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1. 发明授权

US07408083B2 Method for the production of diaminodiarylmethanes 失效
标题翻译：二氨基二芳基甲烷的制备方法
公开(公告)号：US07408083B2
公开(公告)日：2008-08-05
申请号：US10564059
申请日：2004-06-25
申请人： Ulrich Steinbrenner , Eckhard Stroefer , Martin Sohn , Veronika Quaschning , Helmut Moehwald , Kai Thiele , Filip Deberdt , Jan D. Jacobs , Rolf Pinkos
发明人： Ulrich Steinbrenner , Eckhard Stroefer , Martin Sohn , Veronika Quaschning , Helmut Moehwald , Kai Thiele , Filip Deberdt , Jan D. Jacobs , Rolf Pinkos
IPC分类号： C07C209/78
CPC分类号： C07C209/86 , C07C209/78 , C07C211/50
摘要： A process is described for preparing diaminodiarylmethanes comprising the steps a) reacting an aromatic amine with a methylene-donating agent in the presence of homogeneous acid catalysts, b) removing the homogeneous acid catalyst from the reaction product, c) working up and purifying the reaction product, which comprises removing the homogeneous acid catalyst from the reaction mixture by adsorption to a solid adsorbent.
摘要翻译：描述了制备二氨基二芳基甲烷的方法，包括以下步骤：a）在均相酸催化剂存在下使芳族胺与亚甲基供体试剂反应，b）从反应产物中除去均相酸催化剂，c）加工并纯化反应产物，其包括通过吸附到固体吸附剂从反应混合物中除去均相酸催化剂。

2. 发明申请

US20120082872A1 ADDITIVE FOR ELECTROLYTES 审中-公开
标题翻译：电解质添加剂
公开(公告)号：US20120082872A1
公开(公告)日：2012-04-05
申请号：US13249605
申请日：2011-09-30
申请人： Rudiger Schmidt , Daher Michael Badine , Xiao Steimle , Helmut Moehwald , Igor Kovalev , Yuriy V. Mikhaylik
发明人： Rudiger Schmidt , Daher Michael Badine , Xiao Steimle , Helmut Moehwald , Igor Kovalev , Yuriy V. Mikhaylik
IPC分类号： H01M10/056 , H01M4/58 , H01M4/40 , H01M4/48 , H01M10/02 , H01M4/38
CPC分类号： H01M10/0525 , H01M10/0567 , H01M10/0568
摘要： Spiro ammonium salts as an additive for electrolytes in electric current producing cells, in particular electric current producing cells comprising a Li-based anode, are provided. In some embodiments, the electric current producing cell comprises a cathode, a Li-based anode, and at least one electrolyte wherein the electrolyte contains at least one spiro ammonium salt.
摘要翻译：提供螺旋铵盐作为电流产生电池中的电解质的添加剂，特别是包含Li基阳极的电流产生电池。在一些实施例中，电流产生单元包括阴极，Li基阳极和至少一种电解质，其中电解质含有至少一种螺铵盐。

3. 发明申请

US20120052339A1 ELECTROLYTE MATERIALS FOR USE IN ELECTROCHEMICAL CELLS 审中-公开
标题翻译：用于电化学电池的电解质材料
公开(公告)号：US20120052339A1
公开(公告)日：2012-03-01
申请号：US13216579
申请日：2011-08-24
申请人： Yuriy V. Mikhaylik , Igor Kovalev , Helmut Moehwald , Rudiger Schmidt
发明人： Yuriy V. Mikhaylik , Igor Kovalev , Helmut Moehwald , Rudiger Schmidt
IPC分类号： H01M10/0565 , H01M4/38 , H01M4/40 , B05D3/06 , H01M10/056 , B05D5/12 , B32B38/10 , H01M10/052 , H01M4/60
CPC分类号： H01M4/581 , H01M2/145 , H01M2/1673 , H01M4/134 , H01M4/366 , H01M4/382 , H01M4/405 , H01M4/5815 , H01M4/62 , H01M10/0525 , H01M10/0565 , H01M10/0568 , H01M10/0569 , H01M2300/0037
摘要： Electrolyte materials for use in electrochemical cells, electrochemical cells comprising the same, and methods of making such materials and cells, are generally described. In some embodiments, the materials, processes, and uses described herein relate to electrochemical cells comprising sulfur and lithium such as, for example, lithium sulfur batteries. The electrolyte can comprise a polymeric material and, in some cases, an absorbed auxiliary material. For example, the electrolyte material can be capable of forming a gel, and the auxiliary material can comprise an electrolyte solvent. In some instances, the electrolyte material can comprise at least one organic (co)polymer selected from polyethersulfones. The non-fluid material in the electrolyte, when configured for use, can, alone or in combination with the optional absorbed auxiliary material, have a yield strength greater than that of lithium metal, in some embodiments. In some embodiments, the electrochemical cell (e.g., the electrolyte) can be configured such that the electrochemical cell can be cycled at relatively high temperatures without experiencing thermal runaway.
摘要翻译：通常描述用于电化学电池的电解质材料，包含它们的电化学电池以及制备这种材料和电池的方法。在一些实施方案中，本文所述的材料，方法和用途涉及包含硫和锂的电化学电池，例如锂硫电池。电解质可以包括聚合物材料，并且在一些情况下可以包含吸收的辅助材料。例如，电解质材料能够形成凝胶，辅助材料可以包含电解质溶剂。在一些情况下，电解质材料可以包含至少一种选自聚醚砜的有机（共）聚合物。在一些实施例中，电解质中的非流体材料构造成使用时，可单独使用或与任选的吸收辅助材料组合，其屈服强度大于锂金属的屈服强度。在一些实施例中，电化学电池（例如，电解质）可以被配置为使得电化学电池可以在相对较高的温度下循环，而不会发生热失控。

4. 发明申请

US20100291462A1 METHOD FOR PRODUCING MEMBRANES COATED WITH A CATALYST ON BOTH SIDES 审中-公开
标题翻译：用两层催化剂涂覆膜的方法
公开(公告)号：US20100291462A1
公开(公告)日：2010-11-18
申请号：US12063202
申请日：2006-08-15
申请人： Sven Thate , Alexander Khvorost , Helmut Moehwald , Ingolf Hennig
发明人： Sven Thate , Alexander Khvorost , Helmut Moehwald , Ingolf Hennig
IPC分类号： H01M8/10
CPC分类号： H01M8/1004 , B01D2325/10 , H01M4/8814 , H01M4/8825 , H01M4/8875 , H01M2008/1095 , Y02P70/56
摘要： The invention relates to a process for producing catalyst coated membranes for electrochemical devices, which comprises the steps A) production of a first semifinished product by application of a first ionomer layer to a first carrier, application of an anode catalyst layer to the first ionomer layer using a first catalyst ink, drying of the anode catalyst layer, B) production of a second semifinished product by application of a second ionomer layer to a second carrier, application of a cathode catalyst layer to the second ionomer layer using a second catalyst ink, drying of the cathode catalyst layer, C) removal of the first and second carrier from the first and second ionomer layer, respectively, and joining of the first semifinished product to the second semifinished product by joining of the first ionomer layer to the second ionomer layer.
摘要翻译：本发明涉及一种用于生产用于电化学装置的催化剂涂覆膜的方法，其包括以下步骤：A）通过将第一离聚物层应用于第一载体来制备第一半成品，将第一离聚物层施加阳极催化剂层使用第一催化剂油墨，阳极催化剂层的干燥，B）通过将第二离聚物层施加到第二载体来制备第二半成品，使用第二催化剂油墨将阴极催化剂层施加到第二离聚物层，阴极催化剂层的干燥，C）分别从第一和第二离聚物层除去第一和第二载体，以及通过将第一离聚物层与第二离聚物层接合而使第一半成品与第二半成品接合。

5. 发明申请

US20130118980A1 POLYMERIC MATERIAL, PRODUCTION AND USE THEREOF 审中-公开
标题翻译：聚合材料，生产和使用
公开(公告)号：US20130118980A1
公开(公告)日：2013-05-16
申请号：US13676439
申请日：2012-11-14
申请人： ANNA MUELLER-CRISTADORO , Helmut Moehwald , Jelan Kuhn
发明人： ANNA MUELLER-CRISTADORO , Helmut Moehwald , Jelan Kuhn
IPC分类号： B01D15/10 , B01D61/00 , C08G18/76
CPC分类号： B01D15/10 , B01D61/00 , B01D67/0006 , B01D71/64 , B01D71/82 , B01D2323/30 , B01J20/262 , B01J20/285 , C08G18/346 , C08G18/4854 , C08G18/7657 , C08G18/7664
摘要： The present invention relates to a polymeric material obtainable by reaction of (A) at least one polyimide selected from condensation products of (a) at least one polyisocyanate having on average at least two isocyanate groups per molecule and (b) at least one polycarboxylic acid having at least 3 COOH groups per molecule or anhydride thereof, (B) at least one diol or triol.
摘要翻译：本发明涉及通过（A）至少一种聚酰亚胺的反应获得的聚合物材料，所述聚酰亚胺选自（a）每分子平均具有至少两个异氰酸酯基团的至少一种多异氰酸酯的缩合产物和（b）至少一种多元羧酸每分子具有至少3个COOH基团或其酸酐，（B）至少一种二醇或三醇。

6. 发明授权

US08022165B2 Catalytic process for the phosphonylation of high-temperature polymers 有权
标题翻译：用于高温聚合物膦酰化的催化方法
公开(公告)号：US08022165B2
公开(公告)日：2011-09-20
申请号：US12278977
申请日：2007-02-13
申请人： Helmut Moehwald , Thorsten Bock , Rolf Muelhaupt
发明人： Helmut Moehwald , Thorsten Bock , Rolf Muelhaupt
IPC分类号： C08G79/02 , C08G79/04 , C08G79/00
CPC分类号： B01D71/82 , C08G65/48 , C08J5/2256 , C08J2385/02 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M8/1039 , H01M8/1072 , H01M2300/0082 , H01M2300/0091 , Y02P70/56
摘要： Process for preparing polymeric aromatic phosphonates and also polymeric aromatic phosphonates which can be prepared by the process of the invention and blends comprising these polymeric aromatic phosphonates and at least one further polymer and also films, composites and membranes comprising these polymers or blends, the use of the membranes of the invention in fuel cells or in separation technology and also fuel cells comprising the membranes of the invention.
摘要翻译：用于制备聚合芳族膦酸盐的方法以及可通过本发明方法制备的聚合芳族膦酸盐的方法和包含这些聚合芳族膦酸盐和至少一种其它聚合物的共混物以及包含这些聚合物或共混物的膜，复合材料和膜的方法，本发明的膜在燃料电池中或在分离技术中以及包括本发明的膜的燃料电池。

7. 发明授权

US4803596A Solid-state capacitor with an electroconductive polymer as constituent of the solid electrolyte 失效
标题翻译：具有导电聚合物作为固体电解质组分的固态电容器
公开(公告)号：US4803596A
公开(公告)日：1989-02-07
申请号：US111604
申请日：1987-10-23
申请人： Gerhard Hellwig , Ottmar Baur , Klaus Feisst , Helmut Moehwald , Helmut Muenstedt
发明人： Gerhard Hellwig , Ottmar Baur , Klaus Feisst , Helmut Moehwald , Helmut Muenstedt
IPC分类号： H01G9/028 , H01G9/02 , H01G9/025 , H01G9/00 , B01J17/00
CPC分类号： H01G9/025 , H01G11/48 , H01G11/56 , C08G2261/312 , Y02E60/13 , Y10T29/417
摘要： In a solid-state capacitor comprising a positive and a negative electrode, a dielectric medium and a solid electrolyte, the solid electrolyte contains an electroconductive polymer as essential constituent.
摘要翻译：在包含正极和负极，电介质和固体电解质的固态电容器中，固体电解质含有导电聚合物作为必要成分。

8. 发明申请

US20140045070A1 ELECTROCHEMICAL CELLS COMPRISING POLYIMIDES 审中-公开
标题翻译：包含POLYIMIDES的电化学电池
公开(公告)号：US20140045070A1
公开(公告)日：2014-02-13
申请号：US14112554
申请日：2012-05-15
申请人： Anna Mueller-Cristadoro , Helmut Moehwald , Bernd Bruchmann , Raimund Pietruschka , Ingrid Haupt
发明人： Anna Mueller-Cristadoro , Helmut Moehwald , Bernd Bruchmann , Raimund Pietruschka , Ingrid Haupt
IPC分类号： H01M2/16 , H01M2/14
CPC分类号： H01M2/1653 , C08G18/345 , C08G18/7664 , C08G73/1035 , C08G73/1042 , C08G73/1067 , C08G73/1082 , C08G73/1085 , H01M2/145 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/587 , H01M4/625 , H01M10/0525 , H01M10/0568 , H01M10/0585
摘要： Electrochemical cell comprising (A) at least one anode as component (A), (B) at least one cathode as component (B), (C) at least one non-aqueous electrolyte as component (C), (D) at least one separator positioned between anode (A) and cathode (B), as component (D), characterized in that separator (D) is manufactured from at least one polyimide selected from branched condensation products of (a) at least one polycarboxylic acid having at least 3 COOH groups per molecule or an anhydride or ester thereof, and (b) and at least one compound, selected from (b1) at least one polyamine having on average more than two amino groups per molecule and (b2) at least one polyisocyanate having on average more than two isocyanate groups per molecule.
摘要翻译：电化学电池，其包含（A）至少一种作为组分（A）的阳极，（B）至少一种作为组分（B）的阴极，（C）至少一种非水电解质作为组分（C），（D）至少位于阳极（A）和阴极（B）之间的一个分离器，作为组分（D），其特征在于分离器（D）由至少一种选自以下的聚酰亚胺制成：（a）至少一种多元羧酸的分支缩合产物，每分子含有至少3个COOH基团或其酸酐或酯，和（b）和至少一种选自（b1）至少一种每分子平均具有多于两个氨基的多胺的化合物和（b2）至少一种多异氰酸酯每个分子平均有两个以上的异氰酸酯基团。

9. 发明申请

US20130164635A1 USE OF EXPANDED GRAPHITE IN LITHIUM/SULPHUR BATTERIES 有权
标题翻译：在锂/硫电池中使用膨胀石墨
公开(公告)号：US20130164635A1
公开(公告)日：2013-06-27
申请号：US13700696
申请日：2011-05-26
申请人： Ruediger Schmidt , Alexander Panchenko , Bastian Ewald , Philip Hanefeld , Sorin Ivanovici , Helmut Moehwald , Igor P. Kovalev
发明人： Ruediger Schmidt , Alexander Panchenko , Bastian Ewald , Philip Hanefeld , Sorin Ivanovici , Helmut Moehwald , Igor P. Kovalev
IPC分类号： H01M4/133
CPC分类号： H01M4/133 , H01M4/0485 , H01M4/136 , H01M4/1397 , H01M4/38 , H01M4/621 , H01M4/625 , H01M10/052 , Y02E60/122
摘要： The present invention relates to a solid composite for use in the cathode of a lithium- sulphur electric current producing cell wherein the solid composite comprises 1 to 75 wt.-% of expanded graphite, 25 to 99 wt.-% of sulphur, 0 to 50 wt.-% of one or more further conductive agents other than expanded graphite, and 0 to 50 wt.-% one or more binder, based on the total amount of the solid composite, a lithium-sulphur electric current producing cell comprising (i) a cathode comprising the solid composite, (ii) an anode and (iii) an electrolyte interposed between said cathode and said anode, and a process for preparing the solid composite comprising the steps (I) preparing a slurry comprising sulphur, expanded graphite, and optionally further components in a liquid medium by dispersing the sulphur, the expanded graphite, and optionally the further components in the liquid medium; (H) casting the slurry provided in step (I) on a substrate or placing the slurry provided in step (I) into a mold; and (III) removing some or all of the liquid medium from the slurry cast in step (II) to form a solid composite.
摘要翻译：本发明涉及一种用于锂硫电流电池的阴极的固体复合材料，其中固体复合材料包含1至75重量％的膨胀石墨，25至99重量％的硫，0至 50重量％的膨胀石墨以外的一种或多种其它导电剂和0至50重量％的一种或多种粘合剂，基于固体复合材料的总量，锂 - 硫电流产生电池包含（ i）包含固体复合材料的阴极，（ii）阳极和（iii）介于所述阴极和所述阳极之间的电解质，以及制备所述固体复合材料的方法，包括步骤（I）制备包含硫，膨胀石墨，以及任选地通过将硫，膨胀石墨和任选的其它组分分散在液体介质中的液体介质中的其它组分; （H）将步骤（I）中提供的浆料浇铸在基材上或将步骤（I）中提供的浆料放入模具中; 和（III）从步骤（II）中浇铸的浆料中除去一些或全部液体介质以形成固体复合材料。

10. 发明申请

US20120082901A1 LITHIUM-BASED ANODE WITH IONIC LIQUID POLYMER GEL 审中-公开
标题翻译：具有离子液体聚合物凝胶的基于锂的阳极
公开(公告)号：US20120082901A1
公开(公告)日：2012-04-05
申请号：US13249632
申请日：2011-09-30
申请人： Rudiger Schmidt , Daher Michael Badine , Helmut Moehwald , Igor Kovalev , Yuriy V. Mikhaylik
发明人： Rudiger Schmidt , Daher Michael Badine , Helmut Moehwald , Igor Kovalev , Yuriy V. Mikhaylik
IPC分类号： H01M10/056 , H01M4/38 , H01M4/04 , H01M4/48 , H01M4/485 , H01M4/58 , H01M4/62 , H01M4/40
CPC分类号： H01M10/0525 , H01M4/133 , H01M4/134 , H01M10/052 , H01M10/0563 , H01M2300/0045
摘要： Li-based anodes for use in an electric current producing cells having long life time and high capacity are provided. In certain embodiments, the Li-based anode comprises at least one anode active Li-containing compound and a composition comprising at least one polymer, at least one ionic liquid, and optionally at least one lithium salt. The composition may be located between the at least one Li-containing compound and the catholyte used in the electric current producing cell. In some embodiments, the at least one polymer may be incompatible with the catholyte. This configuration of components may lead to separation between the lithium active material of the anode and the catholyte. Processes for preparing the Li-based anode and to electric current producing cells comprising such an anode are also provided.
摘要翻译：提供了用于具有长寿命和高容量的电流产生电池的基于锂的阳极。在某些实施方案中，Li基阳极包含至少一种含阳极活性Li的化合物和包含至少一种聚合物，至少一种离子液体和任选的至少一种锂盐的组合物。组合物可以位于至少一种含Li化合物和在电流产生电池中使用的阴极电解液之间。在一些实施方案中，至少一种聚合物可能与阴极电解液不相容。组分的这种配置可能导致阳极的锂活性材料与阴极电解液之间的分离。还提供了用于制备Li基阳极和包括这种阳极的电流产生单元的方法。

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