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    • 5. 发明授权
    • Process for production of direct reduced iron
    • 生产直接还原铁的工艺
    • US08709128B2
    • 2014-04-29
    • US13122729
    • 2009-09-22
    • Klaus KnopSten Ångström
    • Klaus KnopSten Ångström
    • C21B3/02
    • C21B13/0046B01D2257/504C21B13/0073C21B13/02C21B2100/24C21B2100/26C21B2100/282C21B2100/284C21B2100/44C21B2100/66Y02P10/122Y02P10/126Y02P10/128Y02P10/136Y02P10/143
    • The present invention relates to a process for the direct reduction of iron ore performed by means of a plant comprising a gravitational furnace (2) having at least one iron ore reduction zone (8) in the upper part thereof, and at least one carbon deposition zone (9) and one reduced metal product cooling zone (10) in the lower part thereof, and means for feeding a reducing gas mixture into the reactor in correspondence to the with the reduction zone, means for recycle exhaust or reactor off gas from the reactor to syngas and mixing the recycled gas with natural gas to form a reducing gas mixture. According to the invention a in first reformation step (5) unreacted carbon monoxide CO and steam present in the reactor off gas is reformed to carbon dioxide and hydrogen following the water gas shift reaction CO+H2O=CO2+H2, in a secondary reformation step the de-watered reactor off gas comprising mainly of carbon dioxide and hydrogen is processed to remove carbon dioxide, and in a third reformation step physical separation of both nitrogen and carbon oxide CO from the reducing syngas is carried out to bring down the levels of CO and any existing other gases in the recycled gas to as low level as possible such that recycled reducing gas is as close to pure hydrogen H2 as possible.
    • 本发明涉及一种通过包括在其上部具有至少一个铁矿还原区(8)的重力炉(2)的植物直接还原铁矿石的方法,以及至少一个碳沉积 区域(9)和其下部的一个还原的金属制品冷却区(10),以及用于将还原气体混合物与还原区相对应地供给到反应器中的装置,用于再循环排出的废气或来自 反应器进行合成气并将再循环气体与天然气混合以形成还原气体混合物。 根据本发明,在第一重整步骤(5)中,在二次重整步骤中,在水煤气变换反应CO + H 2 O = CO 2 + H 2之后,存在于反应器废气中的未反应的一氧化碳CO和蒸汽重整成二氧化碳和氢气 处理主要包含二氧化碳和氢气的脱水反应器废气被处理以除去二氧化碳,并且在第三重整步骤中,进行氮和碳氧化物CO与还原性合成气的物理分离以降低CO的含量 和再循环气体中的任何现有其他气体尽可能低的水平,使得再循环的还原气体尽可能接近纯氢气H2。