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1. 发明授权

US12102151B2 Fiber for artificial hair and hair ornament product including same 有权
公开(公告)号：US12102151B2
公开(公告)日：2024-10-01
申请号：US16050584
申请日：2018-07-31
申请人： Kaneka Corporation
发明人： Mika Yorizane , Hiroshi Fujinaga , Kohei Kawamura , Tomomichi Hashimoto
IPC分类号： D01F1/07 , A41G3/00 , A41G5/00 , A63H3/44 , D01D5/22 , D01D5/24 , D01D5/253 , D01F6/62 , D01F6/78 , D01F6/32 , D01F6/40 , D01F6/60 , D01F6/64 , D01F6/76 , D01F6/84
CPC分类号： A41G3/0083 , A41G5/004 , A63H3/44 , D01D5/22 , D01D5/24 , D01D5/253 , D01F1/07 , D01F6/62 , D01F6/78 , D01F6/32 , D01F6/40 , D01F6/60 , D01F6/64 , D01F6/765 , D01F6/84 , D10B2331/04 , D10B2501/00
摘要： The present invention relates to a fiber for artificial hair having a hollow in a center of a fiber cross section. A ratio of an area of the hollow to an entire area of the fiber cross section is 5% to 50%. The fiber cross section has a flat multilobed shape, and the hollow has a first side and a second side that are inclined 70 to 110 degrees relative to a major axis of the fiber cross section. The present invention also relates to hair ornament products including the above fiber for artificial hair. Thus, the present invention provides a fiber for artificial hair having a favorable curl setting property when curling with a hair iron and a favorable combing property after curling with a hair iron, and hair ornament products including the same.

2. 发明申请

US20190241706A1 POLYPHENYLENE SULFIDE POLYMERS HAVING IMPROVED MELT-STABILITY 审中-公开
公开(公告)号：US20190241706A1
公开(公告)日：2019-08-08
申请号：US15889553
申请日：2018-02-06
申请人： SOLVAY SPECIALTY POLYMERS USA, LLC
发明人： Hong CHEN , Peter MUSHENHEIM , Lee CARVELL , Erik NELSON , Charles R. HOPPIN
IPC分类号： C08G75/0231 , C08G75/0213 , C08G75/0259 , D01F6/76
CPC分类号： C08G75/0231 , C08G75/00 , C08G75/02 , C08G75/0209 , C08G75/0213 , C08G75/0259 , D01F6/765 , D10B2401/04 , D10B2505/04
摘要： Described here are polyphenylene sulfide (“PPS”) polymers having significantly improved processability. It was surprisingly found that PPS polymers, terminated with specific end-capping agents in specific amounts, had significantly improved melt stability. Because of the significantly improved melt stability, the PPS polymers can be advantageously incorporated into melt processing techniques.

3. 发明申请

US20170226292A1 POLYPHENYLENE SULFIDE FIBER 审中-公开
公开(公告)号：US20170226292A1
公开(公告)日：2017-08-10
申请号：US15515519
申请日：2015-09-24
申请人： Toray Industries, Inc.
发明人： Hiroo Katsuta , Reo Mitsunaga , Daisuke Yamamoto , Shunsuke Horiuchi , Yoshitsugu Funatsu
IPC分类号： C08G75/16 , C08L23/32 , C08G75/02 , D01F6/76 , B01D39/08 , C08K5/375 , D01D5/12
CPC分类号： D01F6/765 , D02J1/22 , D02J13/00 , D02J13/005
摘要： A poly(phenylene sulfide) fiber changes little in fiber structure and has excellent long-term heat resistance. Namely, the poly(phenylene sulfide) fiber has a degree of crystallization of 45.0% or higher, a content of movable amorphous components of 15.0% or less, and a weight-average molecular weight of 300,000 or less.

4. 发明申请

US20160297172A1 LAMINATED BODY AND PROCESS FOR PRODUCING THE SAME 审中-公开
标题翻译：层压体及其制造方法
公开(公告)号：US20160297172A1
公开(公告)日：2016-10-13
申请号：US14777934
申请日：2014-03-25
申请人： TORAY INDUSTRIES, INC.
发明人： Satoshi Naruko , Takashi Kimura , Tatsushi Kamiya , Takahiro Masegi , Shinichi Kondo
IPC分类号： B32B5/02 , B32B37/14 , B32B27/06 , B32B37/10
CPC分类号： B32B5/022 , B32B5/08 , B32B7/04 , B32B27/06 , B32B27/12 , B32B27/286 , B32B27/36 , B32B37/10 , B32B37/14 , B32B2250/02 , B32B2262/00 , B32B2262/02 , B32B2262/0215 , B32B2274/00 , B32B2307/206 , B32B2307/306 , B32B2307/704 , B32B2307/738 , B32B2457/04 , D01F6/765 , D21H13/20 , D21H27/30
摘要： A laminated body that exhibits heat resistance, chemical resistance, good interfacial adhesion, good varnish-impregnation and also has a three-dimensional formability and results in low variability in the shapes of the products in a forming process and an excellent forming process yield. The laminated body includes a thermoplastic resin sheet layer having a heat of crystallization of 10 J/g or more and a wet-laid nonwoven layer including polyphenylene sulfide fibers and having a heat of crystallization of 10 J/g or more, the wet-laid nonwoven layer being stacked on at least one surface of the thermoplastic resin sheet layer without an adhesive therebetween.
摘要翻译：具有耐热性，耐化学性，良好的界面粘合性，良好的清漆浸渍性的层叠体，也具有三维成型性，导致成型过程中产品的形状变异性低，成型工艺成品率优异。层压体包括结晶热为10J / g以上的热塑性树脂片层和包含聚苯硫醚纤维的湿式非织造层，结晶热为10J / g以上，湿法成网非织造层层叠在热塑性树脂片层的至少一个表面上而无粘合剂。

5. 发明申请

US20150013296A1 POLYPHENYLENE SULFIDE FIBER, FILTER CLOTH COMPRISING POLYPHENYLENE SULFIDE FIBER, AND METHOD FOR PRODUCING POLYPHENYLENE SULFIDE FIBER 有权
标题翻译：聚苯乙烯纤维，包含聚苯乙烯纤维的过滤布及其制备聚苯乙烯纤维的方法
公开(公告)号：US20150013296A1
公开(公告)日：2015-01-15
申请号：US14378542
申请日：2013-02-19
申请人： Toray Industries, Inc.
发明人： Takeshi Sugimoto , Keiji Kaiho , Koichiro Maeda
IPC分类号： D01F6/76 , B29C47/00 , B01D39/08
CPC分类号： D01F6/765 , B01D39/083 , B01D2239/0618 , B29C47/0014 , D01D5/12 , D04H1/4326 , D04H1/46 , D04H1/492
摘要： The present invention provides: a polyphenylene sulfide fiber that has excellent tensile strength; and a polyphenylene sulfide fiber that decreases in toughness to a small extent even when subjected to a long-term heat treatment and has excellent tensile strength. The polyphenylene sulfide fiber according to the present invention is characterized by comprising a polyphenylene sulfide resin having a weight average molecular weight of 50000 to 80000 inclusive, having a rigid amorphous content of 50% or more, and having a crystal size of 5 nm or more in the direction of a (111) crystal plane.
摘要翻译：本发明提供：抗拉强度优异的聚苯硫醚纤维; 以及即使进行长期热处理也能够在较小程度上降低韧性且拉伸强度优异的聚苯硫醚纤维。本发明的聚苯硫醚纤维的特征在于，包含重均分子量为50000〜80000的聚苯硫醚树脂，其硬度为50％以上，无定形含量为5nm以上。沿（111）晶面的方向。

6. 发明申请

US20100151246A1 POLYPHENYLENE SULFIDE SPUNBOND FIBER 有权
标题翻译：聚苯乙烯磺化纤维
公开(公告)号：US20100151246A1
公开(公告)日：2010-06-17
申请号：US12335899
申请日：2008-12-16
申请人： Paul Ellis Rollin, JR.
发明人： Paul Ellis Rollin, JR.
IPC分类号： D02G3/02 , C08G75/04
CPC分类号： D04H3/16 , C08G75/0204 , C08L81/02 , D01D5/0985 , D01F6/765 , Y10T428/2929 , Y10T428/2931 , Y10T428/2973 , Y10T428/298 , C08L81/00
摘要： The present invention is directed to a spunbond fiber comprising polyphenylene sulfide polymer having a zero shear viscosity at 300° C. of about 21,500 to about 28,000 Pa·s.
摘要翻译：本发明涉及一种纺粘纤维，其包含在300℃下零剪切粘度为约21,500至约28,000Pa·s的聚苯硫醚聚合物。

7. 发明授权

US5372760A Process for producing polyarylene sulfide fiber and thereby obtainable polyarylene sulfide multifilament yarn 失效
标题翻译：制备聚芳硫醚纤维的方法，从而得到聚芳硫醚复丝纱线
公开(公告)号：US5372760A
公开(公告)日：1994-12-13
申请号：US79987
申请日：1993-06-18
申请人： Herbert Wellenhofer , Werner Bruckner , Andreas Fischer , Gerhard Leumer
发明人： Herbert Wellenhofer , Werner Bruckner , Andreas Fischer , Gerhard Leumer
IPC分类号： D01D5/092 , D01F6/76 , D02J1/22 , B29C35/10 , D01D5/12
CPC分类号： D01F6/765
摘要： A process for producing fiber from polyarylene sulfide, by melt spinning a polyarylene sulfide into a gas, cooling the spun filaments with a blown gas, taking the filaments off at a high speed, storing the spun filaments, drawing the spun filaments in two stages and after treatment stage, and immediately thereafter heat setting the drawn filaments. Fibers produced by the invention have excellent mechanical properties including tensile strength and transverse strength, and the process is very efficient.
摘要翻译：一种由聚芳硫醚制造纤维的方法，通过将聚芳硫醚熔融纺丝成气体，用吹入气体冷却纺丝丝，高速脱丝，储存纺丝丝，拉伸纺丝丝两个阶段，在处理阶段之后，并立即热定型拉伸的长丝。本发明生产的纤维具有优异的机械性能，包括拉伸强度和横向强度，并且该方法非常有效。

8. 发明授权

US5043112A Process for forming articles comprising poly(phenylene sulfide) (PPS) 失效
标题翻译：用于形成包含聚（苯硫醚）（PPS）的制品的方法
公开(公告)号：US5043112A
公开(公告)日：1991-08-27
申请号：US329666
申请日：1989-03-28
申请人： Henry N. Beck
发明人： Henry N. Beck
IPC分类号： B01D53/22 , B01D67/00 , B01D71/66 , C08J3/09 , C08J9/28 , D01F6/76
CPC分类号： D01F6/765 , B01D53/228 , B01D67/0011 , B01D67/003 , B01D71/66 , C08J3/091 , C08J9/28 , B01D2325/32 , C08J2381/02
摘要： The present invention pertains to a process for the production of an article comprising a polymer itself comprising poly(phenylene sulfide), which process comprises:A. contacting poly(phenylene sulfide) with at least one organic compound, consisting essentially of carbon and hydrogen, and optionally oxygen, nitrogen, sulfur, halogen, or mixtures thereof, having a molecular weight of between about 110 and 450 daltons and having at least one six membered aromatic ring structure, which compound is stable at a temperature of between 160.degree. and 400.degree. C. at ambient pressure, at a temperature of between about 160.degree. and 400.degree. C. at ambient pressure for a time effective to dissolve greater than 10 percent by weight of the poly(phenylene sulfide) present, with the proviso that when oxygen is present, the organic compound is not diphenyl oxide or substituted diphenyl oxide;B. forming the solution of poly(phenylene sulfide) and solvent of Step (A) into a desired article configuration;C. removing the solvent; andD. recovering the article comprising poly(phenylene sulfide) formed thereby. The article is particularly useful when it is in the shape of a thin membrane, hollow fiber or solid fiber and is porous, permeable, semi-permeable or selectively permeable.
摘要翻译：本发明涉及制备包含聚苯醚的聚合物本身的制品的方法，该方法包括：A.将聚（苯硫醚）与至少一种基本由碳和氢组成的有机化合物接触，和任选的氧，氮，硫，卤素或其混合物，其分子量为约110至450道尔顿且具有至少一个六元芳环结构，该化合物在160至400℃的温度下是稳定的在环境压力下，在环境压力下在约160℃至400℃之间的温度下，在存在的聚苯硫醚的存在时间内有效溶解大于10重量％的时间，条件是当氧为存在，有机化合物不是二苯基氧化物或取代的二苯基氧化物; B.将步骤（A）的聚（苯硫醚）溶液和溶剂形成所需的制品构型; C.除去溶剂; 和D.回收包含由其形成的聚（苯硫醚）的制品。当其为薄膜，中空纤维或固体纤维的形状并且是多孔的，可渗透的，半渗透的或选择性渗透的时，该制品是特别有用的。

9. 发明授权

US4816335A High-quality polyarylene-thioether fibers and method for production thereof 失效
标题翻译：高品质聚亚芳基 - 硫醚纤维及其制备方法
公开(公告)号：US4816335A
公开(公告)日：1989-03-28
申请号：US842842
申请日：1986-03-24
申请人： Toshitaka Kouyama , Harunobu Egawa , Yo Iizuka , Zenya Shiiki
发明人： Toshitaka Kouyama , Harunobu Egawa , Yo Iizuka , Zenya Shiiki
IPC分类号： D01D5/12 , D01F6/76 , D02G3/00
CPC分类号： D01F6/765 , Y10T428/2913
摘要： High-quality polyarylene-thioether fibers are provided, which simultaneously satisfy the following conditions:(a) the polyarylene-thioether is a linear polyarylene-thioether having a melt viscosity of 5,300 to 20,000 poise (at 310.degree. C. and a shear velocity of 200 second.sup.-1);(b) the fiber diameter is in the range of 1 to 50 microns;(c) the tensile strength is not less than 40 kg/sq.mm;(d) the tensile modulus of elasticity is not less than 500 kg/sq.mm; and(e) the tensile strength at 200.degree. C. is not less than 20 kg/sq.mm.The fibers are produced by continuously melt-spinning a linear polyarylene-thioether polymer having a melt viscosity of 5,300 to 20,000 poise (at 310.degree. C. and a shear velocity of 200 second.sup.-1), continuously stretching the spun filament, and continuously heat-setting the stretched filament for 0.02 to 100 seconds at a temperature of not lower than the melting point of the polymer minus 100.degree. C.
摘要翻译：提供了高质量的聚亚芳基 - 硫醚纤维，其同时满足以下条件：（a）聚亚芳基 - 硫醚是熔体粘度为5300至20,000泊（线性聚亚芳基 - 硫醚）（在310℃，剪切速度为 200秒-1）; （b）纤维直径在1至50微米的范围内; （c）拉伸强度不小于40kg / sq.mm; （d）拉伸弹性模量不小于500kg / sq.mm; 和（e）200℃下的拉伸强度不小于20kg / sq.mm。纤维通过连续熔融纺丝熔融粘度为5300至20,000泊（在310℃和剪切速度为200秒-1）的线性聚亚芳基 - 硫醚聚合物，连续地拉伸纺丝丝，并连续加热在不低于聚合物的熔点-100℃的温度下将拉伸的长丝固定0.02至100秒。

10. 发明授权

US3539676A Process for producing filaments and films of polymers of alkylene sulfides 失效
标题翻译：生产烯烃硫化物聚合物的膜和膜的方法
公开(公告)号：US3539676A
公开(公告)日：1970-11-10
申请号：US3539676D
申请日：1966-08-29
申请人： CELANESE CORP
发明人： POLESTAK WALTER J
IPC分类号： C08G75/08 , D01D5/24 , D01F6/76 , B28B3/20 , D01D5/22 , D01F3/10
CPC分类号： D01F6/765 , C08G75/08 , D01D5/12 , D01D5/247

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