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1. 发明申请

US20040258603A1 High-yield method of endohedrally encapsulating species inside fluorinated fullerene nanocages 失效
标题翻译：在氟化富勒烯纳米笼内内封装物质的高产率法
公开(公告)号：US20040258603A1
公开(公告)日：2004-12-23
申请号：US10716721
申请日：2003-11-19
申请人： William Marsh Rice University
发明人： Boris I. Yakobson , Pavel V. Avramov , John L. Margrave , Edward T. Mickelson , Robert H. Hauge , Peter J. Boul , Chad B. Huffman , Richard E. Smalley
IPC分类号： D01F009/12
CPC分类号： B82Y30/00 , B01J21/18 , B01J23/74 , B01J23/755 , B01J35/06 , B82Y40/00 , C01B32/152 , C01B32/174 , C01B2202/02 , C01B2202/06 , D01F11/121 , Y10S977/736 , Y10S977/744
摘要： This invention is directed to the fluorination (or derivatization with alternative chemical species) of fullerene carbon nanocages as an efficient way to (a) facilitate synthesis of endohedral complexes by a significant reduction or elimination of the barriers for the entry of guest-ions, -atoms or molecules, and (b) to preserve the chemical stability of final product.
摘要翻译：本发明涉及富勒烯碳纳米线的氟化（或替代化学物种的衍生）作为（a）通过显着减少或消除客体离子进入的障碍来促进内嵌性配合物的有效方法，原子或分子，和（b）保持最终产品的化学稳定性。

2. 发明申请

US20040247516A1 Growth of nanostructures with controlled diameter 有权
标题翻译：具有受控直径的纳米结构的生长
公开(公告)号：US20040247516A1
公开(公告)日：2004-12-09
申请号：US10726394
申请日：2003-12-02
发明人： Lisa Pfefferle , Gary Haller , Dragos Ciuparu
IPC分类号： D01F009/12
CPC分类号： B82Y30/00 , D01F9/127 , Y10S977/842
摘要： Transition metal-substituted MCM-41 framework structures with a high degree of structural order and a narrow pore diameter distribution were reproducibly synthesized by a hydrothermal method using a surfactant and an anti-foaming agent. The pore size and the mesoporous volume depend linearly on the surfactant chain length. The transition metals, such as cobalt, are incorporated substitutionally and highly dispersed in the silica framework. Single wall carbon nanotubes with a narrow diameter distribution that correlates with the pore diameter of the catalytic framework structure were prepared by a Boudouard reaction. Nanostructures with a specified diameter or cross-sectional area can therefore be predictably prepared by selecting a suitable pore size of the framework structure.
摘要翻译：通过使用表面活性剂和消泡剂的水热法可重复合成具有高度结构顺序和窄孔径分布的过渡金属取代的MCM-41骨架结构。孔径和介孔体积与表面活性剂链长度呈线性关系。过渡金属，例如钴，被代替并且高度分散在二氧化硅骨架中。通过Boudouard反应制备具有与催化骨架结构的孔直径相关的窄直径分布的单壁碳纳米管。因此，可以通过选择合适的骨架结构孔径来预测具有特定直径或横截面面积的纳米结构。

3. 发明申请

US20040223901A1 Single-wall carbon nanotubes from high pressure CO 有权
标题翻译：单壁碳纳米管由高压CO
公开(公告)号：US20040223901A1
公开(公告)日：2004-11-11
申请号：US10730630
申请日：2003-12-08
申请人： William Marsh Rice University
发明人： Richard E. Smalley , Ken A. Smith , Daniel T. Colbert , Pavel Nikolaev , Michael J. Bronikowski , Robert K. Bradley , Frank Rohmund
IPC分类号： D01F009/12
CPC分类号： B01J4/002 , B01J3/04 , B01J3/042 , B01J19/121 , B01J19/26 , B01J2219/0875 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , C01B2202/36 , D01F9/1278 , Y10S977/75 , Y10S977/751 , Y10S977/843 , Y10S977/845 , Y10S977/951 , Y10T428/30
摘要： The present invention discloses the process of supplying high pressure (e.g., 30 atmospheres) CO that has been preheated (e.g., to about 1000null C.) and a catalyst precursor gas (e.g., Fe(CO)5) in CO that is kept below the catalyst precursor decomposition temperature to a mixing zone. In this mixing zone, the catalyst precursor is rapidly heated to a temperature that results in (1) precursor decomposition, (2) formation of active catalyst metal atom clusters of the appropriate size, and (3) favorable growth of SWNTs on the catalyst clusters. Preferably a catalyst cluster nucleation agency is employed to enable rapid reaction of the catalyst precursor gas to form many small, active catalyst particles instead of a few large, inactive ones. Such nucleation agencies can include auxiliary metal precursors that cluster more rapidly than the primary catalyst, or through provision of additional energy inputs (e.g., from a pulsed or CW laser) directed precisely at the region where cluster formation is desired. Under these conditions SWNTs nucleate and grow according to the Boudouard reaction. The SWNTs thus formed may be recovered directly or passed through a growth and annealing zone maintained at an elevated temperature (e.g., 1000null C.) in which tubes may continue to grow and coalesce into ropes.
摘要翻译：本发明公开了在被保留的CO中提供已被预热（例如，约1000℃）的高压（例如，30个大气压）的CO和催化剂前体气体（例如，Fe（CO）5）的过程。催化剂前体分解温度低于混合区。在该混合区中，将催化剂前体快速加热到导致（1）前体分解的温度，（2）形成适当尺寸的活性催化剂金属原子簇，和（3）在催化剂簇上的SWNT的有利生长。优选使用催化剂簇成核剂来使催化剂前体气体快速反应以形成许多小的活性催化剂颗粒，而不是几个大的非活性催化剂颗粒。这样的成核机构可以包括比主要催化剂更快地聚集的辅助金属前体，或者通过提供精确地指向需要簇形成的区域的额外的能量输入（例如来自脉冲或CW激光）。在这些条件下，SWNT根据Boudouard反应成核并生长。如此形成的SWNT可以直接回收或通过保持在高温（例如1000℃）的生长和退火区域，其中管可以继续生长并聚结成绳索。

4. 发明申请

US20040221813A1 Carbon nanostructures and methods of preparation 审中-公开
标题翻译：碳纳米结构及其制备方法
公开(公告)号：US20040221813A1
公开(公告)日：2004-11-11
申请号：US10864602
申请日：2004-06-10
发明人： Robert P.H. Chang
IPC分类号： D01F009/12
CPC分类号： B01J19/088 , B01J2219/0809 , B01J2219/083 , B01J2219/0871 , B01J2219/0886 , B01J2219/0894 , B82Y30/00 , B82Y40/00 , C01B32/152 , C01B32/16 , C01B32/162 , C01B32/164 , C01B2202/06 , Y10S977/742 , Y10S977/743 , Y10S977/842 , Y10S977/90
摘要： Methods and apparatus for the preparation of tubular carbon nanostructures by manipulating the heat treatment and pressure of various carbon precursors. Methods and apparatus for the preparation of tubular carbon nanostructures by bombarding graphitizable carbon precursors with the electron charged particles.
摘要翻译：通过操纵各种碳前体的热处理和压力来制备管状碳纳米结构的方法和装置。通过用电子带电粒子轰击石墨化碳前体来制备管状碳纳米结构的方法和装置。

5. 发明申请

US20040202603A1 Functionalized nanotubes 审中-公开
标题翻译：功能化纳米管
公开(公告)号：US20040202603A1
公开(公告)日：2004-10-14
申请号：US10837125
申请日：2004-04-30
申请人： Hyperion Catalysis International, Inc.
发明人： Alan Fischer , Robert Hoch , David Moy , Ming Lu , Mark Martin , Chun Ming Niu , Naoya Ogata , Howard Tennent , Liwen Dong , Ji Sun , Larry Helms , Fabian Jameison , Pam Liang , David Simpson
IPC分类号： D01F009/12 , C07C063/333
CPC分类号： G01N33/54346 , B01D15/327 , B01D15/36 , B01D15/3804 , B01J20/28007 , B01J20/28009 , B01J20/28014 , B01J20/28019 , B01J20/28023 , B01J20/28057 , B01J20/3204 , B01J20/3219 , B01J20/3248 , B01J20/3251 , B01J20/3253 , B01J20/3255 , B01J20/3257 , B01J20/3261 , B01J20/3265 , B01J20/3272 , B01J20/3274 , B01J20/3293 , B82Y30/00 , B82Y40/00 , C01B32/174 , C01B2202/28 , C01B2202/34 , C01B2202/36 , C07K1/1075 , C07K1/1077 , C09C1/46 , C12N11/02 , C12Q1/26 , C12Q1/28 , C12Q1/37 , C12Q1/42 , C12Q1/44 , D01F9/12 , D01F11/14 , G01N2030/8863 , H01M4/60
摘要： Graphitic nanotubes, which includes tubular fullerenes (commonly called nullbuckytubesnull) and fibrils, which are functionalized by chemical substitution or by adsorption of functional moieties. More specifically the invention relates to graphitic nanotubes which are uniformly or non-uniformly substituted with chemical moieties or upon which certain cyclic compounds are adsorbed and to complex structures comprised of such functionalized nanotubes linked to one another. The invention also relates to methods for introducing functional groups onto the surface of such nanotubes. The invention further relates to uses for functionalized nanotubes.
摘要翻译：石墨纳米管，其包括管状富勒烯（通常称为“巴氏管”）和原纤维，其通过化学取代或功能部分的吸附官能化。更具体地，本发明涉及被化学部分均匀或不均匀地取代或其上吸附某些环状化合物的石墨纳米管以及由相互连接的这种官能化纳米管组成的复合结构。本发明还涉及在这种纳米管的表面上引入官能团的方法。本发明还涉及功能化纳米管的用途。

6. 发明申请

US20040197260A1 Method for producing single walled carbon nanotubes 有权
标题翻译：单壁碳纳米管的制备方法
公开(公告)号：US20040197260A1
公开(公告)日：2004-10-07
申请号：US10689258
申请日：2003-10-20
发明人： Daniel E. Resasco , Walter E. Alvarez , Jose E. Herrera , Leandro Balzano
IPC分类号： D01F009/12
CPC分类号： B82Y30/00 , B01J23/88 , B01J23/882 , B82Y15/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , C01B2202/36 , D01F9/127 , D01F9/1278 , Y10S977/742 , Y10S977/748 , Y10S977/843
摘要： A catalyst composition and method of use of the catalyst composition for producing single-walled carbon nanotubes (SWNTs). The catalyst is cobalt (Co) and molybdenum (Mo) on a silica support. The Mo occurs primarily as dispersed Mo oxide clusters on the support while the Co is primarily in an octahedral configuration in a CoMoO4-like phase disposed on the Mo oxide clusters. In the method, the catalyst is used and the process conditions manipulated in such a manner as to enable the diameters of the SWNTs to be substantially controlled.
摘要翻译：催化剂组合物和催化剂组合物用于制备单壁碳纳米管（SWNT）的方法。催化剂是二氧化硅载体上的钴（Co）和钼（Mo）。 Mo主要作为分散的Mo氧化物簇发生在载体上，而Co主要是位于Mo氧化物簇上的CoMoO 4样相中的八面体构型。在该方法中，使用催化剂，并且以使得能够基本上控制SWNT的直径的方式操作工艺条件。

7. 发明申请

US20040191157A1 Method for selective enrichment of carbon nanotubes 有权
标题翻译：选择性富集碳纳米管的方法
公开(公告)号：US20040191157A1
公开(公告)日：2004-09-30
申请号：US10404279
申请日：2003-03-31
发明人： Avetik Harutyunyan , Toshio Tokune
IPC分类号： D01F009/12
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/168 , C01B2202/22 , D01F9/127
摘要： A method for treating carbon nanotubes with microwave energy to selective remove metallic-type carbon nanotubes is provided. A sample containing carbon nanotubes is positioned in a microwave cavity at a location corresponding to a maximum in the electric field component of a stationary wave having a microwave frequency. The sample is exposed to the microwave energy for a sufficient period of time to increase the proportion of semiconducting-type carbon nanotubes within the sample. Alternatively, a sample consisting essentially of metallic-type and semiconducting-type carbon nanotubes is exposed to microwave energy for a sufficient period of time to increase the proportion of semiconducting-type carbon nanotubes within the sample.
摘要翻译：提供了一种用微波能量处理碳纳米管以选择性去除金属型碳纳米管的方法。含有碳纳米管的样品位于与微波频率的固定波的电场分量中的最大值相对应的位置处的微波空腔中。将样品暴露于微波能量足够长的时间以增加样品中半导体型碳纳米管的比例。或者，基本上由金属型和半导体型碳纳米管组成的样品暴露于微波能量足够的时间以增加样品中半导体型碳纳米管的比例。

8. 发明申请

US20040115114A1 Crystals comprising single-walled carbon nanotubes 审中-公开
标题翻译：包含单壁碳纳米管的晶体
公开(公告)号：US20040115114A1
公开(公告)日：2004-06-17
申请号：US10416553
申请日：2004-02-05
发明人： James Gimzewski , Jin Woo Seo , Reto Schlittler , Mark E Welland
IPC分类号： D01F009/12
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , C30B1/00 , C30B23/00 , C30B23/005 , C30B29/02 , C30B29/605
摘要： The invention is directed to a method of manufacturing single-walled carbon nanotubes comprising the steps of providing on a substrate at least one pillar comprising alternate layers of a first precursor material comprising fullerene molecules and a second precursor material comprising a catalyst, and heating the at least one pillar. It further is directed to a precursor arrangement for manufacturing single-walled carbon nanotubes comprising on a substrate at least one pillar comprising alternate layers of a first precursor material comprising fullerene molecules and a second precursor material comprising a catalyst. A third aspect is a nanotube arrangement comprising a substrate and thereupon at least one crystal comprising a bundle of single-walled carbon nanotubes with essentially identical orientation and structure.
摘要翻译：本发明涉及一种制造单壁碳纳米管的方法，包括以下步骤：在基材上提供至少一个柱，该柱包括包含富勒烯分子的第一前体材料和包含催化剂的第二前体材料的交替层，至少一个支柱。本发明还涉及用于制造单壁碳纳米管的前体装置，其包括在至少一个支柱上的至少一个柱，所述至少一个柱包括包含富勒烯分子的第一前体材料的交替层和包含催化剂的第二前体材料。第三方面是纳米管布置，其包括基底，并且随后至少一个晶体包括具有基本上相同取向和结构的单层碳纳米管束。

9. 发明申请

US20040109815A1 Carbon nanotube array and method for making same 有权
标题翻译：碳纳米管阵列及其制造方法
公开(公告)号：US20040109815A1
公开(公告)日：2004-06-10
申请号：US10640340
申请日：2003-08-12
发明人： Liang Liu , Shou-Shan Fan
IPC分类号： D01F009/12
CPC分类号： D01F9/1275 , B82Y30/00 , D01F9/127 , Y10S977/742 , Y10S977/85
摘要： A carbon nanotube-based device (40) includes a substrate (10), a number of catalytic nano-sized particles (131) formed on the substrate, and an aligned carbon nanotube array (15) extending from the alloy catalytic nano-sized particles. The aligned carbon nanotube array progressively bends in a predetermined direction. A method for making the carbon nanotube-based device includes the steps of: providing a substrate; depositing a layer of catalyst on the substrate; depositing a layer of catalyst-doped material on the catalyst layer, for varying a reaction rate of synthesis of the aligned carbon nanotube array; annealing the catalyst and the catalyst-doped material in an oxygen-containing gas at a low temperature; and exposing the nano-sized particles and catalyst-doped material to a carbon-containing source gas at a predetermined temperature such that the aligned carbon nanotube array grows from the substrate.
摘要翻译：基于碳纳米管的器件（40）包括基板（10），形成在基板上的多个催化纳米尺寸颗粒（131）和从合金催化纳米尺寸颗粒延伸的排列的碳纳米管阵列（15）。对准的碳纳米管阵列沿预定方向逐渐弯曲。制造碳纳米管的器件的方法包括以下步骤：提供衬底; 在衬底上沉积催化剂层; 在催化剂层上沉积催化剂掺杂材料层，以改变对准的碳纳米管阵列的合成反应速率; 在低温下在含氧气体中退火催化剂和催化剂掺杂材料; 以及将纳米尺寸颗粒和催化剂掺杂材料暴露于预定温度下的含碳源气体，使得对准的碳纳米管阵列从衬底生长。

10. 发明申请

US20040105807A1 Method for manufacturing carbon nanotubes 审中-公开
标题翻译：制造碳纳米管的方法
公开(公告)号：US20040105807A1
公开(公告)日：2004-06-03
申请号：US10410069
申请日：2003-04-08
发明人： Shoushan Fan , Liang Liu , Kaili Jiang
IPC分类号： D01F009/12
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/16 , C01B32/174 , C01B2202/08 , C01B2202/34 , D01F9/127 , D01F9/1271 , D01F9/1272 , D01F9/1275
摘要： The present invention provides a method for manufacturing carbon nanotubes. The method includes the following steps: (a) providing a substrate (3); (b) depositing a catalyst material (1) onto the substrate; (c) exposing the catalyst material to a carbon containing gas for a predetermined period of time in a predetermined temperature such that an array of carbon nanotube having a predetermined length grows from the substrate in a direction substantially perpendicular to the substrate; (d) removing the carbon nanotubes from the substrate; and (e) dispersing the carbon nanotubes via ultrasonication in a dispersant, the dispersant being ethanol or 1-2 dichloroethane. The carbon nanotubes of the present invention have a predetermined same length and are aligned parallel to each other.
摘要翻译：本发明提供一种碳纳米管的制造方法。该方法包括以下步骤：（a）提供衬底（3）; （b）将催化剂材料（1）沉积到所述基底上; （c）在预定温度下将催化剂材料暴露于含碳气体预定时间段，使得具有预定长度的碳纳米管阵列从基底沿基本垂直于基底的方向生长; （d）从基材除去碳纳米管; 和（e）通过超声波将碳纳米管分散在分散剂中，分散剂是乙醇或1-2二氯乙烷。本发明的碳纳米管具有预定相同的长度并且彼此平行排列。

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