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    • 2. 发明授权
    • Perfluoroaliphatic substituted amine mixtures and the method for
preparing the same
    • 全氟脂肪族取代胺混合物及其制备方法
    • US4059629A
    • 1977-11-22
    • US593173
    • 1975-07-03
    • Louis FoulletierJean-Pierre Lalu
    • Louis FoulletierJean-Pierre Lalu
    • C07B61/00C07C215/08C07C215/24C07C233/02C07C233/12C07F7/12C08F20/56C10M169/00D06M13/322D06M13/33D06M13/408D06M15/277D06M15/295C07C87/127C07C87/22C07C87/26C07C87/32
    • D06M15/295C07B61/00C07C215/08C07C215/24C07C233/02C07C233/12C07F7/12C08F20/56C10M1/08C10M169/00D06M13/322D06M13/33D06M13/408D06M15/277C10M2215/04C10M2215/044C10M2215/06C10M2215/26
    • The invention comprises perfluoroalkyl substituted amines of the formula ##STR1## wherein n is an integer from 1 to about 20, m is an integer between 2 or 4, R.sup.1 and R.sup.2 each is a hydrogen atom or a lower alkyl containing 1 to 3 carbon atoms and R.sup.3 and R.sup.4 each is a hydrogen atom, an alkyl containing 1 to 20 carbon atoms, an alkenyl containing 3 to 10 carbon atoms, a cycloparaffin radical containing 3 to 12 carbon atoms, a cycloalkenyl radical containing 5 to 12 carbon atoms, and N or O ring substituted cycloalkenyl radical containing 5 to 12 carbon atoms, or an aryl, or R.sup.3 or R.sup.4 are joined in the form of an alkylene radical of the formula--(CHR).sub.p --wherein p is an integer from 2 to 6 and R is a hydrogen atom or a lower alkyl containing 1 to 3 carbon atoms. These compounds are prepared by reacting at a temperature in the range between 0.degree. to 200.degree. C. perfluoroalkyl halides of the formulaC.sub.n F.sub.2n+1 (CR.sup.1 R.sup.2).sub.m Y (II)wherein n, m, R.sup.1 and R.sup.2 each has the same meaning as defined hereinabove and Y is an iodine or a bromine atom with amines of the formula ##STR2## wherein R.sup.3 and R.sup.4 have the same meaning as previously stated. The invention also comprises perfluoroalkyl substituted amines of the formula ##STR3## and mixtures of products of formula IV with ##STR4## in which R.sup.1, R.sup.3 and R.sup.4 have the same meaning as designated above and where n is an integer from 4 to 20.The process for producing the products of formulas IV and V and mixtures thereof is the same as that used for the products of the compounds of formula I except that in the starting compounds of formula II at least one of the radicals R.sup.1 or R.sup.2 is hydrogen, m is equal to 2 and n is an integer between 4 and 20.
    • 本发明包括式(I)的全氟烷基取代的胺,其中n为1至约20的整数,m为2或4之间的整数,R 1和R 2各自为氢原子或含有1至 3个碳原子,R 3和R 4各自为氢原子,含有1至20个碳原子的烷基,含有3至10个碳原子的烯基,含有3至12个碳原子的环烷基,含有5至12个碳原子的环烯基 ,并且含有5至12个碳原子的N或O环取代的环烯基或芳基或R 3或R 4以式 - (CHR)p - 亚烷基的亚烷基的形式连接在一起,从2到 6 AND R是氢原子或含有1至3个碳原子的低级烷基。 这些化合物通过在0℃至200℃范围内的温度下反应制备,式C n F 2n + 1(CR 1 R 2)m Y(II)的全氟烷基卤化物,其中n,m,R 1和R 2各自具有与所定义相同的含义 并且Y是碘或溴原子与式(III)的胺,其中R3和R4具有与前述相同的含义。