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    • 5. 发明授权
    • Tungsten layer forming method and laminate structure of tungsten layer
    • 钨层的钨层成型方法和叠层结构
    • US06387445B1
    • 2002-05-14
    • US09646038
    • 2000-09-13
    • Yasushi AibaYukio Koike
    • Yasushi AibaYukio Koike
    • C23C1608
    • C23C16/0281C23C16/14H01L21/28556H01L21/28568
    • A tungsten layer is formed on the surface of an object to be treated (e.g., a semiconductor wafer), supplying a process gas which includes a material gas of a tungsten fluoride (e.g., WF6) gas and a reducing gas (e.g., H2 gas) for reducing the material gas. In this case, an intermediate tungsten film forming step is carried out between a nuclear crystalline film forming step of forming a nuclear crystalline film of tungsten on the surface of the object and a main tungsten film forming step of forming a main tungsten film on the nuclear crystalline film. At the intermediate tungsten film forming step, an intermediate tungsten film is formed while the flow ratio of the material gas to the reducing gas is smaller than that at the main tungsten film forming step. Thus, the incubation time T2 after the deposition of the nuclear crystalline film is removed, so that it is possible to enhance the whole mean deposition rate and to improve the uniformity of the thickness between objects to be processed.
    • 在待处理物体的表面(例如,半导体晶片)上形成钨层,供给包括氟化钨(例如WF 6)气体和还原气体(例如,H 2气体)的原料气体的处理气体 )用于减少原料气体。 在这种情况下,中间钨膜形成步骤是在物体表面上形成钨的核晶体膜的核晶形成步骤和在核上形成主钨膜的主钨膜形成步骤之间进行的 结晶膜。 在中间钨膜形成步骤中,形成中间钨膜,同时原料气体与还原气体的流量比主钨膜形成步骤小。 因此,去除沉积核晶体膜后的孵育时间T2,从而可以提高整个平均沉积速率并提高待处理物体之间厚度的均匀性。
    • 6. 发明授权
    • Process for chemical vapor deposition layer production on a semiconductor surface with absorbing protective gasses
    • 在具有吸收保护气体的半导体表面上生成化学气相沉积层的方法
    • US06194314B1
    • 2001-02-27
    • US09019612
    • 1998-02-06
    • Wolfram KarcherLutz Labs
    • Wolfram KarcherLutz Labs
    • C23C1608
    • H01L21/76838C23C16/0218C23C16/42C23C16/4405
    • In chemical gaseous phase deposition (CVD=Chemical Vapor Deposition), there is frequently the problem of there still being an aggressive gas in the reaction chamber from the preceding layer production process. The aggressive gas can be a remainder of a process gas used for layer production or it can be a remainder gas produced by the reaction of the process gasses. The aggressive gas can cause undesirable reactions on the surface of the semiconductor product, which damage the semiconductor product. A process for layer production on a surface includes supplying at least one protective gas to the surface before and/or during the heating of the surface to the reaction temperature. Through the use of the protective gas, on one hand the aggressive gas still remaining in the reaction chamber is thinned and on the other hand a part of the protective gas adsorbs onto the cold surface so that on the surface, preferably reactions of the aggressive gas with the protective gas occur and the surface layers themselves remain essentially undamaged.
    • 在化学气相沉积(CVD =化学气相沉积)中,常常存在来自前一层生产过程的反应室中仍然存在侵蚀性气体的问题。 侵蚀性气体可以是用于层生产的工艺气体的剩余部分,或者其可以是通过工艺气体的反应产生的剩余气体。 侵蚀性气体可能在半导体产品的表面上引起不期望的反应,这损害半导体产品。 用于在表面上层生产的方法包括在将表面加热到反应温度之前和/或期间向表面供应至少一种保护气体。 通过使用保护气体,一方面仍然残留在反应室中的侵蚀性气体变薄,另一方面,保护气体的一部分吸附到冷表面上,使得在表面上优选侵蚀性气体 发生保护气体并且表面层本身保持基本上没有损坏。
    • 9. 发明授权
    • CVD of integrated Ta and TaNx films from tantalum halide precursors
    • 来自卤化钽前体的集成Ta和TaNx膜的CVD
    • US06410432B1
    • 2002-06-25
    • US09300632
    • 1999-04-27
    • John J. HautalaJohannes F. M. Westendorp
    • John J. HautalaJohannes F. M. Westendorp
    • C23C1608
    • H01L21/76843C23C16/08C23C16/34
    • A chemical vapor deposition (CVD) method for depositing high quality conformal tantalum/tantalum nitride (Ta/TaNx) bilayer films from inorganic tantalum pentahalide (TaX5) precursors and nitrogen is described. The inorganic tantalum halide precursors are tantalum pentafluoride (TaF5), tantalum pentachloride (TaCl5) and tantalum pentabromide (TaBr5). A TaX5 vapor is delivered into a heated reaction chamber. The vapor is combined with a process gas to deposit a Ta film and a process gas containing nitrogen to deposit a TaNx film on a substrate that is heated to 300° C.-500° C. The deposited Ta/TaNx bilayer film is useful for integrated circuits containing copper films, especially in small high aspect ratio features. The high conformality of these films is superior to films deposited by PVD.
    • 描述了一种用于从无机钽五卤化物(TaX5)前体和氮沉积高质量保形钽/氮化钽(Ta / TaNx)双层膜的化学气相沉积(CVD)方法。 无机卤化钽前体是五氟化钽(TaF5),五氯化钽(TaCl5)和五溴化钽(TaBr5)。 将TaX5蒸气输送到加热的反应室中。 将蒸气与处理气体结合以沉积Ta膜和含有氮的工艺气体,以将TaNx膜沉积在加热至300℃-500℃的基底上。沉积的Ta / TaNx双层膜可用于 包含铜膜的集成电路,特别是在小高宽比特征中。 这些膜的高共形性优于PVD沉积的膜。
    • 10. 发明授权
    • Device and method for preparing and/or coating the surfaces of hollow construction elements
    • 用于制备和/或涂覆中空构造元件表面的装置和方法
    • US06180170B2
    • 2001-01-30
    • US09125655
    • 1998-08-21
    • Valentin GrossmannHorst PillhoeferMartin Thoma
    • Valentin GrossmannHorst PillhoeferMartin Thoma
    • C23C1608
    • C23C10/06C23C10/48Y10S118/10Y10S118/11
    • In a method for preparing and/or coating the surfaces of metallic hollow structural elements that have at least two connection openings between their outer and inner surfaces, first and second reaction gas mixtures (I, II) are prepared by reaction gas sources for treating the outer and inner surfaces of the hollow structural elements. The first reaction gas mixture (I) is guided over the outer surfaces and thereafter over the inner surfaces of the structural elements, and then the second reaction gas mixture (II) is guided over the inner surfaces and thereafter over the outer surfaces of the structural elements. An apparatus for carrying out the method includes a reaction vessel enclosing an outer reaction space, a central holding pipe arranged in the reaction vessel and enclosing an inner space, and hollow support arms removably attached on the holding pipe to extend radially outwardly therefrom. Each structural element is mounted on a hollow support arm so that one of the connection openings communicates with the inner space through the hollow support arm and the other one of the connection openings communicates with the outer reaction space.
    • 在用于制备和/或涂覆在其外表面和内表面之间具有至少两个连接开口的金属中空结构元件的表面的方法中,第一和第二反应气体混合物(I,II)由反应气体源制备,用于处理 中空结构元件的外表面和内表面。 第一反应气体混合物(I)被引导在外表面上,然后在结构元件的内表面上引导,然后第二反应气体混合物(II)被引导到内表面上,然后在结构的外表面上引导 元素。 用于执行该方法的装置包括:包围外部反应空间的反应容器,布置在反应容器中并包围内部空间的中央保持管,以及可拆卸地附接在保持管上的径向向外延伸的中空支撑臂。 每个结构元件安装在中空支撑臂上,使得一个连接开口通过中空支撑臂与内部空间连通,另一个连接开口与外部反应空间连通。