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1. 发明授权

US4610829A Polyfluorinated sulphonic acids and their derivatives 失效
标题翻译：多氟磺酸及其衍生物
公开(公告)号：US4610829A
公开(公告)日：1986-09-09
申请号：US966508
申请日：1978-12-04
申请人： Jean-Pierre Lalu , Louis Foulletier
发明人： Jean-Pierre Lalu , Louis Foulletier
IPC分类号： C07B45/02 , C07C309/06 , C11D1/00 , C23F11/16 , C07C143/70
CPC分类号： C07C309/06 , C07B45/02 , C11D1/004 , C23F11/16 , Y10S516/03
摘要： New products and compositions of matter complying with the general formula:[C.sub.n F.sub.2n+1 --CH.sub.2 --.sub.b SO.sub.2 --Z].sub.d Mwherein: C.sub.n F.sub.2n+1 represents a straight or ramified branched perfluorinated chain: n represents a whole number between 1 and 20, b is a whole number between 2 and 20, preferably equal to 2 or 4, Z represents a chlorine, bromine or an oxygen atom (when Z is a chlorine or a bromine atom, M is nothing and d is equal to 1), when Z is an oxygen atom: M is a hydrogen atom in which case, d is equal to 1, M is a metal of the Groups I.sub.A, II.sub.A, I.sub.B, II.sub.B, VIII of the periodic table, the ammonium radical, the aluminum or the lead radical, and in which case d represents the valence of this metal and methods for preparing new products as illustrated by the following representative reactions.
摘要翻译：新产品和符合以下通式的物质组成：[CnF2n + 1-CH2-bSO2-Z] dM其中：CnF2n + 1表示直链或支链支化全氟链：n表示1〜20的整数，b表示 2〜20的整数，优选2或4，Z表示氯，溴或氧原子（当Z为氯或溴原子时，M为无，d为1），当Z为氧原子：M是氢原子，在这种情况下，d等于1，M是元素周期表中IA，IIA，IB，IIB，VIII族的金属，铵基，铝或铅自由基，并且在这种情况下，d表示该金属的化合价和制备新产品的方法，如以下代表性反应所示。

2. 发明授权

US4000175A Polyfluorinated quaternary ammonium salts 失效
标题翻译：多氟季铵盐
公开(公告)号：US4000175A
公开(公告)日：1976-12-28
申请号：US39147
申请日：1970-05-20
申请人： Louis Foulletier , Jean-Pierre Lalu
发明人： Louis Foulletier , Jean-Pierre Lalu
IPC分类号： C09D7/00 , B01F17/00 , B03D1/001 , B03D1/01 , C07C67/00 , C07C213/00 , C07C213/02 , C07C215/40 , C08J7/06 , C09D7/12 , C09K3/00 , C09K3/18 , C07C141/04 , C07C87/30 , C07C91/26
CPC分类号： B03D1/01 , B01F17/0042 , B01F17/0057 , B03D1/012 , B03D2203/02
摘要： This invention relates to new products of the general formula: ##STR1## wherein C.sub.n F.sub.2n.sub.+1 represents a straight or branched perfluorinated hydrocarbon chain in which n is a number between 1 and 20; a is an even number having the value 2 or 4; R represents a hydrogen atom or the methyl radical; Z represents an alkyl hydrocarbon radical containing from 1 to 8 carbon atoms, or the radical -- CH.sub.2 -- CHOHR, or a cycloalkyl hydrocarbon radical containing from 5 to 9 carbon atoms or an aryl hydrocarbon radical containing from 6 to 10 carbon atoms; R' represents an alkyl hydrocarbon radical containing from 1 to 9 carbon atoms; and X is an anion which can be a halide, a sulphate, or an alkyl sulphate. These products are useful as surface active agents.

3. 发明授权

US4000168A Carboxylated polyfluoroamines 失效
标题翻译：羧氧基多氟胺
公开(公告)号：US4000168A
公开(公告)日：1976-12-28
申请号：US495220
申请日：1974-08-06
申请人： Rene Bertocchio , Louis Foulletier , Jean-Pierre Lalu
发明人： Rene Bertocchio , Louis Foulletier , Jean-Pierre Lalu
IPC分类号： C09D7/45 , C09D7/47 , C10M133/16
CPC分类号： C09D7/06 , C09D7/02 , C10M133/16 , C10M2211/00 , C10N2250/10
摘要： This invention relates to carboxylated polyfluoroamine compounds of the general formula ##STR1## wherein the radical C.sub.n F.sub.2n.sub.+1 -- is a straight or branched perfluorinated chain, n is an integer from 1 to 20, a is an integer from 2 to 10, p is an integer from 1 to 10, R.sup.2 and R.sup.3 each is an alkyl radical containing from 1 to 6 carbon atoms and R.sup.1 is a hydrogen atom or an alkyl radical containing from 1 to 6 carbon atoms and the process for their preparation.

4. 发明授权

US4059629A Perfluoroaliphatic substituted amine mixtures and the method for preparing the same 失效
标题翻译：全氟脂肪族取代胺混合物及其制备方法
公开(公告)号：US4059629A
公开(公告)日：1977-11-22
申请号：US593173
申请日：1975-07-03
申请人： Louis Foulletier , Jean-Pierre Lalu
发明人： Louis Foulletier , Jean-Pierre Lalu
IPC分类号： C07B61/00 , C07C215/08 , C07C215/24 , C07C233/02 , C07C233/12 , C07F7/12 , C08F20/56 , C10M169/00 , D06M13/322 , D06M13/33 , D06M13/408 , D06M15/277 , D06M15/295 , C07C87/127 , C07C87/22 , C07C87/26 , C07C87/32
CPC分类号： D06M15/295 , C07B61/00 , C07C215/08 , C07C215/24 , C07C233/02 , C07C233/12 , C07F7/12 , C08F20/56 , C10M1/08 , C10M169/00 , D06M13/322 , D06M13/33 , D06M13/408 , D06M15/277 , C10M2215/04 , C10M2215/044 , C10M2215/06 , C10M2215/26
摘要： The invention comprises perfluoroalkyl substituted amines of the formula ##STR1## wherein n is an integer from 1 to about 20, m is an integer between 2 or 4, R.sup.1 and R.sup.2 each is a hydrogen atom or a lower alkyl containing 1 to 3 carbon atoms and R.sup.3 and R.sup.4 each is a hydrogen atom, an alkyl containing 1 to 20 carbon atoms, an alkenyl containing 3 to 10 carbon atoms, a cycloparaffin radical containing 3 to 12 carbon atoms, a cycloalkenyl radical containing 5 to 12 carbon atoms, and N or O ring substituted cycloalkenyl radical containing 5 to 12 carbon atoms, or an aryl, or R.sup.3 or R.sup.4 are joined in the form of an alkylene radical of the formula--(CHR).sub.p --wherein p is an integer from 2 to 6 and R is a hydrogen atom or a lower alkyl containing 1 to 3 carbon atoms. These compounds are prepared by reacting at a temperature in the range between 0.degree. to 200.degree. C. perfluoroalkyl halides of the formulaC.sub.n F.sub.2n+1 (CR.sup.1 R.sup.2).sub.m Y (II)wherein n, m, R.sup.1 and R.sup.2 each has the same meaning as defined hereinabove and Y is an iodine or a bromine atom with amines of the formula ##STR2## wherein R.sup.3 and R.sup.4 have the same meaning as previously stated. The invention also comprises perfluoroalkyl substituted amines of the formula ##STR3## and mixtures of products of formula IV with ##STR4## in which R.sup.1, R.sup.3 and R.sup.4 have the same meaning as designated above and where n is an integer from 4 to 20.The process for producing the products of formulas IV and V and mixtures thereof is the same as that used for the products of the compounds of formula I except that in the starting compounds of formula II at least one of the radicals R.sup.1 or R.sup.2 is hydrogen, m is equal to 2 and n is an integer between 4 and 20.
摘要翻译：本发明包括式（I）的全氟烷基取代的胺，其中n为1至约20的整数，m为2或4之间的整数，R 1和R 2各自为氢原子或含有1至 3个碳原子，R 3和R 4各自为氢原子，含有1至20个碳原子的烷基，含有3至10个碳原子的烯基，含有3至12个碳原子的环烷基，含有5至12个碳原子的环烯基，并且含有5至12个碳原子的N或O环取代的环烯基或芳基或R 3或R 4以式 - （CHR）p - 亚烷基的亚烷基的形式连接在一起，从2到 6 AND R是氢原子或含有1至3个碳原子的低级烷基。这些化合物通过在0℃至200℃范围内的温度下反应制备，式C n F 2n + 1（CR 1 R 2）m Y（II）的全氟烷基卤化物，其中n，m，R 1和R 2各自具有与所定义相同的含义并且Y是碘或溴原子与式（III）的胺，其中R3和R4具有与前述相同的含义。

5. 发明授权

US4062849A Perfluoroalkylene quaternary heterocyclic nitrogen salts 失效
标题翻译：全氟亚烷基季铵杂环氮盐
公开(公告)号：US4062849A
公开(公告)日：1977-12-13
申请号：US696727
申请日：1976-06-16
申请人： Louis Foulletier , Jean-Pierre Lalu
发明人： Louis Foulletier , Jean-Pierre Lalu
IPC分类号： C07D215/10 , C07D217/10 , C07D219/02 , C07D219/00
CPC分类号： C07D217/10 , C07D215/10 , C07D219/02
摘要： New compositions having the following general formula: ##STR1## in which A. C.sub.n F.sub.2n+1 represents a straight or branched perfluorinated chain with n being 1 and 20.B. X.sup.- is an anion such as a halogen, a sulfate, an alkyl sulfate.Of these anions the preferred ones are halogens such as the fluoride, chloride, bromide and iodide, or sulfates such asCH.sub.3 SO.sub.4.sup.-,c. R', R" and R'" correspond to the following definitions:1. R' is an alkyl radical containing from 1 to 8 atoms of carbons, in which eventI. R" and R'" can be either the same as R' or different, namely, alkyl radicals containing from 1 to 8 atoms of carbon. R" and R'" can also be cycloalkyl radicals containing from 5 to 10 carbon atoms or alkenyl radicals containing from about 3 to 8 atoms of carbon, or cycloalkenyl radicals containing from 5 to 9 atoms of carbon, or ayrl radicals.Ii. R" and R'" together make up a divalent radical linked to the nitrogen by two simple bonds such as cycloalkyl radicals containing from 4 to 9 carbon atoms, cycloalkenyl radicals containing 4 to 9 carbons, or cyclodienic radicals containing from 4 to 9 carbons.2. R', R" and R'" make up together the remainder of an aromatic tertiary amine derived from the pyridine containing from 5 to 18 carbons. Of these aromatic tertiary amine remainders, the preferred ones are C.sub.5 H.sub.5 (pyridine), C.sub.6 H.sub.8 (the picolines), C.sub.9 H.sub.7 (quinoline and isoquinoline), and C.sub.13 H.sub.9 (acridine).
摘要翻译：具有以下通式的新组合物：其中A.CnF2n + 1表示直链或支链全氟链，其中n为1和20。

6. 发明授权

US3997604A Mixtures of perfluoroaliphatic substituted amino compounds and the method for preparing the same 失效
标题翻译：全氟脂肪族取代氨基化合物的混合物及其制备方法
公开(公告)号：US3997604A
公开(公告)日：1976-12-14
申请号：US138810
申请日：1971-04-29
申请人： Louis Foulletier , Jean-Pierre Lalu
发明人： Louis Foulletier , Jean-Pierre Lalu
IPC分类号： C07B61/00 , C07C215/08 , C07C215/24 , C07C233/02 , C07C233/12 , C08F20/56 , C10M133/04 , C10M169/00 , D06M13/322 , D06M13/33 , D06M13/408 , D06M15/277 , C07C103/58
CPC分类号： D06M15/277 , C07B61/00 , C07C215/08 , C07C215/24 , C07C233/02 , C07C233/12 , C08F20/56 , C10M1/08 , C10M133/04 , C10M169/00 , D06M13/322 , D06M13/33 , D06M13/408 , C10M2215/04 , C10M2215/044 , C10M2215/06 , C10M2215/26
摘要： This invention comprises perfluoroaliphatic substituted amino compounds of the formula ##STR1## wherein n is an integer from 6 to 20, m is 2 or 4, R.sup.1 and R.sup.2 each is hydrogen atom or a lower alkyl with 1 to 3 carbon atoms, R.sup.3 is a hydrogen atom, an alkyl containing 1 to 29 carbon atoms, an alkenyl containing 3 to 10 carbon atoms, a cycloalkyl radical containing 3 to 12 carbon atoms, a cycloalkenyl with 5 to 12 carbon atoms, an N or O ring substituted cycloalkenyl radical containing 5 to 12 carbon atoms, an aryl, the radical --(CHR).sub.1 --OH wherein R is a hydrogen atom or a lower alkyl containing 1 to 3 carbon atoms, and R.sup.4 is a hydrogen atom or a methyl group and the method for preparing the same. This invention also comprises perfluoroaliphatic substituted amino compounds of the formula ##STR2## and mixtures of products of formula II with compounds of the formula ##STR3## and the method for preparing the same. The compounds are strong oleophobic and hydrophobic agents.
摘要翻译：本发明包括式（1）的全氟脂肪族取代的氨基化合物，其中n为6至20的整数，m为2或4，R 1和R 2各自为氢原子或具有1至3个碳原子的低级烷基， R3为氢原子，含有1〜29个碳原子的烷基，含有3〜10个碳原子的烯基，含有3〜12个碳原子的环烷基，具有5〜12个碳原子的环烯基，N或O环取代的环烯基含有5至12个碳原子的基团，芳基，基团 - （CHR）1-OH其中R是氢原子或含有1至3个碳原子的低级烷基，R4是氢原子或甲基，并且该方法为准备相同。本发明还包括式（II）的全氟脂肪族取代的氨基化合物和式II的产物与式“IMAGE”的化合物的混合物及其制备方法。这些化合物是强疏油和疏水剂。

7. 发明授权

US4876406A Process for gaseous phase fluorination of aliphatic chlorinated or chlorofluorinated hydrocarbons 失效
标题翻译：脂肪族氯化或氯氟化烃的气相氟化方法
公开(公告)号：US4876406A
公开(公告)日：1989-10-24
申请号：US669404
申请日：1984-11-08
申请人： Louis Foulletier
发明人： Louis Foulletier
IPC分类号： B01J23/26 , B01J27/18 , B01J27/188 , B01J35/10 , C07B61/00 , C07C17/00 , C07C17/20 , C07C19/08 , C07C19/10 , C07C19/12 , C07C67/00
CPC分类号： B01J27/18 , B01J23/26 , B01J35/0026 , B01J35/1019 , B01J35/1061 , B01J35/108 , C07C17/206
摘要： This invention relates to improved catalysts for gaseous phase fluoridation of aliphatic chlorinated and chlorofluorinated hydrocarbons by hydrofluoric acid. The catalysts comprise chromium salts or oxides complexed with aluminum phosphate and are characterized by a total specific surface area greater than about 200 m.sup.2 /g, but less than about 1000 m.sup.2 /g a surface area of pores of 40 to 50 .ANG. in radius above about 5 m.sup.2 /g, but less than about 150 m.sup.2 /g, a surface area of pores greater than or equal to 250 .ANG. in radius above about 2 m.sup.2 /g. but less than about 60 m.sup.2 /g. This invention also relates to gaseous phase fluoridation processes for chlorinated or chlorofluorinated derivatives utilizing these catalysts in fluidized bed reactors.
摘要翻译：本发明涉及通过氢氟酸进行脂族氯化和氯氟化烃气相氟化改进的催化剂。催化剂包括与磷酸铝络合的铬盐或氧化物，其特征在于总共比表面积大于约200m 2 / g，但小于约1000m 2 / ga的孔的表面积为40至50，半径大于约5 m 2 / g，但小于约150m 2 / g，大于或等于250的孔的表面积大约在2m 2 / g以上。但小于约60m2 / g。本发明还涉及在流化床反应器中利用这些催化剂的氯化或氯氟化衍生物的气相氟化方法。

8. 发明授权

US4474895A Catalysts for gaseous phase fluorination of aliphatic chlorinated and chlorofluorinated hydrocarbons 失效
标题翻译：用于脂族氯化和氯氟化烃气相氟化的催化剂
公开(公告)号：US4474895A
公开(公告)日：1984-10-02
申请号：US324414
申请日：1981-11-24
申请人： Louis Foulletier
发明人： Louis Foulletier
IPC分类号： B01J21/18 , B01J23/26 , B01J35/10 , B01J37/26 , C07B61/00 , C07C17/00 , C07C17/20 , C07C19/08 , C07C19/10 , C07C19/12 , C07C45/63 , C07C67/00 , B01J27/12
CPC分类号： B01J35/10 , B01J21/18 , B01J23/26 , C07C17/206 , C07C45/63 , B01J35/1028 , B01J35/1061
摘要： This invention relates to improved catalysts for gaseous phase fluorination of aliphatic chlorinated and chlorofluorinated hydrocarbons by hydrofluoric acid. The catalysts are characterized by an active carbon support having a total specific surface area greater than about 1000 m.sup.2 /g but less than about 2000 m.sup.2 /g, a surface area of pores of 40 to 50 .ANG. in radius above about 5 m.sup.2 /g but less than about 15 m.sup.2 /g, a surface area of pores greater than or equal to 250 .ANG. in radius above about 2 m.sup.2 /g but less than about 6 m.sup.2 /g, which has been impregnated with an aqueous chromium trioxide solution and dried. This invention also relates to gaseous phase fluorination processes for chlorinated or chlorofluorinated derivatives utilizing these catalysts in fluidized bed reactors.
摘要翻译：本发明涉及通过氢氟酸进行脂族氯化和氯氟化烃气相氟化改进的催化剂。催化剂的特征在于具有大于约1000m 2 / g但小于约2000m 2 / g的总比表面积的活性炭载体，半径在约5m 2 / g以上的孔的表面积为40至50，但是小于约15m 2 / g，大于或等于250的孔的表面积大于约2m 2 / g但小于约6m 2 / g，其已用三氧化铬水溶液浸渍并干燥。本发明还涉及在流化床反应器中利用这些催化剂的氯化或氯氟化衍生物的气相氟化方法。

9. 发明授权

US4069158A Fire extinguishing compositions 失效
标题翻译：灭火组合物
公开(公告)号：US4069158A
公开(公告)日：1978-01-17
申请号：US678929
申请日：1976-04-21
申请人： Rene Bertocchio , Louis Foulletier
发明人： Rene Bertocchio , Louis Foulletier
IPC分类号： A62D1/00 , A62D1/02 , A62C1/00 , B01F17/30
CPC分类号： A62D1/0085 , A62D1/0042 , A62D1/0064 , Y10S516/06
摘要： Aqueous fire-extinguishing compositions comprising a mixture of (1) a nonionic surface-active agent, (2) a amphoteric surface active agent and (3) a fluorinated cationic surface active agent containing as a part of the molecule an aromatic radical.
摘要翻译：水性灭火组合物，其包含（1）非离子表面活性剂，（2）两性表面活性剂和（3）作为分子的一部分含有芳香族基团的氟化阳离子表面活性剂的混合物。

10. 发明授权

US4059626A Trifluoroethylanilines 失效
标题翻译：三氟乙基苯胺
公开(公告)号：US4059626A
公开(公告)日：1977-11-22
申请号：US562063
申请日：1975-03-26
申请人： Louis Foulletier , Jacques Pierre Edmond Pechmeze , Robert Frederic Michel Sureau
发明人： Louis Foulletier , Jacques Pierre Edmond Pechmeze , Robert Frederic Michel Sureau
IPC分类号： C07C211/52 , A61K31/135 , C07C20060101 , C07C67/00 , C07C209/00 , C09B29/00 , C07C87/52 , C07C87/56 , C07C91/44 , C07C93/14
CPC分类号： C07C205/12
摘要： Compound of the formula: ##STR1## in which the nucleus A is unsubstituted or substituted by one or two nitro, amino, alkyl, alkoxy, chlorine or bromine and the alkyl and alkoxy each contain up to two carbon atoms capable of being used as intermediate products for preparing dyestuffs, pharmaceutical products or phytopharmaceutical products.
摘要翻译：下式的化合物：其中核A未被取代或被一个或两个硝基，氨基，烷基，烷氧基，氯或溴取代，并且烷基和烷氧基各自含有最多两个可用作中间体的碳原子制备染料，药品或植物药品的产品。

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