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    • 1. 发明授权
    • Azo dyes
    • 偶氮染料
    • US4582897A
    • 1986-04-15
    • US605989
    • 1984-05-02
    • Dieter MausezahlRudolf HurterHansrudolf Schwander
    • Dieter MausezahlRudolf HurterHansrudolf Schwander
    • C09B29/03C09B1/34C09B29/01C09B29/08C09B29/085C09B29/40D06P1/06C09B29/036C09B43/02
    • D06P1/06C09B1/343C09B29/0003C09B29/0803C09B29/3613
    • Monoazo dyes of the formula ##STR1## in which K is a radical of the formula ##STR2## or of the formula ##STR3## in which R.sub.1 and R.sub.2 independently of one another is (sic) hydrogen, C.sub.1-4 -alkyl, which can be substituted by halogen, cyano, hydroxyl, carboxyl, sulfo, sulfato, C.sub.1-4 -alkoxy, C.sub.1-4 -alkoxycarbonyl, C.sub.1-4 -alkanoyloxy, phenyl, sulfophenyl and naphthyl, or cyclohexyl, or C.sub.1-4 -alkenyl, which can be substituted by halogen, or phenyl or naphthyl, or in which R.sub.1 and R.sub.2, together with the nitrogen atom connecting them and where relevant with the inclusion of a further hetero-atom, form a heterocyclic 5-membered or 6-membered ring, R.sub.3 is hydrogen, C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy, which can be substituted by hydroxyl and C.sub.1-4 -alkoxy, or C.sub.1-4 -alkanoylamino, or benzoylamino, which can be substituted in the benzene nucleus by methyl, ethyl, methoxy, ethoxy, chlorine, carboxyl and sulfo, or ureido, C.sub.1-4 -alkylsulfonylamino, or phenylsulfonylamino, which can be substituted in the benzene nucleus by methyl, ethyl, methoxy, ethoxy, chlorine, carboxyl and sulfo, or naphthylsulfonylamino, R.sub.4 is methyl or phenyl and R.sub.5 is hydrogen or C.sub.1-8 -alkyl, and in which, if K is the radical of the formula (2), R.sub.3 may not be hydrogen if R.sub.1 or R.sub.2 is benzyl, produce, on polyamide material, dyeings with good light fastness and wet fastness.
    • 式(1)的单偶氮染料其中K是式​​(IMAG)(2)或式(3)的基团,其中R 1和R 2彼此独立地是(sic)氢 可被卤素,氰基,羟基,羧基,磺基,C 1-4 - 烷氧基,C 1-4 - 烷氧基羰基,C 1-4 - 烷酰氧基,苯基,磺苯基和萘基取代的C 1-4 - 烷基或环己基 或可被卤素取代的C 1-4 - 烯基,或苯基或萘基,或其中R 1和R 2与连接它们的氮原子一起并且在与另外的杂原子相连的情况下形成杂环基 5元或6元环,R 3为氢,可被羟基和C 1-4 - 烷氧基取代的C 1-4 - 烷基,C 1-4 - 烷氧基,或C 1-4 - 烷酰基氨基或苯甲酰基氨基,其可以 在苯核中被甲基,乙基,甲氧基,乙氧基,氯,羧基和磺基取代,或在苯核中可被取代的脲基,C 1-4 - 烷基磺酰基氨基或苯基磺酰基氨基 甲基,乙基,甲氧基,乙氧基,氯,羧基和磺基或萘磺酰氨基,R4是甲基或苯基,R5是氢或C1-8烷基,其中如果K是式(2)的基团, 如果R1或R2是苄基,R3可能不是氢,在聚酰胺材料上产生具有良好耐光性和耐湿牢度的染色。
    • 2. 发明授权
    • Bis(4-((chloro substituted phenyl)azo)anilino methylenes
    • 双(4 - ((氯代苯基)偶氮)苯胺基亚甲基
    • US4562249A
    • 1985-12-31
    • US707548
    • 1985-03-05
    • Hansrudolf SchwanderRudolf Hurter
    • Hansrudolf SchwanderRudolf Hurter
    • C09B33/06C09B43/02C09B62/44C09B62/523C09B33/02C09B33/12C09B33/16
    • C09B33/06
    • There are described novel yellow to red azo compounds of the formula I ##STR1## wherein each D independently of the other is the radical of an aromatic or heterocyclic diazo component, each Z independently of the other is hydrogen or a C.sub.1 -C.sub.4 -alkyl group or an acylamino group, Y is hydrogen or an unsubstituted or substituted C.sub.1 -C.sub.6 -alkyl group, X is either the direct bond or C.sub.1 -C.sub.6 -alkylene, ##STR2## and n is a number from 2 to 6, preferably 2; and the substituent Y, in the case of an unsubstituted or substituted C.sub.1 -C.sub.6 -alkyl group, can also be bonded to the o-position relative to the N atom of the phenylene group to form a six-membered ring, or both Y substituents can be linked together to form a C.sub.1 -C.sub.6 -alkylene bridge; described also are processes for producing the novel compounds, and their use as dyes for dyeing and printing natural and synthetic textile materials, particularly polyamide and wool materials, and also cotton, whereby there are obtained dyeings which are distinguished by good general fastness properties, especially by a good dye build-up, very good fastness to wet processing, good fastness to light, and good resistance to formaldehyde and good stability to hydrolysis.
    • 描述了式I的新颖的黄色至红色偶氮化合物,其中每个D独立于芳族或杂环重氮组分,每个Z独立地为氢或一个 C 1 -C 4烷基或酰氨基,Y为氢或未取代或取代的C 1 -C 6烷基,X为直接键或C 1 -C 6亚烷基,n为 数字从2到6,最好是2; 并且在未取代或取代的C 1 -C 6 - 烷基的情况下,取代基Y也可以相对于亚苯基的N原子与O位键合,形成六元环,或两个Y取代基 可以连接在一起形成C1-C6-亚烷基桥; 还描述了用于生产新化合物的方法,以及它们作为用于染色和印刷天然和合成纺织材料,特别是聚酰胺和羊毛材料以及棉花的染料的用途,由此获得了具有良好的通用牢度性质的染色,特别是 通过良好的染料积聚,湿加工牢度牢固,耐光牢度好,耐甲醛,水解稳定性好。
    • 3. 发明授权
    • Fiber-reactive dyes containing an aniline radical which carries two
different vinylsulfonyl moieties
    • 含有带有两个不同乙烯基磺酰基部分的苯胺基团的纤维反应性染料
    • US4929719A
    • 1990-05-29
    • US394302
    • 1989-08-10
    • Hansrudolf SchwanderAthanassios TzikasPeter Aeschlimann
    • Hansrudolf SchwanderAthanassios TzikasPeter Aeschlimann
    • C09B62/513C09B62/44C09B62/503C09B62/51
    • C09B62/503C09B62/4401
    • Reactive dyes which are particularly suitable for dyeing and printing cellulose containing fiber materials by the cold padbatch process and which produce, in high dye yield, dyeings and prints having good fastness properties containing the radical of an amine of the formula ##STR1## in which R is hydrogen, halogen, hydroxyl or sulfo, Z is a radical of the formula --CH.dbd.CH.sub.2 or --CH.sub.2 --CH.sub.2 --Y, Y is a detachable group, R' is hydrogen or C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by --COOH, --CN, --OH or --SO.sub.3 H, and E is a radical of the formula ##STR2## in which R' and Z are as defined above, alk, alk' and alk" independently of one another are a C.sub.1 -C.sub.6 alkylene radical, U is hydrogen, halogen, hydroxyl, sulfato, C.sub.1 -C.sub.4 alkanoyloxy, cyano, carboxyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, carbamoyl or a radical --SO.sub.2 --Z in which Z is as defined above, V is hydrogen, substituted or unsubstituted C.sub.1 -C.sub.4 alkyl or a radical of the formula ##STR3## in which Z, alk and U are as defined above, and q, r and s independently of one another are an integer from 1 to 6.
    • 特别适用于通过冷拼接方法对含纤维素纤维材料进行染色和印花的活性染料,其以高染料产率,染色和印刷品具有良好的牢固性能,其含有式(1)的胺基团, 其中R是氢,卤素,羟基或磺基,Z是式-CH = CH 2或-CH 2 -CH 2 -Y的基团,Y是可分离的基团,R'是氢或被未取代或取代的C 1 -C 4烷基 通过-COOH,-CN,-OH或-SO 3 H,并且E是下式的基团:其中R'是(R 1) 和Z如上所定义,烷基,烷基和烷基彼此独立地是C 1 -C 6亚烷基,U是氢,卤素,羟基,硫酸根,C 1 -C 4烷酰氧基,氰基,羧基,C 1 -C 4烷氧基羰基, 氨基甲酰基或其中Z如上定义的基团-SO 2-Z,V是氢,取代或未取代的C 1 -C 4烷基或其中Z,alk和U为 并且q,r和s彼此独立地是1至6的整数。
    • 5. 发明授权
    • s-Triazines
    • US4467088A
    • 1984-08-21
    • US425592
    • 1982-09-28
    • Hansrudolf Schwander
    • Hansrudolf Schwander
    • C09B29/08C09B62/085C09B62/44C09B62/527C07D251/46C07D251/52C07D251/70
    • C09B62/085C09B29/0803C09B62/4413C09B62/527
    • s-Triazine compounds of the formula: ##STR1## in which R.sub.1 and R.sub.2 independently of one another are C.sub.1-4 alkyl, R.sub.3 and R.sub.4 independently of one another are one of the following radicals; C.sub.1-10 alkoxy which is unsubstituted or substituted by alkoxy; N-C.sub.1-10 alkylamino which is unsubstituted or substituted by phenyl; phenylamino which is unsubstituted or substituted by halogen, C.sub.1-4 alkyl or C.sub.1-4 alkoxy; naphthylamino which is unsubstituted or substituted by halogen, C.sub.1-4 alkyl or C.sub.1-4 alkoxy; halogen; N-phenyl-N-alkylamino; dialkylamino; alkylmercapto; cyclohexyloxy; N-alkyl-N-cyclohexylamino and cyclohexylamino; M is hydrogen or one equivalent of a cation and n is 1 or 2. These compounds may be used in the preparation of dyes.
    • 其中R 1和R 2彼此独立地是C 1-4烷基,R 3和R 4彼此独立地是下式的其中之一: 未取代或被烷氧基取代的C 1-10烷氧基; 未取代或被苯基取代的N-C 1-10烷基氨基; 苯基氨基,其未被取代或被卤素,C 1-4烷基或C 1-4烷氧基取代; 未被取代或被卤素,C 1-4烷基或C 1-4烷氧基取代的萘基氨基; 卤素; N-苯基-N-烷基氨基; 二烷基氨基; 烷基巯基 环己氧基; N-烷基-N-环己基氨基和环己基氨基; M为氢或1当量阳离子,n为1或2.这些化合物可用于制备染料。
    • 9. 发明授权
    • Reactive dyes comprising a reactive radical bonded to the chromophor by
a urea bridge member
    • 活性染料包括通过尿素桥构件与发色团结合的反应性基团
    • US4841028A
    • 1989-06-20
    • US86173
    • 1987-08-10
    • Peter AeschlimannHansrudolf Schwander
    • Peter AeschlimannHansrudolf Schwander
    • C09B62/503D06P1/384D06P3/66
    • C09B62/503
    • Reactive dyes of the formula ##STR1## in which D is the radical of an organic dye of the monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide series, R is hydrogen or substituted or unsubstituted C.sub.1-4 -alkyl, A is a polymethylene radical having 2 to 6 C atoms (or its branched isomers) which can be substituted by chlorine, bromine, fluorine, hydroxyl, sulfato, acyloxy having 1 to 4 C atoms, cyano, carboxyl, alkoxycarbonyl having 1 to 5 C atoms or carbamoyl, or an alkyleneoxalkylene radical having 1 to 6 C atoms in each alkylene member, independently of each other; Y is a radical --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 --Z, Z is an inorganic or organic radical detachable under alkaline conditions, B is hydrogen or the radical of a substituted or unsubstituted hydrocarbon, and n is 1 or 2, are suitable for dyeing or printing cellulose-containing and nitrogen-containing materials and in a high dyeing yield produce dyeings and prints of good fastness properties.
    • 式(1)的活性染料其中D是单偶氮,多偶氮,金属络合物偶氮,蒽醌,酞菁,甲an,偶氮甲碱,二恶嗪,吩嗪,芪,芪,三苯甲烷,呫吨,噻吨酮的有机染料的基团 ,硝基芳基,萘醌,芘醌或苝四酰亚胺系列,R为氢或取代或未取代的C 1-4 - 烷基,A为可被氯,溴,氟取代的2〜6个C原子的多亚甲基(或其支链异构体) 羟基,硫酸酯,具有1至4个C原子的酰氧基,氰基,羧基,具有1至5个C原子的烷氧基羰基或氨基甲酰基,或每个亚烷基成员中具有1至6个C原子的亚烷基亚烷基,彼此独立; Y是基团-CH = CH 2或-CH 2 CH 2 -Z,Z是在碱性条件下可分离的无机或有机自由基,B是氢或取代或未取代的烃的基团,n是1或2,适用于染色 或印刷含纤维素和含氮材料并且在高染色产率下产生具有良好牢度性质的染色和印花。
    • 10. 发明授权
    • Water soluble phthalimide-azo-aniline dyes and mixtures thereof
    • 水溶性邻苯二甲酰亚胺 - 偶氮苯胺染料及其混合物
    • US4734490A
    • 1988-03-29
    • US901708
    • 1986-08-28
    • Hansrudolf SchwanderChristian Zickendraht
    • Hansrudolf SchwanderChristian Zickendraht
    • C09B29/036C09B29/00C09B29/08C09B29/09D06P1/39D06P3/16D06P3/24C09B29/40
    • C09B29/0033C09B29/0803
    • Novel monoazo compounds of the formula I ##STR1## and mixtures of these compounds with one another are described. The substituents X, R, R.sub.1, R.sub.2 and R.sub.3 are defined as follows: R is a phenyl or naphthyl radical which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkyl, or is a cycloalkyl radical which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkyl, or is a C.sub.1 -C.sub.8 -alkyl radical which is unsubstituted or substituted by cyano, halogen, phenyl or sulfophenyl, or is a propenyl radical which is unsubstituted or substituted by halogen, X is hydrogen or halogen, R.sub.1 is hydrogen or a C.sub.1 -C.sub.4 -alkyl radical, R.sub.2 is C.sub.1 -C.sub.8 -alkyl radical, a C.sub.1 -C.sub.4 -sulfatoalkyl radical, a C.sub.1 -C.sub.4 -sulfoalkyl radical or a cycloalkyl radical and R.sub.3 is a C.sub.1 -C.sub.4 -alkyl radical, or is a cycloalkyl radical which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkyl, or is a ##STR2## radical, in which the phenyl radical can also be substituted, by --SO.sub.3 H, with the condition that the molecule contains a sulfo group in R, R.sub.2 or R.sub.3 or a sulfato group in R.sub.2.The novel monoazo compounds are particularly suitable as dyes for dyeing and printing textile materials, in particular wool and polyamide.
    • 描述了式I的新型单偶氮化合物(I)和这些化合物彼此的混合物。 取代基X,R,R 1,R 2和R 3定义如下:R是未被取代或被C 1 -C 4 - 烷基取代的苯基或萘基,或是未被取代或被C 1 -C 4 - 或未被取代或被氰基,卤素,苯基或磺基苯基取代的C1-C8-烷基,或是未被取代或被卤素取代的丙烯基,X是氢或卤素,R1是氢或C1 -C 1-4 - 烷基,R 2是C 1 -C 8 - 烷基,C 1 -C 4 - 硫酸烷基,C 1 -C 4 - 磺基烷基或环烷基,R 3是C 1 -C 4 - 烷基,或者是环烷基 或未被取代或被C1-C4烷基取代的基团,或者是其中苯基也可以被-SO 3 H取代的基团,条件是分子在R,R 2或R 3中含有磺基 或R2中的硫酸酯基。 新型单偶氮化合物特别适用于染色和印花纺织材料,特别是羊毛和聚酰胺的染料。