号： C08F220/24
CPC分类号： C08F20/24
摘要： The invention provides photopolymerizable compositions comprising (A) at least one ethylenically unsaturated photopolymerizable fluocarbon compound selected from polyfluoroalkyl monoacrylates, polyfluoroalkyl monomethacrylatesor polyfluoroalkyldiacrylates and (B) at least one photoinitiator of the formula (I) R is a radical of the formula (II) s is a number of 1 to 4, r is a number of 1 to 2; Y is a single bond or is a divalent linker group A if s is 1, is a radical A 0 , where A 0 is C 1 -C3oalkyl, C 1 -C 30 alkenyl, C 1 -C 30 alkynyl or C 1 -C 30 aralkyl the radicals being substituted by at least two fluorine atoms and optionally further substituted by OH-, C 1 -C 4 alkoxy-, phenyl-, naphthyl-, halogen-, CN-, SR 7 -, NR 8 R 9 - and/or -O(CO)R 10 -; and the radical A 0 is uninterrupted or interrupted by one or more -O-, -S- or -NR 12 -; A if s is > 1, is a radical A 1 ; where A 1 is C 1 -C 30 alkylene, C 1 -C 3 oalkenylene, C l -C 3 oalkynylene or C 1 -C 30 aralkylene, the radicals being substituted by at least two fluorine atoms and optionally further substituted by OH-, C 1 -C 4 alkoxy-, phenyl-, naphthyl-, halogen-, CN-, SR 7 -, NR 8 R 9 - and/or -O(CO)R 10 -; and the radical A 1 is uninterrupted or interrupted by one or more -0-, -S- or -NR 12 -.
摘要翻译：本发明提供了可光聚合组合物，其包含A至少一种选自多氟烷基单丙烯酸酯，多氟烷基单甲基丙烯酸酯或多氟烷基二丙烯酸酯和至少一种式IR的光引发剂的烯键式不饱和光聚合性氟化烃化合物，式II的基团是1至4的数，r 是1〜2的数，Y是单键，如果s是1，则为二价连接基团A，为基团A0，其中A0为C1-C3烷基，C1-C30烯基，C1-C30炔基或C1-C30芳烷基，基团为被至少两个氟原子取代并任选进一步被OH - ，C 1 -C 4烷氧基 - ，苯基 - ，萘基 - ，卤素 - ，CN-，SR 7 - ，NR 8 R 9 - 和/或-OCOR 10-取代，并且基团A 0不间断或如果s> 1，则被一个或多个-O - ， - S-或-NR 12 - A中断，是基团A1，其中A 1是C 1 -C 30亚烷基，C 1 -C 30亚烯基，C 1 -C 30亚炔基或C 1 -C 30亚烷基，该基团被取代通过至少两个氟原子和任选的f 还被OH-，C 1 -C 4烷氧基 - ，苯基 - ，萘基 - ，卤素 - ，CN-，SR 7 - ，NR 8 R 9 - 和/或-OCOR 10 - 取代，并且基团A1不间断或被一个或多个-O-， -S-或-NR 12 - 。

20. 发明申请

WO2006051047A1 N-SUBSTITUTED IMIDES AS POLYMERIZATION INITIATORS 审中-公开
标题翻译：作为聚合引发剂的N-取代的咪唑
公开(公告)号：WO2006051047A1
公开(公告)日：2006-05-18
申请号：PCT/EP2005/055646
申请日：2005-10-31
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , NESVADBA, Peter , BENKHOFF, Johannes , BUGNON, Lucienne , POWELL, Karin , JUNG, Tunja
发明人： NESVADBA, Peter , BENKHOFF, Johannes , BUGNON, Lucienne , POWELL, Karin , JUNG, Tunja
IPC分类号： C08F4/00 , C07C239/16 , C07D209/48 , C07D207/40 , C07D221/14
CPC分类号： C07D207/404 , B33Y70/00 , C07D207/46 , C07D209/48 , C07D221/14 , C08F4/00
摘要： The invention relates to novel N-substituted imides and polymerizable compositions com¬ prising these N-substituted imides. The invention further relates to the use of N-substituted imides as polymerization initiators. The imides are compounds of the formula (I) and (II) wherein n is 1 or 2; m is 1 or 2; R 1 and R 2 are each, independently of one another, hydrogen, C 1 -C 18 alkyl, C 1 -C- 18 alkenyl C 6 -C 14 aryl, aralkyl, C 5 -C 12 cycloalkyl, each of which may be substituted by halogen, C 1 -C 4 -alkyl, hydroxy, C 1 -C 6 alkoxy, carbonyl, C 1 -C 6 alkoxycarbonyl; or R 1 and R 2 together with the adjacent -CO-N-CO- group may form a monocyclic, bicyclic or polycyclic ring, said ring having up to 50 non hydrogen atoms and wherein said ring may contain the structural element (formula III) more than once; R 3 if n is 1, is C 1 -C 18 alkyl, C 6 -C 14 aryl, aralkyl, C 5 -C 12 cycloalkyl, OR 10 or SR 11 , NR 12 R 13 ; wherein R 3 if n is 2, is C 2 -C 12 alkylene, C 6 -C 14 arylene, xylylene R 4 and R 5 , correspond to R 1 and R 2 ; R 6 if n is 1, is hydrogen, C 1 -C 18 alkyl, C 6 -C 14 aryl, aralkyl, C 5 -C 12 cycloalkyl, NR 14 R 15 ; wherein R 6 if n is 2, is C 2 -C 12 alkylene, C 6 -C 14 arylene, xylylene; R 7 is hydrogen, C 1 -C 18 alkyl, C 6 -C 14 aryl, aralkyl, C 5 -C 12 cycloalkyl, each of which may be substituted by halogen, C 1 -C 4 -alkyl, hydroxy, C 1 -C 6 alkoxy, carbonyl, C 1 -C 6 alkoxy- carbonyl; or R 7 and R 14 or R 7 and R 15 form together with the N-atom attached to R 7 a 5- 6 membered ring, optionally interrupted by -NH-, -N(C 1 -C 8 alkyl)-, -O- and/or S-atoms.
摘要翻译：本发明涉及新型N-取代的酰亚胺和可聚合的组合物，这些组合物包括这些N-取代的酰亚胺。本发明还涉及N-取代的酰亚胺作为聚合引发剂的用途。酰亚胺是式（I）和（II）的化合物，其中n为1或2; m为1或2; R 1和R 2各自彼此独立地为氢，C 1 -C 18烷基， C 1 -C 18 - 烯基C 6 -C 14芳基，芳烷基，C 5 - 其中每一个可被卤素取代，C 1 -C 4 - C 4 - 烷基，羟基，C 1 -C 12 - 羰基，C 1 -C 6烷氧基羰基，C 1 -C 6烷氧基羰基，C 1 -C 6烷氧基羰基，或R 1和R 2与相邻的-CO-N-CO-基团可以形成单环，双环或多环，所述环具有至多50个非氢并且其中所述环可以多次含有结构元素（式III）; 如果n为1，则R 3为C 1 -C 18烷基，C 6 -C 芳基，芳烷基，C 5 -C 12环烷基，OR 10或SR 11， NR _{12 - [R _{13 ; 如果n为2，其中R 3为C 2 -C 12亚烷基，C 6 -C > 14亚芳基，亚二甲苯基R 4和R 5对应于R 1和R 2， ; 如果n为1，则R 6为氢，C 1 -C 18烷基，C 6 -C 芳基，芳烷基，C 5 -C 12环烷基，NR 14 R 15， ; 如果n为2，其中R 6为C 12 -C 12亚烷基，C 6 -C 亚芳基，亚二甲苯; R 7是氢，C 1 -C 18烷基，C 6 -C 14烷基，C 1 -C 6烷基，芳基，芳烷基，C 5 -C 12环烷基，其各自可以被卤素取代，C 1 -C 12 - 4-烷基，羟基，C 1 -C 6烷氧基，羰基，C 1 -C 6烷基，C 1 -C 6烷基，烷氧基 - 羰基; 或R 7和R 14或R 7和R 15和与R连接的N-原子一起形成任选地被-NH-，-N（C 1 -C 8烷基） - ， - O-（C 1 -C 6）烷基取代的5-6元环， - 和/或S-原子。}}

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