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    • 1. 发明授权
    • Water-soluble AZO compound or salt thereof, ink composition, and colored article
    • 水溶性AZO化合物或其盐,油墨组合物和有色制品
    • US08425676B2
    • 2013-04-23
    • US13266081
    • 2010-04-12
    • Ryoutarou MoritaMitsunori AnanJunya Masegi
    • Ryoutarou MoritaMitsunori AnanJunya Masegi
    • C09D11/02C09B33/12
    • C09B43/16C09D11/328
    • Disclosed are: a yellow dye which has a color phase having a high contrast ratio suitable for inkjet recording, can produce recorded materials having high durability, and can be used for the preparation of an ink composition to provide an ink composition having excellent storage stability; and an ink composition containing the yellow dye. Specifically disclosed are: a water-soluble azo compound represented by formula (1) or a salt thereof; and an ink composition containing the compound or the salt thereof. The ink composition has a color phase and a color saturation suitable for inkjet recording, can produce recorded materials having high durability, particularly high light resistance and ozone gas resistance, and can also produce printed images having excellent storage stability or the like. In the formula, Q represents a halogen atom; R represents a C1-C11 alkylene group; p represents an integer of 2 to 4; and n represents 1 or 2.
    • 公开了具有适用于喷墨记录的高对比度的色相的黄色染料,可以制造具有高耐久性的记录材料,并且可用于制备油墨组合物以提供具有优异储存稳定性的油墨组合物; 和含有黄色染料的油墨组合物。 具体公开的是:由式(1)表示的水溶性偶氮化合物或其盐; 和含有该化合物或其盐的油墨组合物。 油墨组合物具有适用于喷墨记录的色相和色饱和度,可以生产具有高耐久性,特别高的耐光性和耐臭氧气体阻力的记录材料,并且还可以生产具有优异储存稳定性等的印刷图像。 在该式中,Q表示卤原子; R表示C1-C11亚烷基; p表示2〜4的整数, n表示1或2。
    • 6. 发明授权
    • Bis(4-((chloro substituted phenyl)azo)anilino methylenes
    • 双(4 - ((氯代苯基)偶氮)苯胺基亚甲基
    • US4562249A
    • 1985-12-31
    • US707548
    • 1985-03-05
    • Hansrudolf SchwanderRudolf Hurter
    • Hansrudolf SchwanderRudolf Hurter
    • C09B33/06C09B43/02C09B62/44C09B62/523C09B33/02C09B33/12C09B33/16
    • C09B33/06
    • There are described novel yellow to red azo compounds of the formula I ##STR1## wherein each D independently of the other is the radical of an aromatic or heterocyclic diazo component, each Z independently of the other is hydrogen or a C.sub.1 -C.sub.4 -alkyl group or an acylamino group, Y is hydrogen or an unsubstituted or substituted C.sub.1 -C.sub.6 -alkyl group, X is either the direct bond or C.sub.1 -C.sub.6 -alkylene, ##STR2## and n is a number from 2 to 6, preferably 2; and the substituent Y, in the case of an unsubstituted or substituted C.sub.1 -C.sub.6 -alkyl group, can also be bonded to the o-position relative to the N atom of the phenylene group to form a six-membered ring, or both Y substituents can be linked together to form a C.sub.1 -C.sub.6 -alkylene bridge; described also are processes for producing the novel compounds, and their use as dyes for dyeing and printing natural and synthetic textile materials, particularly polyamide and wool materials, and also cotton, whereby there are obtained dyeings which are distinguished by good general fastness properties, especially by a good dye build-up, very good fastness to wet processing, good fastness to light, and good resistance to formaldehyde and good stability to hydrolysis.
    • 描述了式I的新颖的黄色至红色偶氮化合物,其中每个D独立于芳族或杂环重氮组分,每个Z独立地为氢或一个 C 1 -C 4烷基或酰氨基,Y为氢或未取代或取代的C 1 -C 6烷基,X为直接键或C 1 -C 6亚烷基,n为 数字从2到6,最好是2; 并且在未取代或取代的C 1 -C 6 - 烷基的情况下,取代基Y也可以相对于亚苯基的N原子与O位键合,形成六元环,或两个Y取代基 可以连接在一起形成C1-C6-亚烷基桥; 还描述了用于生产新化合物的方法,以及它们作为用于染色和印刷天然和合成纺织材料,特别是聚酰胺和羊毛材料以及棉花的染料的用途,由此获得了具有良好的通用牢度性质的染色,特别是 通过良好的染料积聚,湿加工牢度牢固,耐光牢度好,耐甲醛,水解稳定性好。
    • 7. 发明授权
    • Substituted phenyl disazo dyes containing a 2-amino-substituted thiazole
radical
    • 含有2-氨基取代的噻唑基的取代的苯基二偶氮染料
    • US4483795A
    • 1984-11-20
    • US433887
    • 1982-10-13
    • Heinz EilingsfeldGuenter HansenGuenther SeyboldGeorg Zeidler
    • Heinz EilingsfeldGuenter HansenGuenther SeyboldGeorg Zeidler
    • C09B31/14C09B33/12D06P1/18D06P3/54
    • C09B31/14
    • Compounds of the general formula I ##STR1## where D is the radical of a diazo component,R is hydrogen, hydroxy or unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aralkyl, phenyl or heterocyclic ring,R.sup.1 and R.sup.2 independently of one another are hydrogen or unsubstituted or substituted alkyl, alkenyl, alkynyl, cycloalkyl, aralkyl or aryl, orR.sup.1 and R.sup.2 together with the nitrogen are a saturated heterocyclic 5-membered to 7-membered ring,X is hydrogen, chlorine, bromine, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, allyloxy, .beta.-cyanoethoxy, benzyloxy, phenoxy, .beta.-alkoxycarbonylethoxy, where alkoxy is of 1 to 4 carbon atoms, alkylmercapto of 1 to 4 carbon atoms, phenylmercapto or alkanoylamino of 1 to 4 carbon atoms, andY is chlorine, alkyl of 1 to 4 carbon atoms, allyloxy, alkoxy of 1 to 4 carbon atoms or .beta.-cyanoethoxy, orX and Y together are a fused benzene ring which is unsubstituted or substituted by alkyl alkoxy chlorine or bromine.The compounds are in particular suitable for dyeing cotton and union fabrics of cotton and synthetic fibers, preferably polyesters. The dyeings obtained are, in part, very fast.
    • 通式I的化合物其中D是重氮组分的基团,R是氢,羟基或未取代或取代的烷基,烯基,环烷基,芳烷基,苯基或杂环,R 1和R 2彼此独立地是 氢或未取代或取代的烷基,烯基,炔基,环烷基,芳烷基或芳基,或R 1和R 2与氮一起为饱和杂环5元至7元环,X为氢,氯,溴,1至 4个碳原子的烷氧基,1至4个碳原子的烷氧基,烯丙氧基,β-氰基乙氧基,苄氧基,苯氧基,β-烷氧基羰基乙氧基,其中烷氧基为1至4个碳原子,烷基巯基为1至4个碳原子,苯基巯基或烷酰基氨基为1至 4个碳原子,Y为氯,1至4个碳原子的烷基,烯丙氧基,1至4个碳原子的烷氧基或β-氰基乙氧基,或X和Y一起是未被取代或被烷基烷氧基取代的稠合苯环 或溴。 该化合物特别适用于棉和合成纤维,优选聚酯的棉和联合织物的染色。 所获得的染色部分地非常快。