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1. 发明授权

US4327019A Acid azo dyes from a 3-amino-benzisothiazole-[2,1]-5-sulfonic acid diazo component 失效
标题翻译：来自3-氨基 - 苯并异噻唑 - [2,1] -5-磺酸重氮组分的酸偶氮染料
公开(公告)号：US4327019A
公开(公告)日：1982-04-27
申请号：US973800
申请日：1978-12-28
申请人： Heinz Eilingsfeld , Guenter Hansen , Guenther Seybold , Georg Zeidler
发明人： Heinz Eilingsfeld , Guenter Hansen , Guenther Seybold , Georg Zeidler
IPC分类号： C09B29/045 , C09B29/00 , C09B29/06 , C09B29/095 , C09B29/52 , D06P1/06 , C07C107/04 , C09B29/039
CPC分类号： C09B29/06 , C09B29/0081 , C09B29/065 , C09B29/3665 , D06P1/06
摘要： Acid monoazo dyes of the formula ##STR1## in which X is hydrogen, chloro, bromo, nitro, C.sub.1 to C.sub.4 alkyl, methoxy, ethoxy or C.sub.2 to C.sub.4 alkanoylamino and K is a radical of a coupling compound as defined below. The dyes are suitable for dyeing natural or synthetic polyamides giving colorations with very good fastness properties.
摘要翻译：其中X是氢，氯，溴，硝基，C 1至C 4烷基，甲氧基，乙氧基或C 2至C 4烷酰基氨基并且K是如下所定义的偶合化合物的基团的式IMAMA的酸性单偶氮染料。染料适用于染色具有非常好的牢度特性的天然或合成聚酰胺染色。

2. 发明授权

US4483795A Substituted phenyl disazo dyes containing a 2-amino-substituted thiazole radical 失效
标题翻译：含有2-氨基取代的噻唑基的取代的苯基二偶氮染料
公开(公告)号：US4483795A
公开(公告)日：1984-11-20
申请号：US433887
申请日：1982-10-13
申请人： Heinz Eilingsfeld , Guenter Hansen , Guenther Seybold , Georg Zeidler
发明人： Heinz Eilingsfeld , Guenter Hansen , Guenther Seybold , Georg Zeidler
IPC分类号： C09B31/14 , C09B33/12 , D06P1/18 , D06P3/54
CPC分类号： C09B31/14
摘要： Compounds of the general formula I ##STR1## where D is the radical of a diazo component,R is hydrogen, hydroxy or unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aralkyl, phenyl or heterocyclic ring,R.sup.1 and R.sup.2 independently of one another are hydrogen or unsubstituted or substituted alkyl, alkenyl, alkynyl, cycloalkyl, aralkyl or aryl, orR.sup.1 and R.sup.2 together with the nitrogen are a saturated heterocyclic 5-membered to 7-membered ring,X is hydrogen, chlorine, bromine, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, allyloxy, .beta.-cyanoethoxy, benzyloxy, phenoxy, .beta.-alkoxycarbonylethoxy, where alkoxy is of 1 to 4 carbon atoms, alkylmercapto of 1 to 4 carbon atoms, phenylmercapto or alkanoylamino of 1 to 4 carbon atoms, andY is chlorine, alkyl of 1 to 4 carbon atoms, allyloxy, alkoxy of 1 to 4 carbon atoms or .beta.-cyanoethoxy, orX and Y together are a fused benzene ring which is unsubstituted or substituted by alkyl alkoxy chlorine or bromine.The compounds are in particular suitable for dyeing cotton and union fabrics of cotton and synthetic fibers, preferably polyesters. The dyeings obtained are, in part, very fast.
摘要翻译：通式I的化合物其中D是重氮组分的基团，R是氢，羟基或未取代或取代的烷基，烯基，环烷基，芳烷基，苯基或杂环，R 1和R 2彼此独立地是氢或未取代或取代的烷基，烯基，炔基，环烷基，芳烷基或芳基，或R 1和R 2与氮一起为饱和杂环5元至7元环，X为氢，氯，溴，1至 4个碳原子的烷氧基，1至4个碳原子的烷氧基，烯丙氧基，β-氰基乙氧基，苄氧基，苯氧基，β-烷氧基羰基乙氧基，其中烷氧基为1至4个碳原子，烷基巯基为1至4个碳原子，苯基巯基或烷酰基氨基为1至 4个碳原子，Y为氯，1至4个碳原子的烷基，烯丙氧基，1至4个碳原子的烷氧基或β-氰基乙氧基，或X和Y一起是未被取代或被烷基烷氧基取代的稠合苯环或溴。该化合物特别适用于棉和合成纤维，优选聚酯的棉和联合织物的染色。所获得的染色部分地非常快。

3. 发明授权

US4372885A Bisazo dyes containing a 2-amino-substituted thiazole radical 失效
标题翻译：含有2-氨基取代的噻唑基的双偶氮染料
公开(公告)号：US4372885A
公开(公告)日：1983-02-08
申请号：US931248
申请日：1978-08-04
申请人： Heinz Eilingsfeld , Guenter Hansen , Guenther Seybold , Georg Zeidler
发明人： Heinz Eilingsfeld , Guenter Hansen , Guenther Seybold , Georg Zeidler
IPC分类号： C09B31/14 , D06P1/18 , D06P3/36 , D06P3/54
CPC分类号： C09B31/14
摘要： Compounds of the general formula I ##STR1## where D is the radical of a diazo component,R is hydrogen, hydroxy or unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aralkyl, phenyl or heterocyclic ring,R.sup.1 and R.sup.2 independently of one another are hydrogen or unsubstituted or substituted alkyl, alkenyl, alkynyl, cycloalkyl, aralkyl or aryl, orR.sup.1 and R.sup.2 together with the nitrogen are a saturated heterocyclic 5-membered to 7-membered ring,X is hydrogen, chlorine, bromine, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, allyloxy, .beta.-cyanoethoxy, benzyloxy, phenoxy, .beta.-alkoxycarbonylethoxy, where alkoxy is of 1 to 4 carbon atoms, alkylmercapto of 1 to 4 carbon atoms, phenylmercapto or alkanoylamino of 1 to 4 carbon atoms, andY is chlorine, alkyl of 1 to 4 carbon atoms, allyloxy, alkoxy of 1 to 4 carbon atoms or .beta.-cyanoethoxy, orX and Y together are a fused benzene ring which is unsubstituted or substituted by alkyl, alkoxy, chlorine or bromine.The compounds are in particular suitable for dyeing cotton and union fabrics of cotton and synthetic fibers, preferably polyesters. The dyeings obtained are, in part, very fast.
摘要翻译：通式I的化合物其中D是重氮组分的基团，R是氢，羟基或未取代或取代的烷基，烯基，环烷基，芳烷基，苯基或杂环，R 1和R 2彼此独立地是氢或未取代或取代的烷基，烯基，炔基，环烷基，芳烷基或芳基，或R 1和R 2与氮一起为饱和杂环5元至7元环，X为氢，氯，溴，1至 4个碳原子的烷氧基，1至4个碳原子的烷氧基，烯丙氧基，β-氰基乙氧基，苄氧基，苯氧基，β-烷氧基羰基乙氧基，其中烷氧基为1至4个碳原子，1至4个碳原子的烷基巯基，苯基巯基或烷酰基氨基为1至 4个碳原子，Y为氯，1至4个碳原子的烷基，烯丙氧基，1至4个碳原子的烷氧基或β-氰基乙氧基，或X和Y一起是未被取代或被烷基，烷氧基取代的稠合苯环，氯或溴。该化合物特别适用于棉和合成纤维，优选聚酯的棉和联合织物的染色。所获得的染色部分地非常快。

4. 发明授权

US4250090A 2-Amino-5-arylazoarylazothiazole compounds 失效
标题翻译： 2-氨基-5-芳基氮杂芳基唑类化合物
公开(公告)号：US4250090A
公开(公告)日：1981-02-10
申请号：US24248
申请日：1979-03-27
申请人： Heinz Eilingsfeld , Guenter Hansen , Guenther Seybold , Georg Zeidler
发明人： Heinz Eilingsfeld , Guenter Hansen , Guenther Seybold , Georg Zeidler
IPC分类号： C09B29/36 , C09B31/14 , C09B56/00 , D06P1/39 , D06P3/06 , D06P3/32
CPC分类号： C09B31/14 , C09B29/3691 , C09B56/005
摘要： Acid azo dyes containing thiazole coupling components, of the general formula ##STR1## where D is the radical of a diazo component,R is hydrogen, acetyl, benzoyl or an aliphatic, cycloaliphatic, aromatic or heterocyclic radical,R.sup.1 and R.sup.2 independently of one another are optionally substituted alkyl, cycloalkyl, aralkyl or aryl,R.sup.1 may also be hydrogen andR.sup.1 and R.sup.2 together with the nitrogen may be a heterocyclic radical, andthe radicals D, R, R.sup.1 and/or R.sup.2 may in total contain from 1 to 4 --SO.sub.3 H groups.The deeply colored novel compounds are particularly suitable for dyeing polyamides, and the dyeings obtained have very good lightfastness and wetfastness.
摘要翻译：含有噻唑偶联组分的酸性偶氮染料，通式为其中D为重氮组分的基团，R为氢，乙酰基，苯甲酰基或脂族，脂环族，芳族或杂环基团，R1和R2独立地为一个另一个是任选取代的烷基，环烷基，芳烷基或芳基，R 1还可以是氢，R 1和R 2与氮一起可以是杂环基，基团D，R，R 1和/或R 2可以总共含有1至 4个-SO 3 H基团。深色的新型化合物特别适用于染色聚酰胺，所得染色剂具有非常好的耐光性和耐湿性。

5. 发明授权

US4340537A Monoazo dyes of the thiazole series having a heterocyclic substituent in the 4-position 失效
标题翻译：在4位具有杂环取代基的噻唑系单偶氮染料
公开(公告)号：US4340537A
公开(公告)日：1982-07-20
申请号：US124740
申请日：1980-02-26
申请人： Heinz Eilingsfeld , Guenter Hansen , Guenther Seybold
发明人： Heinz Eilingsfeld , Guenter Hansen , Guenther Seybold
IPC分类号： C09B29/36 , C07C107/04
CPC分类号： C09B29/3691
摘要： Dyes of the thiazole series, having the general formula I ##STR1## where D is the radical of an aromatic diazo component,R is a heterocyclic radical andR.sup.1 and R.sup.2 are hydrogen or unsubstituted or substituted hydrocarbon radicals, which may also together form a ring, which may or may not be heterocyclic.The dyes according to the invention are particularly suitable for dyeing synthetic polyesters.
摘要翻译：噻唑系的染料具有通式I I，其中D是芳族重氮组分的基团，R是杂环基团，R 1和R 2是氢或未取代或取代的烃基，其也可以一起形成环，其可以是也可以不是杂环的。根据本发明的染料特别适用于染色合成聚酯。

6. 发明授权

US4239894A Thiazole derivatives 失效
标题翻译：噻唑衍生物
公开(公告)号：US4239894A
公开(公告)日：1980-12-16
申请号：US920638
申请日：1978-06-29
申请人： Guenther Seybold , Heinz Eilingsfeld
发明人： Guenther Seybold , Heinz Eilingsfeld
IPC分类号： C07D277/20 , C07D277/40
CPC分类号： C07D277/20
摘要： An organic compound of the general formula ##STR1## where R.sup.1 and R.sup.2 are cyano, formyl, substituted or unsubstituted alkanoyl or aroyl, a carboxylic acid ester group, substituted or unsubstituted carbamoyl or sulfamoyl, alkylsulfonyl, arylsulfonyl or alkylsulfinyl, orR.sup.1 and R.sup.2 together may be a cyclic radical,R.sup.2 may also be alkyl, aryl or hetaryl,R.sup.3 is hydrogen, substituted or unsubstituted alkyl, aryl or hetaryl,X is CH, CR.sup.5 or N,R.sup.4 is a radical of the formula ##STR2## R.sup.5 to R.sup.10 are substituents conventionally present in dyes. The compounds may be used as dyes for synthetic and natural fibers and give very fast dyeings.
摘要翻译：其中R 1和R 2为氰基，甲酰基，取代或未取代的烷酰基或芳酰基，羧酸酯基，取代或未取代的氨基甲酰基或氨磺酰基，烷基磺酰基，芳基磺酰基或烷基亚磺酰基，或R 1和R 2在一起的有机化合物可以是环状基团，R 2也可以是烷基，芳基或杂芳基，R 3是氢，取代或未取代的烷基，芳基或杂芳基，X是CH，CR 5或N，R 4是下式的基团： R5至R10是染料中通常存在的取代基。这些化合物可以用作合成和天然纤维的染料，并给出非常快的染色。

7. 发明授权

US4153607A Process for the production of 4,5-disubstituted thiazoles 失效
标题翻译：制备4,5-二取代噻唑的方法
公开(公告)号：US4153607A
公开(公告)日：1979-05-08
申请号：US880883
申请日：1978-02-24
申请人： Heinz Eilingsfeld , Guenther Seybold
发明人： Heinz Eilingsfeld , Guenther Seybold
IPC分类号： C07D277/20 , C07D277/40 , C07D277/48 , C07D277/56 , C07D513/04 , C09B29/042 , C07D417/02
CPC分类号： C07D513/04 , C07D277/56
摘要： 4,5-Disubstituted thiazoles are manufactured by reacting 4-amino-5-cyano-thiazoles with hydrogen sulfide in the presence of basic compounds, followed by dehydrogenating cyclization. The new 3-amino-thiazolo-(4,5-c)-isothiazoles I, 4-amino-5-thiocarbamidothiazoles III and 4,5-disubstituted thiazoles IV obtainable by the process of the invention are valuable intermediates for the manufacture of azo dyes and of crop protection agents.
摘要翻译：通过在碱性化合物的存在下使4-氨基-5-氰基 - 噻唑与硫化氢反应，然后脱氢环化来制备4,5-二取代的噻唑。通过本发明方法获得的新的3-氨基 - 噻唑并（4,5-c） - 异噻唑I，4-氨基-5-硫代氨基甲酰基噻唑III和4,5-二取代噻唑IV是制备偶氮的有价值的中间体染料和作物保护剂。

8. 发明授权

US4407810A Thiazol-2-yl-oxamic acid derivatives, and therapeutic agents containing these compounds 失效
标题翻译：噻唑-2-基 - 恶唑酸衍生物和含有这些化合物的治疗剂
公开(公告)号：US4407810A
公开(公告)日：1983-10-04
申请号：US282661
申请日：1981-07-13
申请人： Heinz Eilingsfeld , Peter Neumann , Guenther Seybold , Dieter Lenke , Ludwig Friedrich
发明人： Heinz Eilingsfeld , Peter Neumann , Guenther Seybold , Dieter Lenke , Ludwig Friedrich
IPC分类号： C07D277/20 , A61K31/425 , A61K31/426 , A61P37/08 , C07D277/44 , C07D277/46
CPC分类号： C07D277/46
摘要： Novel 2-substituted thiazol-2-yl-oxamic acid esters, processes for their preparation, and therapeutic agents which contain these compounds and are useful in the treatment of allergic disorders.
摘要翻译：新的2-取代的噻唑-2-基 - 恶唑酸酯，其制备方法和含有这些化合物并可用于治疗过敏性疾病的治疗剂。

9. 发明授权

US4677199A Reactive dyes containing substituted 4-fluoropyridaz-6-one radicals 失效
标题翻译：含有取代的4-氟哒嗪-6-酮基团的活性染料
公开(公告)号：US4677199A
公开(公告)日：1987-06-30
申请号：US777571
申请日：1985-09-19
申请人： Dietmar Augart , Heinz Eilingsfeld , Heinz Krueger , Hartmut Lardon , Ortwin Schaffer , Guenther Seybold
发明人： Dietmar Augart , Heinz Eilingsfeld , Heinz Krueger , Hartmut Lardon , Ortwin Schaffer , Guenther Seybold
IPC分类号： C09B62/02 , C09B62/12 , C09B62/44 , C09B62/004 , C09B62/006 , C09B62/016 , C09B62/018
CPC分类号： C09B62/02 , C09B62/12 , C09B62/442
摘要： Compounds of the general formula I ##STR1## wherein R.sup.1 is hydrogen, fluorine, chlorine or bromine, R.sup.2 is hydrogen, fluorine, chlorine, bromine, or nitro, B is aliphatic or a sulfo-substituted phenylene radical, and X is a dye radical, are useful for dyeing hydroxyl-containing textile material, in particular cotton.
摘要翻译：通式I的化合物其中R 1是氢，氟，氯或溴，R 2是氢，氟，氯，溴或硝基，B是脂族或磺基取代的亚苯基，X是染料自由基可用于染色含羟基的纺织材料，特别是棉花。

10. 发明授权

US4207233A Azo dyes containing a thiazole component 失效
标题翻译：含有噻唑成分的偶氮染料
公开(公告)号：US4207233A
公开(公告)日：1980-06-10
申请号：US827340
申请日：1977-08-24
申请人： Guenther Seybold , Heinz Eilingsfeld
发明人： Guenther Seybold , Heinz Eilingsfeld
IPC分类号： C09B31/02 , C09B31/16 , C09B62/09 , C09B31/04 , C09B31/08 , C09B31/14
CPC分类号： C09B31/16 , C09B31/02 , C09B31/025 , C09B62/09
摘要： Azo dyes of the formula ##STR1## where A is a radical of a diazo component, B is a radical of a coupling component and R is hydrogen, halogen, a substituted or unsubstituted hydrocarbon radical, substituted or unsubstituted alkoxy or aroxy, or substituted amino. The dyes are eminently suitable for dyeing polyester and particularly for cellulose and blends of cellulose with polyesters.
摘要翻译：其中A是重氮组分的基团的偶氮染料，B是偶合组分的基团，R是氢，卤素，取代或未取代的烃基，取代或未取代的烷氧基或羟基或取代的氨基。这些染料特别适用于染色聚酯，特别是纤维素和纤维素与聚酯的共混物。

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