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    • 3. 发明申请
    • Process for removing volatile components in polyarylene sulfide
    • 去除聚芳硫醚中挥发性成分的方法
    • US20040164439A1
    • 2004-08-26
    • US10368564
    • 2003-02-20
    • IDEMITSU PETROCHEMICAL CO., LTD.PETROLEUM ENERGY CENTER
    • Yoshinari Koyama
    • B29C047/60B29C047/76
    • B29C47/767B29C47/0009B29C47/40B29C47/6056B29C47/64B29C47/763
    • There is disclosed a process for removing volatile components in a polyarylene sulfide resin which is produced by subjecting a sulfur source and a dihalogenated aromatic compound to polymerization reaction in an aprotic organic solvent, comprising using an extruder which is equipped with front vent having an opening length in the range of 4D to 11D (D: screw diameter) and which has a distance between a terminal position of a screw in a kneading portion and the opening portion of the front vent being in the range of 4D to 15D. The process is capable of steadily and economically removing volatile components in the polyarylene sulfide resin without necessitating expensive machinery or equipment such as a dryer without plugging up the opening portion of a vent even in the case of degassing a PAS resin having a low molecular weight and further, thus enabling a long-term continuous stable running.
    • 公开了一种除去聚亚芳基硫醚树脂中的挥发性组分的方法,该方法是通过使硫源和二卤代芳族化合物在非质子性有机溶剂中进行聚合反应而制备的,其包括使用挤出机,该挤出机配备有具有开口长度 在4D至11D(D:螺杆直径)的范围内,并且其具有揉捏部分中的螺杆的终端位置与前排气孔的开口部分之间的距离在4D至15D的范围内。 该方法能够稳定且经济地除去聚芳硫醚树脂中的挥发性组分,而不需要昂贵的机械或设备如干燥机,而不会堵塞排气孔的开口部分,即使在脱气低分子量的PAS树脂的情况下, 从而能够长期持续稳定运行。
    • 4. 发明申请
    • Method for removing water and other volatile components from polymer powders
    • 从聚合物粉末中除去水和其他挥发性成分的方法
    • US20030067089A1
    • 2003-04-10
    • US09942066
    • 2001-08-29
    • General Electric Company
    • Hua WangEric Thomas Gohr
    • B29C047/38B29C047/40B29C047/60B29C047/76B29C047/80B29C047/82
    • B29C47/0825B29C47/0009B29C47/0808B29C47/40B29C47/60B29C47/76B29K2069/00C08G64/406
    • A method for removing volatile components from wet, polymer powders using a vacuum vented extruder is described. Polymer powders containing substantial amounts of water, 1-20% by weight, are rapidly converted to polymer compositions containing less than about 0.5% by weight water at high throughput rates while avoiding complications resulting from excessive steam backflow through the extruder feed throat. The method provides a screw design comprising a powder seal section upstream of kneading and melting sections of the extruder. Steam generated as the polymer is heated flows downstream to one or more vacuum vents for removal. The partially devolatilized polymer melt is then subjected to additional melt kneading and vacuum venting. The method converts wet polycarbonate powder containing residual methylene chloride to essentially dry polycarbonate powder containing less than about 1 ppm methylene chloride.
    • 描述了使用真空排气挤出机从湿聚合物粉末中除去挥发性组分的方法。 含有相当量1-20%(重量)的水的聚合物粉末可快速转化为含有低于约0.5%(重量)水的聚合物组合物,同时避免由挤压机进料喉部过量蒸汽回流引起的并发症。 该方法提供了一种螺杆设计,其包括在挤出机的捏合和熔化部分上游的粉末密封部分。 当聚合物被加热时产生的蒸汽向下游流动到一个或多个真空通风口以便去除。 然后对部分脱挥发分的聚合物熔体进行额外的熔融捏合和真空排气。 该方法将含有残余二氯甲烷的湿聚碳酸酯粉末转化成含有少于约1ppm二氯甲烷的基本上干燥的聚碳酸酯粉末。
    • 10. 发明申请
    • Polyethyleneterephthalate extrusion equipment
    • 聚对苯二甲酸乙二醇酯挤出设备
    • US20020100995A1
    • 2002-08-01
    • US10056954
    • 2002-01-25
    • Franco BanderaEnrico Venegoni
    • B29C047/60B29C047/76
    • B29C47/767B29C47/0011B29C47/38B29C47/402B29C47/6025B29K2067/00
    • Polyethyleneterephthalate extrusion equipment of material in granule form, still humid, coming from both ground recovered products and also virgin material, comprising a chassis (29), containing a co-rotating, oil-thermoregulated extruder with two screws (31, 32), which comprises a first zone (A), equipped with an opening (34) where there is an aspiration hood (35) for a first nullopen topnull degassing, a second zone (C) where there is at least one stack (37, 38) for a further degassing, between the two zones (A, C), there being a tight zone (B), and a carrying and loading zone (E) activated by the screws (31, 32). The description also relates to an extrusion process of polyethyleneterephthalate effected in a co-rotating twin-screw extruder which comprises in a first zone (A) an nullopen topnull degassing phase, followed by a stack (37, 38) degassing phase, between the two phases there being a tight zone which does not deteriorate the material, followed by a carrying, loading and amalgamation phase of the molten material and a final pumping phase with the extrusion of polyethyleneterephthalate.
    • 聚对苯二甲酸乙二醇酯挤出设备的颗粒形式,仍然是潮湿的,来自两个研磨的回收产物和原始材料的材料,包括底盘(29),其包含具有两个螺钉(31,32)的同向旋转的油 - 温调挤出机,其中 包括配备有开口(34)的第一区域(A),其中存在用于第一“开顶”脱气的抽吸罩(35),其中存在至少一个堆叠(37,38)的第二区域 )在两个区域(A,C)之间进一步脱气,存在紧密区域(B)以及由螺钉(31,32)启动的搬运和装载区域(E)。 描述还涉及在同向旋转双螺杆挤出机中实现的聚对苯二甲酸乙二醇酯的挤出方法,其包括在第一区(A)“开顶”脱气阶段,随后是堆(37,38)脱气阶段 两相在其中存在不会使材料变质的紧密区域,随后是熔融材料的承载,加载和合并阶段以及挤出聚对苯二甲酸乙二醇酯的最终泵送阶段。