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    • 1. 发明授权
    • Carbonization of wool
    • 羊毛的碳化
    • US3716332A
    • 1973-02-13
    • US3716332D
    • 1970-07-27
    • DUCOMMUN INC
    • LEEDS D
    • D01F9/18C01B31/07
    • D01F9/18Y10S264/19
    • A fibrous carbon product is produced by subjecting a body of wool fibers in a furnace to a reduced pressure to remove essentially all of the oxygen from the furnace and thereafter heating said body of wool fibers at a reduced pressure in the absence of any appreciable oxygen to a temperature of at least about 800*F at which carbonization will occur. An inert gas such as nitrogen is preferably passed over the body during carbonization to remove reaction products.
    • 一种纤维状碳制品是通过使炉体内的羊毛纤维体在较低压力下进行,从而将基本上从炉中除去的全部氧气除去,然后在没有任何明显的氧气的情况下,以减压的方式加热羊毛纤维体, 将发生碳化的至少约800°F的温度。 惰性气体如氮气优选在碳化过程中通过身体以除去反应产物。
    • 5. 发明授权
    • Process for the production of carbon fibers
    • 生产碳纤维的工艺
    • US3723609A
    • 1973-03-27
    • US3723609D
    • 1970-10-07
    • BAYER AG
    • MANSMANN MWINTER GPAMPUS GSCHON N
    • D01F9/16D01F9/17D01F9/18D01F9/21D01F9/24D01F9/26D01F9/28C01B31/07
    • D01F9/18D01F9/16D01F9/17D01F9/21D01F9/24D01F9/245D01F9/26D01F9/28Y10S264/19
    • In the production of carbon fibers wherein a carbon-containing fiber-forming material is spun as a solution, the spun-filaments are converted to solid fibrous material, and the fibrous material is carbonized, the improvement which comprises including in said solution at least one fiber-forming high polymer at a concentration of about 0.001 to 10 percent by weight and a greater amount of a carbon source comprising at least one carboncontaining organic material having a softening or melting point in excess of about 80* C., whereby the solution of said carbon containing material is rendered spinnable by addition of said fiber-forming high polymer, said carbon containing organic material serving as the source of carbon for the carbon fiber; the fiber may thereafter be graphitized. The spinning solution used for fiber production is preferably a solution in a volatile solvent so that it may be dry spun. The carbon source in said solvent by itself would not be spinnable and may be a monomer or low polymer.
    • 在其中将含碳纤维形成材料作为溶液纺丝的碳纤维的生产中,纺丝长丝被转化为固体纤维材料,并且纤维材料被碳化,其改进包括在所述溶液中包含至少一种 浓度为约0.001至10重量%的纤维形成高聚物和更大量的包含至少一种软化点或熔点超过约80℃的含碳有机材料的碳源,由此, 所述含碳材料的溶液通过加入所述形成纤维的高分子,所述含碳有机材料作为碳纤维的碳源,使其可纺丝; 之后纤维可被石墨化。 用于纤维生产的纺丝溶液优选是挥发性溶剂中的溶液,使其可以是干纺的。 所述溶剂中的碳源本身不可纺,可以是单体或低聚物。