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    • 5. 发明授权
    • Tungsten layer forming method and laminate structure of tungsten layer
    • 钨层的钨层成型方法和叠层结构
    • US06387445B1
    • 2002-05-14
    • US09646038
    • 2000-09-13
    • Yasushi AibaYukio Koike
    • Yasushi AibaYukio Koike
    • C23C1608
    • C23C16/0281C23C16/14H01L21/28556H01L21/28568
    • A tungsten layer is formed on the surface of an object to be treated (e.g., a semiconductor wafer), supplying a process gas which includes a material gas of a tungsten fluoride (e.g., WF6) gas and a reducing gas (e.g., H2 gas) for reducing the material gas. In this case, an intermediate tungsten film forming step is carried out between a nuclear crystalline film forming step of forming a nuclear crystalline film of tungsten on the surface of the object and a main tungsten film forming step of forming a main tungsten film on the nuclear crystalline film. At the intermediate tungsten film forming step, an intermediate tungsten film is formed while the flow ratio of the material gas to the reducing gas is smaller than that at the main tungsten film forming step. Thus, the incubation time T2 after the deposition of the nuclear crystalline film is removed, so that it is possible to enhance the whole mean deposition rate and to improve the uniformity of the thickness between objects to be processed.
    • 在待处理物体的表面(例如,半导体晶片)上形成钨层,供给包括氟化钨(例如WF 6)气体和还原气体(例如,H 2气体)的原料气体的处理气体 )用于减少原料气体。 在这种情况下,中间钨膜形成步骤是在物体表面上形成钨的核晶体膜的核晶形成步骤和在核上形成主钨膜的主钨膜形成步骤之间进行的 结晶膜。 在中间钨膜形成步骤中,形成中间钨膜,同时原料气体与还原气体的流量比主钨膜形成步骤小。 因此,去除沉积核晶体膜后的孵育时间T2,从而可以提高整个平均沉积速率并提高待处理物体之间厚度的均匀性。
    • 6. 发明授权
    • Process for chemical vapor deposition layer production on a semiconductor surface with absorbing protective gasses
    • 在具有吸收保护气体的半导体表面上生成化学气相沉积层的方法
    • US06194314B1
    • 2001-02-27
    • US09019612
    • 1998-02-06
    • Wolfram KarcherLutz Labs
    • Wolfram KarcherLutz Labs
    • C23C1608
    • H01L21/76838C23C16/0218C23C16/42C23C16/4405
    • In chemical gaseous phase deposition (CVD=Chemical Vapor Deposition), there is frequently the problem of there still being an aggressive gas in the reaction chamber from the preceding layer production process. The aggressive gas can be a remainder of a process gas used for layer production or it can be a remainder gas produced by the reaction of the process gasses. The aggressive gas can cause undesirable reactions on the surface of the semiconductor product, which damage the semiconductor product. A process for layer production on a surface includes supplying at least one protective gas to the surface before and/or during the heating of the surface to the reaction temperature. Through the use of the protective gas, on one hand the aggressive gas still remaining in the reaction chamber is thinned and on the other hand a part of the protective gas adsorbs onto the cold surface so that on the surface, preferably reactions of the aggressive gas with the protective gas occur and the surface layers themselves remain essentially undamaged.
    • 在化学气相沉积(CVD =化学气相沉积)中,常常存在来自前一层生产过程的反应室中仍然存在侵蚀性气体的问题。 侵蚀性气体可以是用于层生产的工艺气体的剩余部分,或者其可以是通过工艺气体的反应产生的剩余气体。 侵蚀性气体可能在半导体产品的表面上引起不期望的反应,这损害半导体产品。 用于在表面上层生产的方法包括在将表面加热到反应温度之前和/或期间向表面供应至少一种保护气体。 通过使用保护气体,一方面仍然残留在反应室中的侵蚀性气体变薄,另一方面,保护气体的一部分吸附到冷表面上,使得在表面上优选侵蚀性气体 发生保护气体并且表面层本身保持基本上没有损坏。
    • 9. 发明授权
    • Method and apparatus for surface metallization
    • 表面金属化方法和装置
    • US06319554B1
    • 2001-11-20
    • US09329893
    • 1999-06-10
    • Govindarajan NatarajanRobert W. Pasco
    • Govindarajan NatarajanRobert W. Pasco
    • C23C1608
    • H05K3/24C23C16/08C23C16/44
    • The present invention relates generally to a CVD (Chemical Vapor Deposition) process where at least one source metal, such as, nickel (Ni) or alloys thereof, for example, Ni/Cu, Ni/Co, are deposited on metal surfaces which are capable of receiving the source metal, such as, refractory metal, for example, molybdenum, tungsten or alloys thereof, using at least one gaseous Iodide source, such as, an iodic fluid, for example, hydriodic acid gas. The source metal is securely held in place by at least one high strength inert material. The CVD of nickel or alloys thereof, on the surface of refractory metal, such as, molybdenum (Mo) or tungsten (W), where the nickel source is physically isolated from the refractory metal surface to be plated using at least one high strength inert material that is in physical floating contact with the refractory metal surface that needs to be coated with at least one layer of nickel or alloy thereof, and where the nickel source and the high strength inert material are embodied as a single bonded structure.
    • 本发明一般涉及一种CVD(化学气相沉积)方法,其中至少一种源金属例如镍(Ni)或其合金,例如Ni / Cu,Ni / Co沉积在金属表面上, 能够使用至少一种碘化物源(例如碘酸液体,例如氢碘酸气体)接收源金属,例如难熔金属,例如钼,钨或其合金。 源金属通过至少一种高强度惰性材料牢固地保持在适当位置。 在难熔金属表面,例如钼(Mo)或钨(W)的镍或其合金的CVD,其中镍源使用至少一种高强度惰性物质从要镀覆的难熔金属表面物理隔离 与需要涂覆有至少一层镍或其合金的难熔金属表面物理浮动接触的材料,以及其中镍源和高强度惰性材料被实施为单一结合结构的材料。